CN107164821A - 一种竹炭保温羽绒被防绒面料的制备方法 - Google Patents

一种竹炭保温羽绒被防绒面料的制备方法 Download PDF

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CN107164821A
CN107164821A CN201710404612.0A CN201710404612A CN107164821A CN 107164821 A CN107164821 A CN 107164821A CN 201710404612 A CN201710404612 A CN 201710404612A CN 107164821 A CN107164821 A CN 107164821A
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李林刚
汪锐
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Anhui Three Auspicious Feather Ltd By Share Ltd
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Abstract

本发明公开了一种竹炭保温羽绒被防绒面料的制备方法，涉及羽绒被面料加工技术领域，主要包括如下步骤：(1)竹炭改性PTT纤维制备，(2)混纺纱线加工，(3)面料织造，(4)面料轧光前处理，(5)面料轧光。本发明在保留PTT纤维原有优良特性的基础上赋予其竹炭纤维特有的保温性、吸湿透气性以及抑菌抗菌性；并通过对面料进行轧光前处理，在轧光助剂的作用下增强面料的柔软性、透气透湿性和防钻绒性，以便将所制面料作为竹炭保温羽绒被加工用防绒面料，显著提高面料的使用质量。

Description

一种竹炭保温羽绒被防绒面料的制备方法
技术领域：
本发明涉及羽绒被面料加工技术领域，具体涉及一种竹炭保温羽绒被防绒面料的制备方法。
背景技术：
羽绒被的填充物主要是羽绒，由于羽绒是一种动物性蛋白质纤维，比棉花保温性高，且羽绒球状纤维上密布千万个三角形的细小气孔，能随气温变化而收缩膨胀，产生调温功能，可吸收人体散发流动的热气，隔绝外界冷空气的入侵。
羽绒被由被芯和面料组成，该面料通常选用防绒面料，目的是为了防止使用普通面料存在的钻绒问题，同时保证面料的透气透湿性，以发挥羽绒的保暖性。目前，市场上的防绒面料不胜枚举，按成分划分为棉、涤纶、锦纶、锦涤交织等，都能达到基本的防绒要求，但防绒级别有高有低，并且难以兼具透气透湿性和手感好的优点。此外，防绒面料的保温性能也十分重要，直接影响羽绒被的保暖性。并且，如何在保证面料保温性强的同时使其具有优异的透气透湿性是面料加工需要解决的技术问题。
发明内容：
本发明所要解决的技术问题在于提供一种兼具优异防钻绒性、透气透湿性、保温性的竹炭保温羽绒被防绒面料的制备方法。
本发明所要解决的技术问题采用以下的技术方案来实现：
一种竹炭保温羽绒被防绒面料的制备方法，主要包括如下步骤：
(1)竹炭改性PTT纤维制备：将竹炭粉与改性助剂充分混合后加入混炼机中，并于150-160℃下混炼3-5min，再加入PTT切片，继续混炼3-5min，然后熔融纺丝，制得竹炭改性PTT纤维；
(2)混纺纱线加工：将所制竹炭改性PTT纤维经清花、梳棉、并条、粗纱、细纱工序加工制成混纺纱线；
(3)面料织造：将加工所制混纺纱线经整经、浆纱、穿筘后上织布机，织造成平纹面料；
(4)面料轧光前处理：将轧光助剂加沸水搅拌制成质量浓度20-30g/l的溶液，经自然冷却至50-60℃，再将织造所得面料浸渍于该溶液中，并于50-60℃保温15-30min，然后将面料取出，经脱水后于70-80℃下烘干至重量含水量达到5-10％；
(5)面料轧光：将经轧光前处理的面料利用轧光机进行轧光，控制压力在6-7MPa，温度在120-130℃，车速在20-25m/min，反复轧光三次，每次间隔10-15min，最后经自然冷却定型。
所述竹炭粉、改性助剂、PTT切片的质量比为5-10:1-3:40-50。
所述改性助剂由如下重量份数的原料制成：泊洛沙姆/聚乙烯醇缩丁醛10-15份、松香改性酚醛树脂3-5份、聚天门冬氨酸2-3份、六羟甲基三聚氰胺六甲醚1-2份、水解聚马来酸酐0.5-1份、聚季铵盐-70.5-1份、海泡石纤维粉0.1-0.3份，其制备方法为：向松香改性酚醛树脂中加入六羟甲基三聚氰胺六甲醚和水解聚马来酸酐，充分混合后利用微波处理器微波处理5min，再加入聚季铵盐-7和海泡石纤维粉，混合均匀后继续微波处理5min，并以5℃/min的降温速度降温至55-60℃，然后加入泊洛沙姆/聚乙烯醇缩丁醛和聚天门冬氨酸，于55-60℃保温研磨15min后再次微波处理5min，最后经自然冷却至室温，即得改性助剂。
所述微波处理器的工作条件为微波频率2450MHz、输出功率700W。
所述泊洛沙姆/聚乙烯醇缩丁醛由泊洛沙姆和聚乙烯醇缩丁醛复合而成，其制备方法为：搅拌下向泊洛沙姆中加35-40℃水，直至泊洛沙姆完全溶解，再加入羟丙基甲基纤维素和双丙酮丙烯酰胺，升温至回流状态保温搅拌15min，然后加入聚乙烯醇缩丁醛和松节油，继续回流保温搅拌30min，并经自然冷却至室温，即得泊洛沙姆/聚乙烯醇缩丁醛。
所述泊洛沙姆、羟丙基甲基纤维素、双丙酮丙烯酰胺、聚乙烯醇缩丁醛和松节油的质量比为5-10:0.5-1:0.3-0.5:5-10:0.1-0.3。
所述轧光助剂由如下重量份数的原料制成：N-羟甲基丙烯酰胺5-10份、阳离子聚丙烯酰胺3-5份、氢化松香季戊四醇酯1-2份、烯丙基缩水甘油醚1-2份、月桂醇磺基琥珀酸酯二钠0.5-1份、聚四氟乙烯超细粉0.1-0.3份、玻纤粉0.05-0.1份，其制备方法为：向氢化松香季戊四醇酯中加入月桂醇磺基琥珀酸酯二钠和聚四氟乙烯超细粉，升温至125-130℃保温混合15min，再加入烯丙基缩水甘油醚和玻纤粉，继续在125-130℃保温混合15min，并以5℃/min的降温速度降温至55-60℃，然后加入N-羟甲基丙烯酰胺和阳离子聚丙烯酰胺，充分混合后转入0-5℃环境中密封静置1h，最后经超微粉碎机制成微粉，即得轧光助剂。
本发明的有益效果是：本发明以竹炭粉与改性助剂作为改性剂，对PTT进行改性制得竹炭改性PTT纤维，从而在保留PTT纤维(聚对苯二甲酸1.3丙二醇酯纤维)原有优良特性的基础上赋予其竹炭纤维特有的保温性、吸湿透气性以及抑菌抗菌性；并通过对面料进行轧光前处理，在轧光助剂的作用下增强面料的柔软性、透气透湿性和防钻绒性，以便将所制面料作为竹炭保温羽绒被加工用防绒面料，显著提高面料的使用质量。
具体实施方式：
为了使本发明实现的技术手段、创作特征、达成目的与功效易于明白了解，下面结合具体实施例，进一步阐述本发明。
实施例1
(1)竹炭改性PTT纤维制备：将竹炭粉与改性助剂充分混合后加入混炼机中，并于150-160℃下混炼3min，再加入PTT切片，继续混炼5min，然后熔融纺丝，制得竹炭改性PTT纤维；其中，竹炭粉、改性助剂、PTT切片的质量比为8:1:40。
(2)混纺纱线加工：将所制竹炭改性PTT纤维经清花、梳棉、并条、粗纱、细纱工序加工制成混纺纱线；
(3)面料织造：将加工所制混纺纱线经整经、浆纱、穿筘后上织布机，织造成平纹面料；
(4)面料轧光前处理：将轧光助剂加沸水搅拌制成质量浓度20g/l的溶液，经自然冷却至50-60℃，再将织造所得面料浸渍于该溶液中，并于50-60℃保温30min，然后将面料取出，经脱水后于70-80℃下烘干至重量含水量达到5-10％；
(5)面料轧光：将经轧光前处理的面料利用轧光机进行轧光，控制压力在6-7MPa，温度在120-130℃，车速在20-25m/min，反复轧光三次，每次间隔15min，最后经自然冷却定型。
改性助剂的制备：向5g松香改性酚醛树脂中加入1g六羟甲基三聚氰胺六甲醚和0.5g水解聚马来酸酐，充分混合后利用微波频率2450MHz、输出功率700W的微波处理器微波处理5min，再加入0.5g聚季铵盐-7和0.1g海泡石纤维粉，混合均匀后继续微波处理5min，并以5℃/min的降温速度降温至55-60℃，然后加入15g泊洛沙姆/聚乙烯醇缩丁醛和3g聚天门冬氨酸，于55-60℃保温研磨15min后再次微波处理5min，最后经自然冷却至室温，即得改性助剂。
泊洛沙姆/聚乙烯醇缩丁醛由的制备：搅拌下向5g泊洛沙姆中加35-40℃水，直至泊洛沙姆完全溶解，再加入0.5g羟丙基甲基纤维素和0.3g双丙酮丙烯酰胺，升温至回流状态保温搅拌15min，然后加入10g聚乙烯醇缩丁醛和0.2g松节油，继续回流保温搅拌30min，并经自然冷却至室温，即得泊洛沙姆/聚乙烯醇缩丁醛。
轧光助剂的制备：向2g氢化松香季戊四醇酯中加入0.5g月桂醇磺基琥珀酸酯二钠和0.1g聚四氟乙烯超细粉，升温至125-130℃保温混合15min，再加入1g烯丙基缩水甘油醚和0.05g玻纤粉，继续在125-130℃保温混合15min，并以5℃/min的降温速度降温至55-60℃，然后加入8gN-羟甲基丙烯酰胺和5g阳离子聚丙烯酰胺，充分混合后转入0-5℃环境中密封静置1h，最后经超微粉碎机制成微粉，即得轧光助剂。
实施例2
(1)竹炭改性PTT纤维制备：将竹炭粉与改性助剂充分混合后加入混炼机中，并于150-160℃下混炼5min，再加入PTT切片，继续混炼5min，然后熔融纺丝，制得竹炭改性PTT纤维；其中，竹炭粉、改性助剂、PTT切片的质量比为10:1:50。
(2)混纺纱线加工：将所制竹炭改性PTT纤维经清花、梳棉、并条、粗纱、细纱工序加工制成混纺纱线；
(3)面料织造：将加工所制混纺纱线经整经、浆纱、穿筘后上织布机，织造成平纹面料；
(4)面料轧光前处理：将轧光助剂加沸水搅拌制成质量浓度25g/l的溶液，经自然冷却至50-60℃，再将织造所得面料浸渍于该溶液中，并于50-60℃保温30min，然后将面料取出，经脱水后于70-80℃下烘干至重量含水量达到5-10％；
(5)面料轧光：将经轧光前处理的面料利用轧光机进行轧光，控制压力在6-7MPa，温度在120-130℃，车速在20-25m/min，反复轧光三次，每次间隔15min，最后经自然冷却定型。
改性助剂的制备：向3g松香改性酚醛树脂中加入2g六羟甲基三聚氰胺六甲醚和0.5g水解聚马来酸酐，充分混合后利用微波频率2450MHz、输出功率700W的微波处理器微波处理5min，再加入0.5g聚季铵盐-7和0.1g海泡石纤维粉，混合均匀后继续微波处理5min，并以5℃/min的降温速度降温至55-60℃，然后加入10g泊洛沙姆/聚乙烯醇缩丁醛和2g聚天门冬氨酸，于55-60℃保温研磨15min后再次微波处理5min，最后经自然冷却至室温，即得改性助剂。
泊洛沙姆/聚乙烯醇缩丁醛由的制备：搅拌下向10g泊洛沙姆中加35-40℃水，直至泊洛沙姆完全溶解，再加入0.5g羟丙基甲基纤维素和0.5g双丙酮丙烯酰胺，升温至回流状态保温搅拌15min，然后加入5g聚乙烯醇缩丁醛和0.2g松节油，继续回流保温搅拌30min，并经自然冷却至室温，即得泊洛沙姆/聚乙烯醇缩丁醛。
轧光助剂的制备：向2g氢化松香季戊四醇酯中加入0.5g月桂醇磺基琥珀酸酯二钠和0.1g聚四氟乙烯超细粉，升温至125-130℃保温混合15min，再加入2g烯丙基缩水甘油醚和0.05g玻纤粉，继续在125-130℃保温混合15min，并以5℃/min的降温速度降温至55-60℃，然后加入10g N-羟甲基丙烯酰胺和3g阳离子聚丙烯酰胺，充分混合后转入0-5℃环境中密封静置1h，最后经超微粉碎机制成微粉，即得轧光助剂。
对照例1
(1)竹炭改性PTT纤维制备：将竹炭粉与改性助剂充分混合后加入混炼机中，并于150-160℃下混炼5min，再加入PTT切片，继续混炼5min，然后熔融纺丝，制得竹炭改性PTT纤维；其中，竹炭粉、改性助剂、PTT切片的质量比为10:1:50。
(2)混纺纱线加工：将所制竹炭改性PTT纤维经清花、梳棉、并条、粗纱、细纱工序加工制成混纺纱线；
(3)面料织造：将加工所制混纺纱线经整经、浆纱、穿筘后上织布机，织造成平纹面料；
(4)面料轧光前处理：将轧光助剂加沸水搅拌制成质量浓度25g/l的溶液，经自然冷却至50-60℃，再将织造所得面料浸渍于该溶液中，并于50-60℃保温30min，然后将面料取出，经脱水后于70-80℃下烘干至重量含水量达到5-10％；
(5)面料轧光：将经轧光前处理的面料利用轧光机进行轧光，控制压力在6-7MPa，温度在120-130℃，车速在20-25m/min，反复轧光三次，每次间隔15min，最后经自然冷却定型。
改性助剂的制备：向3g松香改性酚醛树脂中加入2g六羟甲基三聚氰胺六甲醚和0.5g水解聚马来酸酐，充分混合后利用微波频率2450MHz、输出功率700W的微波处理器微波处理5min，再加入0.5g聚季铵盐-7和0.1g海泡石纤维粉，混合均匀后继续微波处理5min，并以5℃/min的降温速度降温至55-60℃，然后加入10g泊洛沙姆/聚乙烯醇缩丁醛和2g聚天门冬氨酸，于55-60℃保温研磨15min后再次微波处理5min，最后经自然冷却至室温，即得改性助剂。
泊洛沙姆/聚乙烯醇缩丁醛由的制备：搅拌下向10g泊洛沙姆中加35-40℃水，直至泊洛沙姆完全溶解，升温至回流状态保温搅拌15min，然后加入5g聚乙烯醇缩丁醛，继续回流保温搅拌30min，并经自然冷却至室温，即得泊洛沙姆/聚乙烯醇缩丁醛。
轧光助剂的制备：向2g氢化松香季戊四醇酯中加入0.5g月桂醇磺基琥珀酸酯二钠和0.1g聚四氟乙烯超细粉，升温至125-130℃保温混合15min，再加入2g烯丙基缩水甘油醚和0.05g玻纤粉，继续在125-130℃保温混合15min，并以5℃/min的降温速度降温至55-60℃，然后加入10g N-羟甲基丙烯酰胺和3g阳离子聚丙烯酰胺，充分混合后转入0-5℃环境中密封静置1h，最后经超微粉碎机制成微粉，即得轧光助剂。
对照例2
(1)竹炭改性PTT纤维制备：将竹炭粉加入混炼机中，并于150-160℃下混炼5min，再加入PTT切片，继续混炼5min，然后熔融纺丝，制得竹炭改性PTT纤维；其中，竹炭粉、PTT切片的质量比为10:50。
(2)混纺纱线加工：将所制竹炭改性PTT纤维经清花、梳棉、并条、粗纱、细纱工序加工制成混纺纱线；
(3)面料织造：将加工所制混纺纱线经整经、浆纱、穿筘后上织布机，织造成平纹面料；
(4)面料轧光前处理：将轧光助剂加沸水搅拌制成质量浓度25g/l的溶液，经自然冷却至50-60℃，再将织造所得面料浸渍于该溶液中，并于50-60℃保温30min，然后将面料取出，经脱水后于70-80℃下烘干至重量含水量达到5-10％；
(5)面料轧光：将经轧光前处理的面料利用轧光机进行轧光，控制压力在6-7MPa，温度在120-130℃，车速在20-25m/min，反复轧光三次，每次间隔15min，最后经自然冷却定型。
轧光助剂的制备：向2g氢化松香季戊四醇酯中加入0.5g月桂醇磺基琥珀酸酯二钠和0.1g聚四氟乙烯超细粉，升温至125-130℃保温混合15min，再加入2g烯丙基缩水甘油醚和0.05g玻纤粉，继续在125-130℃保温混合15min，并以5℃/min的降温速度降温至55-60℃，然后加入10g N-羟甲基丙烯酰胺和3g阳离子聚丙烯酰胺，充分混合后转入0-5℃环境中密封静置1h，最后经超微粉碎机制成微粉，即得轧光助剂。
对照例3
(1)竹炭改性PTT纤维制备：将竹炭粉与改性助剂充分混合后加入混炼机中，并于150-160℃下混炼5min，再加入PTT切片，继续混炼5min，然后熔融纺丝，制得竹炭改性PTT纤维；其中，竹炭粉、改性助剂、PTT切片的质量比为10:1:50。
(2)混纺纱线加工：将所制竹炭改性PTT纤维经清花、梳棉、并条、粗纱、细纱工序加工制成混纺纱线；
(3)面料织造：将加工所制混纺纱线经整经、浆纱、穿筘后上织布机，织造成平纹面料；
(4)面料轧光：将面料利用轧光机进行轧光，控制压力在6-7MPa，温度在120-130℃，车速在20-25m/min，反复轧光三次，每次间隔15min，最后经自然冷却定型。
改性助剂的制备：向3g松香改性酚醛树脂中加入2g六羟甲基三聚氰胺六甲醚和0.5g水解聚马来酸酐，充分混合后利用微波频率2450MHz、输出功率700W的微波处理器微波处理5min，再加入0.5g聚季铵盐-7和0.1g海泡石纤维粉，混合均匀后继续微波处理5min，并以5℃/min的降温速度降温至55-60℃，然后加入10g泊洛沙姆/聚乙烯醇缩丁醛和2g聚天门冬氨酸，于55-60℃保温研磨15min后再次微波处理5min，最后经自然冷却至室温，即得改性助剂。
泊洛沙姆/聚乙烯醇缩丁醛由的制备：搅拌下向10g泊洛沙姆中加35-40℃水，直至泊洛沙姆完全溶解，再加入0.5g羟丙基甲基纤维素和0.5g双丙酮丙烯酰胺，升温至回流状态保温搅拌15min，然后加入5g聚乙烯醇缩丁醛和0.2g松节油，继续回流保温搅拌30min，并经自然冷却至室温，即得泊洛沙姆/聚乙烯醇缩丁醛。
实施例3
分别利用实施例1、实施例2、对照例1、对照例2、对照例3所述方法加工制备羽绒被防绒面料，并对其使用性能进行测定，结果如表1所示。
表1本发明加工所制羽绒被防绒面料的使用性能
项目 实施例1 实施例2 对照例1 对照例2 对照例3
柔软度 1级 1级 2级 2级 3级
保温性 0.78 0.79 0.75 0.64 0.53
防钻绒性 2根 2根 2根 3根 5根
透气性mm/s 32.8 33.2 30.3 22.7 16.4
透湿量g/m2.d 8734 8756 8528 7869 7215
以上显示和描述了本发明的基本原理和主要特征和本发明的优点。本行业的技术人员应该了解，本发明不受上述实施例的限制，上述实施例和说明书中描述的只是说明本发明的原理，在不脱离本发明精神和范围的前提下，本发明还会有各种变化和改进，这些变化和改进都落入要求保护的本发明范围内。本发明要求保护范围由所附的权利要求书及其等效物界定。

Claims (7)

1.一种竹炭保温羽绒被防绒面料的制备方法，其特征在于，主要包括如下步骤：
(1)竹炭改性PTT纤维制备：将竹炭粉与改性助剂充分混合后加入混炼机中，并于150-160℃下混炼3-5min，再加入PTT切片，继续混炼3-5min，然后熔融纺丝，制得竹炭改性PTT纤维；
(2)混纺纱线加工：将所制竹炭改性PTT纤维经清花、梳棉、并条、粗纱、细纱工序加工制成混纺纱线；
(3)面料织造：将加工所制混纺纱线经整经、浆纱、穿筘后上织布机，织造成平纹面料；
(4)面料轧光前处理：将轧光助剂加沸水搅拌制成质量浓度20-30g/l的溶液，经自然冷却至50-60℃，再将织造所得面料浸渍于该溶液中，并于50-60℃保温15-30min，然后将面料取出，经脱水后于70-80℃下烘干至重量含水量达到5-10％；
(5)面料轧光：将经轧光前处理的面料利用轧光机进行轧光，控制压力在6-7MPa，温度在120-130℃，车速在20-25m/min，反复轧光三次，每次间隔10-15min，最后经自然冷却定型。
2.根据权利要求1所述的竹炭保温羽绒被防绒面料的制备方法，其特征在于：所述竹炭粉、改性助剂、PTT切片的质量比为5-10:1-3:40-50。
3.根据权利要求1所述的竹炭保温羽绒被防绒面料的制备方法，其特征在于，所述改性助剂由如下重量份数的原料制成：泊洛沙姆/聚乙烯醇缩丁醛10-15份、松香改性酚醛树脂3-5份、聚天门冬氨酸2-3份、六羟甲基三聚氰胺六甲醚1-2份、水解聚马来酸酐0.5-1份、聚季铵盐-70.5-1份、海泡石纤维粉0.1-0.3份，其制备方法为：向松香改性酚醛树脂中加入六羟甲基三聚氰胺六甲醚和水解聚马来酸酐，充分混合后利用微波处理器微波处理5min，再加入聚季铵盐-7和海泡石纤维粉，混合均匀后继续微波处理5min，并以5℃/min的降温速度降温至55-60℃，然后加入泊洛沙姆/聚乙烯醇缩丁醛和聚天门冬氨酸，于55-60℃保温研磨15min后再次微波处理5min，最后经自然冷却至室温，即得改性助剂。
4.根据权利要求3所述的竹炭保温羽绒被防绒面料的制备方法，其特征在于：所述微波处理器的工作条件为微波频率2450MHz、输出功率700W。
5.根据权利要求3所述的竹炭保温羽绒被防绒面料的制备方法，其特征在于：所述泊洛沙姆/聚乙烯醇缩丁醛由泊洛沙姆和聚乙烯醇缩丁醛复合而成，其制备方法为：搅拌下向泊洛沙姆中加35-40℃水，直至泊洛沙姆完全溶解，再加入羟丙基甲基纤维素和双丙酮丙烯酰胺，升温至回流状态保温搅拌15min，然后加入聚乙烯醇缩丁醛和松节油，继续回流保温搅拌30min，并经自然冷却至室温，即得泊洛沙姆/聚乙烯醇缩丁醛。
6.根据权利要求5所述的竹炭保温羽绒被防绒面料的制备方法，其特征在于：所述泊洛沙姆、羟丙基甲基纤维素、双丙酮丙烯酰胺、聚乙烯醇缩丁醛和松节油的质量比为5-10:0.5-1:0.3-0.5:5-10:0.1-0.3。
7.根据权利要求1所述的竹炭保温羽绒被防绒面料的制备方法，其特征在于，所述轧光助剂由如下重量份数的原料制成：N-羟甲基丙烯酰胺5-10份、阳离子聚丙烯酰胺3-5份、氢化松香季戊四醇酯1-2份、烯丙基缩水甘油醚1-2份、月桂醇磺基琥珀酸酯二钠0.5-1份、聚四氟乙烯超细粉0.1-0.3份、玻纤粉0.05-0.1份，其制备方法为：向氢化松香季戊四醇酯中加入月桂醇磺基琥珀酸酯二钠和聚四氟乙烯超细粉，升温至125-130℃保温混合15min，再加入烯丙基缩水甘油醚和玻纤粉，继续在125-130℃保温混合15min，并以5℃/min的降温速度降温至55-60℃，然后加入N-羟甲基丙烯酰胺和阳离子聚丙烯酰胺，充分混合后转入0-5℃环境中密封静置1h，最后经超微粉碎机制成微粉，即得轧光助剂。
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