CN107207649B - 不相容催化剂之间的转换方法 - Google Patents

不相容催化剂之间的转换方法 Download PDF

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CN107207649B
CN107207649B CN201580075645.4A CN201580075645A CN107207649B CN 107207649 B CN107207649 B CN 107207649B CN 201580075645 A CN201580075645 A CN 201580075645A CN 107207649 B CN107207649 B CN 107207649B
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catalyst
reactor
zone
compound
carbon atoms
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CN107207649A (zh
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Y·巴纳特
A·H·阿尔-汉迈迪
S·费尔拉希
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SABIC Global Technologies BV
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/34—Polymerisation in gaseous state
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/0015—Feeding of the particles in the reactor; Evacuation of the particles out of the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/01—Processes of polymerisation characterised by special features of the polymerisation apparatus used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C08F2/42—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation using short-stopping agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/02—Halogenated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/17—Amines; Quaternary ammonium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00743—Feeding or discharging of solids
    • B01J2208/00752—Feeding

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CN201580075645.4A 2014-12-22 2015-12-22 不相容催化剂之间的转换方法 Active CN107207649B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP14199694.2 2014-12-22
EP14199694 2014-12-22
PCT/EP2015/080946 WO2016102548A1 (en) 2014-12-22 2015-12-22 Process for transitioning between incompatible catalysts

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CN107207649A CN107207649A (zh) 2017-09-26
CN107207649B true CN107207649B (zh) 2020-06-23

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US (1) US9944727B2 (https=)
EP (1) EP3237459B1 (https=)
JP (1) JP6761810B2 (https=)
KR (1) KR102554874B1 (https=)
CN (1) CN107207649B (https=)
BR (1) BR112017013272A2 (https=)
EA (1) EA032875B1 (https=)
SA (1) SA517381799B1 (https=)
WO (1) WO2016102548A1 (https=)

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* Cited by examiner, † Cited by third party
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EP3394111B1 (en) * 2015-12-22 2019-08-28 SABIC Global Technologies B.V. Process for transitioning between incompatible catalysts
RU2736067C2 (ru) 2016-04-20 2020-11-11 ЮНИВЕЙШН ТЕКНОЛОДЖИЗ, ЭлЭлСи Модификатор индекса текучести полимера
CN109937213B (zh) * 2016-09-08 2021-03-02 Sabic环球技术有限责任公司 通过不连续添加热失控减少剂制备聚烯烃的方法
EP3728459B1 (en) * 2017-12-22 2023-11-15 SABIC Global Technologies B.V. Polypropylene composition for tapes
KR102060531B1 (ko) * 2018-07-20 2020-02-11 금호석유화학 주식회사 고무 조성물의 제조방법
KR102778829B1 (ko) * 2019-11-29 2025-03-12 롯데케미칼 주식회사 폴리올레핀 제조방법
CN116457086A (zh) * 2020-11-17 2023-07-18 埃克森美孚化学专利公司 气相反应器启动方法
CN114621370B (zh) * 2020-12-10 2023-11-28 中国石油天然气股份有限公司 一种气相法聚乙烯钛系向铬系催化剂在线快速切换方法
CN114621371B (zh) * 2020-12-10 2023-11-28 中国石油天然气股份有限公司 气相法聚乙烯茂金属催化剂向铬系催化剂在线快速切换方法
CN114621369B (zh) * 2020-12-10 2023-11-28 中国石油天然气股份有限公司 乙烯气相聚合牌号切换剂及其制备方法
WO2022232760A1 (en) * 2021-04-30 2022-11-03 Exxonmobil Chemical Patents Inc. Processes for transitioning between different polymerization catalysts in a polymerization reactor
CN113578205B (zh) * 2021-09-29 2021-12-03 东营科宏化工有限公司 邻叔丁基环己醇制备用催化剂的添加装置及添加方法
CN117567675B (zh) * 2024-01-16 2024-04-23 新疆独山子石油化工有限公司 一种铬系聚乙烯转产茂金属聚乙烯的生产方法
CN117567676B (zh) * 2024-01-16 2024-04-16 新疆独山子石油化工有限公司 一种钛系聚乙烯转产茂金属聚乙烯的生产方法
CN119306873B (zh) * 2024-12-16 2026-01-23 新疆独山子石油化工有限公司 减少钛系聚乙烯转产聚烯烃弹性体中过渡料的生产方法
CN119306870A (zh) * 2024-12-16 2025-01-14 新疆独山子石油化工有限公司 铬系聚乙烯转产聚烯烃弹性体的生产方法

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JP2018502210A (ja) 2018-01-25
KR20170109547A (ko) 2017-09-29
EP3237459B1 (en) 2019-01-30
EP3237459A1 (en) 2017-11-01
SA517381799B1 (ar) 2021-04-01
US9944727B2 (en) 2018-04-17
EA201791431A1 (ru) 2018-01-31
WO2016102548A1 (en) 2016-06-30
US20170342174A1 (en) 2017-11-30
BR112017013272A2 (pt) 2018-01-09
JP6761810B2 (ja) 2020-09-30
EA032875B1 (ru) 2019-07-31
CN107207649A (zh) 2017-09-26
KR102554874B1 (ko) 2023-07-12

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