CN107298634B - 用于烃脱氢的催化剂 - Google Patents

用于烃脱氢的催化剂 Download PDF

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CN107298634B
CN107298634B CN201710564462.XA CN201710564462A CN107298634B CN 107298634 B CN107298634 B CN 107298634B CN 201710564462 A CN201710564462 A CN 201710564462A CN 107298634 B CN107298634 B CN 107298634B
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compound
weight
catalyst
dehydrogenation
calculated
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CN107298634A (zh
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F·C·帕特卡斯
C·乌桑
M·迪特勒
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BASF SE
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C07C5/3332—Catalytic processes with metal oxides or metal sulfides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/612—Surface area less than 10 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8892—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04—Mixing
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/10—Magnesium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C07C2523/04—Alkali metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of rare earths
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/20—Vanadium, niobium or tantalum
    • C07C2523/22—Vanadium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/28—Molybdenum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/32—Manganese, technetium or rhenium
    • C07C2523/34—Manganese
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/745—Iron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/85—Chromium, molybdenum or tungsten
    • C07C2523/88—Molybdenum
    • C07C2523/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/889—Manganese, technetium or rhenium

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CN201710564462.XA 2011-12-22 2012-12-20 用于烃脱氢的催化剂 Active CN107298634B (zh)

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EP11195116.6 2011-12-22
EP11195116 2011-12-22
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EP (2) EP3470139B1 (cg-RX-API-DMAC10.html)
JP (1) JP6335788B2 (cg-RX-API-DMAC10.html)
CN (2) CN107298634B (cg-RX-API-DMAC10.html)
IN (1) IN2014CN04377A (cg-RX-API-DMAC10.html)
RU (1) RU2629195C2 (cg-RX-API-DMAC10.html)
WO (1) WO2013093824A1 (cg-RX-API-DMAC10.html)

Families Citing this family (5)

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Publication number Priority date Publication date Assignee Title
US10336667B2 (en) 2014-05-09 2019-07-02 Basf Se Catalyst for dehydrogenating hydrocarbons
CN109046398B (zh) * 2018-08-07 2021-02-19 中国科学院福建物质结构研究所 一种CO脱氢净化用Mn基非贵金属催化剂及其制备方法
CN115518648B (zh) * 2021-06-24 2024-01-26 中国石油化工股份有限公司 稀土氧化物催化剂及其制备方法和应用
JPWO2025142020A1 (cg-RX-API-DMAC10.html) * 2023-12-25 2025-07-03
CN118491533A (zh) * 2024-05-27 2024-08-16 上海润和科华工程设计有限公司 一种c5脱氢制二烯烃催化剂组合物及其制备方法和使用方法

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0181999A1 (de) * 1984-11-22 1986-05-28 Süd-Chemie Ag Dehydrierungskatalysator
EP0502510A1 (en) * 1991-03-05 1992-09-09 Nissan Girdler Catalyst Co., Ltd. Alkyl aromatic hydrocarbon dehydrogenation catalyst and production method thereof
CN1253855A (zh) * 1998-11-18 2000-05-24 中国石油化工集团公司 烷基芳烃脱氢催化剂
WO2003064032A1 (en) * 2002-01-30 2003-08-07 Shell Internationale Research Maatschappij B.V. Iron oxide-based catalyst, its preparation and its use in a dehydrogenation process
CN1470325A (zh) * 2002-07-26 2004-01-28 中国石油天然气股份有限公司 乙苯脱氢制苯乙烯催化剂及其制备方法
CN1810370A (zh) * 2005-01-26 2006-08-02 中国石油化工股份有限公司 用于烷基芳烃脱氢制备烷烯基芳烃的催化剂
CN101422735A (zh) * 2007-11-01 2009-05-06 中国石油天然气股份有限公司 一种高效乙苯脱氢制苯乙烯的催化剂及其制备方法
CN101733113A (zh) * 2008-11-18 2010-06-16 中国石油天然气股份有限公司 乙苯脱氢制苯乙烯的催化剂及其制备方法

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FR2411169A1 (fr) 1977-12-12 1979-07-06 Shell France Procede de deshydrogenation sans oxydation et composition catalytique pour la mise en oeuvre de ce procede
JPH0712434B2 (ja) * 1987-11-27 1995-02-15 日東化学工業株式会社 リン・アンチモン含有酸化物触媒の製法
CA2207564C (en) * 1994-12-14 2007-05-01 Shell Internationale Research Maatschappij B.V. Iron oxide dehydrogenation catalysts and process
WO1996018457A1 (en) 1994-12-14 1996-06-20 Shell Internationale Research Maatschappij B.V. Restructured iron oxide
CN1050535C (zh) 1995-11-15 2000-03-22 中国石油化工总公司 用于生产不饱和芳烃的脱氢催化剂
DE19814080A1 (de) 1998-03-30 1999-10-07 Basf Ag Katalysator zur Dehydrierung von Kohlenwasserstoffen, insbesondere zur Dehydrierung von Ethylbenzol zu Styrol, sowie Verfahren zu seiner Herstellung
US7271126B2 (en) * 2002-05-15 2007-09-18 Sud-Chemie Inc. Catalyst for the dehydrogenation of ethyl benzene to STYRENE prepared with a high purity iron precursor
TW200631934A (en) * 2004-11-18 2006-09-16 Shell Int Research An improved process for the manufacture of an alkenyl aromatic compound under low steam-to-oil process conditions
CN100358632C (zh) * 2005-01-26 2008-01-02 中国石油化工股份有限公司 烷基芳烃脱氢催化剂
CN101602003B (zh) * 2008-06-12 2011-07-20 中国石油化工股份有限公司 用于乙苯脱氢制备苯乙烯的氧化物催化剂

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0181999A1 (de) * 1984-11-22 1986-05-28 Süd-Chemie Ag Dehydrierungskatalysator
EP0502510A1 (en) * 1991-03-05 1992-09-09 Nissan Girdler Catalyst Co., Ltd. Alkyl aromatic hydrocarbon dehydrogenation catalyst and production method thereof
CN1253855A (zh) * 1998-11-18 2000-05-24 中国石油化工集团公司 烷基芳烃脱氢催化剂
WO2003064032A1 (en) * 2002-01-30 2003-08-07 Shell Internationale Research Maatschappij B.V. Iron oxide-based catalyst, its preparation and its use in a dehydrogenation process
CN1470325A (zh) * 2002-07-26 2004-01-28 中国石油天然气股份有限公司 乙苯脱氢制苯乙烯催化剂及其制备方法
CN1810370A (zh) * 2005-01-26 2006-08-02 中国石油化工股份有限公司 用于烷基芳烃脱氢制备烷烯基芳烃的催化剂
CN101422735A (zh) * 2007-11-01 2009-05-06 中国石油天然气股份有限公司 一种高效乙苯脱氢制苯乙烯的催化剂及其制备方法
CN101733113A (zh) * 2008-11-18 2010-06-16 中国石油天然气股份有限公司 乙苯脱氢制苯乙烯的催化剂及其制备方法

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CN104105544B (zh) 2017-08-08
WO2013093824A1 (de) 2013-06-27
RU2014129892A (ru) 2016-02-20
EP2794098A1 (de) 2014-10-29
CN107298634A (zh) 2017-10-27
RU2629195C2 (ru) 2017-08-25
JP2015506830A (ja) 2015-03-05
EP3470139B1 (de) 2020-04-22
CN104105544A (zh) 2014-10-15
JP6335788B2 (ja) 2018-05-30
EP2794098B1 (de) 2019-08-14
EP2794098A4 (de) 2015-12-09
EP3470139A1 (de) 2019-04-17
IN2014CN04377A (cg-RX-API-DMAC10.html) 2015-09-04

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