CN107188687A - A kind of liquid selenium-enriched organic fertilizer and preparation method thereof - Google Patents

A kind of liquid selenium-enriched organic fertilizer and preparation method thereof Download PDF

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Publication number
CN107188687A
CN107188687A CN201710449531.2A CN201710449531A CN107188687A CN 107188687 A CN107188687 A CN 107188687A CN 201710449531 A CN201710449531 A CN 201710449531A CN 107188687 A CN107188687 A CN 107188687A
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CN
China
Prior art keywords
selenium
organic fertilizer
liquid
enriched organic
biogas fermentation
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Pending
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CN201710449531.2A
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Chinese (zh)
Inventor
高宇江
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Inner Mongolia Xun Biotechnology Co Ltd
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Priority to CN201710449531.2A priority Critical patent/CN107188687A/en
Publication of CN107188687A publication Critical patent/CN107188687A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05BPHOSPHATIC FERTILISERS
    • C05B1/00Superphosphates, i.e. fertilisers produced by reacting rock or bone phosphates with sulfuric or phosphoric acid in such amounts and concentrations as to yield solid products directly
    • C05B1/02Superphosphates
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05CNITROGENOUS FERTILISERS
    • C05C9/00Fertilisers containing urea or urea compounds
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/60Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/80Soil conditioners
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G5/00Fertilisers characterised by their form
    • C05G5/20Liquid fertilisers

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Soil Sciences (AREA)
  • Fertilizers (AREA)

Abstract

The present invention relates to a kind of liquid selenium-enriched organic fertilizer and preparation method thereof, the sodium selenite solution of raw material volume 2% to 3% and the urea of raw material volume 1.5% to 2.5% are added in biogas fermentation material;Above-mentioned solution is uniformly mixed and stirred for biogas fermentation material in proportion, the substrate after stirring is added in methane-generating pit, the process such as fermented, stirring, precipitation, filtering prepares liquid selenium-enriched organic fertilizer.Fertilizer quality better of the present invention, nitrogen content is high, utilization rate is high, organic selenium source is provided for crops, the nutritive value of crops after selenium-rich is improved, so as to improve the benefit obtained using biogas fermentation technical finesse kitchen garbage, make using the call by pattern of biogas fermentation technical finesse kitchen garbage to promote, the reluctant problem of kitchen garbage is solved, and cost is low, simple production process.

Description

A kind of liquid selenium-enriched organic fertilizer and preparation method thereof
Technical field
The present invention relates to a kind of liquid selenium-enriched organic fertilizer and preparation method thereof, belong to selenium-rich organic fertilizer production technology neck Domain.
Background technology
Selenium is a kind of necessary trace element with physiologically active of human body, with very high value medical health care, human body Selenium deficiency can induce a variety of diseases.Selenium can strengthen immunity of organisms simultaneously, including cellular immunity, humoral immunity and non-specificity are exempted from Epidemic disease.But, the content of selenium is very dilute micro- in the earth's crust, and air and industrial pollution further destroy absorbing for Selenium By The Plants, make Obtain mankind's selenium deficiency state increasingly serious.Moreover, China's overwhelming majority area is all in poor selenium area, majority's body is interior to lack selenium member Element.Therefore, selenium-supply is particularly important for the fitness for improving our people.Domestic selenium-supply source, mainly inorganic at present Compound sodium selenite etc..This kind of product has the shortcomings that absorptivity is low, toxicity is high, thus adds inorganic in production estimation Selenium can not only reach preferable se complementary effect, and also environment can be polluted, and form potentially hazardous to human body.And pass through Selenium element is enriched in the microorganism selenium produced in the cell protein structure of microorganism, belongs to organic selenium source, human body pair is being met After the psychological need of selenium, it can also be stored in human body, it is to avoid selenium deficiency again in a short time.But, this quasi-microorganism selenium is due to life Production. art is complicated, and cost is higher, and yield is again relatively low, on the one hand can not meet the demand of people's selenium-supply, on the other hand higher valency Lattice make ordinary consumer be difficult to receive.
Kitchen garbage is the discarded object after food processing process and diet consumption.Comparison of ingredients is complicated, containing oil, water, consolidates Body residue mixing vegetables, pericarp, fruit stone, rice and flour, fish, meat, bone and useless tableware, paper handkerchief etc..Kitchen garbage content of organics height, Moisture content is high, therefore easily rotten, rotten.Leakage water meeting polluted-water, air, the influence city appearance of the city and human settlement.And eat Kitchen rubbish is the resource discarded object that can be recycled, if using appropriate processing method to it, kitchen garbage can turn waste into wealth, Turn harm into good.Biogas fermentation technology has with low cost, product resource efficiency high, it is easy to accomplish the characteristics of engineer applied, is Handle kitchen garbage at present and carry out the best-of-breed technology of resource reutilization.But, it is simple to utilize biogas fermentation technical finesse kitchen The cost of rubbish is too high, and the benefit of the generation such as biogas and biogas slurry for being produced in processing procedure is relatively low, causes to utilize biogas fermentation The pattern of technical finesse kitchen garbage can not large-scale promotion.
The content of the invention
Biogas fermentation is utilized to provide a kind of production technology simplicity, the relatively low microorganism selenium fertilizer of production cost, and improving The benefit that technical finesse kitchen garbage is obtained, the present invention provides a kind of liquid selenium-enriched organic fertilizer and preparation method thereof, uses this The liquid selenium-enriched fertilizer that method is produced, serves not only as organic fertilizer and provides the nutrients such as nitrogen, phosphorus, potassium for crops, its institute The microorganism selenium contained also provides organic selenium source for crops, while being crops increase yield, raising quality, also makes selenium-rich Corps nutrient value afterwards is higher, indirectly improves the commercial value of liquid selenium-enriched fertilizer, biogas is utilized so as to improve The benefit that fermentation technique processing kitchen garbage is obtained, makes using the call by pattern of biogas fermentation technical finesse kitchen garbage to push away Extensively, the reluctant problem of kitchen garbage is solved.
To achieve the above object, the technical solution adopted by the present invention is:
A kind of liquid selenium-enriched organic fertilizer, adds the 2.5mol/L of raw material volume 2% to 3% sodium selenite in biogas fermentation material The urea of solution and raw material volume 1.5% to 2.5%.
It can be prepared as follows:Sodium selenite solution is uniformly mixed simultaneously with biogas fermentation material in proportion with urea Stirring, the substrate after stirring is added and fermented in methane-generating pit, is fermented 20 to 25 days under conditions of 35 DEG C or so, draws natural pond Upper strata biogas slurry and it is transferred in gas pond in storage tank, adds the calcium superphosphate solution of material liquid volume 0.1% to 0.2%, add The urea liquid of material liquid volume 0.5% to 1.5%, is staticly settled 18 to 24 hours after being sufficiently stirred for, and is drawn after solution-stabilized Supernatant liquor is preserved with 150 mesh sieve net filtrations, finally sealed, obtains liquid selenium-rich organic fertilizer product.
The beneficial effects of the invention are as follows:All raw material is without noxious materials such as heavy metal cadmium, lead, arsenic, chromium, in microorganism Live body roundworm egg, Escherichia coli and other harmful bacterias have been killed in fermentation process, kitchen garbage has been solved reluctant Problem, and there is provided a kind of preparation method of microorganism selenium fertilizer.The a large amount of organic matters and humic acid contained in fertilizer, can improve soil Earth biochemical activity, improves disease-resistant crops insect prevention ability, reduces interionic antagonism, alleviates soil hardening to a certain extent Problem.The present invention can make that plant roots are deep, full of leaves, stem strong, increase crop yield;Crops can be made to be rich in needed by human body simultaneously Various nutrient elements, and help human body to supplement lacked selenium and other trace elements, improve agricultural products in China in the international market Competitiveness, increases the value of green organic farm products;The biochemical activity of soil can also be improved in addition, reduce making for chemical fertilizer Consumption, safeguards that soil ecology is balanced.
Embodiment:
Embodiment 1
A kind of liquid selenium-enriched organic fertilizer, adds the 2.5mol/L of raw material volume 2% to 3% sodium selenite in biogas fermentation material The urea of solution and raw material volume 1.5% to 2.5%.
It can be prepared as follows:Sodium selenite solution is uniformly mixed simultaneously with biogas fermentation material in proportion with urea Stirring, the substrate after stirring is added and fermented in methane-generating pit, is fermented 20 to 25 days under conditions of 35 DEG C or so, draws natural pond Upper strata biogas slurry and it is transferred in gas pond in storage tank, adds the calcium superphosphate solution of material liquid volume 0.1% to 0.2%, add The urea liquid of material liquid volume 0.5% to 1.5%, is staticly settled 18 to 24 hours after being sufficiently stirred for, and is drawn after solution-stabilized Supernatant liquor is preserved with 150 mesh sieve net filtrations, finally sealed, obtains liquid selenium-rich organic fertilizer product.
Application of the liquid selenium-enriched organic fertilizer on spring wheat, test process(With mu fertilising gauge)For:1st, control base manure is applied 25 kilograms of composite fertilizer, the jointing stage imposes 10 kilograms of urea;2nd, 5 kilograms of 25 kilograms of liquid selenium-enriched organic fertilizer and urea are used as base manure one It is secondary to apply;As a result it is as shown in table 1.
The liquid selenium-enriched organic fertilizer result of the test on spring wheat of table 1
Embodiment 2
A kind of liquid selenium-enriched organic fertilizer, adds the 2.5mol/L of raw material volume 2% to 3% sodium selenite in biogas fermentation material The urea of solution and raw material volume 1.5% to 2.5%.
It can be prepared as follows:Sodium selenite solution is uniformly mixed simultaneously with biogas fermentation material in proportion with urea Stirring, the substrate after stirring is added and fermented in methane-generating pit, is fermented 20 to 25 days under conditions of 35 DEG C or so, draws natural pond Upper strata biogas slurry and it is transferred in gas pond in storage tank, adds the calcium superphosphate solution of material liquid volume 0.1% to 0.2%, add The urea liquid of material liquid volume 0.5% to 1.5%, is staticly settled 18 to 24 hours after being sufficiently stirred for, and is drawn after solution-stabilized Supernatant liquor is preserved with 150 mesh sieve net filtrations, finally sealed, obtains liquid selenium-rich organic fertilizer product.
Application of the liquid selenium-enriched organic fertilizer on Lettuce, test process(With mu fertilising gauge)For:1st, base manure one is compareed 20 kilograms of Ci Xingshi composite fertilizers;2nd, 8 kilograms of liquid selenium-enriched organic fertilizers are added water 1.5 to 2 times of dilutions in Lettuce growth Seedling Stage Applied fertilizer afterwards with drip irrigation, after 12 kilograms of liquid selenium-enriched organic fertilizers to be added water to 0.5 to 1 times of dilution to the Lettuce plant strain growth later stage Use fertigation;As a result it is as shown in table 2.
The liquid selenium-enriched organic fertilizer result of the test on Lettuce of table 2

Claims (5)

1. a kind of liquid selenium-enriched organic fertilizer, it is characterised in that:Raw material volume 2% to 3% is added in biogas fermentation material 2.5mol/L sodium selenite solution and the urea of raw material volume 1.5% to 2.5%.
2. the preparation method of liquid selenium-enriched organic fertilizer described in a kind of claim 1, it is characterised in that:By sodium selenite solution and urine Element is uniformly mixed and stirred for biogas fermentation material in proportion, and the substrate after stirring is added in methane-generating pit, fermented, stirring, The processes such as precipitation, filtering prepare liquid selenium-enriched organic fertilizer.
3. the preparation method of liquid selenium-enriched organic fertilizer according to claim 2, it is characterised in that:The sodium selenite solution is dense Spend for 2.5mol/L.
4. the preparation method of liquid selenium-enriched organic fertilizer according to claim 2, it is characterised in that:The filter progress is used 150 eye mesh screens are filtered.
5. the preparation method of liquid selenium-enriched organic fertilizer according to claim 2, it is characterised in that:The urea is added using liquid Enter method, added by liquid form in material liquid.
CN201710449531.2A 2017-06-15 2017-06-15 A kind of liquid selenium-enriched organic fertilizer and preparation method thereof Pending CN107188687A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710449531.2A CN107188687A (en) 2017-06-15 2017-06-15 A kind of liquid selenium-enriched organic fertilizer and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201710449531.2A CN107188687A (en) 2017-06-15 2017-06-15 A kind of liquid selenium-enriched organic fertilizer and preparation method thereof

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Publication Number Publication Date
CN107188687A true CN107188687A (en) 2017-09-22

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104692962A (en) * 2015-02-06 2015-06-10 罗锦 Selenium-enriched microbial organic fertilizer and preparation method thereof
CN105418193A (en) * 2015-12-25 2016-03-23 山东大学 Selenium-rich biological preparation prepared by taking biogas slurry and biogas residues as raw materials through fermentation as well as preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104692962A (en) * 2015-02-06 2015-06-10 罗锦 Selenium-enriched microbial organic fertilizer and preparation method thereof
CN105418193A (en) * 2015-12-25 2016-03-23 山东大学 Selenium-rich biological preparation prepared by taking biogas slurry and biogas residues as raw materials through fermentation as well as preparation method thereof

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Effective date of registration: 20200820

Address after: 014060 unit 2, building 18, Minxin Jiayuan, Baotou rare earth high tech Zone, Inner Mongolia Autonomous Region 603

Applicant after: Gao Yujiang

Address before: 014060, the Inner Mongolia Autonomous Region, Baotou rare earth hi tech Zone, A District, 18 homes, 2 units, No. 603

Applicant before: INNER MONGOLIA DEXUN BIOTECHNOLOGY Co.,Ltd.

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Application publication date: 20170922

RJ01 Rejection of invention patent application after publication