CN107012565B - 一种防虫防螨型羽绒被面料的加工方法 - Google Patents

一种防虫防螨型羽绒被面料的加工方法 Download PDF

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CN107012565B
CN107012565B CN201710404633.2A CN201710404633A CN107012565B CN 107012565 B CN107012565 B CN 107012565B CN 201710404633 A CN201710404633 A CN 201710404633A CN 107012565 B CN107012565 B CN 107012565B
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李林刚
汪锐
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Lu'an Feng Yu Environmental Protection Technology Co., Ltd.
West Anhui University
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West Anhui University
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Abstract

本发明公开了一种防虫防螨型羽绒被面料的加工方法，涉及羽绒被加工技术领域，主要包括如下步骤：(1)棉纤维选择性氧化，(2)混纺纱线加工，(3)混纺纱线染色，(4)面料织造，(5)面料轧光前处理，(6)面料轧光。本发明在混纺纱线染色过程中加入防虫防螨剂，通过染色工序同时赋予加工所制面料优异的防虫防螨功能，减少另增工序的成本投入，并且借助染料在纤维上的结合力提高防虫防螨有效成分的有效附着率；并通过对面料进行轧光前处理，在轧光助剂的作用下增强面料的透气透湿性和防钻绒性。

Description

一种防虫防螨型羽绒被面料的加工方法
技术领域：
本发明涉及羽绒被加工技术领域，具体涉及一种防虫防螨型羽绒被面料的加工方法。
背景技术：
羽绒被的填充物主要是羽绒，由于羽绒是一种动物性蛋白质纤维，比棉花保温性高，且羽绒球状纤维上密布千万个三角形的细小气孔，能随气温变化而收缩膨胀，产生调温功能，可吸收人体散发流动的热气，隔绝外界冷空气的入侵。
羽绒被由被芯和面料组成，该面料通常选用防绒面料，目的是为了防止使用普通面料存在的钻绒问题，同时保证面料的透气透湿性，以发挥羽绒的保暖性。目前，市场上的防绒面料不胜枚举，按成分划分为棉、涤纶、锦纶、锦涤交织等，都能达到基本的防绒要求，但防绒级别有高有低，并且难以兼具透气性和手感好的优点。
此外，防虫防螨性也属于羽绒被面料性能评价的主要指标之一。由于羽绒的化学组成是一种蛋白质，并伴有动物性脂肪，在预处理过程中即使经过脱脂和水洗工序，仍不能完全除去脂肪及细菌。因此，需要对羽绒被面料进行防虫防螨处理，防止虫螨在面料表面滋生甚至透过面料破坏内部的羽绒，以保证羽绒被的使用质量。
发明内容：
本发明所要解决的技术问题在于提供一种透气透湿性优异、防钻绒性好且对虫螨滋生具有显著防治作用的防虫防螨型羽绒被面料的加工方法。
本发明所要解决的技术问题采用以下的技术方案来实现：
一种防虫防螨型羽绒被面料的加工方法，主要包括如下步骤：
(1)棉纤维选择性氧化：利用4-乙酰氨基-TEMPO-NaClO-NaBr氧化体系对棉纤维进行选择性氧化，经离心、过滤、烘干制得羧基含量0.4-0.5mmol/g的羧基棉纤维；
(2)混纺纱线加工：将所制羧基棉纤维与聚氨酯纤维以质量比5-10:3-5的比例进行混纤，再经清花、梳棉、并条、粗纱、细纱工序加工制成混纺纱线；
(3)混纺纱线染色：对混纺纱线进行浸染，并在染液中混入防虫防螨剂，混纺纱线与防虫防螨剂质量比为1:0.03-0.05，染色结束后于45-55℃固色15-30min，并经水洗、脱水、烘干工序处理；
(4)面料织造：将染色后的混纺纱线经整经、浆纱、穿筘后上织布机，织造成平纹面料；
(5)面料轧光前处理：将轧光助剂加沸水搅拌制成15-25g/l的溶液，经自然冷却至40-50℃，再将织造所得面料浸渍于该溶液中，并于40-50℃保温15-30min，然后将面料取出，经脱水后于70-80℃烘干至重量含水量5-10％；
(6)面料轧光：将经轧光前处理的面料利用轧光机进行轧光，控制压力在6-7MPa，温度在120-130℃，车速在20-25m/min，反复轧光三次，每次间隔15-30min，最后经自然冷却定型。
所述防虫防螨剂由如下重量份数的原料制成：多聚谷氨酸10-15份、泊洛沙姆3-5份、茶皂素1-2份、聚乙烯醇树脂0.5-1份、聚氧化乙烯0.5-1份、六羟甲基三聚氰胺六甲醚0.3-0.5份、十二烷基二甲基苄基氯化铵0.1-0.3份、乙二胺二邻羟苯基大乙酸铁钠0.1-0.3份、纳米银0.05-0.1份，其制备方法为：向多聚谷氨酸中加入泊洛沙姆和聚乙烯醇树脂，所得粉体升温至50-55℃保温研磨10min，再在搅拌下以5ml/min的滴加速度滴加沸水，直至粉体全部溶解，然后加入茶皂素、十二烷基二甲基苄基氯化铵、乙二胺二邻羟苯基大乙酸铁钠和纳米银，充分混合后利用微波处理器微波5min，静置30min后再次微波5min，随后加入聚氧化乙烯和六羟甲基三聚氰胺六甲醚，混合均匀后将所得混合液送入喷雾干燥机中，干燥所得颗粒经超微粉碎机制成微粉，即得防虫防螨剂。
所述微波处理器的工作条件为微波频率2450MHz、输出功率700W。
防虫防螨剂制备过程中以多聚谷氨酸、泊洛沙姆、聚乙烯醇树脂、聚氧化乙烯和六羟甲基三聚氰胺六甲醚作为虫螨防治成分的载体和助剂，提高虫螨防治成分在纤维上的牢固附着率。
所述轧光助剂由如下重量份数的原料制成：N-羟甲基丙烯酰胺5-10份、阳离子聚丙烯酰胺3-5份、氢化松香季戊四醇酯1-2份、烯丙基缩水甘油醚1-2份、月桂醇磺基琥珀酸酯二钠0.5-1份、聚四氟乙烯超细粉0.1-0.3份、玻纤粉0.05-0.1份，其制备方法为：向氢化松香季戊四醇酯中加入月桂醇磺基琥珀酸酯二钠和聚四氟乙烯超细粉，升温至125-130℃保温混合15min，再加入烯丙基缩水甘油醚和玻纤粉，继续在125-130℃保温混合15min，并以5℃/min的降温速度降温至55-60℃，然后加入N-羟甲基丙烯酰胺和阳离子聚丙烯酰胺，充分混合后转入0-5℃环境中密封静置1h，最后经超微粉碎机制成微粉，即得轧光助剂。
本发明的有益效果是：本发明在混纺纱线染色过程中加入防虫防螨剂，通过染色工序同时赋予加工所制面料优异的防虫防螨功能，减少另增工序的成本投入，并且借助染料在纤维上的结合力提高防虫防螨有效成分的有效附着率；并通过对面料进行轧光前处理，在轧光助剂的作用下增强面料的透气透湿性和防钻绒性，从而使加工所制面料满足作为羽绒被面料的使用性能要求，提高羽绒被的使用质量。
具体实施方式：
为了使本发明实现的技术手段、创作特征、达成目的与功效易于明白了解，下面结合具体实施例，进一步阐述本发明。
实施例1
(1)棉纤维选择性氧化：利用4-乙酰氨基-TEMPO-NaClO-NaBr氧化体系对棉纤维进行选择性氧化，经离心、过滤、烘干制得羧基含量0.4-0.5mmol/g的羧基棉纤维；
(2)混纺纱线加工：将所制羧基棉纤维与聚氨酯纤维以质量比5:3的比例进行混纤，再经清花、梳棉、并条、粗纱、细纱工序加工制成混纺纱线；
(3)混纺纱线染色：对混纺纱线进行浸染，并在染液中混入防虫防螨剂，混纺纱线与防虫防螨剂质量比为1:0.05，染色结束后于45-55℃固色30min，并经水洗、脱水、烘干工序处理；
(4)面料织造：将染色后的混纺纱线经整经、浆纱、穿筘后上织布机，织造成平纹面料；
(5)面料轧光前处理：将轧光助剂加沸水搅拌制成25g/l的溶液，经自然冷却至40-50℃，再将织造所得面料浸渍于该溶液中，并于40-50℃保温30min，然后将面料取出，经脱水后于70-80℃烘干至重量含水量5-10％；
(6)面料轧光：将经轧光前处理的面料利用轧光机进行轧光，控制压力在6-7MPa，温度在120-130℃，车速在20-25m/min，反复轧光三次，每次间隔30min，最后经自然冷却定型。
防虫防螨剂的制备：向15g多聚谷氨酸中加入3g泊洛沙姆和0.5g聚乙烯醇树脂，所得粉体升温至50-55℃保温研磨10min，再在搅拌下以5ml/min的滴加速度滴加沸水，直至粉体全部溶解，然后加入1g茶皂素、0.3g十二烷基二甲基苄基氯化铵、0.2g乙二胺二邻羟苯基大乙酸铁钠和0.05g纳米银，充分混合后利用微波频率2450MHz、输出功率700W的微波处理器微波5min，静置30min后再次微波5min，随后加入0.5g聚氧化乙烯和0.5g六羟甲基三聚氰胺六甲醚，混合均匀后将所得混合液送入喷雾干燥机中，干燥所得颗粒经超微粉碎机制成微粉，即得防虫防螨剂。
轧光助剂的制备：向2g氢化松香季戊四醇酯中加入0.5g月桂醇磺基琥珀酸酯二钠和0.1g聚四氟乙烯超细粉，升温至125-130℃保温混合15min，再加入1g烯丙基缩水甘油醚和0.05g玻纤粉，继续在125-130℃保温混合15min，并以5℃/min的降温速度降温至55-60℃，然后加入8gN-羟甲基丙烯酰胺和5g阳离子聚丙烯酰胺，充分混合后转入0-5℃环境中密封静置1h，最后经超微粉碎机制成微粉，即得轧光助剂。
实施例2
(1)棉纤维选择性氧化：利用4-乙酰氨基-TEMPO-NaClO-NaBr氧化体系对棉纤维进行选择性氧化，经离心、过滤、烘干制得羧基含量0.4-0.5mmol/g的羧基棉纤维；
(2)混纺纱线加工：将所制羧基棉纤维与聚氨酯纤维以质量比5:3的比例进行混纤，再经清花、梳棉、并条、粗纱、细纱工序加工制成混纺纱线；
(3)混纺纱线染色：对混纺纱线进行浸染，并在染液中混入防虫防螨剂，混纺纱线与防虫防螨剂质量比为1:0.05，染色结束后于45-55℃固色30min，并经水洗、脱水、烘干工序处理；
(4)面料织造：将染色后的混纺纱线经整经、浆纱、穿筘后上织布机，织造成平纹面料；
(5)面料轧光前处理：将轧光助剂加沸水搅拌制成25g/l的溶液，经自然冷却至40-50℃，再将织造所得面料浸渍于该溶液中，并于40-50℃保温30min，然后将面料取出，经脱水后于70-80℃烘干至重量含水量5-10％；
(6)面料轧光：将经轧光前处理的面料利用轧光机进行轧光，控制压力在6-7MPa，温度在120-130℃，车速在20-25m/min，反复轧光三次，每次间隔30min，最后经自然冷却定型。
防虫防螨剂的制备：向10g多聚谷氨酸中加入5g泊洛沙姆和0.5g聚乙烯醇树脂，所得粉体升温至50-55℃保温研磨10min，再在搅拌下以5ml/min的滴加速度滴加沸水，直至粉体全部溶解，然后加入1g茶皂素、0.2g十二烷基二甲基苄基氯化铵、0.2g乙二胺二邻羟苯基大乙酸铁钠和0.05g纳米银，充分混合后利用微波频率2450MHz、输出功率700W的微波处理器微波5min，静置30min后再次微波5min，随后加入0.5g聚氧化乙烯和0.3g六羟甲基三聚氰胺六甲醚，混合均匀后将所得混合液送入喷雾干燥机中，干燥所得颗粒经超微粉碎机制成微粉，即得防虫防螨剂。
轧光助剂的制备：向2g氢化松香季戊四醇酯中加入0.5g月桂醇磺基琥珀酸酯二钠和0.1g聚四氟乙烯超细粉，升温至125-130℃保温混合15min，再加入2g烯丙基缩水甘油醚和0.05g玻纤粉，继续在125-130℃保温混合15min，并以5℃/min的降温速度降温至55-60℃，然后加入10g N-羟甲基丙烯酰胺和3g阳离子聚丙烯酰胺，充分混合后转入0-5℃环境中密封静置1h，最后经超微粉碎机制成微粉，即得轧光助剂。
对照例1
(1)棉纤维选择性氧化：利用4-乙酰氨基-TEMPO-NaClO-NaBr氧化体系对棉纤维进行选择性氧化，经离心、过滤、烘干制得羧基含量0.4-0.5mmol/g的羧基棉纤维；
(2)混纺纱线加工：将所制羧基棉纤维与聚氨酯纤维以质量比5:3的比例进行混纤，再经清花、梳棉、并条、粗纱、细纱工序加工制成混纺纱线；
(3)混纺纱线染色：对混纺纱线进行浸染，并在染液中混入防虫防螨剂，混纺纱线与防虫防螨剂质量比为1:0.05，染色结束后于45-55℃固色30min，并经水洗、脱水、烘干工序处理；
(4)面料织造：将染色后的混纺纱线经整经、浆纱、穿筘后上织布机，织造成平纹面料；
(5)面料轧光前处理：将轧光助剂加沸水搅拌制成25g/l的溶液，经自然冷却至40-50℃，再将织造所得面料浸渍于该溶液中，并于40-50℃保温30min，然后将面料取出，经脱水后于70-80℃烘干至重量含水量5-10％；
(6)面料轧光：将经轧光前处理的面料利用轧光机进行轧光，控制压力在6-7MPa，温度在120-130℃，车速在20-25m/min，反复轧光三次，每次间隔30min，最后经自然冷却定型。
根据实施例2所用防虫防螨剂用量，计算其包含的茶皂素、十二烷基二甲基苄基氯化铵、乙二胺二邻羟苯基大乙酸铁钠和纳米银的质量，再将等量茶皂素、十二烷基二甲基苄基氯化铵、乙二胺二邻羟苯基大乙酸铁钠和纳米银混合后加入本对照例的染液中，以进行载体和助剂的空白对照。
轧光助剂的制备：向2g氢化松香季戊四醇酯中加入0.5g月桂醇磺基琥珀酸酯二钠和0.1g聚四氟乙烯超细粉，升温至125-130℃保温混合15min，再加入2g烯丙基缩水甘油醚和0.05g玻纤粉，继续在125-130℃保温混合15min，并以5℃/min的降温速度降温至55-60℃，然后加入10g N-羟甲基丙烯酰胺和3g阳离子聚丙烯酰胺，充分混合后转入0-5℃环境中密封静置1h，最后经超微粉碎机制成微粉，即得轧光助剂。
对照例2
(1)棉纤维选择性氧化：利用4-乙酰氨基-TEMPO-NaClO-NaBr氧化体系对棉纤维进行选择性氧化，经离心、过滤、烘干制得羧基含量0.4-0.5mmol/g的羧基棉纤维；
(2)混纺纱线加工：将所制羧基棉纤维与聚氨酯纤维以质量比5:3的比例进行混纤，再经清花、梳棉、并条、粗纱、细纱工序加工制成混纺纱线；
(3)混纺纱线染色：对混纺纱线进行浸染，染色结束后于45-55℃固色30min，并经水洗、脱水、烘干工序处理；
(4)面料织造：将染色后的混纺纱线经整经、浆纱、穿筘后上织布机，织造成平纹面料；
(5)面料轧光前处理：将轧光助剂加沸水搅拌制成25g/l的溶液，经自然冷却至40-50℃，再将织造所得面料浸渍于该溶液中，并于40-50℃保温30min，然后将面料取出，经脱水后于70-80℃烘干至重量含水量5-10％；
(6)面料轧光：将经轧光前处理的面料利用轧光机进行轧光，控制压力在6-7MPa，温度在120-130℃，车速在20-25m/min，反复轧光三次，每次间隔30min，最后经自然冷却定型。
轧光助剂的制备：向2g氢化松香季戊四醇酯中加入0.5g月桂醇磺基琥珀酸酯二钠和0.1g聚四氟乙烯超细粉，升温至125-130℃保温混合15min，再加入2g烯丙基缩水甘油醚和0.05g玻纤粉，继续在125-130℃保温混合15min，并以5℃/min的降温速度降温至55-60℃，然后加入10g N-羟甲基丙烯酰胺和3g阳离子聚丙烯酰胺，充分混合后转入0-5℃环境中密封静置1h，最后经超微粉碎机制成微粉，即得轧光助剂。
对照例3
(1)棉纤维选择性氧化：利用4-乙酰氨基-TEMPO-NaClO-NaBr氧化体系对棉纤维进行选择性氧化，经离心、过滤、烘干制得羧基含量0.4-0.5mmol/g的羧基棉纤维；
(2)混纺纱线加工：将所制羧基棉纤维与聚氨酯纤维以质量比5:3的比例进行混纤，再经清花、梳棉、并条、粗纱、细纱工序加工制成混纺纱线；
(3)混纺纱线染色：对混纺纱线进行浸染，并在染液中混入防虫防螨剂，混纺纱线与防虫防螨剂质量比为1:0.05，染色结束后于45-55℃固色30min，并经水洗、脱水、烘干工序处理；
(4)面料织造：将染色后的混纺纱线经整经、浆纱、穿筘后上织布机，织造成平纹面料；
(5)面料轧光：将织造所得面料利用轧光机进行轧光，控制压力在6-7MPa，温度在120-130℃，车速在20-25m/min，反复轧光三次，每次间隔30min，最后经自然冷却定型。
防虫防螨剂的制备：向10g多聚谷氨酸中加入5g泊洛沙姆和0.5g聚乙烯醇树脂，所得粉体升温至50-55℃保温研磨10min，再在搅拌下以5ml/min的滴加速度滴加沸水，直至粉体全部溶解，然后加入1g茶皂素、0.2g十二烷基二甲基苄基氯化铵、0.2g乙二胺二邻羟苯基大乙酸铁钠和0.05g纳米银，充分混合后利用微波频率2450MHz、输出功率700W的微波处理器微波5min，静置30min后再次微波5min，随后加入0.5g聚氧化乙烯和0.3g六羟甲基三聚氰胺六甲醚，混合均匀后将所得混合液送入喷雾干燥机中，干燥所得颗粒经超微粉碎机制成微粉，即得防虫防螨剂。
实施例3
分别利用实施例1、实施例2、对照例1、对照例2和对照例3所述方法加工制备防虫防螨型羽绒被面料，并通过相同测试方法测定所制面料的防虫防螨性能、透气透湿性和防钻绒性，结果如表1所示。
表1本发明所制防虫防螨型面料的使用性能
项目 实施例1 实施例2 对照例1 对照例2 对照例3
虫螨防治率％ 99.58 99.64 98.47 94.65 98.89
防钻绒性 2根 2根 3根 3根 5根
透气率mm/s 29.8 30.2 28.5 25.9 21.8
透湿量g/m2.d 8741 8802 8316 8035 6423
以上显示和描述了本发明的基本原理和主要特征和本发明的优点。本行业的技术人员应该了解，本发明不受上述实施例的限制，上述实施例和说明书中描述的只是说明本发明的原理，在不脱离本发明精神和范围的前提下，本发明还会有各种变化和改进，这些变化和改进都落入要求保护的本发明范围内。本发明要求保护范围由所附的权利要求书及其等效物界定。

Claims (2)

1.一种防虫防螨型羽绒被面料的加工方法，其特征在于，主要包括如下步骤：
(1)棉纤维选择性氧化：利用4-乙酰氨基-TEMPO-NaClO-NaBr氧化体系对棉纤维进行选择性氧化，经离心、过滤、烘干制得羧基含量0.4-0.5mmol/g的羧基棉纤维；
(2)混纺纱线加工：将所制羧基棉纤维与聚氨酯纤维以质量比5-10:3-5的比例进行混纤，再经清花、梳棉、并条、粗纱、细纱工序加工制成混纺纱线；
(3)混纺纱线染色：对混纺纱线进行浸染，并在染液中混入防虫防螨剂，混纺纱线与防虫防螨剂质量比为1:0.03-0.05，染色结束后于45-55℃固色15-30min，并经水洗、脱水、烘干工序处理；
(4)面料织造：将染色后的混纺纱线经整经、浆纱、穿筘后上织布机，织造成平纹面料；
(5)面料轧光前处理：将轧光助剂加沸水搅拌制成15-25g/l的溶液，经自然冷却至40-50℃，再将织造所得面料浸渍于该溶液中，并于40-50℃保温15-30min，然后将面料取出，经脱水后于70-80℃烘干至重量含水量5-10％；
(6)面料轧光：将经轧光前处理的面料利用轧光机进行轧光，控制压力在6-7MPa，温度在120-130℃，车速在20-25m/min，反复轧光三次，每次间隔15-30min，最后经自然冷却定型；
所述防虫防螨剂由如下重量份数的原料制成：多聚谷氨酸10-15份、泊洛沙姆3-5份、茶皂素1-2份、聚乙烯醇树脂0.5-1份、聚氧化乙烯0.5-1份、六羟甲基三聚氰胺六甲醚0.3-0.5份、十二烷基二甲基苄基氯化铵0.1-0.3份、乙二胺二邻羟苯基大乙酸铁钠0.1-0.3份、纳米银0.05-0.1份，其制备方法为：向多聚谷氨酸中加入泊洛沙姆和聚乙烯醇树脂，所得粉体升温至50-55℃保温研磨10min，再在搅拌下以5ml/min的滴加速度滴加沸水，直至粉体全部溶解，然后加入茶皂素、十二烷基二甲基苄基氯化铵、乙二胺二邻羟苯基大乙酸铁钠和纳米银，充分混合后利用微波处理器微波5min，静置30min后再次微波5min，随后加入聚氧化乙烯和六羟甲基三聚氰胺六甲醚，混合均匀后将所得混合液送入喷雾干燥机中，干燥所得颗粒经超微粉碎机制成微粉，即得防虫防螨剂；
所述轧光助剂由如下重量份数的原料制成：N-羟甲基丙烯酰胺5-10份、阳离子聚丙烯酰胺3-5份、氢化松香季戊四醇酯1-2份、烯丙基缩水甘油醚1-2份、月桂醇磺基琥珀酸酯二钠0.5-1份、聚四氟乙烯超细粉0.1-0.3份、玻纤粉0.05-0.1份，其制备方法为：向氢化松香季戊四醇酯中加入月桂醇磺基琥珀酸酯二钠和聚四氟乙烯超细粉，升温至125-130℃保温混合15min，再加入烯丙基缩水甘油醚和玻纤粉，继续在125-130℃保温混合15min，并以5℃/min的降温速度降温至55-60℃，然后加入N-羟甲基丙烯酰胺和阳离子聚丙烯酰胺，充分混合后转入0-5℃环境中密封静置1h，最后经超微粉碎机制成微粉，即得轧光助剂。
2.据权利要求1所述的防虫防螨型羽绒被面料的加工方法，其特征在于：所述微波处理器的工作条件为微波频率2450MHz、输出功率700W。
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