CN110477439B - Sugar ester essence for heating non-burning cigarette, tobacco sheet and non-burning cigarette - Google Patents
Sugar ester essence for heating non-burning cigarette, tobacco sheet and non-burning cigarette Download PDFInfo
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- CN110477439B CN110477439B CN201910615128.1A CN201910615128A CN110477439B CN 110477439 B CN110477439 B CN 110477439B CN 201910615128 A CN201910615128 A CN 201910615128A CN 110477439 B CN110477439 B CN 110477439B
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
- A24B15/30—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/0007—Aliphatic compounds
- C11B9/0015—Aliphatic compounds containing oxygen as the only heteroatom
Abstract
The invention discloses sugar ester essence for heating non-burning cigarettes, a tobacco sheet and the non-burning cigarettes, wherein the sugar ester essence comprises a sugar ester essence base and an auxiliary essence base; the sugar ester base comprises a base agent and sugar esters, the sugar esters comprise at least five glucose tetraesters and at least four methyl glucose tetraesters, and the ratio of the sum of the masses of the sugar esters to the mass of the base agent is (63-127.5): (777.5-887); the auxiliary perfume base comprises perfume oil, heliotropin, vanillin and dihydrocoumarin; the ratio of the sum of the mass of the sugar esters to the mass of the auxiliary fragrance base is (63-127.5) to (50-95). The method adopts the sugar ester as the fragrance source of the micromolecular fatty acid, effectively overcomes the defects of easy volatilization, high reaction activity and strong corrosivity of the micromolecular fatty acid, and has the advantage of difficult deterioration compared with the common saccharide component.
Description
Technical Field
The invention relates to the field of heating non-combustible cigarettes, in particular to sugar ester essence and a tobacco sheet for heating non-combustible cigarettes and the non-combustible cigarettes.
Background
In recent years, with the rapid development of social economy and the rapid improvement of the living standard of people, the majority of consumers increasingly pay attention to personal health, and increasingly high requirements such as low tar, low stimulation, faint scent, high comfort and the like are put forward on the inherent quality of tobacco consumption products. The tobacco industry improves the traditional cigarettes and researches and develops novel tobacco products, and the cigarette which is not burnt is heated, namely the cigarette which is developed most rapidly.
When the cigarette is heated and is not burnt for smoking, a heating appliance and a cigarette bullet are needed, and the tobacco sheets in the cigarette bullet are heated through the heating appliance, so that nicotine and flavor substances in the sheets are volatilized, and smoke is generated to meet the requirements of smokers. The heating temperature for heating the non-burning cigarette is 280-330 ℃, which is far lower than the burning temperature of the traditional cigarette, generates few harmful substances, and meets the requirements of the current consumers, thereby becoming a product which is sought after by the consumers.
The essence and the spice are the most key core technology for heating the non-combustible cigarette. The essence and the spice not only endow the heated non-combustible cigarette with different style characteristics, but also improve the smoking quality of the heated non-combustible cigarette. The micromolecular fatty acid is widely used in various tobacco products, plays an important role in improving the quality of cigarettes, can endow the cigarettes with comfortable smell, and plays an important role in improving the quality of the cigarettes. However, the micromolecular fatty acid has small molecular weight, strong volatility, reactivity and corrosiveness, can pollute the working environment and a production line, and is easy to chemically react with other substances in tobacco essence and tobacco leaves to influence the quality of cigarettes. In addition, when the existing micromolecular fatty acid is added into the cigarette which is not burnt by heating, the problem of gradual mouth attenuation exists. That is, the aroma and flavor generated by the small-molecular fatty acid are weakened as the number of the smoking openings increases, and the aroma is very thin at the end of the cigarette, so that the smoking feeling of uniform release of the aroma cannot be obtained.
Therefore, how to provide a small molecular fatty acid substitute essence suitable for heating non-burning cigarettes becomes a technical problem to be solved urgently in the field.
Disclosure of Invention
One object of the present invention is to provide a new technical solution of sugar ester flavor suitable for heating non-burning cigarettes.
According to a first aspect of the present invention there is provided a sugar ester flavour for use in heating non-combustible cigarettes.
The sugar ester essence for heating the non-combustible cigarette comprises a sugar ester essence base and an auxiliary essence base; wherein the content of the first and second substances,
the sugar ester base comprises a base agent and sugar esters, the sugar esters comprise at least five glucose tetraesters and at least four methyl glucose tetraesters, and the ratio of the sum of the masses of the sugar esters to the mass of the base agent is (63-127.5): (777.5-887);
the auxiliary perfume base comprises perfume oil, heliotropin, vanillin and dihydrocoumarin;
the ratio of the sum of the mass of the sugar esters to the mass of the auxiliary fragrance base is (63-127.5) to (50-95).
Optionally, the base agent is propylene glycol.
Optionally, the difference between the boiling points of the sugar esters is less than or equal to 100 ℃, and the boiling points of the sugar esters are greater than or equal to 350 ℃.
Optionally, the glucose tetraesters include 6-O-acetyl-2, 3, 4-tri-O-propionyl-D-glucopyranose, 6-O-acetyl-2, 3, 4-tri-O-butyryl-D-glucopyranose, 6-O-acetyl-2, 3, 4-tri-O-pentanoyl-D-glucopyranose, 6-O-acetyl-2, 3, 4-tri-O-hexanoyl-D-glucopyranose, and 6-O-acetyl-2, 3, 4-tri-O-heptanoyl-D-glucopyranose, the methylglucose tetraesters include 6-O-acetyl-2, 3, 4-tri-O-isobutyryl- α -D-methyl glucopyranoside, 6-O-acetyl-2, 3, 4-tri-O-isovaleryl- α -D-methyl glucopyranose, 6-O-acetyl-2, 3, 4-tri-O-2-methylbutyryl- α -D-methyl glucopyranose and 6-O-acetyl-2, 3, 4-tri-O-3-methylpentanoyl- α -D-methyl glucopyranose.
Optionally, the 6-O-acetyl-2, 3, 4-tri-O-propionyl-D-glucopyranose, the 6-O-acetyl-2, 3, 4-tri-O-butyryl-D-glucopyranose, the 6-O-acetyl-2, 3, 4-tri-O-pentanoyl-D-glucopyranose, the 6-O-acetyl-2, 3, 4-tri-O-hexanoyl-D-glucopyranose, the 6-O-acetyl-2, 3, 4-tri-O-heptanoyl-D-glucopyranose, the 6-O-acetyl-2, the mass ratio of the 6-O-acetyl-2, 3, 4-tri-O-isovaleryl-alpha-D-methyl glucopyranose, the 6-O-acetyl-2, 3, 4-tri-O-2-methylbutyryl-alpha-D-methyl glucopyranose and the 6-O-acetyl-2, 3, 4-tri-O-3-methylpentanyl-alpha-D-methyl glucopyranose is (1.0-1.5): 0.5-1.0): 0.3-0.8: (0.6-1.2): 0.2-0.5): 0.4-0.8: (0.6-1.2): 0.4-0.9: (0.2-0.6).
Optionally, the perfume oil comprises geranium oil, clove oil, nutmeg oil, lavender oil, cinnamon leaf oil, balsam pear tree bark oil, rose oil and cinnamon oil.
Optionally, the mass ratio of the geranium oil, the clove oil, the nutmeg oil, the lavender oil, the cinnamon leaf oil, the bitter cedar bark oil, the rose oil and the cinnamon oil is (12-18): 4-6): 2-5): 4-8): 1-4): 3-6): 5-10): 2-8.
Optionally, the mass ratio of the geranium oil, the clove oil, the nutmeg oil, the lavender oil, the cinnamon oil, the bitter wood bark oil, the rose oil, the cinnamon oil, the heliotropin, the vanillin, and the dihydrocoumarin is (12-18): 4-6): 4-8: (1-4): 3-6): 5-10: (2-8): 4-8): 5-10: 8-12. According to a second aspect of the present invention, there is provided a tobacco sheet for heating a non-combustible cigarette.
The sugar ester essence for heating the non-combustible cigarette is added to the tobacco sheet for heating the non-combustible cigarette, and the mass percentage of the sugar ester essence for heating the non-combustible cigarette is 6-8%.
According to a third aspect of the present invention, there is provided a non-combustible cigarette.
The non-combustible cigarette comprises the tobacco sheet for heating a non-combustible cigarette of the present invention.
The method adopts the sugar ester as the fragrance source of the micromolecular fatty acid, effectively overcomes the defects of easy volatilization, high reaction activity and strong corrosivity of the micromolecular fatty acid, and has the advantage of difficult deterioration compared with the common saccharide component. Moreover, the fragrance precursor substance disclosed by the invention can be cracked at about 300 ℃ to release fragrance substances such as 2-methylpropionaldehyde, 3-propionaldehyde-2-ketone, 2-cyclopentene-1-ketone, isovaleric anhydride, furfuryl methyl acetate, various organic acids and the like, the cracking transfer rate is up to 75%, the fragrance precursor substance can be fully matched with the heating temperature of 280 ℃ and 330 ℃ for heating the non-combustible cigarette and can play respective advantages and effects, and fragrance can be uniformly and stably released in the heating of the non-combustible cigarette.
In addition, the special formula of the auxiliary base can be coordinated with the fragrance of the sugar ester base, so that the problem of single fragrance and taste is solved, the fragrance can be further improved and modified, the fragrance quality is improved, the fragrance amount is increased, miscellaneous gases are covered, the sweet and moist feeling is increased, the tobacco fragrance is coordinated, the smoke concentration is increased, the sensory comfort is increased, the irritation is reduced, and the smoking taste and aftertaste are improved.
Further features of the invention and advantages thereof will become apparent from the following detailed description of exemplary embodiments.
Detailed Description
The following description of at least one exemplary embodiment is merely illustrative in nature and is in no way intended to limit the invention, its application, or uses.
Techniques, methods, and apparatus known to those of ordinary skill in the relevant art may not be discussed in detail but are intended to be part of the specification where appropriate.
In all examples shown and discussed herein, any particular value should be construed as merely illustrative, and not limiting. Thus, other examples of the exemplary embodiments may have different values.
The sugar ester essence for heating the non-combustible cigarette comprises a sugar ester essence base and an auxiliary essence base. The sugar ester essence group is a source for adding fragrance to tobacco leaves. The auxiliary perfume base can play a role in modifying and improving the fragrance.
The sugar ester base comprises a base agent and sugar ester. The substrate can be an organic solvent, and the skilled person can flexibly select the substrate according to actual needs. The sugar esters include at least five glucose tetraesters and at least four methyl glucose tetraesters. The compounding formula of various different types of sugar ester is beneficial to improving the coordination of the fragrance. The sugar ester may be, for example, 6-O-acetyl-2, 3, 4-tri-O-propionyl-D-glucopyranose, 6-O-acetyl-2, 3, 4-tri-O-butyryl-D-glucopyranose, 6-O-acetyl-2, 3, 4-tri-O-pentanoyl-D-glucopyranose, 6-O-acetyl-2, 3, 4-tri-O-hexanoyl-D-glucopyranose, 6-O-acetyl-2, 3, 4-tri-O-heptanoyl-D-glucopyranose, 6-O-acetyl-2, 3, 4-tri-O-isobutyryl-alpha-D-methyl glucopyranoside 6-O-acetyl-2, 3, 4-tri-O-isovaleryl-alpha-D-methyl glucopyranose, 6-O-acetyl-2, 3, 4-tri-O-2-methylbutyryl-alpha-D-methyl glucopyranose, and 6-O-acetyl-2, 3, 4-tri-O-3-methyl pentanoyl-alpha-D-methyl glucopyranose, and the like.
The ratio of the sum of the masses of the sugar esters to the mass of the base agent is (63-127.5): (777.5-887).
The sugar ester molecules can form a protective film on the surface of the tobacco sheet to prevent water from losing and achieve the effect of moisture retention.
The auxiliary perfume base comprises perfume oil, heliotropin, vanillin and dihydrocoumarin. The content ratio of each component in the auxiliary perfume base can be selected according to requirements.
The perfume oil can be, for example, geranium oil, clove oil, nutmeg oil, lavender oil, cinnamon leaf oil, bitter cedar wood oil, rose oil, cinnamon oil, and the like. The skilled person can flexibly select the method according to actual requirements.
The ratio of the sum of the mass of the sugar esters to the mass of the auxiliary fragrance base is (63-127.5) to (50-95).
The method adopts the sugar ester as the fragrance source of the micromolecular fatty acid, effectively overcomes the defects of easy volatilization, high reaction activity and strong corrosivity of the micromolecular fatty acid, and has the advantage of difficult deterioration compared with the common saccharide component. Moreover, the fragrance precursor substance disclosed by the invention can be cracked at about 300 ℃ to release fragrance substances such as 2-methylpropionaldehyde, 3-propionaldehyde-2-ketone, 2-cyclopentene-1-ketone, isovaleric anhydride, furfuryl methyl acetate, various organic acids and the like, the cracking transfer rate is up to 75%, the fragrance precursor substance can be fully matched with the heating temperature of 280 ℃ and 330 ℃ for heating the non-combustible cigarette and can play respective advantages and effects, and fragrance can be uniformly and stably released in the heating of the non-combustible cigarette.
In addition, the special formula of the auxiliary base can be coordinated with the fragrance of the sugar ester base, so that the problem of single fragrance and taste is solved, the fragrance can be further improved and modified, the fragrance quality is improved, the fragrance amount is increased, miscellaneous gases are covered, the sweet and moist feeling is increased, the tobacco fragrance is coordinated, the smoke concentration is increased, the sensory comfort is increased, the irritation is reduced, and the smoking taste and aftertaste are improved.
In one embodiment of the sugar ester flavor for a heat non-combustible cigarette of the present disclosure, the base agent is propylene glycol.
In one embodiment of the sugar ester flavor for a heat-not-burn cigarette of the present disclosure, in order to improve the harmony of the aroma released upon smoking, the difference between the boiling points of the respective sugar esters is 100 ℃ or less, and the boiling points of the respective sugar esters are 350 ℃ or more.
In one embodiment of the sugar ester flavour for non-combustible heated cigarettes of the present disclosure, the glucose tetraesters include 6-O-acetyl-2, 3, 4-tri-O-propionyl-D-glucopyranose, 6-O-acetyl-2, 3, 4-tri-O-butyryl-D-glucopyranose, 6-O-acetyl-2, 3, 4-tri-O-pentanoyl-D-glucopyranose, 6-O-acetyl-2, 3, 4-tri-O-hexanoyl-D-glucopyranose and 6-O-acetyl-2, 3, 4-tri-O-heptanoyl-D-glucopyranose, the methyl glucose tetraesters include 6-O-acetyl-2, 3, 4-tri-O-isobutyryl-alpha-D-methyl glucopyranoside, 6-O-acetyl-2, 3, 4-tri-O-isovaleryl-alpha-D-methyl glucopyranose, 6-O-acetyl-2, 3, 4-tri-O-2-methylbutyryl-alpha-D-methyl glucopyranose and 6-O-acetyl-2, 3, 4-tri-O-3-methyl valeryl-alpha-D-methyl glucopyranose. The six sugar esters have the characteristics of high boiling point, difficult volatilization and the like, not only effectively avoid the volatilization, reaction loss and corrosivity of the micromolecule fatty acid in the processing process of the heating non-combustible cigarette, but also better solve the problems of gradual volatilization, attenuation and the like of the micromolecule fatty acid in the storage and placement process of the heating non-combustible cigarette.
Further, 6-O-acetyl-2, 3, 4-tri-O-propionyl-D-glucopyranose, 6-O-acetyl-2, 3, 4-tri-O-butyryl-D-glucopyranose, 6-O-acetyl-2, 3, 4-tri-O-valeryl-D-glucopyranose, 6-O-acetyl-2, 3, 4-tri-O-hexanoyl-D-glucopyranose, 6-O-acetyl-2, 3, 4-tri-O-heptanoyl-D-glucopyranose, 6-O-acetyl-2, 3, 4-tri-O-isobutyryl-alpha-D-methyl glucopyranoside, The mass ratio of 6-O-acetyl-2, 3, 4-tri-O-isovaleryl-alpha-D-methyl glucopyranose to 6-O-acetyl-2, 3, 4-tri-O-2-methylbutyryl-alpha-D-methyl glucopyranose to 6-O-acetyl-2, 3, 4-tri-O-3-methyl pentanoyl-alpha-D-methyl glucopyranose is (1.0-1.5): 0.5-1.0): 0.3-0.8): 0.6-1.2): 0.2-0.5): 0.4-0.8): 0.6-1.2): 0.4-0.9): 0.2-0.6.
In one embodiment of the sugar ester flavor for heating non-combustible cigarettes of the present disclosure, the flavor oils include geranium oil, clove oil, nutmeg oil, lavender oil, pimenta oil, coriander oil, rose oil, and cinnamon oil for better aroma improvement and modification.
Further, the mass ratio of the geranium oil, the clove oil, the nutmeg oil, the lavender oil, the cinnamon leaf oil, the bitter cedar bark oil, the rose oil and the cinnamon oil is (12-18): 4-6): 2-5): 4-8): 1-4: (3-6): 5-10): 2-8.
Further, the mass ratio of geranium oil, clove oil, nutmeg oil, lavender oil, cinnamon leaf oil, bitter cedar bark oil, rose oil, cinnamon oil, heliotropin, vanillin and dihydrocoumarin is (12-18): 4-6): 2-5): 4-8): 1-4: (3-6): 5-10): 2-8: (4-8): 5-10): 8-12.
The present disclosure also provides a tobacco sheet for heating a non-combustible cigarette.
The sugar ester essence for heating the non-combustible cigarette is added on the tobacco sheet for heating the non-combustible cigarette. The mass percentage of the sugar ester essence for heating the non-combustible cigarette is 6-8%.
The present disclosure also provides a non-combustible cigarette.
The non-combustible cigarette includes the tobacco sheet for heating a non-combustible cigarette of the present disclosure.
The experimental procedures used in the examples below are conventional unless otherwise specified, the materials and reagents used therein are commercially available, and the equipment used in the experiments are well known to those skilled in the art without otherwise specified.
Example one
Preparing 15g of 6-O-acetyl-2, 3, 4-tri-O-propionyl-D-glucopyranose, 7.5g of 6-O-acetyl-2, 3, 4-tri-O-butyryl-D-glucopyranose, 4.5g of 6-O-acetyl-2, 3, 4-tri-O-valeryl-D-glucopyranose, 9.0g of 6-O-acetyl-2, 3, 4-tri-O-hexanoyl-D-glucopyranose, 3.0g of 6-O-acetyl-2, 3, 4-tri-O-heptanoyl-D-glucopyranose and 6-O-acetyl-2, 6.0g of 3, 4-tri-O-isobutyryl-alpha-D-methyl glucopyranoside, 9.0g of 6-O-acetyl-2, 3, 4-tri-O-isovaleryl-alpha-D-methyl glucopyranose, 6-O-acetyl-2, 3, 4-tri-O-2-methyl butyryl-alpha-D-methyl glucopyranose and 3.0g of 6-O-acetyl-2, 3, 4-tri-O-3-methyl valeryl-alpha-D-methyl glucopyranose are fully and uniformly stirred to prepare sugar ester balsam. Weighing 12.0g of geranium oil, 4.0g of clove oil, 2.0g of nutmeg oil, 4.0g of lavender oil, 1.0g of cinnamon leaf oil, 3.0g of bitter cedar wood oil, 5.0g of rose oil, 2.0g of cinnamon oil, 4.0g of piperonal, 5.0g of vanillin and 8.0g of dihydrocoumarin, and fully oscillating, mixing and dissolving to prepare an auxiliary fragrance base; mixing the prepared sugar ester essence and auxiliary essence, adding 887.0g propylene glycol, and fully oscillating to obtain sugar ester essence S1 for heating non-combustible cigarettes.
6 wt% of sugar ester essence S1 is added to the tobacco sheet, and then the tobacco sheet is made into comfortable type D1 with fragrance and non-burning tobacco.
Example two
The preparation method comprises mixing 6-O-acetyl-2, 3, 4-tri-O-propionyl-D-glucopyranose 17.5g, 6-O-acetyl-2, 3, 4-tri-O-butyryl-D-glucopyranose 10.0g, 6-O-acetyl-2, 3, 4-tri-O-valeryl-D-glucopyranose 7.0g, 6-O-acetyl-2, 3, 4-tri-O-hexanoyl-D-glucopyranose 12g, 6-O-acetyl-2, 3, 4-tri-O-heptanoyl-D-glucopyranose 5.0g and 6-O-acetyl-2, 9.0g of 3, 4-tri-O-isobutyryl-alpha-D-methyl glucopyranoside, 12.0g of 6-O-acetyl-2, 3, 4-tri-O-isovaleryl-alpha-D-methyl glucopyranose, 9.0g of 6-O-acetyl-2, 3, 4-tri-O-2-methyl butyryl-alpha-D-methyl glucopyranose and 4.0g of 6-O-acetyl-2, 3, 4-tri-O-3-methyl valeryl-alpha-D-methyl glucopyranose are fully stirred uniformly to prepare sugar ester balsam. Weighing 15.0g of geranium oil, 5.0g of clove oil, 4.0g of nutmeg oil, 6.0g of lavender oil, 2.0g of cinnamon leaf oil, 5.0g of bitter cedar wood oil, 8.0g of rose oil, 5.0g of cinnamon oil, 6.0g of heliotropin, 8.0g of vanillin and 10.0g of dihydrocoumarin, and fully oscillating, mixing and dissolving to prepare an auxiliary fragrance base; mixing the prepared sugar ester essence and auxiliary essence, adding 840.5g propylene glycol, and fully oscillating to obtain sugar ester essence S2 for heating non-combustible cigarettes.
After 7 wt% of sugar ester essence S2 was added to the tobacco sheet, the tobacco sheet was made into comfortable flavor nonflammable cigarette D2.
EXAMPLE III
Preparing 20.0g of 6-O-acetyl-2, 3, 4-tri-O-propionyl-D-glucopyranose, 12.5g of 6-O-acetyl-2, 3, 4-tri-O-butyryl-D-glucopyranose, 10.0g of 6-O-acetyl-2, 3, 4-tri-O-valeryl-D-glucopyranose, 15g of 6-O-acetyl-2, 3, 4-tri-O-hexanoyl-D-glucopyranose, 6-O-acetyl-2, 3, 4-tri-O-heptanoyl-D-glucopyranose, 6.0g of 6-O-acetyl-2, 3, 4-tri-O-heptanoyl-D-glucopyranose and 6-O-acetyl-2, 10.0g of 3, 4-tri-O-isobutyryl-alpha-D-methyl glucopyranoside, 15.0g of 6-O-acetyl-2, 3, 4-tri-O-isovaleryl-alpha-D-methyl glucopyranose, 12.0g of 6-O-acetyl-2, 3, 4-tri-O-2-methyl butyryl-alpha-D-methyl glucopyranose and 6.0g of 6-O-acetyl-2, 3, 4-tri-O-3-methyl valeryl-alpha-D-methyl glucopyranose are fully stirred uniformly to prepare sugar ester balsam. Weighing 16.0g of geranium oil, 5.0g of clove oil, 4.0g of nutmeg oil, 7.0g of lavender oil, 3.0g of cinnamon leaf oil, 5.0g of bitter cedar wood oil, 9.0g of rose oil, 6.0g of cinnamon oil, 6.0g of piperonal, 9.0g of vanillin and 11.0g of dihydrocoumarin, and fully oscillating, mixing and dissolving to prepare an auxiliary fragrance base; mixing the prepared sugar ester essence and auxiliary essence, adding 812.5g of propylene glycol, and fully oscillating to obtain the sugar ester essence S3 for heating the non-combustible cigarette.
8 wt% of sugar ester essence S3 is added to the tobacco sheet, and then the tobacco sheet is made into comfortable type D3 with fragrance and non-burning tobacco.
Example four
The preparation method comprises mixing 6-O-acetyl-2, 3, 4-tri-O-propionyl-D-glucopyranose 22.5g, 6-O-acetyl-2, 3, 4-tri-O-butyryl-D-glucopyranose 15.0g, 6-O-acetyl-2, 3, 4-tri-O-valeryl-D-glucopyranose 12.0g, 6-O-acetyl-2, 3, 4-tri-O-hexanoyl-D-glucopyranose 18g, 6-O-acetyl-2, 3, 4-tri-O-heptanoyl-D-glucopyranose 7.5g and 6-O-acetyl-2, 12.0g of 3, 4-tri-O-isobutyryl-alpha-D-methyl glucopyranoside, 18.0g of 6-O-acetyl-2, 3, 4-tri-O-isovaleryl-alpha-D-methyl glucopyranose, 13.5g of 6-O-acetyl-2, 3, 4-tri-O-2-methyl butyryl-alpha-D-methyl glucopyranose and 9.0g of 6-O-acetyl-2, 3, 4-tri-O-3-methyl valeryl-alpha-D-methyl glucopyranose are fully stirred uniformly to prepare sugar ester balsam. Weighing 18g of geranium oil, 6g of clove oil, 5g of nutmeg oil, 8g of lavender oil, 4g of cinnamon leaf oil, 6g of bitter cedar wood oil, 10g of rose oil, 8g of cinnamon oil, 8g of heliotropin, 10g of vanillin and 12g of dihydrocoumarin, and fully oscillating, mixing and dissolving to prepare an auxiliary essence base; mixing the prepared sugar ester essence and auxiliary essence, adding 777.5g propylene glycol, and fully oscillating to obtain sugar ester essence S4 for heating non-combustible cigarettes.
6 wt% of sugar ester essence S4 is added to the tobacco sheet, and then the tobacco sheet is made into comfortable type D4 with fragrance and non-burning tobacco.
The prepared comfortable cigarette without burning aroma D1-D4 and the blank cigarette without adding sugar ester essence are respectively inserted into a cigarette bullet, and smoking evaluation is carried out on the cigarette, and the results are shown in the following table.
As can be seen from the above table, the comfortable cigarette which is not burnt by heating prepared by the method has better harmony between the spice and the cigarette fragrance compared with a blank cigarette, and can effectively reduce the irritation, relieve the dryness, cover up the miscellaneous gas, increase the sweetness, increase the comfortableness of the oral cavity and the nasal cavity and improve the aftertaste. But the dosage of the sugar ester essence cannot be too large, otherwise, the sweet and greasy feeling occurs, the tobacco fragrance is covered due to the overweight spice, the fragrance quality is reduced, the smoke concentration and the penetrability are reduced, the irritation is increased, the oral cavity is remained, and the like.
Although some specific embodiments of the present invention have been described in detail by way of examples, it should be understood by those skilled in the art that the above examples are for illustrative purposes only and are not intended to limit the scope of the present invention. It will be appreciated by those skilled in the art that modifications may be made to the above embodiments without departing from the scope and spirit of the invention. The scope of the invention is defined by the appended claims.
Claims (7)
1. The sugar ester essence for heating the non-combustible cigarette is characterized by comprising a sugar ester essence base and an auxiliary essence base; wherein the content of the first and second substances,
the sugar ester base comprises a base agent and sugar esters, the sugar esters comprise at least five glucose tetraesters and at least four methyl glucose tetraesters, and the ratio of the sum of the masses of the sugar esters to the mass of the base agent is (63-127.5): (777.5-887);
the auxiliary perfume base comprises perfume oil, heliotropin, vanillin and dihydrocoumarin;
the ratio of the sum of the masses of the sugar esters to the mass of the auxiliary fragrance base is (63-127.5) to (50-95);
the difference between the boiling points of the sugar esters is less than or equal to 100 ℃, and the boiling points of the sugar esters are greater than or equal to 350 ℃;
the glucose tetraesters include 6-O-acetyl-2, 3, 4-tri-O-propionyl-D-glucopyranose, 6-O-acetyl-2, 3, 4-tri-O-butyryl-D-glucopyranose, 6-O-acetyl-2, 3, 4-tri-O-pentanoyl-D-glucopyranose, 6-O-acetyl-2, 3, 4-tri-O-hexanoyl-D-glucopyranose and 6-O-acetyl-2, 3, 4-tri-O-heptanoyl-D-glucopyranose, the methylglucose tetraesters include 6-O-acetyl-2, 3, 4-tri-O-isobutyryl- α -D-methyl glucopyranoside, 6-O-acetyl-2, 3, 4-tri-O-isovaleryl- α -D-methyl glucopyranose, 6-O-acetyl-2, 3, 4-tri-O-2-methylbutyryl- α -D-methyl glucopyranose, and 6-O-acetyl-2, 3, 4-tri-O-3-methylpentanoyl- α -D-methyl glucopyranose;
the 6-O-acetyl-2, 3, 4-tri-O-propionyl-D-glucopyranose, the 6-O-acetyl-2, 3, 4-tri-O-butyryl-D-glucopyranose, the 6-O-acetyl-2, 3, 4-tri-O-pentanoyl-D-glucopyranose, the 6-O-acetyl-2, 3, 4-tri-O-hexanoyl-D-glucopyranose, the 6-O-acetyl-2, 3, 4-tri-O-heptanoyl-D-glucopyranose, the 6-O-acetyl-2, the mass ratio of the 6-O-acetyl-2, 3, 4-tri-O-isovaleryl-alpha-D-methyl glucopyranose, the 6-O-acetyl-2, 3, 4-tri-O-2-methylbutyryl-alpha-D-methyl glucopyranose and the 6-O-acetyl-2, 3, 4-tri-O-3-methylpentanyl-alpha-D-methyl glucopyranose is (1.0-1.5): 0.5-1.0): 0.3-0.8: (0.6-1.2): 0.2-0.5): 0.4-0.8: (0.6-1.2): 0.4-0.9: (0.2-0.6).
2. The sugar ester flavor for heating non-combustible cigarettes according to claim 1, wherein the base agent is propylene glycol.
3. A sugar ester flavour for heating non-combustible cigarettes according to claim 1, wherein the flavour oil comprises geranium oil, clove oil, nutmeg oil, lavender oil, pimenta officinalis oil, balsamiferous wood oil, rose oil and cinnamon oil.
4. The sugar ester essence for heating non-burning cigarettes according to claim 3, wherein the mass ratio of the geranium oil, the clove oil, the nutmeg oil, the lavender oil, the pimenta officinalis leaf oil, the picrorhiza kurroa bark oil, the rose oil and the cinnamon oil is (12-18): 4-6): 2-5): 4-8): 1-4): 3-6): 5-10): 2-8.
5. The sugar ester essence for heating non-burning cigarettes according to claim 3, wherein the mass ratio of the geranium oil, the clove oil, the nutmeg oil, the lavender oil, the pimenta officinalis oil, the picrasma oil, the rose oil, the cinnamon oil, the heliotropin, the vanillin, and the dihydrocoumarin is (12-18): 4-6): 2-5): 4-8): 1-4): 3-6): 5-10): 2-8: (4-8): 5-10): 8-12.
6. A tobacco sheet for heating a non-burning cigarette is characterized in that the sugar ester essence for heating the non-burning cigarette as claimed in any one of claims 1 to 5 is added on the tobacco sheet for heating the non-burning cigarette, and the mass percentage of the sugar ester essence for heating the non-burning cigarette is 6-8%.
7. A non-combustible cigarette, characterized by comprising the tobacco sheet for heating a non-combustible cigarette as claimed in claim 6.
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| CN112155249A (en) * | 2020-10-16 | 2021-01-01 | 河南中烟工业有限责任公司 | Essence for improving sense comfort and cigarette paper |
| CN115029185B (en) * | 2022-06-30 | 2023-08-18 | 河南中烟工业有限责任公司 | Method for catalyzing low-temperature cracking of sugar ester compound and application thereof |
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