CN107353989A - A kind of environment-friendly type water base cutting fluid and preparation method thereof - Google Patents

A kind of environment-friendly type water base cutting fluid and preparation method thereof Download PDF

Info

Publication number
CN107353989A
CN107353989A CN201710424685.6A CN201710424685A CN107353989A CN 107353989 A CN107353989 A CN 107353989A CN 201710424685 A CN201710424685 A CN 201710424685A CN 107353989 A CN107353989 A CN 107353989A
Authority
CN
China
Prior art keywords
environment
cutting fluid
type water
friendly type
base cutting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710424685.6A
Other languages
Chinese (zh)
Inventor
王海霞
宋昊
李雪晴
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Changzhou Jie Xuan Textile Technology Co Ltd
Original Assignee
Changzhou Jie Xuan Textile Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Changzhou Jie Xuan Textile Technology Co Ltd filed Critical Changzhou Jie Xuan Textile Technology Co Ltd
Priority to CN201710424685.6A priority Critical patent/CN107353989A/en
Publication of CN107353989A publication Critical patent/CN107353989A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00—Lubricating compositions containing more than 10% water
    • C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M177/00—Special methods of preparation of lubricating compositions; Chemical modification by after-treatment of components or of the whole of a lubricating composition, not covered by other classes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06—Metal compounds
    • C10M2201/062—Oxides; Hydroxides; Carbonates or bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/06—Organic compounds derived from inorganic acids or metal salts
    • C10M2227/061—Esters derived from boron
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04—Siloxanes with specific structure
    • C10M2229/041—Siloxanes with specific structure containing aliphatic substituents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/16—Antiseptic; (micro) biocidal or bactericidal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Cosmetics (AREA)

Abstract

The invention discloses a kind of environment-friendly type water base cutting fluid and preparation method thereof, belong to Machining Technology for Cutting field.The present invention is used as adhesive using sodium metasilicate, reacted by acid in triethanolamine and linseed oil, introduce triethanolamine, again with butanediol, boric acid mixes, catalyst is used as using titanium dioxide, in the presence of ultraviolet, form triethanolamine borate class material, combined simultaneously with linseed oil, improve anti-microbial property, finally and deionized water, chitosan etc. adds dimethicone after mixing, environment-friendly type water base cutting fluid can be obtained after scattered, environment-friendly type water base cutting fluid prepared by the present invention is not easy breed bacteria, generation corruption, with good lubricity and rust-proof effect, the water-base cutting fluid that uses at present is efficiently solved on ecological environment and the influential defect of user's health.

Description

A kind of environment-friendly type water base cutting fluid and preparation method thereof
Technical field
The invention discloses a kind of environment-friendly type water base cutting fluid and preparation method thereof, belong to Machining Technology for Cutting field.
Background technology
Cutting fluid is widely used in metal cutting process, and it act as the cooling of metal parts, lubrication, cleaning, anti- Rust etc..At present, the cutting fluid of machinery industry is oil base emulsion, belongs to mixed aqueous solution, is more or less contained in its composition There is natrium nitrosum, there is certain toxic side effect to user, easily occur to go bad during use, smell is serious, pollutes environment.With The continuous progressive and development of mechanical industry, the cutting speed of metal cutting equipment improves constantly, and mechanical development is simultaneously to machine The indexs such as the precision of tool part, performance propose higher requirement, to the dimensional accuracy of final parts, surface roughness, subtract Mill abrasion resistance and surface diamagnetism etc. it is also proposed higher requirement.
Cutting fluid can be divided into two classes, oil-soluble cutting fluid and water-soluble metalworking liquid at present.General oil-soluble cutting fluid lubrication Performance is good, but poor cooling performance, and contains large amount of organic, pollutes environment.Although some water-soluble metalworking liquid cooling performances are good, But easy breed bacteria, corruption occurs, lubricity is poor with rust-proof effect, and the usage time life-span is not grown, in order to improve cutting fluid Anti-microbial property, usually add bactericide, still, cutting fluid containing bactericide influences ecological environment and the body of end user Body health, and the follow-up feature of environmental protection processing of waste liquid can also trigger a series of processing cost problem.Therefore a kind of lubricity is researched and developed Excellent, antibacterial, mildew resistance are good, and the preferable Environmental Protection Cutting Fluid of cooling effect, are the emphasis studied in the industry at present.
The content of the invention
The technical problems to be solved by the invention：For the easy breed bacteria of water-base cutting fluid used at present, corruption occurs, Poor lubricity, and bactericide is added on the influential defect of the health of ecological environment and user, there is provided a kind of environmental protection Type water-base cutting fluid and preparation method thereof.
In order to solve the above technical problems, the present invention is using technical scheme as described below：
The environment-friendly type water base cutting fluid of the present invention, is made up of the raw material of following parts by weight, and 200~230 parts of deionized waters, 110~ 140 parts of environment-friendly type water base cutting fluid base fluids, 20~23 parts of chitosans, 10~15 parts of dodecyl sodium sulfates and 10~16 parts of diformazans Base silicone oil.
The preparation of the environment-friendly type water base cutting fluid base fluid, comprises the following steps：
（1）Sodium metasilicate and linseed oil are put into container, stirred at 70~75 DEG C, using nitrogen by the gas in container Discharge, then triethanolamine is added dropwise in container, and rise temperature is to 85~90 DEG C, 2~3h of stirring reaction；
（2）Question response is cooled to room temperature after terminating, the reaction-ure mixture in collection vessel, takes 90~130 parts of reactants mixing Thing, 60~65 parts of butanediols and 46~57 parts of boric acid, it is well mixed, is put into reflux, is returned at 110~115 DEG C Stream；
（3）After backflow terminates, titanium dioxide is added into reflux, raises temperature to 123~129 DEG C, insulation 50~ 70min, the material in reflux is put into distilling apparatus, is cooled to 104~108 DEG C, is distilled；
（4）Room temperature is cooled to after distillation terminates, distillation residue is collected, is placed in ultraviolet lamp, it is purple at 32~36 DEG C Outside line is irradiated, and is refiltered, and is collected filtered fluid, is obtained environment-friendly type water base cutting fluid base fluid.
The step（1）The mass ratio of sodium metasilicate, linseed oil and triethanolamine is 1.0~1.5:9~12:29~32.
The step（2）Middle return time is 1~2h.
The step（3）The addition of middle titanium dioxide is the 10~15% of sodium metasilicate quality.
The preparation method of environment-friendly type water base cutting fluid of the present invention, comprises the following steps：
（1）Raw material is taken in parts by weight；
（2）Deionized water, environment-friendly type water base cutting fluid base fluid, chitosan, dodecyl sodium sulfate are put into mixer, with 300r/min stirs 30~35min, collects stirring mixture；
（3）Stirring mixture is put into dispersion machine with dimethicone, under 50~55 DEG C of environment, disperses 1~2h, collects and divide Dissipate thing, you can obtain environment-friendly type water base cutting fluid.
Compared with other method, advantageous effects are the present invention：
（1）The present invention is reacted by acid in triethanolamine and linseed oil using sodium metasilicate as adhesive, is introduced three ethanol Amine, then mixed with butanediol, boric acid, using titanium dioxide as catalyst, in the presence of ultraviolet, form triethanolamine boric acid Ester, while combined with linseed oil, anti-microbial property is improved, then add chitosan and further improve anti-microbial property, make simultaneously Increase lubrication and rust-proof effect with dimethicone；
（2）Environment-friendly type water base cutting fluid prepared by the present invention is not easy breed bacteria, and corruption occurs, and has good lubricity with preventing Become rusty effect, efficiently solve the water-base cutting fluid that uses at present to ecological environment and the influential defect of user's health；
（3）Environment-friendly type water base cutting fluid prepared by the present invention is prepared simply, and required cost is low, easy to use, has wide answer Use prospect.
Embodiment
The preparation of environment-friendly type water base cutting fluid base fluid, comprises the following steps：
（1）Sodium metasilicate and linseed oil are put into container, 15~20min is stirred with 150r/min at 70~75 DEG C, use nitrogen Gas in container is discharged, then triethanolamine is added dropwise in container with per minute 40 by gas, raises temperature to 85~90 DEG C, 2~3h of stirring reaction；The mass ratio of the sodium metasilicate, linseed oil and triethanolamine is 1.0~1.5:9~12:29~32；
（2）Question response is cooled to room temperature after terminating, the reaction-ure mixture in collection vessel, takes 90~130 parts of reactants mixing Thing, 60~65 parts of butanediols and 46~57 parts of boric acid, it is well mixed, is put into reflux, is protected using nitrogen, 110~ 1~2h of backflow is carried out at 115 DEG C；
（3）After backflow terminates, titanium dioxide is added into reflux, raises temperature to 123~129 DEG C, insulation 50~ 70min, the material in reflux is put into distilling apparatus, is cooled to 104~108 DEG C, carry out 1~2h of distillation；Described two The addition of titanium oxide is the 10~15% of sodium metasilicate quality；
（4）Room temperature is cooled to after distillation terminates, distillation residue is collected, is placed in ultraviolet lamp, at 32~36 DEG C, makes Irradiated, refiltered with the ultraviolet that wavelength is 80~100nm, collected filtered fluid, obtain environment-friendly type water base cutting fluid base fluid.
The environment-friendly type water base cutting fluid of the present invention, is made up of the raw material of following parts by weight, 200~230 parts of deionized waters, 110~140 parts of environment-friendly type water base cutting fluid base fluids, 20~23 parts of chitosans, 10~15 parts of dodecyl sodium sulfates and 10~16 Part dimethicone.
The preparation method of environment-friendly type water base cutting fluid of the present invention, comprises the following steps：
（1）Raw material is taken in parts by weight；
（2）Deionized water, environment-friendly type water base cutting fluid base fluid, chitosan, dodecyl sodium sulfate are put into mixer, with 300r/min stirs 30~35min, collects stirring mixture；
（3）Stirring mixture is put into dispersion machine with dimethicone, under 50~55 DEG C of environment, disperses 1~2h, collects and divide Dissipate thing, you can obtain environment-friendly type water base cutting fluid.
Example 1
The preparation of environment-friendly type water base cutting fluid base fluid, comprises the following steps：
（1）Sodium metasilicate and linseed oil are put into container, 15min is stirred with 150r/min at 70 DEG C, using nitrogen by container In gas discharge, then triethanolamine is added dropwise in container with per minute 40, raises temperature to 85 DEG C, stirring reaction 2h； The mass ratio of the sodium metasilicate, linseed oil and triethanolamine is 1.0:9:29；
（2）Question response is cooled to room temperature after terminating, the reaction-ure mixture in collection vessel, take 90 parts of reaction-ure mixtures, 60 Part butanediol and 46 parts of boric acid, it is well mixed, is put into reflux, is protected using nitrogen, backflow 1h is carried out at 110 DEG C；
（3）After backflow terminates, titanium dioxide is added into reflux, rise temperature is incubated 50min, will flowed back to 123 DEG C Material in device is put into distilling apparatus, is cooled to 104 DEG C, carries out distillation 1h；The addition of the titanium dioxide is silicic acid The 10% of sodium quality；
（4）Room temperature is cooled to after distillation terminates, distillation residue is collected, is placed in ultraviolet lamp, at 32 DEG C, uses ripple A length of 80nm ultraviolet irradiation, refilters, collects filtered fluid, obtain environment-friendly type water base cutting fluid base fluid.
The environment-friendly type water base cutting fluid of the present invention, is made up of, 200 parts of deionized waters, 110 parts of rings the raw material of following parts by weight Guarantor's type water-base cutting fluid base fluid, 20 parts of chitosans, 10 parts of dodecyl sodium sulfates and 10 parts of dimethicones.
The preparation method of environment-friendly type water base cutting fluid of the present invention, comprises the following steps：
（1）Raw material is taken in parts by weight；
（2）Deionized water, environment-friendly type water base cutting fluid base fluid, chitosan, dodecyl sodium sulfate are put into mixer, with 300r/min stirs 30min, collects stirring mixture；
（3）Stirring mixture is put into dispersion machine with dimethicone, under 50 DEG C of environment, disperses 1h, collects dispersion, i.e., Environment-friendly type water base cutting fluid can be obtained.
Example 2
The preparation of environment-friendly type water base cutting fluid base fluid, comprises the following steps：
（1）Sodium metasilicate and linseed oil are put into container, 18min is stirred with 150r/min at 73 DEG C, using nitrogen by container In gas discharge, then triethanolamine is added dropwise in container with per minute 40, raises temperature to 88 DEG C, stirring reaction 2h； The mass ratio of the sodium metasilicate, linseed oil and triethanolamine is 1.3:10:30；
（2）Question response is cooled to room temperature after terminating, the reaction-ure mixture in collection vessel, take 110 parts of reaction-ure mixtures, 63 Part butanediol and 51 parts of boric acid, it is well mixed, is put into reflux, is protected using nitrogen, backflow 1h is carried out at 113 DEG C；
（3）After backflow terminates, titanium dioxide is added into reflux, rise temperature is incubated 60min, will flowed back to 126 DEG C Material in device is put into distilling apparatus, is cooled to 106 DEG C, carries out distillation 1h；The addition of the titanium dioxide is silicic acid The 13% of sodium quality；
（4）Room temperature is cooled to after distillation terminates, distillation residue is collected, is placed in ultraviolet lamp, at 34 DEG C, uses ripple A length of 90nm ultraviolet irradiation, refilters, collects filtered fluid, obtain environment-friendly type water base cutting fluid base fluid.
The environment-friendly type water base cutting fluid of the present invention, is made up of, 215 parts of deionized waters, 125 parts of rings the raw material of following parts by weight Guarantor's type water-base cutting fluid base fluid, 21 parts of chitosans, 13 parts of dodecyl sodium sulfates and 13 parts of dimethicones.
The preparation method of environment-friendly type water base cutting fluid of the present invention, comprises the following steps：
（1）Raw material is taken in parts by weight；
（2）Deionized water, environment-friendly type water base cutting fluid base fluid, chitosan, dodecyl sodium sulfate are put into mixer, with 300r/min stirs 33min, collects stirring mixture；
（3）Stirring mixture is put into dispersion machine with dimethicone, under 53 DEG C of environment, disperses 1h, collects dispersion, i.e., Environment-friendly type water base cutting fluid can be obtained.
Example 3
The preparation of environment-friendly type water base cutting fluid base fluid, comprises the following steps：
（1）Sodium metasilicate and linseed oil are put into container, 20min is stirred with 150r/min at 75 DEG C, using nitrogen by container In gas discharge, then triethanolamine is added dropwise in container with per minute 40, raises temperature to 90 DEG C, stirring reaction 3h； The mass ratio of the sodium metasilicate, linseed oil and triethanolamine is 1.5:12:32；
（2）Question response is cooled to room temperature after terminating, the reaction-ure mixture in collection vessel, take 130 parts of reaction-ure mixtures, 65 Part butanediol and 57 parts of boric acid, it is well mixed, is put into reflux, is protected using nitrogen, backflow 2h is carried out at 115 DEG C；
（3）After backflow terminates, titanium dioxide is added into reflux, rise temperature is incubated 70min, will flowed back to 129 DEG C Material in device is put into distilling apparatus, is cooled to 108 DEG C, carries out distillation 2h；The addition of the titanium dioxide is silicic acid The 15% of sodium quality；
（4）Room temperature is cooled to after distillation terminates, distillation residue is collected, is placed in ultraviolet lamp, at 36 DEG C, uses ripple A length of 100nm ultraviolet irradiation, refilters, collects filtered fluid, obtain environment-friendly type water base cutting fluid base fluid.
The environment-friendly type water base cutting fluid of the present invention, is made up of, 230 parts of deionized waters, 140 parts of rings the raw material of following parts by weight Guarantor's type water-base cutting fluid base fluid, 23 parts of chitosans, 15 parts of dodecyl sodium sulfates and 16 parts of dimethicones.
The preparation method of environment-friendly type water base cutting fluid of the present invention, comprises the following steps：
（1）Raw material is taken in parts by weight；
（2）Deionized water, environment-friendly type water base cutting fluid base fluid, chitosan, dodecyl sodium sulfate are put into mixer, with 300r/min stirs 35min, collects stirring mixture；
（3）Stirring mixture is put into dispersion machine with dimethicone, under 55 DEG C of environment, disperses 2h, collects dispersion, i.e., Environment-friendly type water base cutting fluid can be obtained.
To environment-friendly type water base cutting fluid made from example 1~3 and commercially available Weir water-base cutting fluid（Comparative example）Carry out performance Detection, its testing result such as table 1 below：
Table 1
In summary, the environment-friendly type water base cutting fluid that prepared by the present invention is green, harmful without natrium nitrosum etc. Material, while cutting fluid lubrication excellent performance, antibacterial and mouldproof are worked well, and machinery, part will not be caused damage after use, energy Effectively meet metallic element fine design demand.

Claims (6)

  1. A kind of 1. environment-friendly type water base cutting fluid, it is characterised in that：It is made up of the raw material of following parts by weight, 200~230 parts of deionizations Water, 110~140 parts of environment-friendly type water base cutting fluid base fluids, 20~23 parts of chitosans, 10~15 parts of dodecyl sodium sulfates and 10~ 16 parts of dimethicones.
  2. A kind of 2. environment-friendly type water base cutting fluid according to claim 1, it is characterised in that：The environment-friendly type water base cutting fluid The preparation of base fluid, comprises the following steps：
    （1）Sodium metasilicate and linseed oil are put into container, stirred at 70~75 DEG C, using nitrogen by the gas in container Discharge, then triethanolamine is added dropwise in container, and rise temperature is to 85~90 DEG C, 2~3h of stirring reaction；
    （2）Question response is cooled to room temperature after terminating, the reaction-ure mixture in collection vessel, takes 90~130 parts of reactants mixing Thing, 60~65 parts of butanediols and 46~57 parts of boric acid, it is well mixed, is put into reflux, is returned at 110~115 DEG C Stream；
    （3）After backflow terminates, titanium dioxide is added into reflux, raises temperature to 123~129 DEG C, insulation 50~ 70min, the material in reflux is put into distilling apparatus, is cooled to 104~108 DEG C, is distilled；
    （4）Room temperature is cooled to after distillation terminates, distillation residue is collected, is placed in ultraviolet lamp, it is purple at 32~36 DEG C Outside line is irradiated, and is refiltered, and is collected filtered fluid, is obtained environment-friendly type water base cutting fluid base fluid.
  3. A kind of 3. environment-friendly type water base cutting fluid according to claim 2, it is characterised in that：The step（1）Sodium metasilicate, Asia The mass ratio of sesame oil and triethanolamine is 1.0~1.5:9~12:29~32.
  4. A kind of 4. environment-friendly type water base cutting fluid according to claim 2, it is characterised in that：The step（2）During middle backflow Between be 1~2h.
  5. A kind of 5. environment-friendly type water base cutting fluid according to claim 2, it is characterised in that：The step（3）Middle titanium dioxide The addition of titanium is the 10~15% of sodium metasilicate quality.
  6. A kind of 6. preparation method of environment-friendly type water base cutting fluid as claimed in claim 1 or 2, it is characterised in that：Including as follows Step：
    （1）Raw material is taken in parts by weight；
    （2）Deionized water, environment-friendly type water base cutting fluid base fluid, chitosan, dodecyl sodium sulfate are put into mixer, with 300r/min stirs 30~35min, collects stirring mixture；
    （3）Stirring mixture is put into dispersion machine with dimethicone, under 50~55 DEG C of environment, disperses 1~2h, collects and divide Dissipate thing, you can obtain environment-friendly type water base cutting fluid.
CN201710424685.6A 2017-06-07 2017-06-07 A kind of environment-friendly type water base cutting fluid and preparation method thereof Pending CN107353989A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710424685.6A CN107353989A (en) 2017-06-07 2017-06-07 A kind of environment-friendly type water base cutting fluid and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710424685.6A CN107353989A (en) 2017-06-07 2017-06-07 A kind of environment-friendly type water base cutting fluid and preparation method thereof

Publications (1)

Publication Number Publication Date
CN107353989A true CN107353989A (en) 2017-11-17

Family

ID=60272340

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710424685.6A Pending CN107353989A (en) 2017-06-07 2017-06-07 A kind of environment-friendly type water base cutting fluid and preparation method thereof

Country Status (1)

Country Link
CN (1) CN107353989A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115161102A (en) * 2022-02-22 2022-10-11 江苏中晟高科环境股份有限公司 Environment-friendly fully-synthetic cutting fluid without ethanolamine

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4430234A (en) * 1981-07-10 1984-02-07 Nissan Motor Co., Ltd. Machining fluid of water soluble type using organic surfactants
CN103865623A (en) * 2014-03-20 2014-06-18 陕西省石油化工研究设计院 Multifunctional non-toxic water-based rust-proof cutting fluid
CN106350182A (en) * 2016-08-30 2017-01-25 天长市润达金属防锈助剂有限公司 Extreme pressure and anti-wear micro-emulsion cutting fluid and preparing method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4430234A (en) * 1981-07-10 1984-02-07 Nissan Motor Co., Ltd. Machining fluid of water soluble type using organic surfactants
CN103865623A (en) * 2014-03-20 2014-06-18 陕西省石油化工研究设计院 Multifunctional non-toxic water-based rust-proof cutting fluid
CN106350182A (en) * 2016-08-30 2017-01-25 天长市润达金属防锈助剂有限公司 Extreme pressure and anti-wear micro-emulsion cutting fluid and preparing method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
刘建芳等: "环境友好型水基润滑剂的摩擦学性能研究", 《武汉工业学院学报》 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115161102A (en) * 2022-02-22 2022-10-11 江苏中晟高科环境股份有限公司 Environment-friendly fully-synthetic cutting fluid without ethanolamine

Similar Documents

Publication Publication Date Title
CN102634407B (en) Novel total-synthesis water-soluble magnesium alloy cutting solution and preparation method thereof
CN104120015B (en) Cutting fluid that a kind of antirust, anti-corrosive lubricity cooling is good and preparation method thereof
CN106590906A (en) Graphene oxide-containing water-based metal cutting fluid and preparation method thereof
CN102628000A (en) Novel totally-synthetic processing fluid for wire-cutting metal by electric sparks
CN104560346A (en) Total-synthesis water-soluble cutting fluid
CN103113970A (en) Water-soluble quasi-dry cutting liquid as well as preparation method and use thereof
CN104327929A (en) High-abrasion resistance water-based cutting fluid and preparation method thereof
CN107353989A (en) A kind of environment-friendly type water base cutting fluid and preparation method thereof
CN103725400B (en) A kind of water base environmental protection cutting fluid and preparation method thereof
CN109797034A (en) A kind of pure magnesium working fluid of environment-friendly type and preparation method thereof
CN107325877A (en) A kind of water-soluble fully synthetic hard alloy cuts grinding fluid
CN104830492B (en) Cutting fluid
CN107353995A (en) A kind of environment-friendly type fully synthetic cutting fluid and preparation method thereof
CN107604366A (en) A kind of steel surface environmental-protecting chemical polishing fluid
CN104560352A (en) Water-based cutting fluid with remarkable rust prevention effect and good dispersity and preparation method of water-based cutting fluid
CN104120017B (en) Water-base cutting fluid of the strong good antirust property of a kind of penetration and preparation method thereof
CN104911015A (en) Honing solution and preparation method thereof
CN107815675A (en) A kind of Chrome-free oxidation solution
CN104263486A (en) Water-based metal wire drawing liquid with good lubricating effect and preparation method thereof
CN104312710A (en) Fully synthesized magnesium alloy cutting fluid and preparation method thereof
CN102703188A (en) Environment-friendly microemulsion cutting fluid without corrosion to machine tools
CN107236593A (en) A kind of machine tooling environmental-friendly plant oil base emulsion cutting fluid
CN109913302A (en) Lubricant compositions and preparation method thereof and the combination prepare micro lubricating agent
CN106010742A (en) Rust-proof cutting fluid for numerically-controlled machine tool metal processing and preparation method thereof
CN109054977A (en) Graphene cutting fluid and preparation method thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20171117