CN107207881A - 耐火、绝热、生态和耐腐蚀的涂料 - Google Patents

耐火、绝热、生态和耐腐蚀的涂料 Download PDF

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CN107207881A
CN107207881A CN201480084608.5A CN201480084608A CN107207881A CN 107207881 A CN107207881 A CN 107207881A CN 201480084608 A CN201480084608 A CN 201480084608A CN 107207881 A CN107207881 A CN 107207881A
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M.菲格罗阿马丁内斯
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Abstract

本发明涉及用作耐火、绝热、生态和耐腐蚀的涂料的组合物，其包括：23‑50％水、4‑20％硅藻土C110(Celite

Description

耐火、绝热、生态和耐腐蚀的涂料
发明领域
本发明涉及具有数种工业用途的绝热、耐火、耐腐蚀和生态的水性涂料组合物。
背景技术
在现有技术中存在多种涂料组合物，其可提供例如阻燃性、耐腐蚀性、耐热性、防水性或耐酸或碱性的许多性能。
例如，欧洲专利申请EP 0 583 051 A1教导了具有阻燃性、耐腐蚀性、耐热性和耐酸或碱性的水性涂料组合物，但其具有非常有限的用途以及热膨胀、热冲击、烟雾、机械性能、耐候性和环保性质，更不用说其成本高，由昂贵的原材料制成，且因其特定的和限定的组成和制造方法而需要复杂的混合技术并会产生矿物和冶金废料，所述水性涂料组合物包括在碱金属硅酸盐水溶液中的耐热金属氧化物和耐热二氧化硅或硅酸铝。
同样地，美国专利申请US 2008/0233295 A1教导了用途以及热膨胀、热冲击、烟雾、机械性能、耐候性和环保性质均非常有限的抗氧化涂料组合物，更不用说其成本高，由昂贵的原材料制成，因其特定的和限定的组成和制造方法而需要复杂的混合技术并且会产生矿物和冶金废料，所述抗氧化涂料组合物包括基于锰矿、冶金固体废料、铝粉、有机增稠剂和无机粘合剂的混合物的制成膏体(prepared paste)。
类似地，国际PCT申请WO 2005/030671教导了耐火组合物，但其具有非常有限的用途以及热膨胀、热冲击、烟雾、机械性能、耐候性和环保性质，更不用说其成本高，由昂贵的原材料制成，因其特定的和限定的组成和制造方法而需要复杂的混合技术并且会产生矿物和冶金废料，所述耐火组合物包括有机或无机纤维、粉煤灰、耐火剂和固化阻燃(fire-cured resistant)树脂。
最后，美国专利申请US 5,612,130教导了具有耐火、耐腐蚀、耐酸、耐碱、耐电解质、耐微生物或耐强热流体的多用途涂料，但其具有非常有限的用途以及热膨胀、热冲击、烟雾、机械性能、耐候性和环保性质，更不用说其成本高，由昂贵的原材料制成，因其特定的和限定的组成和制造方法而需要复杂的混合技术并且会产生矿物和冶金废料，所述多用途涂料包括耐火的氧化石墨基连续下层和包含无机疏水粉末、粘合剂、硅酮液体和挥发性有机溶剂的疏水上层。
尽管如此，现有技术中存在的所有涂料组合物均不具备环保性质，并且当涉及热膨胀、热冲击、烟雾、机械性能、耐候性和环保性质时其也不能具备高性能，更不用说如本申请中所力图保护的组合物之一那样，低成本、需要非常简单的制备技术以及廉价原材料。
发明内容
本发明涉及耐火、绝热、生态和耐腐蚀的涂料组合物。
本发明涉及包括以下的水性涂料组合物：23-50％水、4-20％硅藻土C110(Celite)、2-8％氧化锰、3-10％煅烧氧化铝、7-24％弹性丙烯酸树脂、1-4％丙烯酸增稠剂、0.3-2％氢氧化铵和5-14％陶瓷纤维。优选地，所述组合物还任选包括以下组分以提供耐火、绝热、生态和耐腐蚀性质：1-7％二氧化钛、1-9％己二醇、2-18％邻苯二甲酸二丁酯、1-9％醇酯十二(texanol)、0.7-4％杀真菌剂或0.4-3％防泡剂。
具体实施方式
本发明涉及耐火、绝热、生态和耐腐蚀的涂料组合物，所述涂料组合物包括：23-50％水、4-20％硅藻土C110(Celite)、2-8％氧化锰、3-10％煅烧氧化铝、7-24％弹性丙烯酸树脂、1-4％丙烯酸增稠剂、0.3-2％氢氧化铵和5-14％陶瓷纤维。优选地，所述组合物还任选包括以下组分以提供耐火、绝热、生态和耐腐蚀的性质：1-7％二氧化钛、1-9％己二醇、2-18％邻苯二甲酸二丁酯、1-9％醇酯十二(texanol)、0.7-4％杀真菌剂或0.4-3％防泡剂。
所述耐火、绝热、生态和耐腐蚀的涂料是设计为具有广泛用途的涂料，其中无论是通过直接火焰接触还是通过液体流动或气化时均具有耐高温性和抑制高温性。
通过前述性质，所述涂料的多种用途包括：(1)耐火涂料防止火焰接触所导致的温度传递，这可归因于该涂料基于陶瓷材料开发的事实；(2)热绝缘体取代矿棉。通过所述涂料组合物，作为厚度的函数提供的绝热性质提供了极好的性能，并且，由于其低重量，其可被施加到任何类型的基材、管线涂层或管道上。由于其机械性能和腐蚀抑制，所述涂料可施加到任何类型的管道上，无论其直径多少，因为其可通过洒水法(aspersion method)施加。由此，管道被赋予更长的操作可用寿命，以及具有将提供全部前述益处的涂层。
所述涂料的物理和化学性质符合工业中的最高标准和规格，诸如ASTM C87工业标准，其涉及涂料中的氯化物含量，后者根据相应方法学得到2ppm(百万分之一)的结果。由于这些结果，当其与火焰直接或间接接触时不产生任何有害气体。
所述涂料因其组成而被认为属于腐蚀抑制剂分类。该涂料用作其所施加于其中的基材的封装剂(encapsulator)，从而通过经由不与所涂布的表面直接接触来消除元素之一(在这种情况下是氧)来破坏腐蚀三角(corrosion triangle)并阻止其经历氧化过程。
所述涂料根据ASTM E84工业标准进行评价，所述工业标准包括耐燃烧性(burnresistance)，其中需要在直接火操作中的最短时间为4小时，以通过其获得符合工业标准的的必要耐性。
本发明，遍及其组成，不含任何碱或不可生物降解的成分，因为其所有成分都是惰性矿物，因此可迅速融入环境中，并且出于此原因而被认为是可生物降解的。
所述涂料作为热绝缘体不允许其所施加于其中的元件发生膨胀或收缩从而避免在覆盖层中的裂缝。
所述涂料组合物也是可生物降解的，因此在溢出的情况下不会对环境造成损害，这可归因于其在水中乳化，并且不含石棉，并且对野生动物是环境友好的。
由于其低密度和低分子量，所述涂料还导致低生产成本，这可归因于使用了廉价原材料和简化混合技术。
实施例1
所述组合物得自23.17％水、4.63％硅藻土C110(Celite)、2.32％氧化锰、1.54％二氧化钛、3.09％煅烧氧化铝、1.25％己二醇、2.54％邻苯二甲酸二丁酯、1.25％醇酯十二(texanol)、7.72％弹性丙烯酸树脂、3.86％丙烯酸增稠剂、0.77％杀真菌剂、0.39％氢氧化铵、0.42％防泡剂和5.79％陶瓷纤维，其显示所述涂料具有极大的柔韧性，这可归因于其低固含量、极好的抗腐蚀性质、中等范围(fire resistance medium range)(650℃)耐火性、较小的结构重量，对于同时需要高耐候性和柔韧性的那些元件来说是理想的。
实施例2
通过重新设计涂料组合物，实现了更好的耐候性和机械性能，条件是所述组合物包括50.19％水、19.31％硅藻土C110(Celite)、7.72％氧化锰、6.95％二氧化钛、9.65％煅烧氧化铝、8.25％己二醇、17.5％邻苯二甲酸二丁酯、8.25％醇酯十二(texanol)、23.17％弹性丙烯酸树脂、1.93％丙烯酸增稠剂、3.09％杀真菌剂、1.54％氢氧化铵、2.32％防泡剂和13.51％陶瓷纤维。在该实施方式中，所述组合物显示，该涂料具有更好的机械性能以及耐候性、更高的操作温度、更长的连续火接触曝露时间。
实施例3
使用以下大致比例，实现了更高水平的稳定性和均匀性：38.61％水、9.65％硅藻土C110(Celite)、3.86％氧化锰、3.86％二氧化钛、3.86％煅烧氧化铝、3.86％己二醇、7.65％邻苯二甲酸二丁酯、3.86％醇酯十二(texanol)、15.44％弹性丙烯酸树脂、2.70％丙烯酸增稠剂、2.32％杀真菌剂、0.77％氢氧化铵、1.54％防泡剂和9.65％陶瓷纤维。通过使用这些组分百分比，得到了如下的设计质量：更长时间的耐火，不允许吸收环境中湿气的拒水材料，在封装原理下阻止氧化发生，阻止温度传递，并且防白蚁。由于其硬度，在与火焰接触时没有烟雾生成，并且当打开或使用其时没有味道/气味散发，具有高于900℃的耐热性和低结构重量。
实施例4
当陶瓷纤维比变化时，经历传热百分比的升高和降低，同时涂料仍保持稳定。在这种情况下，同样地，耐热冲击性升高或降低其操作范围。所述质量在制造或生产过程中用于操作部件，该部件因其低重量和宽操作范围而被置于操作中心，从而在操作中心内减少传热并优化效率，消除传统的绝热体积。
实施例5
使用以下大致比例，得到基本固体形式的防水产物：37.62％水、7.83％硅藻土C110(Celite)、3.76％二氧化钛、3.76％煅烧氧化铝、3.86％己二醇、7.65％邻苯二甲酸二丁酯、3.86％醇酯十二(texanol)、15.44％弹性丙烯酸树脂、2.70％丙烯酸增稠剂、2.32％杀真菌剂、0.77％氢氧化铵、1.54％防泡剂和9.65％陶瓷纤维。
在本发明的用作涂料的组合物的许多用途中，人们可发现其在包括采矿、航空、油气、建筑、海洋、医药等的多种工业中用于施加到任何类型的表面上，诸如金属、混凝土、木、干墙及其衍生物、塑料、玻璃等……。

Claims (7)

1.用作耐火、绝热、生态和耐腐蚀的涂料的组合物，包括：
23-50％水，
4-20％硅藻土C110(Celite)，
2-8％氧化锰，
3-10％煅烧氧化铝，
7-24％弹性丙烯酸树脂，
1-4％丙烯酸增稠剂，
0.3-2％氢氧化铵和
5-14％陶瓷纤维。
2.根据权利要求1所述的组合物，还包括1-7％二氧化钛。
3.根据权利要求1所述的组合物，还包括1-9％己二醇。
4.根据权利要求1所述的组合物，还包括2-18％邻苯二甲酸二丁酯。
5.根据权利要求1所述的组合物，还包括1-9％醇酯十二(texanol)。
6.根据权利要求1所述的组合物，还包括0.7-4％杀真菌剂。
7.根据权利要求1所述的组合物，还包括0.4-3％防泡剂。
CN201480084608.5A 2014-12-16 2014-12-16 耐火、绝热、生态和耐腐蚀的涂料 Pending CN107207881A (zh)

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