CN103725400B - A kind of water base environmental protection cutting fluid and preparation method thereof - Google Patents
A kind of water base environmental protection cutting fluid and preparation method thereof Download PDFInfo
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- CN103725400B CN103725400B CN201310653358.XA CN201310653358A CN103725400B CN 103725400 B CN103725400 B CN 103725400B CN 201310653358 A CN201310653358 A CN 201310653358A CN 103725400 B CN103725400 B CN 103725400B
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- Prior art keywords
- water
- cutting fluid
- polyethylene glycol
- auxiliary agent
- environmental protection
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- 239000002173 cutting fluid Substances 0.000 title claims abstract description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 21
- 230000007613 environmental effect Effects 0.000 title claims abstract description 14
- 238000002360 preparation method Methods 0.000 title claims description 9
- -1 ethoxylated dodecyl alcohol sodium sulphate Chemical class 0.000 claims abstract description 11
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 10
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 8
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 claims abstract description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims abstract description 7
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 6
- 229940008099 dimethicone Drugs 0.000 claims abstract description 6
- 239000004205 dimethyl polysiloxane Substances 0.000 claims abstract description 6
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims abstract description 6
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims abstract description 6
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 6
- 239000002994 raw material Substances 0.000 claims abstract description 6
- 229910052938 sodium sulfate Inorganic materials 0.000 claims abstract description 6
- PMZURENOXWZQFD-UHFFFAOYSA-L sodium sulphate Substances [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims abstract description 6
- 235000011152 sodium sulphate Nutrition 0.000 claims abstract description 6
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 claims abstract description 4
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 claims abstract description 4
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 4
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 claims abstract description 4
- 229940113115 polyethylene glycol 200 Drugs 0.000 claims abstract description 4
- 239000011787 zinc oxide Substances 0.000 claims abstract description 4
- 229920000604 Polyethylene Glycol 200 Polymers 0.000 claims abstract description 3
- 238000003756 stirring Methods 0.000 claims description 12
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 8
- 239000012467 final product Substances 0.000 claims description 5
- 239000004698 Polyethylene Substances 0.000 claims description 4
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 4
- 229920000573 polyethylene Polymers 0.000 claims description 4
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 claims description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 2
- 235000006040 Prunus persica var persica Nutrition 0.000 claims description 2
- 240000006413 Prunus persica var. persica Species 0.000 claims description 2
- 239000004115 Sodium Silicate Substances 0.000 claims description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 2
- 239000004202 carbamide Substances 0.000 claims description 2
- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical compound Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 claims description 2
- 239000000463 material Substances 0.000 claims description 2
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims description 2
- 235000019795 sodium metasilicate Nutrition 0.000 claims description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 2
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 2
- 238000001816 cooling Methods 0.000 abstract description 6
- 238000004140 cleaning Methods 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 3
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 abstract description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract description 2
- 231100000481 chemical toxicant Toxicity 0.000 abstract description 2
- 238000005260 corrosion Methods 0.000 abstract description 2
- 230000007797 corrosion Effects 0.000 abstract description 2
- 239000006260 foam Substances 0.000 abstract description 2
- 230000005764 inhibitory process Effects 0.000 abstract description 2
- 239000003440 toxic substance Substances 0.000 abstract description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000005555 metalworking Methods 0.000 description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical class CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000009972 noncorrosive effect Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 235000020354 squash Nutrition 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
Landscapes
- Lubricants (AREA)
Abstract
Does is a kind of water base environmental protection cutting fluid, made up of the raw material of following weight portion: polyethylene glycol 12-14, dimethicone 5-7, disodium ethylene diamine tetraacetate 2-3, triethanolamine 1-2, zinc oxide 1-2, zinc nitrate 1-2, paraphthaloyl chloride 2-3, polyethylene glycol-200? 8-10, ethoxylated dodecyl alcohol sodium sulphate 2-3, auxiliary agent 6-8, water 200; Cutting fluid of the present invention is lubricity, cooling and cleaning excellence not only, and there is corrosion inhibition, do not corrode workpiece, add non-foam in man-hour, improve workpiece surface finish and reduce tool wear effect remarkable, containing the toxic chemical such as nitrite, organic phenol that human body or environment are had a negative impact, little to environmental hazard.
Description
Technical field
The present invention relates to cutting fluid field, relate in particular to a kind of water base environmental protection cutting fluid and preparation method thereof.
Background technology
Cutting fluid should possess good cooling performance, greasy property, rustless property, oil removing cleaning function, anticorrosionFunction, easily dilutable feature. Cutting fluid can be divided into two classes, oil-soluble cutting fluid and water-soluble metalworking liquid at present. OneAs oil-soluble cutting fluid lubrication performance good, but poor cooling performance, and contain large amount of organic, contaminated environment. OneAlthough a little water-soluble metalworking liquid cooling performances are good, have again the poor problem of lubricity and rust-proof effect, therefore research and developmentHave lubricity, cooling, rust-preventing characteristic, easy cleaning, nontoxic, tasteless, non-corrosive to human body, to equipment not concurrentlyBurn into just seems very important to the non-staining cutting fluid of environment.
Summary of the invention
The object of the present invention is to provide a kind of water base environmental protection cutting fluid and preparation method thereof, this cutting fluid lubricationGood, good antirust property, good, the environment protection health of resistance to extreme pressure energy.
Technical scheme of the present invention is as follows:
A kind of water base environmental protection cutting fluid, is characterized in that being made up of the raw material of following weight portion: polyethylene glycol12-14, dimethicone 5-7, disodium ethylene diamine tetraacetate 2-3, triethanolamine 1-2, zinc oxide 1-2,Zinc nitrate 1-2, paraphthaloyl chloride 2-3, polyethylene glycol-2008-10, ethoxylated dodecyl alcohol sodium sulphate2-3, auxiliary agent 6-8, water 200;
The preparation method of described water base environmental protection cutting fluid, is characterized in that comprising the following steps: by water, diformazanBase silicone oil, ethoxylated dodecyl alcohol sodium sulphate mix, and are heated to 40-50 DEG C; Add, polyethylene glycol, rightPhthalyl chloride, polyethylene glycol-200, auxiliary agent continue to be heated under 1000-1200 rev/min of stirring70-80 DEG C, stirs 10-15 minute; Add other residual components, continue to stir 14-18 minute, to obtain final product.
Beneficial effect of the present invention
Cutting fluid of the present invention is lubricity, cooling and cleaning excellence not only, and has corrosion inhibition, noCorrosion workpiece, adds non-foam in man-hour, improves workpiece surface finish remarkable with minimizing tool wear effect, does not containThe toxic chemical such as nitrite, organic phenol that human body or environment are had a negative impact is little to environmental hazard.
Detailed description of the invention
A kind of water base environmental protection cutting fluid, by following weight portion (kilogram) raw material make: polyethylene glycol 13,Dimethicone 6, disodium ethylene diamine tetraacetate 2.5, triethanolamine 1.5, zinc oxide 1.5, zinc nitrate 1.5,Paraphthaloyl chloride 2.5, polyethylene glycol-2009, ethoxylated dodecyl alcohol sodium sulphate 2.5, auxiliary agent 7,Water 200; Described auxiliary agent by following weight portion (kilogram) raw material make: polyoxyethylene sorbitol acid anhydride listOleate 3, nano aluminum nitride 0.1, carbonic hydroammonium 3, monoethanolamine 1, CMC 2, diethylene glycolButyl ether 1, propane diols 8, peach gum 3, sodium metasilicate 1, urea 4, ammonium persulfate 2, water 20; Preparation method isAfter ammonium persulfate is water-soluble, then add other leftover materials, stir 10-15 minute, be heated to 70-80 DEG C,Stirring reaction 1-2 hour, to obtain final product.
The preparation method of described water base environmental protection cutting fluid, comprises the following steps: by water, dimethicone, bayAlcohol polyethenoxy ether sodium sulfate mixes, and is heated to 45 DEG C; Add, polyethylene glycol, paraphthaloyl chloride, poly-Ethylene glycol-200, auxiliary agent continue to be heated to 75 DEG C under 1100 revs/min of stirrings, stir 13 minutes; AddOther residual components, continue to stir 16 minutes, to obtain final product.
The water base environmental protection cutting fluid test data that this embodiment obtains is as follows:
Claims (2)
1. a water base environmental protection cutting fluid, is characterized in that being made up of the raw material of following weight portion: polyethylene glycol 12-14, dimethicone 5-7, disodium ethylene diamine tetraacetate 2-3, triethanolamine 1-2, zinc oxide 1-2, zinc nitrate 1-2, paraphthaloyl chloride 2-3, polyethylene glycol-2008-10, ethoxylated dodecyl alcohol sodium sulphate 2-3, auxiliary agent 6-8, water 200; Described auxiliary agent is made up of the raw material of following weight portion: Tween-81 2-3, nano aluminum nitride 0.1-0.2, carbonic hydroammonium 2-3, monoethanolamine 1-2, CMC 2-3, diethylene glycol butyl ether 1-2, propane diols 5-8, peach gum 2-3, sodium metasilicate 1-2, urea 3-4, ammonium persulfate 1-2, water 20-24; The preparation method of described auxiliary agent be ammonium persulfate is water-soluble after, then add other leftover materials, stir 10-15 minute, be heated to 70-80 DEG C, stirring reaction 1-2 hour, to obtain final product.
2. the preparation method of water base environmental protection cutting fluid according to claim 1, is characterized in that comprising the following steps: water, dimethicone, ethoxylated dodecyl alcohol sodium sulphate are mixed, be heated to 40-50 DEG C; Add polyethylene glycol, paraphthaloyl chloride, polyethylene glycol-200, auxiliary agent, under 1000-1200 rev/min of stirring, continue to be heated to 70-80 DEG C, stir 10-15 minute; Add other residual components, continue to stir 14-18 minute, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310653358.XA CN103725400B (en) | 2013-12-06 | 2013-12-06 | A kind of water base environmental protection cutting fluid and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310653358.XA CN103725400B (en) | 2013-12-06 | 2013-12-06 | A kind of water base environmental protection cutting fluid and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
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| CN103725400A CN103725400A (en) | 2014-04-16 |
| CN103725400B true CN103725400B (en) | 2016-05-25 |
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| CN201310653358.XA Active CN103725400B (en) | 2013-12-06 | 2013-12-06 | A kind of water base environmental protection cutting fluid and preparation method thereof |
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Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104109580A (en) * | 2014-06-25 | 2014-10-22 | 安徽豪鼎金属制品有限公司 | Environmental protection cutting fluid by adding abrasive and preparation method thereof |
| CN104109579B (en) * | 2014-06-25 | 2016-07-06 | 安徽豪鼎金属制品有限公司 | High cutting fluid of performance that a kind of applicable metal uses and preparation method thereof |
| CN104120009A (en) * | 2014-06-30 | 2014-10-29 | 安徽铖友汽车零部件制造有限公司 | Waterborne cutting liquid suitable for various metals and preparation method of cutting liquid |
| CN106010732B (en) * | 2016-05-18 | 2018-09-07 | 上海金兆节能科技有限公司 | Environment-friendly metal processes grinding fluid and preparation method thereof |
| CN107603726A (en) * | 2017-10-11 | 2018-01-19 | 陈有平 | A kind of water base lubricant |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7435707B2 (en) * | 2002-05-23 | 2008-10-14 | The Lubrizol Corporation | Oil-in-water emulsions and a method of producing |
| CN103361157A (en) * | 2013-06-21 | 2013-10-23 | 马鞍山市恒毅机械制造有限公司 | Microemulsion cutting fluid and preparation method thereof |
| CN103396872A (en) * | 2013-06-25 | 2013-11-20 | 岳西县新峰机械制造有限公司 | Environment-friendly cutting fluid and its preparation method |
-
2013
- 2013-12-06 CN CN201310653358.XA patent/CN103725400B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7435707B2 (en) * | 2002-05-23 | 2008-10-14 | The Lubrizol Corporation | Oil-in-water emulsions and a method of producing |
| CN103361157A (en) * | 2013-06-21 | 2013-10-23 | 马鞍山市恒毅机械制造有限公司 | Microemulsion cutting fluid and preparation method thereof |
| CN103396872A (en) * | 2013-06-25 | 2013-11-20 | 岳西县新峰机械制造有限公司 | Environment-friendly cutting fluid and its preparation method |
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| CN103725400A (en) | 2014-04-16 |
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Address after: Concentrated area of Taibai town 243181 Anhui city of Ma'anshan province Dangtu County Industrial Applicant after: DANTU JINLONG MACHINERY CO.,LTD. Address before: Concentrated area of Taibai town 243181 Anhui city of Ma'anshan province Dangtu County Industrial Applicant before: Dangtu Jinlong Machinery Factory |
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Address after: 243181 industrial concentration zone, Taibai Town, Dangtu County, Ma'anshan City, Anhui Province Patentee after: Dangtu jinlongfeng Technology Co.,Ltd. Address before: 243181 industrial concentration zone, Taibai Town, Dangtu County, Ma'anshan City, Anhui Province Patentee before: DANTU JINLONG MACHINERY CO.,LTD. |
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Effective date of registration: 20231010 Address after: No.19, Xinfeng street, Taibai Town, Dangtu County, Ma'anshan City, Anhui Province 243100 Patentee after: Ma'anshan ningtuo Heavy Industry Technology Co.,Ltd. Address before: 243181 industrial concentration zone, Taibai Town, Dangtu County, Ma'anshan City, Anhui Province Patentee before: Dangtu jinlongfeng Technology Co.,Ltd. |