CN107200430A - A kind of processing method for biogas slurry of raising pigs - Google Patents

A kind of processing method for biogas slurry of raising pigs Download PDF

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Publication number
CN107200430A
CN107200430A CN201710337116.8A CN201710337116A CN107200430A CN 107200430 A CN107200430 A CN 107200430A CN 201710337116 A CN201710337116 A CN 201710337116A CN 107200430 A CN107200430 A CN 107200430A
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biogas slurry
processing
pond
raising pigs
processing method
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CN107200430B (en
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谢新昇
盛开洋
宋昊
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Anhui tiechong Agricultural Technology Development Co.,Ltd.
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谢新昇
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/281Treatment of water, waste water, or sewage by sorption using inorganic sorbents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/30Treatment of water, waste water, or sewage by irradiation
    • C02F1/32Treatment of water, waste water, or sewage by irradiation with ultraviolet light
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/50Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/105Phosphorus compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/16Nitrogen compounds, e.g. ammonia
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/32Biological treatment of water, waste water, or sewage characterised by the animals or plants used, e.g. algae
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/34Biological treatment of water, waste water, or sewage characterised by the microorganisms used
    • C02F3/342Biological treatment of water, waste water, or sewage characterised by the microorganisms used characterised by the enzymes used

Abstract

The invention discloses a kind of processing method for biogas slurry of raising pigs, belong to pig biogas slurry treatment technical field.Pig biogas slurry is filtered to obtain filtered fluid by the present invention, stirred after limestone powder mixing, then with AEO, through standing, filtering to get filtrate, with being stood after the native mixed aeration of self-control processing, standing terminates, and is implanted into Eichhornia crassipes, plants and is removed after certain moon number, residue is filtered into obtain filter residue and filtered fluid again, filter residue natural drying is obtained and discharged after soil enrichment material, filtered fluid sterilizing, you can complete the processing to biogas slurry of raising pigs.The beneficial effects of the invention are as follows:Processing method of the present invention is simple, and operating cost is low, operation controllability is strong, has preferable removal effect to the nitrogen in biogas slurry, phosphorus.

Description

A kind of processing method for biogas slurry of raising pigs
Technical field
The invention belongs to technical field of waste water processing, and in particular to a kind of processing method of pig biogas slurry.
Background technology
With expanding economy, people's living standard is improved constantly, and the especially pig industry of China's animal husbandry in recent years is obtained Develop rapidly, environment and health are caused sternly while solving animal products supply and driving rural economic development Ghost image rings.If pig biogas slurry is not dealt carefully with, nitrogen therein, phosphorus and organic matter etc. can cause such as water eutrophication The environmental problems such as change, underground water pollution.Pig biogas slurry is mainly handled by way of anaerobic fermentation, at anaerobism Contain a large amount of hardly degraded organic substances in biogas slurry after reason, and its nitrogen and phosphorus content is high, carbon-nitrogen ratio is relatively low, therefore when using catalytic oxidation During these traditional method of wastewater treatment such as method, SBR methods, oxidation ditch process, treatment effect is not ideal, and has operation unstable Fixed, operating cost is higher, while the also COD containing higher concentration in biogas slurry(500~2500mg/L), total phosphorus etc.(5~30mg/ L)Deng polluter, these polluters will influence agricultural development and the life of environmental quality and people.Membrane bioreactor (MBR)Floor space is small, high treating effect, stable, and microorganism can be retained, so that ensure the security of water outlet, And also there is preferable degradation effect to hardly degraded organic substance, but cause absorption contact scar using rear easy blocking fenestra.
The processing method for biogas slurry of raising pigs also has following several, such as use artificial swamp method, A/O-MBR methods, bird at present The tupes such as coprolite crystallisation.But these methods are because operating cost is too high and operates the features such as controllability is poor at present, It is difficult to promote in raiser, and these methods are poor for the nitrogen in biogas slurry, phosphorus ligands effect.Therefore, for new pig natural pond The research of liquid treatment technology is necessary.
How a kind of pig biogas slurry treatment side that operates controllability good, to nitrogen in biogas slurry, phosphorus ligands effect good is realized Method is technical problem urgently to be resolved hurrily in the industry.
The content of the invention
The technical problems to be solved by the invention:It is poor for tradition pig biogas slurry treatment method operation controllability, it is difficult to Raiser promote, and to the nitrogen in biogas slurry, phosphorus ligands effect is poor the drawbacks of there is provided it is a kind of raise pigs biogas slurry processing side Method.
In order to solve the above technical problems, the present invention is using technical scheme as described below:
A kind of processing method for biogas slurry of raising pigs, it is characterised in that specifically process step is:
(1)In mass ratio 2:1, take meal wheat stone and sepiolite to be put into calcining furnace, design temperature is 1300~1400 DEG C, calcining 1 ~3h, collects calcined material, and is put into pulverizer and is crushed, and crushed material is crossed into 100 mesh sieves, collects the particle that sieves;
(2)Pond Silt is taken to carry out natural drying, it is 50~55% to dry to water content, collects the Pond Silt after drying, presses Parts by weight meter, takes the Pond Silt after 70~90 parts of dryings, 35~40 portions of above-mentioned sieving particles, 30~32 portions of soybean respectively Root, 18~22 parts of sodium humates and 10~13 parts of peat are put into mixer, and 20~30min is stirred with 200r/min, and collection is stirred Mix mixture, you can soil must be handled, it is standby;
(3)Take pig biogas slurry and limestone powder to be put into container, and container is heated, be heated to 60~70 DEG C, stirring After 30~50min, 45~50 DEG C are cooled to, then AEO is added into container, continues to stir 5~10min, it is quiet Put, the mixture in container is filtered, collect filtrate;
(4)Standby processing soil and filtrate are put into processing pond, stirred, control process pond internal temperature is 20~25 DEG C, Air is passed through from processing pond bottom, ventilation stops ventilation after 2~3 days, stands 4~6 days;
(5)Eichhornia crassipes seed is implanted into processing pond, implantation amount is at 12~15 Eichhornia crassipes seeds of every square metre of implantation, control It is 20~23 DEG C to manage the temperature in pond, is planted 3~5 months, the Eichhornia crassipes in removal processing;
(6)After Eichhornia crassipes removal, the residue in processing pond is filtered, filtered fluid and filter residue is collected, filter residue is natural It is 20~25% to dry to water content, collects and dries thing, obtains soil enrichment material, then by filtered fluid by ultraviolet radiation for sterilizing and disinfecting, Discharged, you can complete the processing to biogas slurry of raising pigs.
The step(1)The mass ratio of middle pig biogas slurry and limestone powder is 4:1~6:1.
The step(1)The addition of middle AEO is the 7~9% of pig biogas slurry quality.
The step(2)Native and filtrate the mass ratio of middle processing is 1:3~1:5.
The step(2)In be passed through air throughput be 0.8~1.3m3/h。
The present invention is compared with other method, and advantageous effects are:
(1)The present invention is adsorbed using the sepiolite of water imbibition to pig biogas slurry, by the bactericidal properties and adsorptivity of meal wheat stone, The absorption of the material such as sterilization processing and N P and K is carried out to pig biogas slurry, while using the microorganism in Pond Silt to sepiolite And meal wheat stone carries out bio-modification, change internal structure, the enzyme material produced using sepiolite and meal wheat stone absorption microorganism, Using the high bioactivity of meal wheat stone, the activity of enzyme is improved, and then increase the treatment effeciency to biogas slurry of raising pigs;
(2)The present invention makes full use of gained filter residue after biogas slurry treatment that soil enrichment material is made, and effectively realizes the recycling of resource;
(3)Operation controllability of the present invention is strong, good to pig biogas slurry treatment effect, has preferable removal to the nitrogen in biogas slurry, phosphorus Effect.
Embodiment
Handle the preparation of soil:In mass ratio 2:1, take meal wheat stone and sepiolite to be put into calcining furnace, design temperature is 1300 ~1400 DEG C, 1~3h is calcined, calcined material is collected, and is put into pulverizer and is crushed, crushed material is crossed into 100 mesh sieves, collected Sieve particle;Pond Silt is taken to carry out natural drying, it is 50~55% to dry to water content, collects the Pond Silt after drying, presses Parts by weight meter, takes the Pond Silt after 70~90 parts of dryings, 35~40 parts of sieving particles, 30~32 parts of Soybean Roots, 18 respectively ~22 parts of sodium humates and 10~13 parts of peat are put into mixer, and 20~30min is stirred with 200r/min, collect stirring mixing Thing, you can soil must be handled.
The processing for biogas slurry of raising pigs:In mass ratio 4:1~6:1, take pig biogas slurry and 150 mesh limestone powders to be put into container In, and container is heated, be heated to 60~70 DEG C, 30~50min is stirred with 150r/min, be cooled to 45~50 DEG C, then The AEO of pig biogas slurry quality 7~9% is added into container, continues to stir after 5~10min, standing 3~ 5h, is then filtered to the mixture in container, collects filtrate;In mass ratio 1:3~1:5, take processing soil and filtrate to be put into In processing pond, stir, control process pond internal temperature is 20~25 DEG C, air, control ventilation are passed through from processing pond bottom Measure as 0.8~1.3m3/ h, ventilation stops ventilation after 2~3 days, stands 4~6 days;Eichhornia crassipes seed is implanted into processing pond, is planted It is 20~23 DEG C to enter amount for every square metre of temperature being implanted into 12~15 Eichhornia crassipes seeds, control process pond, plants 3~5 Month, the Eichhornia crassipes in removal processing;Eichhornia crassipes removal after, the residue in processing pond is filtered, collect filtered fluid with Filter residue, is 20~25% by filter residue natural drying to water content, collects and dry thing, obtain soil enrichment material, then filtered fluid is passed through Ultraviolet radiation for sterilizing and disinfecting, is discharged, you can complete the processing to biogas slurry of raising pigs.
Example 1
Handle the preparation of soil:In mass ratio 2:1, take meal wheat stone and sepiolite to be put into calcining furnace, design temperature is 1300 DEG C, is forged 1h is burnt, calcined material is collected, and is put into pulverizer and is crushed, crushed material is crossed into 100 mesh sieves, the particle that sieves is collected;Take pond Mud carries out natural drying, and it is 50% to dry to water content, collects the Pond Silt after drying, counts, take respectively by weight Pond Silt, 35 parts of sieving particles, 30 parts of Soybean Roots, 18 parts of sodium humates and 10 parts of peat after 70 parts of dryings are put into mixer In, 20min is stirred with 200r/min, stirring mixture is collected, you can soil must be handled.
The processing for biogas slurry of raising pigs:In mass ratio 4:1, take pig biogas slurry and 150 mesh limestone powders to be put into container, and it is right Container is heated, and is heated to 60 DEG C, and 30min is stirred with 150r/min, is cooled to 45 DEG C, then the addition pig biogas slurry into container The AEO of quality 7%, continues to stir after 5min, stands 3h, then the mixture in container is filtered, Collect filtrate;In mass ratio 1:3, take processing soil and filtrate to be put into processing pond, stir, control process pond internal temperature is 20 DEG C, air is passed through from processing pond bottom, it is 0.8m to control throughput3/ h, ventilation stops ventilation after 2 days, stands 4 days;To place Reason pond is implanted into Eichhornia crassipes seed, and implantation amount is that the temperature in 12 Eichhornia crassipes seeds of every square metre of implantation, control process pond is 20 DEG C, plant 3 months, the Eichhornia crassipes in removal processing;After Eichhornia crassipes removal, the residue in processing pond is filtered, Filtered fluid and filter residue are collected, is 20% by filter residue natural drying to water content, collects and dry thing, soil enrichment material is obtained, then incited somebody to action Filtrate is discharged by ultraviolet radiation for sterilizing and disinfecting, you can complete the processing to biogas slurry of raising pigs.
Soil enrichment material is made in gained filter residue after biogas slurry treatment in this example, and the nitrogen content of fertilizer is 4.9%, and phosphorus content is 4.9%, potassium content 3.7%.
Table one:
Pig biogas slurry COD(mg/L) Ammonia nitrogen(mg/L) Total phosphorus(mg/L) Total nitrogen(mg/L)
Before processing pig biogas slurry water quality 350 420 60 460
Pig biogas slurry water quality after processing 12.3 0.121 0.21 0.69
Example 2
Handle the preparation of soil:In mass ratio 2:1, take meal wheat stone and sepiolite to be put into calcining furnace, design temperature is 1350 DEG C, is forged 2h is burnt, calcined material is collected, and is put into pulverizer and is crushed, crushed material is crossed into 100 mesh sieves, the particle that sieves is collected;Take pond Mud carries out natural drying, and it is 53% to dry to water content, collects the Pond Silt after drying, counts, take respectively by weight Pond Silt, 38 parts of sieving particles, 31 parts of Soybean Roots, 20 parts of sodium humates and 11 parts of peat after 80 parts of dryings are put into mixer In, 25min is stirred with 200r/min, stirring mixture is collected, you can soil must be handled.
The processing for biogas slurry of raising pigs:In mass ratio 5:1, take pig biogas slurry and 150 mesh limestone powders to be put into container, and it is right Container is heated, and is heated to 65 DEG C, and 40min is stirred with 150r/min, is cooled to 48 DEG C, then the addition pig biogas slurry into container The AEO of quality 8%, continues to stir after 8min, stands 4h, then the mixture in container is filtered, Collect filtrate;In mass ratio 1:4, take processing soil and filtrate to be put into processing pond, stir, control process pond internal temperature is 23 DEG C, air is passed through from processing pond bottom, it is 1.1m to control throughput3/ h, ventilation stops ventilation after 3 days, stands 5 days;To place Reason pond is implanted into Eichhornia crassipes seed, and implantation amount is that the temperature in 13 Eichhornia crassipes seeds of every square metre of implantation, control process pond is 21 DEG C, plant 4 months, the Eichhornia crassipes in removal processing;After Eichhornia crassipes removal, the residue in processing pond is filtered, Filtered fluid and filter residue are collected, is 23% by filter residue natural drying to water content, collects and dry thing, soil enrichment material is obtained, then incited somebody to action Filtrate is discharged by ultraviolet radiation for sterilizing and disinfecting, you can complete the processing to biogas slurry of raising pigs.
Soil enrichment material is made in gained filter residue after biogas slurry treatment in this example, and the nitrogen content of fertilizer is 5.1%, and phosphorus content is 5.2%, potassium content 3.9%.
Table two:
Pig biogas slurry COD(mg/L) Ammonia nitrogen(mg/L) Total phosphorus(mg/L) Total nitrogen(mg/L)
Before processing pig biogas slurry water quality 750 850 80 880
Pig biogas slurry water quality after processing 11.0 0.086 0.18 0.58
Example 3
Handle the preparation of soil:In mass ratio 2:1, take meal wheat stone and sepiolite to be put into calcining furnace, design temperature is 1400 DEG C, is forged 3h is burnt, calcined material is collected, and is put into pulverizer and is crushed, crushed material is crossed into 100 mesh sieves, the particle that sieves is collected;Take pond Mud carries out natural drying, and it is 55% to dry to water content, collects the Pond Silt after drying, counts, take respectively by weight Pond Silt, 40 parts of sieving particles, 32 parts of Soybean Roots, 22 parts of sodium humates and 13 parts of peat after 90 parts of dryings are put into mixer In, 30min is stirred with 200r/min, stirring mixture is collected, you can soil must be handled.
The processing for biogas slurry of raising pigs:In mass ratio 6:1, take pig biogas slurry and 150 mesh limestone powders to be put into container, and it is right Container is heated, and is heated to 70 DEG C, and 50min is stirred with 150r/min, is cooled to 50 DEG C, then the addition pig biogas slurry into container The AEO of quality 9%, continues to stir after 10min, stands 5h, then the mixture in container was carried out Filter, collects filtrate;In mass ratio 1:5, take processing soil and filtrate to be put into processing pond, stir, temperature inside control process pond Spend for 25 DEG C, air is passed through from processing pond bottom, it is 1.3m to control throughput3/ h, ventilation stops ventilation after 3 days, stands 6 days; Eichhornia crassipes seed is implanted into processing pond, implantation amount is the temperature in 15 Eichhornia crassipes seeds of every square metre of implantation, control process pond Spend for 23 DEG C, plant 5 months, the Eichhornia crassipes in removal processing;After Eichhornia crassipes removal, the residue in processing pond was carried out Filter, collects filtered fluid and filter residue, is 25% by filter residue natural drying to water content, collects and dry thing, obtains soil enrichment material, then will Filtered fluid is discharged by ultraviolet radiation for sterilizing and disinfecting, you can complete the processing to biogas slurry of raising pigs.
Soil enrichment material is made in gained filter residue after biogas slurry treatment in this example, and the nitrogen content of fertilizer is 5.0%, and phosphorus content is 5.1%, potassium content 3.8%.
Table three:
Pig biogas slurry COD(mg/L) Ammonia nitrogen(mg/L) Total phosphorus(mg/L) Total nitrogen(mg/L)
Before processing pig biogas slurry water quality 1200 1100 95 1180
Pig biogas slurry water quality after processing 13.6 0.156 0.24 0.81
Above-described embodiment is not limited for the present invention preferably embodiment, but embodiments of the present invention by above-described embodiment System, other any Spirit Essences without departing from the present invention and the change made under principle, modification, replacement, combine, simplification, Equivalent substitute mode is should be, is included within protection scope of the present invention.

Claims (5)

1. a kind of processing method for biogas slurry of raising pigs, it is characterised in that specifically process step is:
(1)In mass ratio 2:1, take meal wheat stone and sepiolite to be put into calcining furnace, design temperature is 1300~1400 DEG C, calcining 1 ~3h, collects calcined material, and is put into pulverizer and is crushed, and crushed material is crossed into 100 mesh sieves, collects the particle that sieves;
(2)Pond Silt is taken to carry out natural drying, it is 50~55% to dry to water content, collects the Pond Silt after drying, presses Parts by weight meter, takes the Pond Silt after 70~90 parts of dryings, 35~40 portions of above-mentioned sieving particles, 30~32 portions of soybean respectively Root, 18~22 parts of sodium humates and 10~13 parts of peat are put into mixer, and 20~30min is stirred with 200r/min, and collection is stirred Mix mixture, you can soil must be handled, it is standby;
(3)Take pig biogas slurry and limestone powder to be put into container, and container is heated, be heated to 60~70 DEG C, stirring After 30~50min, 45~50 DEG C are cooled to, then AEO is added into container, continues to stir 5~10min, it is quiet Put, the mixture in container is filtered, collect filtrate;
(4)Standby processing soil and filtrate are put into processing pond, stirred, control process pond internal temperature is 20~25 DEG C, Air is passed through from processing pond bottom, ventilation stops ventilation after 2~3 days, stands 4~6 days;
(5)Eichhornia crassipes seed is implanted into processing pond, implantation amount is at 12~15 Eichhornia crassipes seeds of every square metre of implantation, control It is 20~23 DEG C to manage the temperature in pond, is planted 3~5 months, the Eichhornia crassipes in removal processing;
(6)After Eichhornia crassipes removal, the residue in processing pond is filtered, filtered fluid and filter residue is collected, filter residue is natural It is 20~25% to dry to water content, collects and dries thing, obtains soil enrichment material, then by filtered fluid by ultraviolet radiation for sterilizing and disinfecting, Discharged, you can complete the processing to biogas slurry of raising pigs.
2. a kind of processing method of biogas slurry of raising pigs according to claim 1, it is characterised in that:The step(1)Middle pig The mass ratio of biogas slurry and limestone powder is 4:1~6:1.
3. a kind of processing method of biogas slurry of raising pigs according to claim 1, it is characterised in that:The step(1)Middle fat The addition of alcohol APEO is the 7~9% of pig biogas slurry quality.
4. a kind of processing method of biogas slurry of raising pigs according to claim 1, it is characterised in that:The step(2)Middle processing Soil and the mass ratio of filtrate are 1:3~1:5.
5. a kind of processing method of biogas slurry of raising pigs according to claim 1, it is characterised in that:The step(2)In be passed through The throughput of air is 0.8~1.3m3/h。
CN201710337116.8A 2017-05-14 2017-05-14 Treatment method of pig raising biogas slurry Active CN107200430B (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4021966A (en) * 1975-04-15 1977-05-10 G.A. Serlachius Oy Plantcup element
CN105084440A (en) * 2015-09-11 2015-11-25 江苏振宇环保科技有限公司 Preparation method of biological particles for treating chrome-containing wastewater
CN106498534A (en) * 2016-10-20 2017-03-15 常州市鼎日环保科技有限公司 A kind of preparation method of antibacterial nylon fiber
CN106544034A (en) * 2016-10-14 2017-03-29 吴迪 A kind of preparation method of soil conditioner

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4021966A (en) * 1975-04-15 1977-05-10 G.A. Serlachius Oy Plantcup element
CN105084440A (en) * 2015-09-11 2015-11-25 江苏振宇环保科技有限公司 Preparation method of biological particles for treating chrome-containing wastewater
CN106544034A (en) * 2016-10-14 2017-03-29 吴迪 A kind of preparation method of soil conditioner
CN106498534A (en) * 2016-10-20 2017-03-15 常州市鼎日环保科技有限公司 A kind of preparation method of antibacterial nylon fiber

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