CN107326126A - A kind of Chinese herbal medicine leather and fur conditioning liquid and preparation method thereof - Google Patents

A kind of Chinese herbal medicine leather and fur conditioning liquid and preparation method thereof Download PDF

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Publication number
CN107326126A
CN107326126A CN201710488625.0A CN201710488625A CN107326126A CN 107326126 A CN107326126 A CN 107326126A CN 201710488625 A CN201710488625 A CN 201710488625A CN 107326126 A CN107326126 A CN 107326126A
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herbal medicine
chinese herbal
conditioning liquid
leather
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CN107326126B (en
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黄崇军
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Liuzhou Shuangcheng Technology Co.,Ltd.
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Ningbo City Haishu District Ivanka Agricultural Science And Technology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C14SKINS; HIDES; PELTS; LEATHER
    • C14CCHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
    • C14C11/00Surface finishing of leather
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D11/00Solvent extraction
    • B01D11/02Solvent extraction of solids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D11/00Solvent extraction
    • B01D11/02Solvent extraction of solids
    • B01D11/0261Solvent extraction of solids comprising vibrating mechanisms, e.g. mechanical, acoustical
    • B01D11/0265Applying ultrasound
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D11/00Solvent extraction
    • B01D11/02Solvent extraction of solids
    • B01D11/0288Applications, solvents

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Acoustics & Sound (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Medicines That Contain Protein Lipid Enzymes And Other Medicines (AREA)
  • Peptides Or Proteins (AREA)
  • Medicines Containing Plant Substances (AREA)

Abstract

The invention discloses a kind of Chinese herbal medicine leather and fur conditioning liquid and preparation method thereof, the composition and its parts by weight of conditioning liquid are:30 37 parts of Chinese herbal medicine extract, 12 parts of brightener, 12 parts of emulsifying agent, 0.2 0.3 parts of antistatic additive, 12 parts of dispersant, 0.3 0.6 parts of flavouring agent, 55 60 parts of water.Have the beneficial effect that:Conditioning liquid primary raw material of the present invention is Chinese herbal medicine extract, and various composition is reasonably combined, and collaboration plays a role, environmental protection, and long-acting nursing efficacy is good, to fur not damaged, and anti-mould and anti-moth effect is good, prevents hair from coming off, non-aging;The conditioning liquid formula compatibility rationally, between each composition cooperate, with it is antibacterial, anti-oxidant, neutralize grease, antifungi, fixation advantage;The preparation method of conditioning liquid of the present invention is simple, and with short production cycle, production process will not discharge environmentally harmful waste water and gas, be an environment amenable process.

Description

A kind of Chinese herbal medicine leather and fur conditioning liquid and preparation method thereof
Technical field
The present invention relates to leather and fur nursing field, more particularly to a kind of Chinese herbal medicine leather and fur conditioning liquid and preparation method thereof.
Background technology
Leather and fur is the winter warm and beautiful good thing of resisting cold, and brushy texture makes women more aobvious with luxurious rare style Graceful and fashion.With the improvement of people's life quality, the demand of leather and fur product also more and more higher, in addition, leather products are for we One of important exporting of state, creates substantial amounts of export exchange for China every year.But existing leather and fur is rich in due to itself Protein, so maintenance gets up extremely difficult, particularly in damp and hot summer, high temperature and moist environment can deform fur Even come off.With increasing for leather and fur product, maintenance, maintenance, the cleaning of the leather and fur product of high value also naturally turn into One it is new the problem of and business opportunity.Consumer, which puts on even to put in a year or so, just can be appreciated that oneself loved leather and fur some months There is cortex aging in product, and hair loss fades, the problems such as intensely dark.The applicable object of existing care product is ox mostly One kind in the leather shoes such as skin, sheepskin or fur clothing, applicable object is single, and effect is single, and product is generally chemical synthesis composition composition, tool Irritant smell, it is harmful to leather and fur product and human body, be not suitable for the daily maintenance product of leather and fur product, lead to not full Sufficient consumer demand.
Prior art such as Authorization Notice No. is the B of CN 101736098 Chinese invention patent, discloses Chinese herbal medicine type leather and fur Care product and its production technology, are comprised the following raw materials by weight percent:Product contains:5.0-10.0 the sponge gourd of parts by weight Bleeding sap, the kuh-seng Aqueous extracts of 8.0-17.0 parts by weight, the frutus cnidii Aqueous extracts of 10.0-16.0 parts by weight, 15.0-22.0 weight Goldenrod Aqueous extracts, the beeswax (liquid wax), the emulsifying agent of 1.0-4.0 parts by weight, the 25.0- of 2.5-5.5 parts by weight of part 45.0 deionized water.The care product by decontamination, glazing, moisten, waterproof, it is mould proof once complete, change using a variety of shields Reason product, which can be only achieved, makes all leather and fur products, reaches cleaning, glazing, moist, waterproof, mould proof cumbersome present situation, makes nursing pair As comprehensive, nursing function is settled at one go simultaneously, pure natural substance mainly is used for main component, green, environmental protection, but the preparation Process is complicated, is not suitable for industrialized production.
The content of the invention
It is an object of the invention to provide a kind of compatibility rationally, various composition collaboration plays a role, environmental protection, long-acting shield Reason and anti-mould and anti-moth effect are good, to fur not damaged, non-aging Chinese herbal medicine leather and fur conditioning liquid and preparation method thereof.
The present invention is directed to the problem of being mentioned in above-mentioned technology, and the technical scheme taken is:A kind of Chinese herbal medicine leather and fur conditioning liquid, Composition and its parts by weight are:30-37 parts of Chinese herbal medicine extract, 1-2 parts of brightener, 1-2 parts of emulsifying agent, antistatic additive 0.2-0.3 Part, 1-2 parts of dispersant, 0.3-0.6 parts of flavouring agent, 55-60 parts of water.The composition and its parts by weight of flavouring agent be:5-10 parts of camomile, 5-10 parts of the root of herbaceous peony, 2-3 parts of peppermint, 2-3 parts of lemon, 0.1-0.5 parts of rose, 0.2-0.4 parts of jasmine, the flavouring agent smell are light, Do not stimulate, the bad smell of Chinese herbal medicine can be covered, and each composition has no adverse effects to leather and fur.Above-mentioned conditioning liquid primary raw material is Chinese herbal medicine extract, various composition is reasonably combined, and collaboration plays a role, environmental protection, and long-acting nursing efficacy is good, lossless to fur Wound, anti-mould and anti-moth effect is good, prevents hair from coming off, non-aging.
A kind of preparation method of Chinese herbal medicine leather and fur conditioning liquid, specifically includes following steps:
Chinese herbal medicine decocting:Chinese herbal medicine powder is weighed by formula, plus 3-5 times is measured water, adds Chinese herbal medicine powder weight 0.03-0.04% work Property polypeptide, small fire is heated to reflux 2-3 times, each 30-40min, filtering, merging filtrate, centrifugation, takes supernatant, -0.1- - Decompression is concentrated into the 40-50% of total dose at 0.08MPa, 70-75 DEG C, and standby, the amino acid sequence of active peptides is HSHARCLRCRVLHPGCVNCYRCSR, the active peptides can destroy the cell wall substance of Chinese herbal medicine, change Chinese herbal medicine cell Osmotic pressure, allow the water to quickly enter intracellular, cause the rupture of cell membrane, enable intracellular active ingredient fast and effectively Discharge, shorten digestion time, improve boiling efficiency, and the activity of Chinese herbal medicine effective ingredientses is had no effect;
Chinese herbal medicine is purified:Decoction liquor is pressed 1:1-2 volume ratio is put after adding 60-70% ethanol solution, 20~30min of immersion Enter in ultrasonic wave, 50-60min is extracted at 40-50 DEG C, centrifuge, take supernatant, in -0.1- -0.08MPa, 70-75 DEG C of decline Pressure is concentrated into the 40-50% of total dose, and standby, ethyl alcohol purification and ultrasonic wave are combined by the extracting method, can allow impurity substances It is quickly dissolved in ethanol, substantially reduces the purification time, extraction effect is high, while improves the purity of medium-height grass extract;
Chinese herbal medicine decolourizes:The activated carbon that 1-5% is added in liquid will be purified, decolourize 30-35min at 50-60 DEG C, filtering, you can, Decolourized with physical adsorption process, can be and with low cost with the activity of maximized protection Chinese herbal medicine extract, to environment without Harmful effect;
Conditioning liquid is prepared:Chinese herbal medicine extract, brightener, emulsifying agent, antistatic additive, dispersant, flavouring agent, water are taken by formula, It is well mixed, it is filling, Chinese herbal medicine leather and fur conditioning liquid is produced, the conditioning liquid primary raw material is Chinese herbal medicine extract, various composition Reasonably combined, collaboration plays a role, environmental protection, and long-acting nursing efficacy is good, to fur not damaged, and anti-mould and anti-moth effect is good, prevents Only hair comes off, non-aging.
It is preferred that, the composition and its parts by weight of Chinese herbal medicine powder are:22-25 parts of tealeaves, 15-19 parts of tripterygium wilfordii, shaddock leaf 15- 18 parts, 16-20 parts of camphortree leaf, 5-9 parts of cloves, the Chinese herbal medicine compatibility rationally, between each composition cooperate so that the Chinese herbal medicine Extract has antibacterial, anti-oxidant, neutralization grease, antifungi, the advantage of fixation, and there is moist, antibacterial and sterilization to make to leather and fur With.
Compared with prior art, the advantage of the invention is that:Conditioning liquid primary raw material of the present invention is Chinese herbal medicine extract, Various composition is reasonably combined, and collaboration plays a role, environmental protection, and long-acting nursing efficacy is good, to fur not damaged, anti-mould and anti-moth effect It is really good, prevent hair from coming off, it is non-aging;The conditioning liquid formula compatibility rationally, cooperates, with antibacterial, anti-between each composition Oxidation, neutralization grease, antifungi, the advantage of fixation;The preparation method of conditioning liquid of the present invention is simple, with short production cycle, produces Cheng Buhui discharges environmentally harmful waste water and gas, is an environment amenable process.
Embodiment
The present invention program is described further below by embodiment:
Embodiment 1:
A kind of Chinese herbal medicine leather and fur conditioning liquid, composition and its parts by weight are:35 parts of Chinese herbal medicine extract, 1.2 parts of brightener, emulsifying agent 1.5 parts, 0.24 part of antistatic additive, 1.5 parts of dispersant, 0.4 part of flavouring agent, 58 parts of water.The composition and its parts by weight of flavouring agent be: 6 parts of camomile, 8 parts of the root of herbaceous peony, 2.5 parts of peppermint, 3 parts of lemon, 0.2 part of rose, 0.35 part of jasmine, the flavouring agent smell are light, do not pierce Swash, the bad smell of Chinese herbal medicine can be covered, and each composition has no adverse effects to leather and fur.
A kind of preparation method of Chinese herbal medicine leather and fur conditioning liquid, specifically includes following steps:
1)Chinese herbal medicine decocting:Chinese herbal medicine powder, plus 4 times of amount water are weighed by formula, the activity for adding Chinese herbal medicine powder weight 0.035% is more Peptide, small fire is heated to reflux 3 times, each 35min, filtering, merging filtrate, and centrifugation takes supernatant, is depressured at -0.1MPa, 70 DEG C The 50% of total dose is concentrated into, standby, the amino acid sequence of active peptides is HSHARCLRCRVLHPGCVNCYRCSR, the activity Polypeptide can destroy the cell wall substance of Chinese herbal medicine, change the osmotic pressure of Chinese herbal medicine cell, allow the water to quickly enter intracellular, draw The rupture of cell membrane is played, intracellular active ingredient is fast and effectively discharged, shortens digestion time, boiling effect is improved Rate, and the activity of Chinese herbal medicine effective ingredientses is had no effect;
2)Chinese herbal medicine is purified:Decoction liquor is pressed 1:2 volume ratio is put into ultrasonic wave after adding 65% ethanol solution, immersion 25min It is interior, 55min is extracted at 50 DEG C, centrifuges, takes supernatant, decompression is concentrated into the 50% of total dose at -0.1MPa, 70 DEG C, standby With ethyl alcohol purification and ultrasonic wave are combined by the extracting method, impurity substances can be allowed to be quickly dissolved in ethanol, substantially reduced Purification time, extraction effect is high, while improving the purity of medium-height grass extract;
3)Chinese herbal medicine decolourizes:The activated carbon that 2% is added in liquid will be purified, decolourize 32min at 55 DEG C, filtering, you can, use physics Adsorption method is decolourized, can be and with low cost with the activity of maximized protection Chinese herbal medicine extract, to environment without bad shadow Ring;
4)Conditioning liquid is prepared:By formula take Chinese herbal medicine extract, brightener, emulsifying agent, antistatic additive, dispersant, flavouring agent, Water, be well mixed, it is filling, produce Chinese herbal medicine leather and fur conditioning liquid, the conditioning liquid primary raw material is Chinese herbal medicine extract, it is various into Divide reasonably combined, collaboration plays a role, environmental protection, and long-acting nursing efficacy is good, to fur not damaged, and anti-mould and anti-moth effect is good, Prevent hair from coming off, it is non-aging.
The composition and its parts by weight of said herbal medicine powder be:23 parts of tealeaves, 16 parts of tripterygium wilfordii, 15 parts of shaddock leaf, camphortree leaf 17 parts, 8 parts of cloves, the Chinese herbal medicine compatibility rationally, between each composition cooperate so that the Chinese herbal medicine extract have it is antibacterial, Anti-oxidant, neutralization grease, antifungi, the advantage of fixation, have moist, antibacterial and bactericidal action to leather and fur.
Embodiment 2:
A kind of Chinese herbal medicine leather and fur conditioning liquid, composition and its parts by weight are:32 parts of Chinese herbal medicine extract, 2 parts of brightener, emulsifying agent 1.5 parts, 0.25 part of antistatic additive, 1.5 parts of dispersant, 0.5 part of flavouring agent, 58 parts of water.The composition and its parts by weight of flavouring agent be: 8 parts of camomile, 7 parts of the root of herbaceous peony, 2.5 parts of peppermint, 3 parts of lemon, 0.5 part of rose, 0.3 part of jasmine, the flavouring agent smell are light, do not pierce Swash, the bad smell of Chinese herbal medicine can be covered, and each composition has no adverse effects to leather and fur.
A kind of preparation method of Chinese herbal medicine leather and fur conditioning liquid, specifically includes following steps:
1)Chinese herbal medicine powder, plus 5 times of amount water are weighed by formula, the active peptides of Chinese herbal medicine powder weight 0.04% are added, small fire is heated back Stream 2 times, each 36min, filtering, merging filtrate, centrifugation takes supernatant, is concentrated into the 45% of total dose, standby, active peptides Amino acid sequence is HSHARCLRCRVLHPGCVNCYRCSR, and the active peptides can destroy the cell wall substance of Chinese herbal medicine, change Become the osmotic pressure of Chinese herbal medicine cell, allow the water to quickly enter intracellular, cause the rupture of cell membrane, make intracellular active ingredient It can fast and effectively discharge, shorten digestion time, improve boiling efficiency, and the activity nothing of Chinese herbal medicine effective ingredientses is appointed What influences;
2)Decoction liquor is pressed 1:1-2 volume ratio is put into ultrasonic wave after adding 70% ethanol solution, immersion 30min, at 45 DEG C Lower extraction 55min, centrifugation, takes supernatant, is concentrated into the 45% of total dose, standby, and the extracting method is by ethyl alcohol purification and ultrasonic wave It is combined, impurity substances can be allowed to be quickly dissolved in ethanol, substantially reduce the purification time, extraction effect is high, while in improves The purity of careless extract;
3)The activated carbon that 3.5% is added in liquid will be purified, decolourize 30min at 60 DEG C, filtering, you can, entered with physical adsorption process Row is decolourized, can be and with low cost with the activity of maximized protection Chinese herbal medicine extract, and environment is had no adverse effects;
4)Chinese herbal medicine extract, brightener, emulsifying agent, antistatic additive, dispersant, flavouring agent, water are taken by formula, is well mixed, It is filling, Chinese herbal medicine leather and fur conditioning liquid is produced, the conditioning liquid primary raw material is Chinese herbal medicine extract, and various composition is reasonably combined, Collaboration plays a role, environmental protection, and long-acting nursing efficacy is good, to fur not damaged, and anti-mould and anti-moth effect is good, prevents hair from coming off, It is non-aging.
The composition and its parts by weight of said herbal medicine powder be:24 parts of tealeaves, 18 parts of tripterygium wilfordii, 17 parts of shaddock leaf, camphortree leaf 18 parts, 8 parts of cloves, the Chinese herbal medicine compatibility rationally, between each composition cooperate so that the Chinese herbal medicine extract have it is antibacterial, Anti-oxidant, neutralization grease, antifungi, the advantage of fixation, have moist, antibacterial and bactericidal action to leather and fur.
Embodiment 3:
A kind of Chinese herbal medicine leather and fur conditioning liquid, composition and its parts by weight are:36 parts of Chinese herbal medicine extract, 1.6 parts of brightener, emulsifying agent 1.2 parts, 0.3 part of antistatic additive, 1 part of dispersant, 0.6 part of flavouring agent, 60 parts of water.The composition and its parts by weight of flavouring agent be:It is sweet 8 parts of chrysanthemum, 7 parts of the root of herbaceous peony, 2.5 parts of peppermint, 2 parts of lemon, 0.3 part of rose, 0.3 part of jasmine.
A kind of preparation method of Chinese herbal medicine leather and fur conditioning liquid, is concretely comprised the following steps:22 parts of tealeaves, tripterygium wilfordii 16 are taken by weight Part, 17 parts of shaddock leaf, 18 parts of camphortree leaf, 8 parts of cloves, plus the water that 5 times of Chinese herbal medicine is measured, add the work of Chinese herbal medicine powder weight 0.038% Property polypeptide, small fire is heated to reflux, and filters, centrifugation, takes supernatant concentration;Decoction liquor is pressed 1:2 volume ratio adds 66% ethanol It is put into after solution, immersion 30min in ultrasonic wave, 60min is extracted at 48 DEG C, centrifuges, takes supernatant concentration;It will add in purification liquid Enter 3% activated carbon, decolourize 30min at 58 DEG C, filtering;Each dispensing is taken with nursing formula of liquid, is well mixed, it is filling, in producing Herbal medicine leather and fur conditioning liquid.
Routine operation in the operating procedure of the present invention is well known to those skilled in the art, herein without repeating.
Technical scheme is described in detail embodiment described above, it should be understood that it is described above only For the specific embodiment of the present invention, it is not intended to limit the invention, all any modifications made in the spirit of the present invention, Supplement or similar fashion replacement etc., should be included in the scope of the protection.
SEQUENCE LISTING
<110>Ningbo City Haishu District Yi Wanka agricultural science and technologys Co., Ltd
<120>A kind of Chinese herbal medicine leather and fur conditioning liquid and preparation method thereof
<130> 1
<160> 1
<170> PatentIn version 3.5
<210> 1
<211> 24
<212> PRT
<213>It is artificial synthesized
<400> 1
His Ser His Ala Arg Cys Leu Arg Cys Arg Val Leu His Pro Gly Cys
1 5 10 15
Val Asn Cys Tyr Arg Cys Ser Arg
20

Claims (10)

1. a kind of Chinese herbal medicine leather and fur conditioning liquid, it is characterised in that:The composition and its parts by weight of described conditioning liquid be:Chinese herbal medicine is carried Take 30-37 parts of thing, 1-2 parts of brightener, 1-2 parts of emulsifying agent, 0.2-0.3 parts of antistatic additive, 1-2 parts of dispersant, flavouring agent 0.3- 0.6 part, 55-60 parts of water.
2. a kind of Chinese herbal medicine leather and fur conditioning liquid according to claim 1, it is characterised in that:The composition of described flavouring agent and Its parts by weight is:5-10 parts of camomile, 5-10 parts of the root of herbaceous peony, 2-3 parts of peppermint, 2-3 parts of lemon, 0.1-0.5 parts of rose, jasmine 0.2- 0.4 part.
3. a kind of preparation method of Chinese herbal medicine leather and fur conditioning liquid, it is characterised in that:Described preparation method is concretely comprised the following steps:
1)Chinese herbal medicine decocting:Chinese herbal medicine powder is weighed by formula, adds water and active peptides, is heated to reflux, is filtered, centrifugation takes supernatant Liquid is concentrated, standby;
2)Chinese herbal medicine is purified:Decoction liquor is added extraction in ultrasonic wave is put into after ethanol solution, immersion, centrifugation takes supernatant dense Contracting, it is standby;
3)Chinese herbal medicine decolourizes:Activated carbon decolorizing will be added in purification liquid, filtered, you can;
4)Conditioning liquid is prepared:By formula take Chinese herbal medicine extract, brightener, emulsifying agent, antistatic additive, dispersant, flavouring agent, Water, is well mixed, filling, produces Chinese herbal medicine leather and fur conditioning liquid.
4. a kind of preparation method of Chinese herbal medicine leather and fur conditioning liquid according to claim 3, it is characterised in that:Described step The addition of active peptides is the 0.03-0.04% of Chinese herbal medicine powder weight in 1, and its amino acid sequence is HSHARCLRCRVLHPGCVNCYRCSR。
5. a kind of preparation method of Chinese herbal medicine leather and fur conditioning liquid according to claim 3, it is characterised in that:Described step The composition and its parts by weight of Chinese herbal medicine powder are in 1:22-25 parts of tealeaves, 15-19 parts of tripterygium wilfordii, 15-18 parts of shaddock leaf, camphortree leaf 16-20 parts, 5-9 parts of cloves.
6. a kind of preparation method of Chinese herbal medicine leather and fur conditioning liquid according to claim 3, it is characterised in that:Described step Small fire is heated to reflux 2-3 times in 1, each 30-40min.
7. a kind of preparation method of Chinese herbal medicine leather and fur conditioning liquid according to claim 3, it is characterised in that:Described step The concentration of ethanol solution is 60-70% in 2, soaks 20-30min.
8. a kind of preparation method of Chinese herbal medicine leather and fur conditioning liquid according to claim 3, it is characterised in that:Described step Ultrasonic wave extraction temperature is 40-50 DEG C in 2, and the time is 50-60min.
9. a kind of preparation method of Chinese herbal medicine leather and fur conditioning liquid according to claim 3, it is characterised in that:Described step The addition of activated carbon is the 1-5% of purification liquid in 3.
10. a kind of preparation method of Chinese herbal medicine leather and fur conditioning liquid according to claim 3, it is characterised in that:Described step Bleaching temperature is 50-60 DEG C in rapid 3, and the time is 30-35min.
CN201710488625.0A 2017-06-23 2017-06-23 A kind of Chinese herbal medicine leather and fur conditioning liquid and preparation method thereof Active CN107326126B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108085969A (en) * 2017-11-24 2018-05-29 湖州织里创塑塑料科技有限公司 The antiseptic finish method of knitting wool
CN108486295A (en) * 2018-04-08 2018-09-04 上海睿沁环保科技有限公司 A kind of surface peculiar smell removing care agent of leather furniture

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101721571A (en) * 2009-12-19 2010-06-09 顾一平 Chinese herbal medicine footherapy fragrant flower
CN105039610A (en) * 2015-06-30 2015-11-11 深圳市艾思生物技术有限公司 Leather care solution and preparation method thereof
CN105256085A (en) * 2015-09-23 2016-01-20 威海市春光服装有限公司 Fur nursing solution

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101721571A (en) * 2009-12-19 2010-06-09 顾一平 Chinese herbal medicine footherapy fragrant flower
CN105039610A (en) * 2015-06-30 2015-11-11 深圳市艾思生物技术有限公司 Leather care solution and preparation method thereof
CN105256085A (en) * 2015-09-23 2016-01-20 威海市春光服装有限公司 Fur nursing solution

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108085969A (en) * 2017-11-24 2018-05-29 湖州织里创塑塑料科技有限公司 The antiseptic finish method of knitting wool
CN108486295A (en) * 2018-04-08 2018-09-04 上海睿沁环保科技有限公司 A kind of surface peculiar smell removing care agent of leather furniture

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