CN103361157A - Microemulsion cutting fluid and preparation method thereof - Google Patents
Microemulsion cutting fluid and preparation method thereof Download PDFInfo
- Publication number
- CN103361157A CN103361157A CN2013102476643A CN201310247664A CN103361157A CN 103361157 A CN103361157 A CN 103361157A CN 2013102476643 A CN2013102476643 A CN 2013102476643A CN 201310247664 A CN201310247664 A CN 201310247664A CN 103361157 A CN103361157 A CN 103361157A
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- CN
- China
- Prior art keywords
- parts
- cutting fluid
- preparation
- ricinolic acid
- chitosan
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000002173 cutting fluid Substances 0.000 title claims abstract description 17
- 239000004530 micro-emulsion Substances 0.000 title claims abstract description 15
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 229960003656 ricinoleic acid Drugs 0.000 claims abstract description 13
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229920001661 Chitosan Polymers 0.000 claims abstract description 7
- LVTYICIALWPMFW-UHFFFAOYSA-N diisopropanolamine Chemical compound CC(O)CNCC(C)O LVTYICIALWPMFW-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229940043276 diisopropanolamine Drugs 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims description 12
- WBHHMMIMDMUBKC-QJWNTBNXSA-N ricinoleic acid Chemical compound CCCCCC[C@@H](O)C\C=C/CCCCCCCC(O)=O WBHHMMIMDMUBKC-QJWNTBNXSA-N 0.000 claims description 12
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 6
- VGGLHLAESQEWCR-UHFFFAOYSA-N N-(hydroxymethyl)urea Chemical compound NC(=O)NCO VGGLHLAESQEWCR-UHFFFAOYSA-N 0.000 claims description 6
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 6
- WERKSKAQRVDLDW-ANOHMWSOSA-N [(2s,3r,4r,5r)-2,3,4,5,6-pentahydroxyhexyl] (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO WERKSKAQRVDLDW-ANOHMWSOSA-N 0.000 claims description 6
- 239000012752 auxiliary agent Substances 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 6
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 claims description 6
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical class CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims description 6
- -1 ethoxylated dodecyl alcohol sodium sulfate Chemical class 0.000 claims description 6
- 239000012467 final product Substances 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 150000004780 naphthols Chemical class 0.000 claims description 3
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 3
- 235000011152 sodium sulphate Nutrition 0.000 claims description 3
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 abstract description 2
- 239000007788 liquid Substances 0.000 abstract description 2
- 229940051841 polyoxyethylene ether Drugs 0.000 abstract 3
- 229920000056 polyoxyethylene ether Polymers 0.000 abstract 3
- AWIJHZIZSALXDG-UHFFFAOYSA-N 2-(2-phenylethyl)naphthalen-1-ol Chemical compound C1=CC2=CC=CC=C2C(O)=C1CCC1=CC=CC=C1 AWIJHZIZSALXDG-UHFFFAOYSA-N 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 1
- 239000012528 membrane Substances 0.000 abstract 1
- 239000012188 paraffin wax Substances 0.000 abstract 1
- WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical compound CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 229910021653 sulphate ion Inorganic materials 0.000 abstract 1
- 238000001816 cooling Methods 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Abstract
The invention relates to a microemulsion cutting fluid and a preparation method thereof. The microemulsion cutting fluid is characterized by being prepared from the following raw materials in parts by weight: 3-4 parts of phenethyl naphthol polyoxyethylene ether, 1-2 parts of laurinol polyoxyethylene ether, 2-3 parts of chitosan, 1-2 parts of ricinoleic acid, 2-3 parts of sodium lauryl polyoxyethylene ether sulphate, 4-5 parts of chlorinated paraffin, 1-2 parts of diisopropanolamine, 5-6 parts of membrane auxiliary and 200 parts of water. The microemulsion cutting fluid is a semitransparent and transparent liquid, is easy in field operation and does not contain substances harmful to the environment and human health, such as nitrite; and the microemulsion cutting fluid has excellent processability and strong universality.
Description
Technical field
The invention belongs to the cutting fluid technical field, relate to a kind of micro-emulsion cutting fluid and preparation method thereof.
Background technology
In the mechanical processing industry, be to cut with lubricating oil or with the kerosene apply oil to lubricate and cooling basically.In the course of processing, the oil product waste is very serious, and environment and operator are caused very large injury; And be difficult to obtain desirable finished surface.And it is slow to add the man-hour radiating rate, behind the processing work, and very easy upper rust.
It is good to be badly in need of now the design oilness, and rustless property is superior, the cutting fluid that speed of cooling is fast, cleaning performance is good.
Summary of the invention
The purpose of this invention is to provide a kind of micro-emulsion cutting fluid and preparation method thereof,
The technical solution adopted in the present invention is:
A kind of micro-emulsion cutting fluid is characterized in that being made by the raw material of following weight part:
Styroyl naphthols Soxylat A 25-7 3-4, ethoxylated dodecyl alcohol 1-2, chitosan 2-3, ricinolic acid 1-2, ethoxylated dodecyl alcohol sodium sulfate 2-3, clorafin 4-5, diisopropanolamine (DIPA) 1-2, film auxiliary agent 5-6, water 200.
Described film auxiliary agent is made by the raw material of following weight part: ricinolic acid 3-4,2-amino-2-methyl-1-propyl alcohol 2-3, Silane coupling agent KH550 1-2, sorbitol monooleate 1-2, vinyl cyanide 1-2, methylolurea 2-3, tertbutyl peroxide 0.2-0.3, morpholine 1-2.
The preparation method is: ricinolic acid, 2-amino-2-methyl-1-propyl alcohol, vinyl cyanide, sorbitol monooleate are mixed, add tertbutyl peroxide, stirring reaction 2-3 hour, be heated to 130-140 ℃, add again Silane coupling agent KH550, methylolurea, morpholine, continue stirring reaction 1-2 hour and get final product.
The preparation method of described micro-emulsion cutting fluid, it is characterized in that may further comprise the steps: ethoxylated dodecyl alcohol, chitosan, ricinolic acid, clorafin, water are mixed, be heated to 75-85 ℃, stirred 60-80 minute, then, add other remaining component, stirred 30-40 minute, the accent pH value is 7-8, and get final product.
Micro-emulsion cutting fluid among the present invention makes things convenient for execute-in-place for translucent to transparent liquid, does not contain the materials harmful to environmental and human health impacts such as nitrite; Has excellent processing characteristics, highly versatile.
Embodiment
A kind of micro-emulsion cutting fluid, made by the raw material of following weight part (kilogram):
Styroyl naphthols Soxylat A 25-7 4, ethoxylated dodecyl alcohol 2, chitosan 3, ricinolic acid 2, ethoxylated dodecyl alcohol sodium sulfate 2, clorafin 5, diisopropanolamine (DIPA) 2, film auxiliary agent 6, water 200.
Described film auxiliary agent is made by the raw material of following weight part (kilogram): ricinolic acid 4,2-amino-2-methyl-1-propyl alcohol 3, Silane coupling agent KH550 2, sorbitol monooleate 2, vinyl cyanide 2, methylolurea 2, tertbutyl peroxide 0.3, morpholine 1.
The preparation method is: ricinolic acid, 2-amino-2-methyl-1-propyl alcohol, vinyl cyanide, sorbitol monooleate are mixed, add tertbutyl peroxide, stirring reaction 2-3 hour, be heated to 130-140 ℃, add again Silane coupling agent KH550, methylolurea, morpholine, continue stirring reaction 1-2 hour and get final product.
The preparation method of micro-emulsion cutting fluid may further comprise the steps: ethoxylated dodecyl alcohol, chitosan, ricinolic acid, clorafin, water are mixed, be heated to 75-85 ℃, stirred 60-80 minute, and then, added other remaining component, stirred 30-40 minute, the accent pH value is 7-8, and get final product.
Utilizing the present invention to carry out steel disc rust prevention test (55 ± 2 ℃) soaks entirely: 30 to go up to the sky without corrosion phenomenon.
Claims (2)
1. micro-emulsion cutting fluid is characterized in that being made by the raw material of following weight part:
Styroyl naphthols Soxylat A 25-7 3-4, ethoxylated dodecyl alcohol 1-2, chitosan 2-3, ricinolic acid 1-2, ethoxylated dodecyl alcohol sodium sulfate 2-3, clorafin 4-5, diisopropanolamine (DIPA) 1-2, film auxiliary agent 5-6, water 200;
Described film auxiliary agent is made by the raw material of following weight part: ricinolic acid 3-4,2-amino-2-methyl-1-propyl alcohol 2-3, Silane coupling agent KH550 1-2, sorbitol monooleate 1-2, vinyl cyanide 1-2, methylolurea 2-3, tertbutyl peroxide 0.2-0.3, morpholine 1-2;
The preparation method is: ricinolic acid, 2-amino-2-methyl-1-propyl alcohol, vinyl cyanide, sorbitol monooleate are mixed, add tertbutyl peroxide, stirring reaction 2-3 hour, be heated to 130-140 ℃, add again Silane coupling agent KH550, methylolurea, morpholine, continue stirring reaction 1-2 hour and get final product.
2. the preparation method of micro-emulsion cutting fluid according to claim 1 is characterized in that may further comprise the steps:
Ethoxylated dodecyl alcohol, chitosan, ricinolic acid, clorafin, water are mixed, be heated to 75-85 ℃, stirred 60-80 minute, then, add other remaining component, stirred 30-40 minute, the accent pH value is 7-8, and get final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310247664.3A CN103361157B (en) | 2013-06-21 | 2013-06-21 | Microemulsion cutting fluid and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310247664.3A CN103361157B (en) | 2013-06-21 | 2013-06-21 | Microemulsion cutting fluid and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103361157A true CN103361157A (en) | 2013-10-23 |
| CN103361157B CN103361157B (en) | 2014-12-03 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310247664.3A Expired - Fee Related CN103361157B (en) | 2013-06-21 | 2013-06-21 | Microemulsion cutting fluid and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103361157B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103725389A (en) * | 2013-12-06 | 2014-04-16 | 当涂县金龙机械厂 | Cutting fluid for ferrous metal processing and preparation method of cutting fluid |
| CN103725400A (en) * | 2013-12-06 | 2014-04-16 | 当涂县金龙机械厂 | Water-based environment-friendly cutting fluid and preparation method thereof |
| CN104293467A (en) * | 2014-09-30 | 2015-01-21 | 苏州长盛机电有限公司 | Micro-emulsion cutting fluid for aluminum alloy, and preparation method of micro-emulsion cutting fluid |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1031107A (en) * | 1987-08-07 | 1989-02-15 | 湖南省长沙化工机械厂 | The preparation method of general metal cutting fluid |
| US6221814B1 (en) * | 1998-04-21 | 2001-04-24 | Shin-Etsu Handotai Co., Ltd. | Aqueous compositions, aqueous cutting fluid using the same, method for preparation thereof, and cutting method using the cutting fluid |
| CN101265437A (en) * | 2008-04-23 | 2008-09-17 | 常州市夏雷化学有限公司 | Water-soluble low oil fog anti-rust cutting liquid |
-
2013
- 2013-06-21 CN CN201310247664.3A patent/CN103361157B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1031107A (en) * | 1987-08-07 | 1989-02-15 | 湖南省长沙化工机械厂 | The preparation method of general metal cutting fluid |
| US6221814B1 (en) * | 1998-04-21 | 2001-04-24 | Shin-Etsu Handotai Co., Ltd. | Aqueous compositions, aqueous cutting fluid using the same, method for preparation thereof, and cutting method using the cutting fluid |
| CN101265437A (en) * | 2008-04-23 | 2008-09-17 | 常州市夏雷化学有限公司 | Water-soluble low oil fog anti-rust cutting liquid |
Non-Patent Citations (1)
| Title |
|---|
| 李玮等: "水基金属切削液的研究进展", 《合成润滑材料》, vol. 36, no. 4, 31 December 2009 (2009-12-31), pages 19 - 23 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103725389A (en) * | 2013-12-06 | 2014-04-16 | 当涂县金龙机械厂 | Cutting fluid for ferrous metal processing and preparation method of cutting fluid |
| CN103725400A (en) * | 2013-12-06 | 2014-04-16 | 当涂县金龙机械厂 | Water-based environment-friendly cutting fluid and preparation method thereof |
| CN103725389B (en) * | 2013-12-06 | 2016-03-23 | 当涂县金龙机械厂 | A kind of ferrous metal processing cutting fluid and preparation method thereof |
| CN103725400B (en) * | 2013-12-06 | 2016-05-25 | 当涂县金龙机械有限公司 | A kind of water base environmental protection cutting fluid and preparation method thereof |
| CN104293467A (en) * | 2014-09-30 | 2015-01-21 | 苏州长盛机电有限公司 | Micro-emulsion cutting fluid for aluminum alloy, and preparation method of micro-emulsion cutting fluid |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103361157B (en) | 2014-12-03 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20170515 Address after: 312365 Zhejiang Province, Shaoxing city Shangyu District Songxia Town City Station International Plaza building 36 unit room 1-101 Patentee after: Zhejiang Hongsheng Technology Transfer Services Ltd. Address before: Taibai Industrial Park, 243181 Anhui city of Ma'anshan province Dangtu County Patentee before: Maanshan Machinery Manufacturing Co., Ltd. |
|
| TR01 | Transfer of patent right | ||
| CB03 | Change of inventor or designer information | ||
| CB03 | Change of inventor or designer information |
Inventor after: Shi Keqin Inventor before: Zhang Gongguo Inventor before: Xie Yong |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20170711 Address after: Dalang Zhen Yang village pond 523770 Guangdong city in Dongguan province Fu Yang Road No. 138 of Patentee after: Dongguan city TEXMO lubricating oil Technology Co. Ltd. Address before: 312365 Zhejiang Province, Shaoxing city Shangyu District Songxia Town City Station International Plaza building 36 unit room 1-101 Patentee before: Zhejiang Hongsheng Technology Transfer Services Ltd. |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20141203 Termination date: 20170621 |