CN107090714A - 一种抗菌吸汗型羽绒被面料的加工方法 - Google Patents

一种抗菌吸汗型羽绒被面料的加工方法 Download PDF

Info

Publication number
CN107090714A
CN107090714A CN201710404221.9A CN201710404221A CN107090714A CN 107090714 A CN107090714 A CN 107090714A CN 201710404221 A CN201710404221 A CN 201710404221A CN 107090714 A CN107090714 A CN 107090714A
Authority
CN
China
Prior art keywords
fabric
parts
calendering
scribbled
sweat
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710404221.9A
Other languages
English (en)
Inventor
李林刚
汪锐
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Three Auspicious Feather Ltd By Share Ltd
Original Assignee
Anhui Three Auspicious Feather Ltd By Share Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Three Auspicious Feather Ltd By Share Ltd filed Critical Anhui Three Auspicious Feather Ltd By Share Ltd
Priority to CN201710404221.9A priority Critical patent/CN107090714A/zh
Publication of CN107090714A publication Critical patent/CN107090714A/zh
Pending legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/59—Polyamides; Polyimides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
    • C08B15/00—Preparation of other cellulose derivatives or modified cellulose, e.g. complexes
    • C08B15/02—Oxycellulose; Hydrocellulose; Cellulosehydrate, e.g. microcrystalline cellulose
    • C08B15/04—Carboxycellulose, e.g. prepared by oxidation with nitrogen dioxide
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/04—Blended or other yarns or threads containing components made from different materials
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
    • D06B3/04—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of yarns, threads or filaments
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06C—FINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
    • D06C15/00—Calendering, pressing, ironing, glossing or glazing textile fabrics
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/35—Heterocyclic compounds
    • D06M13/355—Heterocyclic compounds having six-membered heterocyclic rings
    • D06M13/358—Triazines
    • D06M13/364—Cyanuric acid; Isocyanuric acid; Derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D06M13/41—Amides derived from unsaturated carboxylic acids, e.g. acrylamide
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/52—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment combined with mechanical treatment
    • D06M13/525—Embossing; Calendering; Pressing
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/17—Natural resins, resinous alcohols, resinous acids, or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/244—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons
    • D06M15/256—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons containing fluorine
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/285—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acid amides or imides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
    • D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/01—Natural vegetable fibres
    • D10B2201/02—Cotton
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00—Physical properties
    • D10B2401/02—Moisture-responsive characteristics
    • D10B2401/022—Moisture-responsive characteristics hydrophylic
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00—Physical properties
    • D10B2401/13—Physical properties anti-allergenic or anti-bacterial

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Biochemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

本发明公开了一种抗菌吸汗型羽绒被面料的加工方法，涉及羽绒被加工技术领域，主要包括如下步骤：(1)棉纤维选择性氧化，(2)混纺纱线加工，(3)混纺纱线染色，(4)面料织造，(5)面料轧光前处理，(6)面料轧光。本发明在混纺纱线染色过程中加入抗菌吸汗剂，通过染色工序同时赋予加工所制面料优异的抗菌吸汗功能，减少另增工序的成本投入，并且借助染料在纤维上的结合力提高抗菌吸汗剂的有效附着率；并通过对面料进行轧光前处理，在轧光助剂的作用下增强面料的透湿性和防钻绒性。

Description

一种抗菌吸汗型羽绒被面料的加工方法
技术领域：
本发明涉及羽绒被加工技术领域，具体涉及一种抗菌吸汗型羽绒被面料的加工方法。
背景技术：
羽绒被的填充物主要是羽绒，由于羽绒是一种动物性蛋白质纤维，比棉花保温性高，且羽绒球状纤维上密布千万个三角形的细小气孔，能随气温变化而收缩膨胀，产生调温功能，可吸收人体散发流动的热气，隔绝外界冷空气的入侵。
羽绒被由被芯和面料组成，该面料通常选用防绒面料，目的是为了防止使用普通面料存在的钻绒问题，同时保证面料的透气透湿性，以发挥羽绒的保暖性。目前，市场上的防绒面料不胜枚举，按成分划分为棉、涤纶、锦纶、锦涤交织等，都能达到基本的防绒要求，但防绒级别有高有低，并且难以兼具透气性和手感好的优点。
此外，抗菌吸汗性也属于羽绒被面料性能评价的主要指标之一。如果羽绒被面料的透气透湿性差，就很容易造成汗液在面料表面难以快速挥干，并且影响内部羽绒的透气透湿性，从而导致细菌和霉菌的滋生，影响羽绒被的使用卫生性。由于羽绒被清洗不便，因此直接影响了羽绒被的使用寿命，降低羽绒被的市场竞争力。
发明内容：
本发明所要解决的技术问题在于提供一种透气透湿性优异、防钻绒性好且对细菌和病菌滋生具有防治作用的抗菌吸汗型羽绒被面料的加工方法。
本发明所要解决的技术问题采用以下的技术方案来实现：
一种抗菌吸汗型羽绒被面料的加工方法，主要包括如下步骤：
(1)棉纤维选择性氧化：利用4-乙酰氨基-TEMPO-NaClO-NaBr氧化体系对棉纤维进行选择性氧化，经离心、过滤、烘干制得羧基含量0.4-0.5mmol/g的羧基棉纤维；
(2)混纺纱线加工：将所制羧基棉纤维与涤纶纤维以质量比5-10:3-5的比例进行混纤，再经清花、梳棉、并条、粗纱、细纱工序加工制成混纺纱线；
(3)混纺纱线染色：对混纺纱线进行浸染，并在染液中混入抗菌吸汗剂，混纺纱线与抗菌吸汗剂质量比为1:0.03-0.05，染色结束后于45-55℃固色15-30min，并经水洗、脱水、烘干工序处理；
(4)面料织造：将染色后的混纺纱线经整经、浆纱、穿筘后上织布机，织造成平纹面料；
(5)面料轧光前处理：将轧光助剂加沸水搅拌制成10-25g/l的溶液，经自然冷却至40-50℃，再将织造所得面料浸渍于该溶液中，并于40-50℃保温15-30min，然后将面料取出，经脱水后于70-80℃烘干至重量含水量5-10％；
(6)面料轧光：将经轧光前处理的面料利用轧光机进行轧光，控制压力在6-7MPa，温度在120-130℃，车速在20-25m/min，反复轧光三次，每次间隔15-30min，最后经自然冷却定型。
所述抗菌吸汗剂由如下重量份数的原料制成：多聚谷氨酸10-15份、泊洛沙姆3-5份、茶皂素1-2份、聚乙烯醇树脂0.5-1份、聚氧化乙烯0.5-1份、六羟甲基三聚氰胺六甲醚0.3-0.5份、纳米钛白粉0.1-0.3份、纳米银0.05-0.1份、二茂铁0.05-0.1份，其制备方法为：向多聚谷氨酸中加入泊洛沙姆和聚乙烯醇树脂，所得粉体升温至50-55℃保温研磨10min，再在搅拌下以5ml/min的滴加速度滴加沸水，直至粉体全部溶解，然后加入茶皂素、纳米钛白粉、纳米银和二茂铁，充分混合后利用微波处理器微波5min，静置30min后再次微波5min，随后加入聚氧化乙烯和六羟甲基三聚氰胺六甲醚，混合均匀后将所得混合液送入喷雾干燥机中，干燥所得颗粒经超微粉碎机制成微粉，即得抗菌吸汗剂。
所述微波处理器的工作条件为微波频率2450MHz、输出功率700W。
所述轧光助剂由如下重量份数的原料制成：N-羟甲基丙烯酰胺5-10份、阳离子聚丙烯酰胺3-5份、氢化松香季戊四醇酯1-2份、烯丙基缩水甘油醚1-2份、月桂醇磺基琥珀酸酯二钠0.5-1份、聚四氟乙烯超细粉0.1-0.3份、玻纤粉0.05-0.1份，其制备方法为：向氢化松香季戊四醇酯中加入月桂醇磺基琥珀酸酯二钠和聚四氟乙烯超细粉，升温至125-130℃保温混合15min，再加入烯丙基缩水甘油醚和玻纤粉，继续在125-130℃保温混合15min，并以5℃/min的降温速度降温至55-60℃，然后加入N-羟甲基丙烯酰胺和阳离子聚丙烯酰胺，充分混合后转入0-5℃环境中密封静置1h，最后经超微粉碎机制成微粉，即得轧光助剂。
本发明的有益效果是：在混纺纱线染色过程中加入抗菌吸汗剂，通过染色工序同时赋予加工所制面料优异的抗菌吸汗功能，减少另增工序的成本投入，并且借助染料在纤维上的结合力提高抗菌吸汗剂的有效附着率；并通过对面料进行轧光前处理，在轧光助剂的作用下增强面料的透湿性和防钻绒性，从而使加工所制面料满足作为羽绒被面料的使用性能要求，提高羽绒被的使用质量。
具体实施方式：
为了使本发明实现的技术手段、创作特征、达成目的与功效易于明白了解，下面结合具体实施例，进一步阐述本发明。
实施例1
(1)棉纤维选择性氧化：利用4-乙酰氨基-TEMPO-NaClO-NaBr氧化体系对棉纤维进行选择性氧化，经离心、过滤、烘干制得羧基含量0.4-0.5mmol/g的羧基棉纤维；
(2)混纺纱线加工：将所制羧基棉纤维与涤纶纤维以质量比8:3的比例进行混纤，再经清花、梳棉、并条、粗纱、细纱工序加工制成混纺纱线；
(3)混纺纱线染色：对混纺纱线进行浸染，并在染液中混入抗菌吸汗剂，混纺纱线与抗菌吸汗剂质量比为1:0.05，染色结束后于50-55℃固色30min，并经水洗、脱水、烘干工序处理；
(4)面料织造：将染色后的混纺纱线经整经、浆纱、穿筘后上织布机，织造成平纹面料；
(5)面料轧光前处理：将轧光助剂加沸水搅拌制成20g/l的溶液，经自然冷却至45-50℃，再将织造所得面料浸渍于该溶液中，并于45-50℃保温15-30min，然后将面料取出，经脱水后于70-75℃烘干至重量含水量5-10％；
(6)面料轧光：将经轧光前处理的面料利用轧光机进行轧光，控制压力在6-7MPa，温度在125-130℃，车速在20-25m/min，反复轧光三次，每次间隔15min，最后经自然冷却定型。
抗菌吸汗剂的制备：向15g多聚谷氨酸中加入5g泊洛沙姆和0.5g聚乙烯醇树脂，所得粉体升温至50-55℃保温研磨10min，再在搅拌下以5ml/min的滴加速度滴加沸水，直至粉体全部溶解，然后加入2g茶皂素、0.2g纳米钛白粉、0.05g纳米银和0.05g二茂铁，充分混合后利用微波频率2450MHz、输出功率700W的微波处理器微波5min，静置30min后再次微波5min，随后加入0.5g聚氧化乙烯和0.3g六羟甲基三聚氰胺六甲醚，混合均匀后将所得混合液送入喷雾干燥机中，干燥所得颗粒经超微粉碎机制成微粉，即得抗菌吸汗剂。
轧光助剂的制备：向2g氢化松香季戊四醇酯中加入0.5g月桂醇磺基琥珀酸酯二钠和0.1g聚四氟乙烯超细粉，升温至125-130℃保温混合15min，再加入1g烯丙基缩水甘油醚和0.05g玻纤粉，继续在125-130℃保温混合15min，并以5℃/min的降温速度降温至55-60℃，然后加入8gN-羟甲基丙烯酰胺和5g阳离子聚丙烯酰胺，充分混合后转入0-5℃环境中密封静置1h，最后经超微粉碎机制成微粉，即得轧光助剂。
实施例2
(1)棉纤维选择性氧化：利用4-乙酰氨基-TEMPO-NaClO-NaBr氧化体系对棉纤维进行选择性氧化，经离心、过滤、烘干制得羧基含量0.4-0.5mmol/g的羧基棉纤维；
(2)混纺纱线加工：将所制羧基棉纤维与涤纶纤维以质量比8:3的比例进行混纤，再经清花、梳棉、并条、粗纱、细纱工序加工制成混纺纱线；
(3)混纺纱线染色：对混纺纱线进行浸染，并在染液中混入抗菌吸汗剂，混纺纱线与抗菌吸汗剂质量比为1:0.05，染色结束后于50-55℃固色30min，并经水洗、脱水、烘干工序处理；
(4)面料织造：将染色后的混纺纱线经整经、浆纱、穿筘后上织布机，织造成平纹面料；
(5)面料轧光前处理：将轧光助剂加沸水搅拌制成25g/l的溶液，经自然冷却至45-50℃，再将织造所得面料浸渍于该溶液中，并于45-50℃保温15-30min，然后将面料取出，经脱水后于70-75℃烘干至重量含水量5-10％；
(6)面料轧光：将经轧光前处理的面料利用轧光机进行轧光，控制压力在6-7MPa，温度在125-130℃，车速在20-25m/min，反复轧光三次，每次间隔15min，最后经自然冷却定型。
抗菌吸汗剂的制备：向12g多聚谷氨酸中加入3g泊洛沙姆和0.5g聚乙烯醇树脂，所得粉体升温至50-55℃保温研磨10min，再在搅拌下以5ml/min的滴加速度滴加沸水，直至粉体全部溶解，然后加入1g茶皂素、0.2g纳米钛白粉、0.05g纳米银和0.05g二茂铁，充分混合后利用微波频率2450MHz、输出功率700W的微波处理器微波5min，静置30min后再次微波5min，随后加入0.5g聚氧化乙烯和0.3g六羟甲基三聚氰胺六甲醚，混合均匀后将所得混合液送入喷雾干燥机中，干燥所得颗粒经超微粉碎机制成微粉，即得抗菌吸汗剂。
轧光助剂的制备：向2g氢化松香季戊四醇酯中加入0.5g月桂醇磺基琥珀酸酯二钠和0.1g聚四氟乙烯超细粉，升温至125-130℃保温混合15min，再加入2g烯丙基缩水甘油醚和0.05g玻纤粉，继续在125-130℃保温混合15min，并以5℃/min的降温速度降温至55-60℃，然后加入10g N-羟甲基丙烯酰胺和3g阳离子聚丙烯酰胺，充分混合后转入0-5℃环境中密封静置1h，最后经超微粉碎机制成微粉，即得轧光助剂。
对照例1
(1)棉纤维选择性氧化：利用4-乙酰氨基-TEMPO-NaClO-NaBr氧化体系对棉纤维进行选择性氧化，经离心、过滤、烘干制得羧基含量0.4-0.5mmol/g的羧基棉纤维；
(2)混纺纱线加工：将所制羧基棉纤维与涤纶纤维以质量比8:3的比例进行混纤，再经清花、梳棉、并条、粗纱、细纱工序加工制成混纺纱线；
(3)混纺纱线染色：对混纺纱线进行浸染，染色结束后于50-55℃固色30min，并经水洗、脱水、烘干工序处理；
(4)面料织造：将染色后的混纺纱线经整经、浆纱、穿筘后上织布机，织造成平纹面料；
(5)面料轧光前处理：将轧光助剂加沸水搅拌制成25g/l的溶液，经自然冷却至45-50℃，再将织造所得面料浸渍于该溶液中，并于45-50℃保温15-30min，然后将面料取出，经脱水后于70-75℃烘干至重量含水量5-10％；
(6)面料轧光：将经轧光前处理的面料利用轧光机进行轧光，控制压力在6-7MPa，温度在125-130℃，车速在20-25m/min，反复轧光三次，每次间隔15min，最后经自然冷却定型。
轧光助剂的制备：向2g氢化松香季戊四醇酯中加入0.5g月桂醇磺基琥珀酸酯二钠和0.1g聚四氟乙烯超细粉，升温至125-130℃保温混合15min，再加入2g烯丙基缩水甘油醚和0.05g玻纤粉，继续在125-130℃保温混合15min，并以5℃/min的降温速度降温至55-60℃，然后加入10g N-羟甲基丙烯酰胺和3g阳离子聚丙烯酰胺，充分混合后转入0-5℃环境中密封静置1h，最后经超微粉碎机制成微粉，即得轧光助剂。
对照例2
(1)棉纤维选择性氧化：利用4-乙酰氨基-TEMPO-NaClO-NaBr氧化体系对棉纤维进行选择性氧化，经离心、过滤、烘干制得羧基含量0.4-0.5mmol/g的羧基棉纤维；
(2)混纺纱线加工：将所制羧基棉纤维与涤纶纤维以质量比8:3的比例进行混纤，再经清花、梳棉、并条、粗纱、细纱工序加工制成混纺纱线；
(3)混纺纱线染色：对混纺纱线进行浸染，并在染液中混入抗菌吸汗剂，混纺纱线与抗菌吸汗剂质量比为1:0.05，染色结束后于50-55℃固色30min，并经水洗、脱水、烘干工序处理；
(4)面料织造：将染色后的混纺纱线经整经、浆纱、穿筘后上织布机，织造成平纹面料；
(5)面料轧光：将面料利用轧光机进行轧光，控制压力在6-7MPa，温度在125-130℃，车速在20-25m/min，反复轧光三次，每次间隔15min，最后经自然冷却定型。
抗菌吸汗剂的制备：向12g多聚谷氨酸中加入3g泊洛沙姆和0.5g聚乙烯醇树脂，所得粉体升温至50-55℃保温研磨10min，再在搅拌下以5ml/min的滴加速度滴加沸水，直至粉体全部溶解，然后加入1g茶皂素、0.2g纳米钛白粉、0.05g纳米银和0.05g二茂铁，充分混合后利用微波频率2450MHz、输出功率700W的微波处理器微波5min，静置30min后再次微波5min，随后加入0.5g聚氧化乙烯和0.3g六羟甲基三聚氰胺六甲醚，混合均匀后将所得混合液送入喷雾干燥机中，干燥所得颗粒经超微粉碎机制成微粉，即得抗菌吸汗剂。
对照例3
(1)棉纤维选择性氧化：利用4-乙酰氨基-TEMPO-NaClO-NaBr氧化体系对棉纤维进行选择性氧化，经离心、过滤、烘干制得羧基含量0.4-0.5mmol/g的羧基棉纤维；
(2)混纺纱线加工：将所制羧基棉纤维与涤纶纤维以质量比8:3的比例进行混纤，再经清花、梳棉、并条、粗纱、细纱工序加工制成混纺纱线；
(3)混纺纱线染色：对混纺纱线进行浸染，染色结束后于50-55℃固色30min，并经水洗、脱水、烘干工序处理；
(4)面料织造：将染色后的混纺纱线经整经、浆纱、穿筘后上织布机，织造成平纹面料；
(5)面料轧光：将面料利用轧光机进行轧光，控制压力在6-7MPa，温度在125-130℃，车速在20-25m/min，反复轧光三次，每次间隔15min，最后经自然冷却定型。
实施例3
分别利用实施例1、实施例2、对照例1、对照例2和对照例3所述方法加工制备抗菌吸汗型羽绒被面料，并通过相同测试方法测定所制面料的抗菌吸汗性能、透气透湿性和防钻绒性，结果如表1所示。
表1本发明所制抗菌吸汗型面料的使用性能
项目 实施例1 实施例2 对照例1 对照例2 对照例3
平均抑菌率％ 99.2 99.3 93.5 99.0 92.8
防钻绒性 2根 2根 4根 5根 5根
透气度mm/s 28.9 29.1 26.6 22.3 20.7
透湿量g/m2.d 8657 8712 7930 6685 5514
其中，平均抑制率是指对金色葡萄球菌、白色念珠球菌和大肠杆菌的平均抑菌率。
以上显示和描述了本发明的基本原理和主要特征和本发明的优点。本行业的技术人员应该了解，本发明不受上述实施例的限制，上述实施例和说明书中描述的只是说明本发明的原理，在不脱离本发明精神和范围的前提下，本发明还会有各种变化和改进，这些变化和改进都落入要求保护的本发明范围内。本发明要求保护范围由所附的权利要求书及其等效物界定。

Claims (4)

1.一种抗菌吸汗型羽绒被面料的加工方法，其特征在于，主要包括如下步骤：
(1)棉纤维选择性氧化：利用4-乙酰氨基-TEMPO-NaClO-NaBr氧化体系对棉纤维进行选择性氧化，经离心、过滤、烘干制得羧基含量0.4-0.5mmol/g的羧基棉纤维；
(2)混纺纱线加工：将所制羧基棉纤维与涤纶纤维以质量比5-10:3-5的比例进行混纤，再经清花、梳棉、并条、粗纱、细纱工序加工制成混纺纱线；
(3)混纺纱线染色：对混纺纱线进行浸染，并在染液中混入抗菌吸汗剂，混纺纱线与抗菌吸汗剂质量比为1:0.03-0.05，染色结束后于45-55℃固色15-30min，并经水洗、脱水、烘干工序处理；
(4)面料织造：将染色后的混纺纱线经整经、浆纱、穿筘后上织布机，织造成平纹面料；
(5)面料轧光前处理：将轧光助剂加沸水搅拌制成10-25g/l的溶液，经自然冷却至40-50℃，再将织造所得面料浸渍于该溶液中，并于40-50℃保温15-30min，然后将面料取出，经脱水后于70-80℃烘干至重量含水量5-10％；
(6)面料轧光：将经轧光前处理的面料利用轧光机进行轧光，控制压力在6-7MPa，温度在120-130℃，车速在20-25m/min，反复轧光三次，每次间隔15-30min，最后经自然冷却定型。
2.根据权利要求1所述的抗菌吸汗型羽绒被面料的加工方法，其特征在于，所述抗菌吸汗剂由如下重量份数的原料制成：多聚谷氨酸10-15份、泊洛沙姆3-5份、茶皂素1-2份、聚乙烯醇树脂0.5-1份、聚氧化乙烯0.5-1份、六羟甲基三聚氰胺六甲醚0.3-0.5份、纳米钛白粉0.1-0.3份、纳米银0.05-0.1份、二茂铁0.05-0.1份，其制备方法为：向多聚谷氨酸中加入泊洛沙姆和聚乙烯醇树脂，所得粉体升温至50-55℃保温研磨10min，再在搅拌下以5ml/min的滴加速度滴加沸水，直至粉体全部溶解，然后加入茶皂素、纳米钛白粉、纳米银和二茂铁，充分混合后利用微波处理器微波5min，静置30min后再次微波5min，随后加入聚氧化乙烯和六羟甲基三聚氰胺六甲醚，混合均匀后将所得混合液送入喷雾干燥机中，干燥所得颗粒经超微粉碎机制成微粉，即得抗菌吸汗剂。
3.根据权利要求2所述的抗菌吸汗型羽绒被面料的加工方法，其特征在于：所述微波处理器的工作条件为微波频率2450MHz、输出功率700W。
4.根据权利要求1所述的抗菌吸汗型羽绒被面料的加工方法，其特征在于，所述轧光助剂由如下重量份数的原料制成：N-羟甲基丙烯酰胺5-10份、阳离子聚丙烯酰胺3-5份、氢化松香季戊四醇酯1-2份、烯丙基缩水甘油醚1-2份、月桂醇磺基琥珀酸酯二钠0.5-1份、聚四氟乙烯超细粉0.1-0.3份、玻纤粉0.05-0.1份，其制备方法为：向氢化松香季戊四醇酯中加入月桂醇磺基琥珀酸酯二钠和聚四氟乙烯超细粉，升温至125-130℃保温混合15min，再加入烯丙基缩水甘油醚和玻纤粉，继续在125-130℃保温混合15min，并以5℃/min的降温速度降温至55-60℃，然后加入N-羟甲基丙烯酰胺和阳离子聚丙烯酰胺，充分混合后转入0-5℃环境中密封静置1h，最后经超微粉碎机制成微粉，即得轧光助剂。
CN201710404221.9A 2017-06-01 2017-06-01 一种抗菌吸汗型羽绒被面料的加工方法 Pending CN107090714A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710404221.9A CN107090714A (zh) 2017-06-01 2017-06-01 一种抗菌吸汗型羽绒被面料的加工方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710404221.9A CN107090714A (zh) 2017-06-01 2017-06-01 一种抗菌吸汗型羽绒被面料的加工方法

Publications (1)

Publication Number Publication Date
CN107090714A true CN107090714A (zh) 2017-08-25

Family

ID=59639890

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710404221.9A Pending CN107090714A (zh) 2017-06-01 2017-06-01 一种抗菌吸汗型羽绒被面料的加工方法

Country Status (1)

Country Link
CN (1) CN107090714A (zh)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109338576A (zh) * 2018-10-24 2019-02-15 迦南(福建)新材料科技有限公司 一种蜂窝状面料及其制作工艺
CN110067139A (zh) * 2019-03-21 2019-07-30 杭州康浩一家家居科技有限公司 一种抗菌保温面料及其制造工艺、使用该面料的羽绒被
CN110215095A (zh) * 2019-06-12 2019-09-10 凯盛家纺股份有限公司 一种抗菌透气羽绒蚕丝被的生产工艺
CN114059210A (zh) * 2020-07-30 2022-02-18 湖南科力嘉纺织股份有限公司 一种高吸湿性纱线及其制备方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103898659A (zh) * 2014-03-24 2014-07-02 昆山华成织染有限公司 一种高强度防绒织物及其生产方法
CN103938471A (zh) * 2014-04-18 2014-07-23 长兴宏峰纺织印染有限公司 一种棉织物的印染工艺
CN106012260A (zh) * 2016-06-06 2016-10-12 宁波狮丹努集团有限公司 仪纶/棉混纺纬平针针织面料及其制备方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103898659A (zh) * 2014-03-24 2014-07-02 昆山华成织染有限公司 一种高强度防绒织物及其生产方法
CN103938471A (zh) * 2014-04-18 2014-07-23 长兴宏峰纺织印染有限公司 一种棉织物的印染工艺
CN106012260A (zh) * 2016-06-06 2016-10-12 宁波狮丹努集团有限公司 仪纶/棉混纺纬平针针织面料及其制备方法

Non-Patent Citations (10)

* Cited by examiner, † Cited by third party
Title
《工业毒理学》编写组: "《工业毒理学（下册）》", 31 August 1977, 上海人民出版社 *
乔庆东等: "《碳五烯烃的精细化工利用》", 31 January 2015, 辽宁科学技术出版社 *
刘一山等: "《制浆造纸助剂及其应用技术》", 31 August 2010, 中国轻工业出版社 *
孙宝国: "《日用化工词典》", 30 June 2002, 化学工业出版社 *
张书华等: "《高性能电缆材料及其应用技术》", 30 November 2015, 上海交通大学出版社 *
李广宇等: "《胶粘剂原材料手册》", 31 August 2004, 国防工业出版社 *
董银卯: "《化妆品配方设计与生产工艺》", 30 April 2004, 中国纺织出版社 *
陈宗懋等: "《中国茶叶词典》", 31 July 2013, 上海文化出版社 *
陈清等: "《水溶性肥料生产与施用》", 30 June 2016, 中国农业出版社 *
陈溥等: "《纺织染整助剂手册》", 31 August 1995, 中国轻工业出版社 *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109338576A (zh) * 2018-10-24 2019-02-15 迦南(福建)新材料科技有限公司 一种蜂窝状面料及其制作工艺
CN110067139A (zh) * 2019-03-21 2019-07-30 杭州康浩一家家居科技有限公司 一种抗菌保温面料及其制造工艺、使用该面料的羽绒被
CN110067139B (zh) * 2019-03-21 2021-12-21 杭州康浩一家家居科技有限公司 一种抗菌保温面料及其制造工艺、使用该面料的羽绒被
CN110215095A (zh) * 2019-06-12 2019-09-10 凯盛家纺股份有限公司 一种抗菌透气羽绒蚕丝被的生产工艺
CN114059210A (zh) * 2020-07-30 2022-02-18 湖南科力嘉纺织股份有限公司 一种高吸湿性纱线及其制备方法

Similar Documents

Publication Publication Date Title
CN107090714A (zh) 一种抗菌吸汗型羽绒被面料的加工方法
CN103361805B (zh) 汉麻、莫代尔和涤纶混纺面料
CN103361997B (zh) 蚕蛹蛋白、棉和涤纶混纺面料
CN104988742B (zh) 一种棉质衬衫的凉感免烫处理方法
CN103526374B (zh) 远红外莫代尔纤维家纺面料
CN104695227B (zh) 一种远红外棉纤维的生产工艺
CN106436329A (zh) 一种衬衫的护肤持久抗菌免烫整理液及其整理方法
CN107201578A (zh) 一种热湿舒适性纺织品加工用复合纤维
CN107012565B (zh) 一种防虫防螨型羽绒被面料的加工方法
CN103103809A (zh) 绿色环保纤维混纺面料
CN106592225A (zh) 一种衬衫的香薰护肤型免烫整理液及其整理方法
CN103382599B (zh) 牛奶蛋白纤维、Viloft纤维和涤纶混纺面料
CN106436298A (zh) 一种衬衫的吸水导湿环保抗皱型免烫整理液及其整理方法
CN103388268A (zh) 亚麻、羊毛和涤纶混纺面料
CN107227638A (zh) 由亲水性聚酯纤维/羧基棉纤维所制混纺织物的染色工艺
CN107034563A (zh) 利用亲水性聚酯纤维/羧基棉纤维制作混纺纱线的工艺
CN103498250A (zh) 甲壳素纤维、Coolmax纤维和涤纶混纺面料
CN107938109A (zh) 仿羊绒面料
CN107354730A (zh) 一种混纺纱线加工用抗静电剂及其制备方法
CN104342777B (zh) 一种具有远红外功能的涤纶单丝及其制备方法
CN110172794A (zh) 洗涤吸色布及其制备工艺
CN104153030A (zh) 一种有色玉米纤维织物的制造方法
CN107326475A (zh) 一种吸热透气的女性内衣面料以及加工方法
CN107630259A (zh) 多功能夏季用清凉感面料的制备方法
CN110306272A (zh) 一种免染棉缝纫线高强度生产工艺

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20170825