CN107257849A - 具有减少的染料转移性能的组合物 - Google Patents

具有减少的染料转移性能的组合物 Download PDF

Info

Publication number
CN107257849A
CN107257849A CN201680011136.XA CN201680011136A CN107257849A CN 107257849 A CN107257849 A CN 107257849A CN 201680011136 A CN201680011136 A CN 201680011136A CN 107257849 A CN107257849 A CN 107257849A
Authority
CN
China
Prior art keywords
biosurfactant
rhamnolipid
surfactant system
weight
base material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201680011136.XA
Other languages
English (en)
Other versions
CN107257849B (zh
Inventor
J·T·佩特科夫
P·S·史蒂文森
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Unilever IP Holdings BV
Original Assignee
Unilever NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Unilever NV filed Critical Unilever NV
Publication of CN107257849A publication Critical patent/CN107257849A/zh
Application granted granted Critical
Publication of CN107257849B publication Critical patent/CN107257849B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0021—Dye-stain or dye-transfer inhibiting compositions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60—Sugars; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60—Sugars; Derivatives thereof
    • A61K8/602—Glycosides, e.g. rutin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • A61K8/9728—Fungi, e.g. yeasts
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/004—Preparations used to protect coloured hair
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C11D1/06—Ether- or thioether carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/36—Anionic compounds of unknown constitution, e.g. natural products
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/046—Salts
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2041—Dihydric alcohols
    • C11D3/2044—Dihydric alcohols linear
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2079—Monocarboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2086—Hydroxy carboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/30—Amines; Substituted amines ; Quaternized amines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/36—Organic compounds containing phosphorus
    • C11D3/361—Phosphonates, phosphinates or phosphonites
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3707—Polyethers, e.g. polyalkyleneoxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
    • C11D3/3773—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines in liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/40—Dyes ; Pigments
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146—Sulfuric acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Mycology (AREA)
  • Microbiology (AREA)
  • Emergency Medicine (AREA)
  • Biotechnology (AREA)
  • Botany (AREA)
  • Molecular Biology (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)
  • Coloring (AREA)
  • Tropical Medicine & Parasitology (AREA)

Abstract

一种在暴露于含水清洁溶液期间保护着色或染色基材免受染料转移的方法，该方法包括用包含表面活性剂体系的组合物处理所述染色或着色基材的步骤，其中所述体系包含总表面活性剂体系的50‑100重量％范围内的生物表面活性剂。

Description

具有减少的染料转移性能的组合物
技术领域
本发明涉及用于着色或染色基材(如织物和餐具)的水基处理中的染料转移减少的组合物。
背景技术
在某些洗涤情况下，染料损失或染料褪色是不希望的，例如洗涤明亮/深色的织物或染色的毛发，其中所需的染料转移到洗涤溶液中，例如在织物洗涤中，从基材转移到其它基材。
发明内容
本发明的目的是提供一种具有染料转移减少的用于个人洗澡和餐具和/或织物的手洗的组合物和方法。
根据本发明的第一方面，提供了一种在暴露于含水清洁溶液期间保护着色或染色基材免受染料转移的方法，该方法包括用含有表面活性剂体系的组合物处理染色或着色基材的步骤，其中所述表面活性剂体系包含(总表面活性剂体系的)50-100重量％范围内的生物表面活性剂。
优选地，生物表面活性剂是糖脂。
优选地，组合物中生物表面活性剂的量在总表面活性剂体系的50-100重量％的范围内。
优选地，表面活性剂体系构成组合物的唯一表面活性剂内容物。
根据本发明的另一方面，提供了包含糖脂生物表面活性剂的洗涤组合物在洗涤过程中减少从着色或染色基材的染料转移的用途。
基材优选是着色或染色的织物或硬表面或毛发。颜色/染色可以是天然的，或者可以由染料或颜料或其组合的人工着色产生。
在本发明的另一方面，提供了一种用于上述方法的清洁组合物，该组合物包含含有糖脂生物表面活性剂的表面活性剂体系，所述糖脂生物表面活性剂以所述表面活性剂体系中总表面活性剂的50-100重量％的水平存在。
优选地，组合物中生物表面活性剂的量在总表面活性剂体系的50-100重量％的范围内。优选地，表面活性剂体系构成组合物的唯一表面活性剂内容物。
优选地，糖脂生物表面活性剂包含鼠李糖脂。
糖脂生物表面活性剂优选包含槐糖脂。如果包括槐糖脂，则优选酸性形式的槐糖脂。
糖脂生物表面活性剂可以包含不同糖脂生物表面活性剂的组合。
对于鼠李糖脂，在本专利说明书通篇中，分别使用前缀单和二表示单鼠李糖脂(具有单个鼠李糖糖环)和二鼠李糖脂(具有两个鼠李糖糖环)。如果使用缩写，R1是单鼠李糖脂，R2是二鼠李糖脂。优选地，R1：R2的比率使得按比例R2总是大于R1，更优选的是鼠李糖脂100重量％是R2。
优选地，糖脂以表面活性剂组合的75-95重量％存在。
最优选地，糖脂生物表面活性剂是以75-95重量％存在的鼠李糖脂。
表面活性剂组合优选包含合成阴离子表面活性剂。“阴离子表面活性剂”在本文中定义为包含一个或多个官能团的两亲分子，当在正常洗涤pH为4-11的水溶液中时，其呈现净阴离子电荷。
优选地，有机硫反应产物的碱金属盐在其分子结构中具有含有约6-24个碳原子、更优选大于12个碳原子的烷基部分，优选还包括选自磺酸酯和硫酸酯部分的部分。另外或替代地，阴离子表面活性剂优选具有低水平的乙氧基化，优选每分子包含1-12个、更优选1-3个、甚至更优选1个环氧乙烷单元。环氧乙烷的单元可以是平均值。
为制剂科学家提供使用更长的碳链长度和/或较低乙氧基化水平的自由是非常有益的，特别是考虑到成本。然而，这些因素增加了钙不耐受性，因此这种表面活性剂是本发明的有利选择。
尽管可以使用下文所述的任何阴离子表面活性剂，例如伯烷基硫酸盐(PAS)如十二烷基硫酸钠(SLS)和如烷基醚硫酸盐如月桂基醚硫酸钠(SLES)、皂、脂肪酸酯磺酸盐、脂肪酸硫酸盐或磺酸盐；烷基苯磺酸盐(LAS)、磺基琥珀酸酯、烯烃磺酸盐、链烷烃磺酸盐和有机磷酸盐；脂肪醇硫酸盐；烷基酚醚硫酸盐；脂肪酰基羟乙基磺酸盐产物，该产物包含脂肪酰基羟乙基磺酸盐和游离脂肪酸和/或脂肪酸盐；烷基磺酸盐如烷基磺酸钠。优选的阴离子表面活性剂是上述的碱(例如铵或三乙铵)和碱土金属盐。来源油/醇可以是植物或动物例如椰子或棕榈或牛油等衍生的。
表面活性剂体系以3-85重量％、优选3-60重量％、更优选3-40重量％、最优选3-35重量％的水平存在于织物或硬表面洗涤组合物中。
表面活性剂体系以5-60％、优选10-40％的表面活性剂水平存在于个人(人皮肤和头发)洗涤组合物中，而化妆品组合物不需要包含任何表面活性剂，但优选包含1-30重量％，更优选1-15重量％的表面活性剂。
本发明的组合物可以包含下文所述的其它成分。
手洗和织物清洁组合物可以包含实质为聚酯的污垢释放聚合物、助水溶剂、遮光剂、着色剂、其它酶、其它表面活性剂，例如非离子、阳离子和/或两性表面活性剂、成分例如香料或护理添加剂的微胶囊、软化剂、用于防止污垢再沉积的聚合物、漂白剂、漂白活化剂和漂白催化剂、抗氧化剂、pH控制剂和缓冲剂、增稠剂、用于流变改性的外部结构化剂、可视化剂、其中含有或不含有嵌入的功能成分和本领域技术人员已知的其它成分。
本发明的组合物包含可倾倒的液体，并且优选具有在Haake RotoviscometerRV20中剪切速率为10s@-1和25℃下测量的250-100,000mPa·s(cP)的粘度。
洗发组合物优选在5000-8000cp的范围内。
本发明的组合物可以配制成用于洗涤织物、皮肤或毛发的产品，并且可以包括可冲洗、可擦拭掉和免洗(leave-on)护理产品。
组合物优选是液体、凝胶，但也可以是自由流动的颗粒、糊剂或片剂。
具体实施方式
将参照以下非限制性实施例进一步描述本发明。
示例性洗衣配方
实施例1和2
对于实施例1和2的备注：
OOA是制备制剂时的添加顺序；
Tinopal CBS SP浆料33，二苯乙烯基联苯衍生物CAS号：27344-41-8；
Acusol 820，丙烯酸与C18的共聚物，具有EO20C18侧链，MW约为500,000；
Prifac 5908是氢化顶部棕榈仁脂肪酸＝；
Dequest 2010是1-羟基亚乙基-1,1-二膦酸HEDP；
Sokolan HP20是乙氧基化聚乙烯亚胺；
Neodol 25-7是伯C12-C15醇乙氧基化物，每摩尔醇平均含有7摩尔环氧乙烷；
Acusol 820是疏水改性的碱溶性丙烯酸聚合物乳液；
EU LAS是直链烷基苯磺酸盐；
SLES 3EO是月桂基醚硫酸钠，每摩尔月桂基硫酸钠平均分布3摩尔环氧乙烷；
鼠李糖脂JBR 425是单鼠李糖脂和二鼠李糖脂的混合物，其中单鼠李糖脂的IUPAC名称为3-[3-[(2R,3R,4R,5R,6S)-3,4,5-三羟基-6-甲基氧杂环己烷(oxan)-2-基]氧癸酰氧基]癸酸，二鼠李糖脂是3-[3-[4,5-二羟基-6-甲基-3-(3,4,5-三羟基-6-甲基氧杂环己烷-2-基)氧基氧杂环己烷-2-基]氧癸酰氧基]癸酸；
Soladona 2012是IFF提供的香料；
Accusol OP301＝作为乳液提供的遮光剂。
实施例3-6毛发组合物
1脂肪酰基羟乙基磺酸盐产品是联合利华公司内部生产的椰油酰羟乙基磺酸钠、硬脂酸、椰子脂肪酸、羟乙基磺酸钠和水；
2来自Wacker和Dow的硅氧烷乳液混合物；
3使用Brookfield粘度计在30℃和20rpm下使用转子N5测量制剂的粘度；所有这些都在5000-8000Cp之间；
4生物表面活性剂是鼠李糖脂JBR425(CAS号147858-26-2)，来自JeneilBiosurfactant Co.,LLC。
实验
进行以下实验以通过溶液中不同表面活性剂体系评估染发剂从染色毛样中的去除。
方法
该方法测量上清液在溶液中染料浓度对应的波长处的吸光度。将染色的假发在各种洗涤剂溶液中浸泡后制备上清液，洗涤剂溶液在对照测试中由存在或不存在生物表面活性剂制成。吸光度越低，上清液中残留的染料量越少，由此表明染料从毛样中的去除越少。
材料
SLES-1EO-Texapon N71-Shell
JBR425-鼠李糖脂-Jeneil
根据International Colour Chart(ICC)，具有1级色调(shade)(黑色)或2级色调(最深棕色)的永久毛发着色剂。
色差法
将2.5g之前漂白的6”假发*使用市售的永久着色剂进行染色；
将10g着色剂应用于假发上，用刷子摩擦30秒，直到颜色均匀分布；
然后将假发放置35分钟，然后在受控温度(37℃)和流速(4L/min)下漂洗2分钟；
将150g生物表面活性剂和/或合成的表面活性剂溶液或(如标题表面活性剂的结果部分中概述的)组合以1％w/w制备，然后将假发置于表面活性剂溶液中并在环境温度下保持1小时。
1小时后，将假发从表面活性剂中取出。然后将所得溶液的样品加入比色皿中，并用Jasco 600UV光谱仪在522nm的设定波长下测量吸光度。
*假发的准备-漂白
所需设备：
L'Oreal Platine精密粉末漂白剂
Excel Crème Peroxide-9体积％
着色碗
着色刷
铝箔
停表
使用流量/温度被控制的水龙头进行所有冲洗和洗涤。流速设定为4升/分钟，温度设定为35℃～40℃。
第一次漂白应用...
1.在足够大的板凳上放置四张铝箔，允许假发被包裹在箔中，一旦应用漂白剂就显色；
2.称量漂白粉至着色碗中。
3.通过将其轻轻倒入粉末中使粉末完全被淹没称量过氧化物膏料。使用设有搅拌器的IKA-WERKEEurostar Power Control-Visc顶置搅拌器将其混合成奶油稠度。以400rpm混合60秒。着色碗必须牢固地平放在适当位置。确保没有结块，因为这将使假发上的颜色不均匀。混合物一旦准备好就必须立即使用。
4.在箔片上将毛发之一(以扇形)展开。
5.用着色刷涂上漂白混合物。通过转动确保毛发的均匀覆盖，并将漂白剂应用于每侧两次，；
侧面1应用45秒，翻转；
侧面2应用45秒，翻转；
侧面1应用45秒，翻转；
侧面2应用45秒。
6.将头发纤维放在一起，使假发保持正常形状，将假发包裹在铝箔中并在环境温度下显色30分钟。请注意假发需要在铝箔顶部使用永久标记进行冲洗的时间。
7.用剩余的假发重复。
8.当显色时间结束时，从箔上取下假发并在水龙头下冲洗2分钟，每20秒使手指捋顺毛发。
头发必须完全冲洗干净。如果有漂白剂留下，它将继续显色。
9.将假发放在水槽边缘并使用MatadorSawcut 4号梳的宽齿；仔细梳理假发中的缠结。从尖端开始并缓慢地整理到根部。一旦梳理出所有的缠结，即用梳子的窄齿完成。
10.使拇指和中指捋顺假发，并在环境温度下干燥过夜。
第二次漂白应用...重复上述步骤1-10，一次完成洗涤并彻底冲洗假发以除去任何残留的漂白剂。
结果
数据显示，在该过程结束时，对于SLES基表面活性剂体系，从染色假发释放到溶液中的染料的量明显更大。在用鼠李糖脂的毛发洗涤过程中，用鼠李糖脂代替SLES可显著减少从毛发损失的染料的量，从而增加染发剂的使用寿命。

Claims (15)

1.一种在暴露于含水清洁溶液期间保护着色或染色基材免受染料转移的方法，所述方法包括用含有表面活性剂体系的组合物处理所述染色或着色基材的步骤，其中所述表面活性剂体系包含总表面活性剂体系的50-100重量％范围内的生物表面活性剂。
2.根据权利要求1所述的方法，其中所述方法还包括将染料应用到所述基材的步骤。
3.根据权利要求1或权利要求2所述的方法，其中所述方法包括在冲洗之前将包含所述组合物的含水溶液应用到所述基材1分钟至2小时的时间段的步骤。
4.一种染色基材的方法，所述方法包括以下步骤：
a.将染料应用到所述基材，和
b.向所述基材应用包含表面活性剂体系的组合物，所述表面活性剂体系包含相对于总表面活性剂体系50-100重量％的生物表面活性剂。
5.根据权利要求3或4所述的方法，其中步骤b在步骤a之后。
6.根据权利要求3-5中任一项所述的方法，其还包括使用水从所述基材冲洗所应用的染料和/或生物表面活性剂的步骤。
7.根据前述权利要求中任一项所述的方法，其中所述基材是织物和/或人发。
8.根据前述权利要求中任一项所述的方法，其中所述生物表面活性剂包含鼠李糖脂或槐糖脂。
9.根据权利要求8所述的方法，其中所述鼠李糖脂包含一定比率的单鼠李糖脂：二鼠李糖脂(R1：R2)，使得按重量比例R2总是大于R1。
10.根据权利要求9所述的方法，其中所述鼠李糖脂是100重量％的二鼠李糖脂(R2)。
11.包含糖脂生物表面活性剂的洗涤组合物在洗涤过程中减少从着色或染色基材的染料转移的用途。
12.根据权利要求11所述的用途，其中所述基材是人发和/或织物。
13.用于前述权利要求中任一项的清洁组合物，其包含表面活性剂体系，所述表面活性剂体系含有在所述表面活性剂体系中以总表面活性剂的50-100重量％存在的糖脂生物表面活性剂。
14.根据权利要求14所述的清洁组合物，其中所述糖脂生物表面活性剂是鼠李糖脂，并且鼠李糖脂是100重量％的二鼠李糖脂(R2)。
15.一种用于染发的试剂盒，其包含染料组合物和包含糖脂生物表面活性剂的组合物。
CN201680011136.XA 2015-03-02 2016-02-09 具有减少的染料转移性能的组合物 Active CN107257849B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP15157244 2015-03-02
EP15157244.3 2015-03-02
PCT/EP2016/052680 WO2016139032A1 (en) 2015-03-02 2016-02-09 Compositions with reduced dye-transfer properties

Publications (2)

Publication Number Publication Date
CN107257849A true CN107257849A (zh) 2017-10-17
CN107257849B CN107257849B (zh) 2019-09-27

Family

ID=52589310

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201680011136.XA Active CN107257849B (zh) 2015-03-02 2016-02-09 具有减少的染料转移性能的组合物

Country Status (5)

Country Link
US (1) US10487294B2 (zh)
CN (1) CN107257849B (zh)
AR (1) AR104008A1 (zh)
BR (1) BR112017018714B1 (zh)
WO (1) WO2016139032A1 (zh)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112574829A (zh) * 2019-09-29 2021-03-30 天津工业大学 一种活性染料染色棉织物的环保型皂洗剂及其制备方法与用途
WO2022011839A1 (zh) * 2020-09-27 2022-01-20 北京锐盛明杰知识产权代理有限公司 皂洗剂及其制备方法与用途
CN114025737A (zh) * 2019-06-25 2022-02-08 莱雅公司 包含生物表面活性剂和羧基甜菜碱聚合物的组合物

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3775127B1 (en) * 2018-05-17 2022-07-20 Unilever IP Holdings B.V. Cleaning composition
EP3824057B1 (en) * 2018-07-17 2023-10-18 Unilever Global IP Limited Use of a rhamnolipid in a surfactant system
EP3686265A1 (en) 2019-01-23 2020-07-29 BlueSun Consumer Brands, S.L. Detergent composition with sophorolipids
FR3136666A1 (fr) * 2022-06-20 2023-12-22 L'oreal Composition comprenant au moins un glycolipide, au moins un polymère carboxyvinylique et au moins un polymère polysaccharide à une certaine teneur

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998038270A1 (en) * 1997-02-28 1998-09-03 Henkel Corporation Dye transfer inhibition system
CN1729217A (zh) * 2002-12-23 2006-02-01 西巴特殊化学品控股有限公司 作为洗衣添加剂的疏水改性聚合物
WO2011120776A1 (en) * 2010-03-31 2011-10-06 Unilever Plc Mild to the skin, foaming detergent composition
EP2410039A1 (en) * 2010-07-22 2012-01-25 Unilever PLC Rhamnolipids with improved cleaning
CN103702656A (zh) * 2011-05-25 2014-04-02 株式会社资生堂 香波组合物
CN103797102A (zh) * 2011-09-20 2014-05-14 宝洁公司 包含含有类异戊二烯衍生的表面活性剂的可持续的表面活性剂体系的洗涤剂组合物
WO2014095367A1 (en) * 2012-12-17 2014-06-26 Unilever Plc Personal care compositions

Family Cites Families (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2182306A (en) 1935-05-10 1939-12-05 Ig Farbenindustrie Ag Polymerization of ethylene imines
US2208095A (en) 1937-01-05 1940-07-16 Ig Farbenindustrie Ag Process of producing insoluble condensation products containing sulphur and nitrogen
US2553696A (en) 1944-01-12 1951-05-22 Union Carbide & Carbon Corp Method for making water-soluble polymers of lower alkylene imines
US2806839A (en) 1953-02-24 1957-09-17 Arnold Hoffman & Co Inc Preparation of polyimines from 2-oxazolidone
BE615597A (zh) 1958-06-19
GB8727221D0 (en) 1987-11-20 1987-12-23 Unilever Plc Glycoside hydrolysis
DE4237334A1 (de) 1992-11-05 1994-05-11 Hoechst Ag Verfahren zur quantitativen Aufreinigung von Glycolipiden
US5578563A (en) 1994-08-12 1996-11-26 The Procter & Gamble Company Composition for reducing malodor impression on inanimate surfaces
US6077816A (en) 1995-08-07 2000-06-20 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Liquid cleansing composition comprising soluble, lamellar phase inducing structurant
DE19648439A1 (de) 1996-11-22 1998-05-28 Henkel Kgaa Verwendung von Mischungen aus Glycolipiden und Tensiden
US6903064B1 (en) 1999-05-26 2005-06-07 Procter & Gamble Company Detergent composition comprising polymeric suds volume and suds duration enhancers
JP2003013093A (ja) 2001-06-27 2003-01-15 Saraya Kk 低泡性洗浄剤組成物
EP1384470B2 (en) 2002-07-22 2014-09-24 Kao Corporation Skin cleansing composition
US6924256B2 (en) 2002-11-08 2005-08-02 Unilever Home & Personal Care Usa Division Of Conopco, Inc. Liquid cleansing composition having simultaneous exfoliating and moisturizing properties
BR0316878B1 (pt) 2002-12-23 2012-08-21 polìmeros hidrofobicamente modificados, produto de limpeza, formulação de processo têxtil, auxiliares de tingimento ou impressão e/ou agentes de acabamento, e método para processamento têxtil.
EP1445302B1 (en) 2003-01-28 2006-06-07 Ecover Belgium Detergent compositions
JP5384791B2 (ja) 2003-11-03 2014-01-08 チバ ホールディング インコーポレーテッド 安定化されたボディケア製品、家庭用製品、生地及び繊維
US7736525B2 (en) 2005-02-08 2010-06-15 Basf Corporation Method of making an alkoxylated polyethylenimine product
US20060183662A1 (en) 2005-02-16 2006-08-17 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Liquid cleansing composition with unique sensory properties
CN101407831A (zh) 2008-10-15 2009-04-15 辛明秀 一种大孔树脂制备鼠李糖脂的方法
DE102009046169A1 (de) 2009-10-29 2011-05-05 Henkel Ag & Co. Kgaa Rückstandsarmer Reiniger für harte Oberflächen
HRP20100108A2 (hr) 2010-03-01 2011-09-30 Piljac Goran Upotreba ramnolipida kao lijeka izbora u slučaju nuklearnih katastrofa za liječenje kombiniranih radijacijskih ozljeda i bolesti u ljudi i životinja
JP4912483B2 (ja) 2010-04-12 2012-04-11 株式会社 資生堂 濃縮液状洗浄剤組成物及びその製造方法
ES2561553T3 (es) * 2010-07-22 2016-02-26 Unilever N.V. Combinaciones de ramnolípidos y enzimas para una limpieza mejorada
ITVA20110008A1 (it) 2011-03-25 2012-09-26 Lamberti Spa Composizioni detergenti
EP2707472B1 (en) 2011-05-13 2015-07-08 Unilever PLC Aqueous concentrated laundry detergent compositions
CN104968325B (zh) 2013-01-30 2018-07-20 荷兰联合利华有限公司 具有改进的美观和感觉性质的组合物
WO2014173659A1 (en) 2013-04-25 2014-10-30 Unilever Plc Cleansing compositions with improved dispensing and suspension properties
US20180044614A1 (en) 2015-03-02 2018-02-15 Conopco, Inc., D/B/A Unilever Perfumed filled cleaning fluids

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998038270A1 (en) * 1997-02-28 1998-09-03 Henkel Corporation Dye transfer inhibition system
CN1729217A (zh) * 2002-12-23 2006-02-01 西巴特殊化学品控股有限公司 作为洗衣添加剂的疏水改性聚合物
WO2011120776A1 (en) * 2010-03-31 2011-10-06 Unilever Plc Mild to the skin, foaming detergent composition
EP2410039A1 (en) * 2010-07-22 2012-01-25 Unilever PLC Rhamnolipids with improved cleaning
CN103702656A (zh) * 2011-05-25 2014-04-02 株式会社资生堂 香波组合物
CN103797102A (zh) * 2011-09-20 2014-05-14 宝洁公司 包含含有类异戊二烯衍生的表面活性剂的可持续的表面活性剂体系的洗涤剂组合物
WO2014095367A1 (en) * 2012-12-17 2014-06-26 Unilever Plc Personal care compositions

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114025737A (zh) * 2019-06-25 2022-02-08 莱雅公司 包含生物表面活性剂和羧基甜菜碱聚合物的组合物
CN114025737B (zh) * 2019-06-25 2024-04-16 莱雅公司 包含生物表面活性剂和羧基甜菜碱聚合物的组合物
CN112574829A (zh) * 2019-09-29 2021-03-30 天津工业大学 一种活性染料染色棉织物的环保型皂洗剂及其制备方法与用途
CN112574829B (zh) * 2019-09-29 2021-11-09 天津工业大学 一种活性染料染色棉织物的皂洗剂及其制备方法与用途
WO2022011839A1 (zh) * 2020-09-27 2022-01-20 北京锐盛明杰知识产权代理有限公司 皂洗剂及其制备方法与用途

Also Published As

Publication number Publication date
BR112017018714B1 (pt) 2021-04-20
AR104008A1 (es) 2017-06-21
US10487294B2 (en) 2019-11-26
WO2016139032A1 (en) 2016-09-09
CN107257849B (zh) 2019-09-27
US20180044612A1 (en) 2018-02-15
BR112017018714A2 (pt) 2018-04-17

Similar Documents

Publication Publication Date Title
CN107257849B (zh) 具有减少的染料转移性能的组合物
CA2967514C (en) Fabric treatment composition
CN102414308B (zh) 溶剂、溶液、清洁组合物以及方法
CN103242973B (zh) 三效合一洗衣液组合物及制备方法
CN106232791A (zh) 包含烷氧基化的聚亚烷基亚胺、有机改性的硅氧烷和基于硅氧烷的稀释剂的清洁组合物
CN101772522B (zh) 缔合性增稠剂分散体
DE60316340T2 (de) Flüssige waschmittelzusammensetzung
CN105007884A (zh) 减轻角蛋白基质上的聚硅氧烷沉积损失的聚合物和方法
CN103827280A (zh) 包含特定共混比率的基于类异戊二烯表面活性剂的洗涤剂组合物
JPH01305019A (ja) 透明なシャンプー組成物
TW201717904A (zh) 頭髮用透明組合物
MX2010014388A (es) Composicion para el lavado de ropa.
BR112016013055B1 (pt) Manta que compreende uma estrutura fibrosa solúvel em água
ES2878183T3 (es) Composición cosmética sólida de tensioactivo
CN105408398A (zh) 嵌段阳离子有机聚硅氧烷
MX2010014389A (es) Composicion para el lavado de ropa.
CN106255707A (zh) 聚α‑1，3‑葡聚糖醚类作为粘度调节剂的用途
CN102660401B (zh) 加酶洗涤剂
JPS61210022A (ja) シヤンプ−組成物
CN102753671B (zh) 共聚物在具有较低泛灰倾向的液体洗涤剂中作为增稠剂的用途
BR0309939B1 (pt) Composição polimérica catiônica, seu processo de produção, e composições para condicionamento de superfícies e para tratamentos doméstico e pessoal.
CN103797101A (zh) 包含含有高度支化的基于类异戊二烯的主表面活性剂体系和其它表面活性剂的洗涤剂组合物
BRPI0809169A2 (pt) Composição de cuidado pessoal, métodos de produzir composição de cuidado pessoal, de limpar e de condicionar uma superfície queratinosa, de prevenir pele seca ou couro cabeludo sedo e de prolongar a liberação de umidade a uma superfície queratinosa, e, produto para lavagem do corpo.
JP2014009177A (ja) 毛髪洗浄剤組成物
CN104531406A (zh) 一种液体织物洗涤剂组合物及提升其护色性能的方法

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
TR01 Transfer of patent right

Effective date of registration: 20210824

Address after: Rotterdam

Patentee after: Unilever Intellectual Property Holdings Ltd.

Address before: Rotterdam

Patentee before: Netherlands Unilever Co.,Ltd.

TR01 Transfer of patent right