CN107136559B - Natural eutectic solvent humectant for smoke of glucose-type and its preparation method and application - Google Patents
Natural eutectic solvent humectant for smoke of glucose-type and its preparation method and application Download PDFInfo
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- CN107136559B CN107136559B CN201710545073.2A CN201710545073A CN107136559B CN 107136559 B CN107136559 B CN 107136559B CN 201710545073 A CN201710545073 A CN 201710545073A CN 107136559 B CN107136559 B CN 107136559B
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
- A24B15/30—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances
- A24B15/302—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances by natural substances obtained from animals or plants
Abstract
A kind of natural eutectic solvent humectant for smoke of glucose-type and its application in cigarette, the humectant are mixed with by following components：The natural eutectic solvent of glucose-type 10% 50%, preservative 0.1% 0.5%, antifoaming agent 0.1% 0.5%, water 10% 70%.This humectant is applied to cigarette humectation, the degrading resistance property of tobacco can not only be improved, reduction tobacco leaf is made broken, reduce the consumption of cigarette tobacco leaf in process, and jealous and mouthfeel can also be improved, reduce the effects that flue gas stimulation, play while improving the effect of the humectation of tobacco physics and sense organ humectation.It is an advantage of the invention that the natural eutectic solvent synthetic method of glucose-type is simple, and it is non-volatile, it is nonflammable；Synthesis material is the ingredient contained in natural products and tobacco, environmentally protective；Meanwhile synthesis material is also flue gas latent aromatic substance, has certain effect to improving cigarette sense organ fragrance, has potential popularizing application prospect.
Description
Technical field
The present invention relates to a kind of tobacco additive agent technology, the specifically natural eutectic solvent tobacco humectations of glucose-type
The preparation of agent and its application in cigarette, the humectant is environmentally protective, has while improving the humectation of tobacco physics and sense organ is protected
The double effects of profit.
Background technology
Tobacco humectant can improve the physical property of tobacco, enhance humectation and wettability power, reduce tobacco leaf in process
In make it is broken.Meanwhile humectant also has the function of reducing flue gas stimulation, improves jealous and mouthfeel.Currently, China's tobacco business
In mainly use the polyhydroxy substances such as glycerine, propylene glycol, xylitol and sorbierite as humectant.But propylene glycol is in cigarette
To generate acetaldehyde and acetone in aspiration procedure, harmful substances from flue gases content is caused to increase.Meanwhile propylene glycol can also give flue gas band
Carry out penetrating odor.Therefore, with the development of modern science and technology, having become the heat of research to the exploitation of new type natural humectant at present
Point.
Eutectic solvent was reported in 2003 by Abbott etc. for the first time, referred to passing through hydrogen by hydrogen bond donor and hydrogen bond receptor
The eutectic mixture for the binary or ternary that key effect is composed.It is liquid under eutectic solvent room temperature, is a kind of novel
Ionic liquid.As ionic liquid, eutectic solvent volatility is low, fusing point is low, nonflammable；Meanwhile eutectic solvent also has
There is the features such as non-toxic, synthesis is simple, biodegradable, environmental-friendly.Natural eutectic solvent refers to by native compound（Such as
Sugar, amino acid, organic acid etc.）The eutectic solvent of composition, is widely present in plant.Since water can be molten with natural eutectic
Hydrogen bond action in agent, natural eutectic solvent have excellent water retention property.Meanwhile natural eutectic solvent is basic by plant
Metabolome is the ingredient that tobacco itself contains at, green natural, is important flavor precursor.Therefore, exploitation is natural
Eutectic solvent has very strong practical value to improving tobacco physics humectation ability and improving cigarette taste, has wide popularization
Application prospect.
Invention content
The purpose of the present invention is based on above-mentioned prior art situation and a kind of new and effective, environmentally protective Portugal for developing
The natural eutectic solvent tobacco humectant of grape sugar-type, the humectant have same using the natural eutectic solvent of glucose-type as raw material
The double effects of the Shi Gaishan humectation of tobacco physics and sense organ humectation.
The purpose of the present invention is achieved through the following technical solutions：
A kind of natural eutectic solvent tobacco humectant of glucose-type, is mixed with by following components in percentage by weight
It forms：The natural eutectic solvent 10%-50% of glucose-type, preservative 0.1%-0.5%, antifoaming agent 0.1%-0.5%, surplus is water,
PH value is neutrality；
The natural eutectic solvent of glucose-type is the natural eutectic solvent of following four binary glucose-type：D-(+)-
Glucose-D, L MALIC ACID, D- (+)-glucose-L- (+) tartaric acid, D- (+)-glucose-D/L- proline, D- (+)-grape
Any one of sugar-Serine；Or a kind of natural eutectic solvent of ternary glucose-type：D- (+)-glucose-D- (-)-
Fructose-sucrose.
The natural eutectic solvent of binary glucose-type synthesizes in accordance with the following methods：By D- (+)-glucose and another group
Point D, L MALIC ACID, L- (+) tartaric acid, D/L- proline, Serine any one solid powder according to molar ratio 1:1 or
1:2 are added in round-bottomed flask, and heating water bath stirring is formed up to transparency liquid, water bath heating temperature 70oC-90 oC, instead
It is 2-3 h between seasonable.
The natural eutectic solvent of ternary glucose-type synthesizes in accordance with the following methods：By D- (+)-glucose, D- (-)-
Fructose, sucrose solids powder are according to molar ratio 1:1:1 or 1:2:1 is added in round-bottomed flask, and heating water bath stirring is until transparent
Liquid is formed, water bath heating temperature 70oC-90 oC, water-bath time are 2-3 h.
The preparation method of the natural eutectic solvent tobacco humectant of glucose-type is as follows：By the glucose-type day of above-mentioned synthesis
Right eutectic solvent is proportionally added into water, adjust pH to neutrality, then adds the preservative of 0.1%-0.5%, 0.1%-0.5%
Antifoaming agent can be prepared by the natural eutectic solvent humectant of glucose-type.
It is hydrochloric acid or sodium hydrate aqueous solution, a concentration of weight ratio 0.5-5% of aqueous hydrochloric acid solution to adjust pH value agents useful for same；
A concentration of weight ratio 0.5-10% of sodium hydrate aqueous solution.
By the natural eutectic solvent tobacco humectant of glucose-type, uniformly sprinkling in the tobacco, has while improving tobacco
The effect of humectation and sense organ humectation is managed, dosage is the 0.1%-1.5% of tobacco quality.
It is an advantage of the invention that raw materials used is the natural eutectic solvent of glucose-type, and it is environmentally protective, it is non-volatile, it is not easy
Combustion, synthetic method are simple；Due to the hydrogen bond action of hydrogen bond and water, there is excellent water retention property.In addition, synthesis material is day
The flue gas latent aromatic substance contained in right product and tobacco has certain effect to improving cigarette sense organ fragrance.Therefore, Portugal
The natural eutectic solvent of grape sugar-type not only has the effect of tobacco humectation, but also has some improvement to flue gas sense organ tool.
Meanwhile by adding the natural eutectic solvent tobacco humectant of glucose-type in the present invention, the resist processing of tobacco can be improved
Can, reduce tobacco leaf in process make it is broken.
Specific implementation mode
Invention is described further with reference to embodiment, but the scope of the invention is not limited to these embodiments.
Embodiment 1. weighs D- (+)-glucose and D, L MALIC ACID solid powder, according to molar ratio 1:1, total amount 100
G is added in round-bottomed flask, and 80oC water-baths are added and stir, until transparency liquid is formed, water-bath time is 2.5 small
When.200 milliliters of water is added by synthesized D- (+)-glucose-D, in the natural eutectic solvent of L MALIC ACID, quality is added dropwise
It is neutrality that 5% sodium hydroxide solution of score, which adjusts pH,.Addition 1.0g preservatives and 1.0g antifoaming agent can be prepared by D- (+)-grape
Sugar-D, the natural eutectic solvent humectant of L MALIC ACID.10g humectants are weighed, are uniformly sprayed onto on 1000g pipe tobaccos, humectant
Dosage be quality of tobacco 1%.Cigarette sample is prepared with the pipe tobacco.
Embodiment 2. weighs D- (+)-glucose and L- (+) tartaric acid solid powder, according to molar ratio 1:2, total amount is
100 g, are added in round-bottomed flask, and 75oC water-baths are added and stir, until transparency liquid is formed, water-bath time is 3 small
When.200 milliliters of water will be added in synthesized D- (+)-natural eutectic solvent of glucose-L- (+) tartaric acid, quality is added dropwise
It is neutrality that 5% sodium hydroxide solution of score, which adjusts pH,.Addition 1.0g preservatives and 1.0g antifoaming agent can be prepared by D- (+)-grape
The natural eutectic solvent humectant of sugar-L- (+) tartaric acid.10g humectants are weighed, are uniformly sprayed onto on 1000g pipe tobaccos, humectant
Dosage be quality of tobacco 1%.Cigarette sample is prepared with the pipe tobacco.
Embodiment 3. weighs D- (+)-glucose, D- (-)-fructose and sucrose solids powder, according to molar ratio 1:1:1, always
Amount is 100 g, is added in round-bottomed flask, 80oC water-baths are added and stir, until transparency liquid is formed, water-bath time
It is 2 hours.It is water-soluble by 300 milliliters are added in synthesized D- (+)-glucose-D- (-)-fructose-natural eutectic solvent of sucrose
Liquid.It is molten that addition 1.2g preservatives and 1.2g antifoaming agent can be prepared by D- (+)-glucose-D- (-)-fructose-natural eutectic of sucrose
Agent humectant.10g humectants are weighed, are uniformly sprayed onto on 1000g pipe tobaccos, the dosage of humectant is quality of tobacco 1%.With the cigarette
Silk prepares cigarette sample.
The natural eutectic solvent of glucose-type provided by the present invention, which is applied to cigarette industry production, preferably cigarette
Physics humectation ability and sense organ humectation effect.Applicant is to inventing three kinds of provided embodiments with the prior art in tobacco business
Main propylene glycol to be used has carried out the comparative evaluation of physics humectation ability, and evaluation results are shown in Table 1.Simultaneously to sense organ humectation effect
Comparison has been carried out using two different modes of smokeing panel test to smoke panel test, and 2 are shown in Table by the evaluation result of tobacco additive agent sensory evaluating smoking's method.
It is shown in Table 3 by the evaluation result of Sensory Quality of Cigarette evaluation method.
The physics humectation evaluation of the different humectants of table 1
Note：RH=relative humidity, pipe tobacco equilibration time are 48h
The sense organ humectation evaluation of the different humectants of table 2（Method one）
3 sense organ humectation of table is evaluated（Method two）
The natural eutectic solvent cigarette humectation of glucose-type provided in three embodiments of the invention as can be seen from Table 1
Agent water holding capacity is better than propylene glycol, has preferable physics humectation effect to cigarette.In sensory evaluation, judging panel gives character property
It summarizes：Propylene glycol free from extraneous odour, perfume quantity is sufficient, and fragrance is sent out more thoroughly, and flue gas slightly shows coarse, slightly stimulates；Glucose-type is naturally low
Congruent melting solvent humectant for smoke free from extraneous odour, perfume quantity is sufficient, and fragrance is sent out more thoroughly, and flue gas is finer and smoother, soft, stimulates smaller, pleasant impression
It is relatively clean, it is preferable to return sweet tea.By table 2, table 3 it is also seen that the natural eutectic solvent humectant for smoke of glucose-type can be effective
Improving the mouthfeel of flue gas, mitigate irritation and improves pleasant impression comfort level, sensory effects are better than propylene glycol used in the prior art,
Three embodiment scores are above propylene glycol.
Claims (7)
1. a kind of natural eutectic solvent tobacco humectant of glucose-type, it is characterised in that：It is by the group of following weight percent
Divide and is mixed with：Glucose-type natural eutectic solvent 10%-50%, preservative 0.1%-0.5%, antifoaming agent 0.1%-0.5%,
Surplus is water, and pH value is neutrality；
The natural eutectic solvent of glucose-type is the natural eutectic solvent of following four binary glucose-type：D- (+)-grape
Sugar-D, L MALIC ACID, D- (+)-glucose-L- (+) tartaric acid, D- (+)-glucose-D/L- proline, D- (+)-glucose-
Any one of Serine；Or a kind of natural eutectic solvent of ternary glucose-type：D- (+)-glucose-D- (-)-fruit
Sugar-sucrose.
2. the natural eutectic solvent tobacco humectant of glucose-type according to claim 1, it is characterised in that：The binary
The natural eutectic solvent of glucose-type synthesizes in accordance with the following methods：By D- (+)-glucose and another component D, L MALIC ACID, L-
(+) tartaric acid, D/L- proline, Serine any one solid powder according to molar ratio 1:1 or 1:2 are added to round bottom burning
In bottle, until transparency liquid is formed, water bath heating temperature is 70 DEG C -90 DEG C for heating water bath stirring, and the reaction time is 2-3 h.
3. the natural eutectic solvent tobacco humectant of glucose-type according to claim 1, it is characterised in that：The ternary
The natural eutectic solvent of glucose-type synthesizes in accordance with the following methods：By D- (+)-glucose, D- (-)-fructose, sucrose solids powder
According to molar ratio 1:1:1 or 1:2:1 is added in round-bottomed flask, and heating water bath stirring is formed up to transparency liquid, heating water bath
Temperature is 70 DEG C -90 DEG C, and water-bath time is 2-3 h.
4. a kind of preparation method of the natural eutectic solvent tobacco humectant of glucose-type described in claim 1, feature exist
In：The natural eutectic solvent of the glucose-type of above-mentioned synthesis is proportionally added into water, adjusts pH to neutrality, then add
The preservative of 0.1%-0.5%, the antifoaming agent of 0.1%-0.5% can be prepared by the natural eutectic solvent humectant of glucose-type.
5. the preparation method of the natural eutectic solvent tobacco humectant of glucose-type according to claim 4, feature exist
In：It is hydrochloric acid or sodium hydrate aqueous solution to adjust pH value agents useful for same.
6. the preparation method of the natural eutectic solvent tobacco humectant of glucose-type according to claim 4, feature exist
In：A concentration of weight ratio 0.5-5% of aqueous hydrochloric acid solution；A concentration of weight ratio 0.5-10% of sodium hydrate aqueous solution.
7. a kind of application of natural eutectic solvent tobacco humectant of glucose-type as described in claim 1 in cigarette,
It is characterized in that：By the natural eutectic solvent tobacco humectant of glucose-type, uniformly sprinkling in the tobacco, has while improving tobacco
The effect of physics humectation and sense organ humectation, dosage are the 0.1%-1.5% of tobacco quality.
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| CN201710545073.2A CN107136559B (en) | 2017-07-06 | 2017-07-06 | Natural eutectic solvent humectant for smoke of glucose-type and its preparation method and application |
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| CN201710545073.2A CN107136559B (en) | 2017-07-06 | 2017-07-06 | Natural eutectic solvent humectant for smoke of glucose-type and its preparation method and application |
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| CN107136559B true CN107136559B (en) | 2018-08-03 |
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| CN113125482A (en) * | 2021-04-20 | 2021-07-16 | 浙江科技学院 | Eutectic solvent for sample preparation of cryoelectron microscope and preparation method thereof |
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| US5860428A (en) * | 1993-01-11 | 1999-01-19 | Craig Lesser | Cigarette filter containing a humectant |
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