CN110477439A - For heating the sugar ester essence and reconstituted tobacoo and the cigarette that do not burn of the cigarette that do not burn - Google Patents
For heating the sugar ester essence and reconstituted tobacoo and the cigarette that do not burn of the cigarette that do not burn Download PDFInfo
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- CN110477439A CN110477439A CN201910615128.1A CN201910615128A CN110477439A CN 110477439 A CN110477439 A CN 110477439A CN 201910615128 A CN201910615128 A CN 201910615128A CN 110477439 A CN110477439 A CN 110477439A
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
- A24B15/30—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/0007—Aliphatic compounds
- C11B9/0015—Aliphatic compounds containing oxygen as the only heteroatom
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Abstract
The sugar ester essence and reconstituted tobacoo that the invention discloses a kind of for heating the cigarette that do not burn and the cigarette that do not burn, sugar ester essence include sugar ester perfume base and auxiliary perfume base；Sugar ester perfume base includes substrate agent and sugar ester, and sugar ester includes at least four ester of five kinds of glucose tetra-esters and at least four methyl glucosides, and the ratio of the quality of the quality sum of each sugar ester and the substrate agent is (63-127.5): (777.5-887)；Assisting perfume base includes spice oil, heliotropin, vanillic aldehyde and dihydrocoumarin；The ratio of the quality of the quality sum and auxiliary perfume base of each sugar ester is (63-127.5): (50-95).The disclosure uses aroma source of the sugar ester as small molecule fatty acid, effectively improves the disadvantage that small molecule fatty acid is volatile, reactivity is high and corrosivity is strong, also has the advantages that be unlikely to deteriorate compared to common carbohydrate content.
Description
Technical field
The present invention relates to cigarette field of not burning is heated, more particularly, to a kind of for heating the sugar for the cigarette that do not burn
Ester essence and reconstituted tobacoo and the cigarette that do not burn.
Background technique
In recent years, with the rapid development of social economy with the rapid raising of living standards of the people, the majority of consumers are increasingly
Pay attention to personal health, in tobacco consumption product quality propose low tar, low stimulation, delicate fragrance type, high comfortably etc. more next
Higher requirement.Tobacco business is studied and has been opened to new tobacco products while improving to traditional cigarette, also
Hair, heating the cigarette that do not burn is exactly one kind wherein with fastest developing speed.
It heats and needs having heaters tool and smoke grenade when not burning smoking property of cigarette, it is thin to the tobacco in smoke grenade by heating utensil
Piece is heated, so that nicotine and fragrance matter in the thin slice that volatilizees, generate flue gas to meet smoker's demand.It heats non-ignitable
The heating temperature for burning cigarette is 280-330 DEG C, is far below traditional cigarette ignition temperature, and generation harmful substance is few, meets and disappears now
The person's of expense demand, therefore become the product that consumer pursues.
Flavors and fragrances is to heat the core technology for the cigarette most critical that do not burn.Flavors and fragrances can not only assign heating and not burn
Cigarette different-style feature, and improve and heat smoking property of cigarette quality of not burning.Small molecule fatty acid is widely used in various tobaccos
It in product, plays an important role to cigarette quality is promoted, can assign cigarette comfortable breath, played to cigarette quality is promoted
Important role.But small molecule fatty acid molecule amount is smaller, has very strong volatility, reactivity and corrosivity, not only
Working environment and production line can be polluted, and is easy to chemically react with the other materials in tobacco essence and tobacco leaf, is influenced
Cigarette quality.In addition, existing small molecule fatty acid is added to when heating in the cigarette that do not burn, exist by mouth attenuation problem.
It is that fragrance and fragrance that small molecule fatty acid generates weaken with the increase of puff number, has arrived cigarette end, fragrance is non-
It is often thin, the suction that fragrance uniformly discharges cannot be obtained and felt.
Therefore, how to provide it is a kind of suitable for heat the cigarette that do not burn small molecule fatty acid substitute essence become this field
The technical problem of urgent need to resolve.
Summary of the invention
The new solution that it is an object of the present invention to provide a kind of suitable for heating the sugar ester essence for the cigarette that do not burn.
According to the first aspect of the invention, it provides a kind of for heating the sugar ester essence for the cigarette that do not burn.
This is used to heat the sugar ester essence for the cigarette that do not burn, including sugar ester perfume base and auxiliary perfume base；Wherein,
The sugar ester perfume base includes substrate agent and sugar ester, and the sugar ester includes at least five kinds of glucose tetra-esters and at least four
The ratio of the quality of four ester of methyl glucoside, the quality sum of each sugar ester and the substrate agent is (63-127.5): (777.5-
887)；
The auxiliary perfume base includes spice oil, heliotropin, vanillic aldehyde and dihydrocoumarin；
The ratio of the quality sum of each sugar ester and the quality of the auxiliary perfume base is (63-127.5): (50-95).
Optionally, the substrate agent is propylene glycol.
Optionally, the difference of the boiling point of each sugar ester be less than or equal to 100 DEG C, and the boiling point of each sugar ester be all larger than or
Equal to 350 DEG C.
Optionally, the glucose tetra-ester includes 6-O- acetyl group -2,3, tri--O- propiono-D- glucopyranose of 4-, 6-
Three-O- bytyry-D- glucopyranose of O- acetyl group -2,3,4-, the three-O- valeryl-D- pyrans Portugal 6-O- acetyl group -2,3,4-
Grape sugar, three-O- caproyl-D- glucopyranose of 6-O- acetyl group -2,3,4- and three-O- heptanoyl group of 6-O- acetyl group -2,3,4- -
D- glucopyranose, four ester of methyl glucoside include 6-O- acetyl group -2,3, tri--O- isobutyryl-α-D- methyl pyrrole of 4-
Glucopyranoside glycosides, three-O- isovaleryl-α-D- Methylpyrane glucose of 6-O- acetyl group -2,3,4-, acetyl group -2,3 6-O-,
Three-O-3- methylvaleryl-α of tri--O-2- methylbutyryl-α-D- Methylpyrane glucose of 4- and 6-O- acetyl group -2,3,4- -
D- Methylpyrane glucose.
Optionally, the 6-O- acetyl group -2,3, tri--O- propiono-D- glucopyranose of 4-, the 6-O- acetyl group -
Tri--O- bytyry-D- glucopyranose of 2,3,4-, three-O- valeryl-D- glucopyranose of the 6-O- acetyl group -2,3,4-,
Three-O- caproyl-D- the glucopyranose of 6-O- acetyl group -2,3,4-, the three-O- oenanthyl of 6-O- acetyl group -2,3,4-
It is base-D- glucopyranose, three-O- isobutyryl-α-D- methyl glucopyranoside of the 6-O- acetyl group -2,3,4-, described
Three-O- isovaleryl-α-D- Methylpyrane glucose of 6-O- acetyl group -2,3,4-, the three-O- of 6-O- acetyl group -2,3,4-
Three-O-3- methylvaleryl-α-D- of 2- methylbutyryl-α-D- Methylpyrane glucose and the 6-O- acetyl group -2,3,4-
The mass ratio of Methylpyrane glucose is (1.0-1.5): (0.5-1.0): (0.3-0.8): (0.6-1.2): (0.2-0.5):
(0.4-0.8):(0.6-1.2):(0.4-0.9):(0.2-0.6)。
Optionally, the spice oil includes geranium oil, caryophyllus oil, mace oil, lavender oil, myrcia oil, bitter incense wood
Skin oil, attar of rose and cinnamon oil.
Optionally, the geranium oil, the caryophyllus oil, the mace oil, the lavender oil, the myrcia oil,
The mass ratio of the hardship incense wood skin oil, the attar of rose and the cinnamon oil is (12-18): (4-6): (2-5): (4-8): (1-
4):(3-6):(5-10):(2-8)。
Optionally, the geranium oil, the caryophyllus oil, the mace oil, the lavender oil, the myrcia oil,
The hardship incense wood skin oil, the attar of rose, the cinnamon oil, the heliotropin, the vanillic aldehyde and the dihydrocoumarin
Mass ratio be (12-18): (4-6): (2-5): (4-8): (1-4): (3-6): (5-10): (2-8): (4-8): (5-10): (8-
12).According to the second aspect of the invention, it provides a kind of for heating the reconstituted tobacoo for the cigarette that do not burn.
This is used to heat on the reconstituted tobacoo for the cigarette that do not burn added with of the invention for heating the sugar for the cigarette that do not burn
Ester essence, the mass percentage for heating the sugar ester essence for the cigarette that do not burn are 6-8%.
According to the third aspect of the invention we, a kind of cigarette that do not burn is provided.
The cigarette that do not burn includes of the invention for heating the reconstituted tobacoo for the cigarette that do not burn.
The disclosure uses aroma source of the sugar ester as small molecule fatty acid, effectively improves small molecule fatty acid and easily waves
The disadvantage that hair, reactivity are high and corrosivity is strong, also has the advantages that be unlikely to deteriorate compared to common carbohydrate content.Moreover, this
Disclosed fragrance precursor substance equal cleavable at a temperature of 300 DEG C or so releases 2 methyl propanal, 3- propionic aldehyde -2- ketone, 2- ring
The fragrance matters such as amylene -1- ketone, isovaleric anhydride, acetic acid furfural base methyl esters and a variety of organic acids, the cracking rate of transform are up to 75%, with
Respective advantage and effect can sufficiently be agreed with and be played to do not burn 280-330 DEG C of the heating temperature of cigarette of heating, and fragrance can be
It heats in the cigarette that do not burn and obtains uniform and stable release.
In addition, the special formulation of the auxiliary perfume base of the disclosure can be coordinated with the fragrant sense of sugar ester perfume base, fragrance and mouthfeel are solved
Single problem, and can further improve and modify fragrance, improve aroma quality, improve perfume quantity, cover miscellaneous gas, increases sweet tea
Moisture feeling coordinates cigarette perfume, improves flue gas concentration, increases sense organ comfort level, reduces irritation, and improve and inhale taste and pleasant impression.
By the detailed description of following exemplary embodiment, other feature of the invention and its advantage will be become apparent.
Specific embodiment
Be to the description only actually of at least one exemplary embodiment below it is illustrative, never as to the present invention
And its application or any restrictions used.
Technology, method and apparatus known to person of ordinary skill in the relevant may be not discussed in detail, but suitable
In the case of, the technology, method and apparatus should be considered as part of specification.
It is shown here and discuss all examples in, any occurrence should be construed as merely illustratively, without
It is as limitation.Therefore, other examples of exemplary embodiment can have different values.
The sugar ester essence that the disclosure is used to heat the cigarette that do not burn includes sugar ester perfume base and auxiliary perfume base.Sugar ester perfume base is cigarette
The source of leaf addition fragrance.Auxiliary perfume base can play the role of modification and improve fragrance.
Sugar ester perfume base includes substrate agent and sugar ester.Substrate agent can be organic solvent, and those skilled in the art can be according to reality
Demand flexible choice.Sugar ester includes at least four ester of five kinds of glucose tetra-esters and at least four methyl glucosides.A variety of different types
Sugar ester compounding formula be conducive to raising fragrance harmony.Sugar ester may be, for example, three-O- propionyl of 6-O- acetyl group -2,3,4-
Base-D- glucopyranose, three-O- bytyry-D- glucopyranose of 6-O- acetyl group -2,3,4-, 6-O- acetyl group -2,3,4-
Three-O- valeryl-D- glucopyranoses, three-O- caproyl-D- glucopyranose of 6-O- acetyl group -2,3,4-, 6-O- acetyl
Three-O- heptanoyl group-D- glucopyranose of base -2,3,4-, three-O- isobutyryl-α-D- Methylpyrane of 6-O- acetyl group -2,3,4-
Glucoside, three-O- isovaleryl-α-D- Methylpyrane glucose of 6-O- acetyl group -2,3,4-, 6-O- acetyl group -2,3,4-
Three-O-3- methylvaleryl-α-D- of three-O-2- methylbutyryl-α-D- Methylpyrane glucose and 6-O- acetyl group -2,3,4-
Methylpyrane glucose etc..
The ratio of the quality of the quality sum and substrate agent of each sugar ester is (63-127.5): (777.5-887).
Sugar ester molecule can form a kind of protective film on reconstituted tobacoo surface, prevent moisture loss, have the function that humectation.
Assisting perfume base includes spice oil, heliotropin, vanillic aldehyde and dihydrocoumarin.Assist the content of each ingredient in perfume base
Proportion can be selected according to demand.
Spice oil may be, for example, geranium oil, caryophyllus oil, mace oil, lavender oil, myrcia oil, bitter incense wood skin oil, rose
Rare oil and cinnamon oil etc..Those skilled in the art can flexible choice according to actual needs.
The ratio of the quality of the quality sum and auxiliary perfume base of each sugar ester is (63-127.5): (50-95).
The disclosure uses aroma source of the sugar ester as small molecule fatty acid, effectively improves small molecule fatty acid and easily waves
The disadvantage that hair, reactivity are high and corrosivity is strong, also has the advantages that be unlikely to deteriorate compared to common carbohydrate content.Moreover, this
Disclosed fragrance precursor substance equal cleavable at a temperature of 300 DEG C or so releases 2 methyl propanal, 3- propionic aldehyde -2- ketone, 2- ring
The fragrance matters such as amylene -1- ketone, isovaleric anhydride, acetic acid furfural base methyl esters and a variety of organic acids, the cracking rate of transform are up to 75%, with
Respective advantage and effect can sufficiently be agreed with and be played to do not burn 280-330 DEG C of the heating temperature of cigarette of heating, and fragrance can be
It heats in the cigarette that do not burn and obtains uniform and stable release.
In addition, the special formulation of the auxiliary perfume base of the disclosure can be coordinated with the fragrant sense of sugar ester perfume base, fragrance and mouthfeel are solved
Single problem, and can further improve and modify fragrance, improve aroma quality, improve perfume quantity, cover miscellaneous gas, increases sweet tea
Moisture feeling coordinates cigarette perfume, improves flue gas concentration, increases sense organ comfort level, reduces irritation, and improve and inhale taste and pleasant impression.
In a kind of embodiment of the sugar ester essence for heating the cigarette that do not burn of the disclosure, substrate agent is the third two
Alcohol.
In a kind of embodiment of the sugar ester essence for heating the cigarette that do not burn of the disclosure, when in order to improve suction
The harmony of the fragrant sense of release, the difference of the boiling point of each sugar ester is less than or equal to 100 DEG C, and the boiling point of each sugar ester is all larger than or is equal to
350℃。
In a kind of embodiment of the sugar ester essence for heating the cigarette that do not burn of the disclosure, glucose tetra-ester includes
Three-O- propiono-D- glucopyranose of 6-O- acetyl group -2,3,4-, three-O- bytyry-D- pyrans of 6-O- acetyl group -2,3,4-
Glucose, three-O- valeryl-D- glucopyranose of 6-O- acetyl group -2,3,4-, three-O- hexanoyl of 6-O- acetyl group -2,3,4-
Base-D- glucopyranose and 6-O- acetyl group -2,3, tri--O- heptanoyl group-D- glucopyranose of 4-, four ester of methyl glucoside include
Three-O- isobutyryl-α-D- methyl glucopyranoside of 6-O- acetyl group -2,3,4-, three-O- of 6-O- acetyl group -2,3,4- are different
Valeryl-α-D- Methylpyrane glucose, three-O-2- methylbutyryl-α-D- Methylpyrane grape of 6-O- acetyl group -2,3,4-
Sugar and three-O-3- methylvaleryl-α-D- Methylpyrane glucose of 6-O- acetyl group -2,3,4-.This six kinds of sugar esters have boiling point
The features such as high, not volatile, not only more effectively avoids and heats waving for the cigarette processing process small molecular fatty acid that do not burn
Hair, loss of reaction and corrosivity, and preferably solve heating and do not burn cigarette in storage placement process small molecular fat
The problems such as acid gradually volatilizees, decays.
Further, 6-O- acetyl group -2,3, tri--O- propiono-D- glucopyranose of 4-, 6-O- acetyl group -2,3,4-
Three-O- bytyry-D- glucopyranoses, three-O- valeryl-D- glucopyranose of 6-O- acetyl group -2,3,4-, 6-O- acetyl
Three-O- caproyl-D- glucopyranose of base -2,3,4-, three-O- heptanoyl group-D- glucopyranose of 6-O- acetyl group -2,3,4-,
Three-O- isobutyryl-α-D- methyl glucopyranoside of 6-O- acetyl group -2,3,4-, three-O- of 6-O- acetyl group -2,3,4- are different
Valeryl-α-D- Methylpyrane glucose, three-O-2- methylbutyryl-α-D- Methylpyrane grape of 6-O- acetyl group -2,3,4-
The mass ratio of sugar and three-O-3- methylvaleryl-α-D- Methylpyrane glucose of 6-O- acetyl group -2,3,4- is (1.0-1.5):
(0.5-1.0):(0.3-0.8):(0.6-1.2):(0.2-0.5):(0.4-0.8):(0.6-1.2):(0.4-0.9):(0.2-
0.6)。
In a kind of embodiment of the sugar ester essence for heating the cigarette that do not burn of the disclosure, in order to preferably improve
With modification fragrance, spice oil includes geranium oil, caryophyllus oil, mace oil, lavender oil, myrcia oil, bitter incense wood skin oil, rose
Oil and cinnamon oil.
Further, geranium oil, caryophyllus oil, mace oil, lavender oil, myrcia oil, bitter incense wood skin oil, attar of rose and
The mass ratio of cinnamon oil is (12-18): (4-6): (2-5): (4-8): (1-4): (3-6): (5-10): (2-8).
Further, geranium oil, caryophyllus oil, mace oil, lavender oil, myrcia oil, bitter incense wood skin oil, attar of rose,
Cinnamon oil, heliotropin, vanillic aldehyde and dihydrocoumarin mass ratio be (12-18): (4-6): (2-5): (4-8): (1-4):
(3-6):(5-10):(2-8):(4-8):(5-10):(8-12)。
The disclosure additionally provides a kind of for heating the reconstituted tobacoo for the cigarette that do not burn.
This is used to heat on the reconstituted tobacoo for the cigarette that do not burn the sugar for being used to heat the cigarette that do not burn added with the disclosure
Ester essence.The mass percentage of sugar ester essence for heating the cigarette that do not burn is 6-8%.
The disclosure additionally provides a kind of cigarette that do not burn.
The cigarette that do not burn includes the disclosure for heating the reconstituted tobacoo for the cigarette that do not burn.
Experimental method used in following embodiments is conventional method unless otherwise specified, used material and
Reagent is commercially available unless otherwise specified, and equipment used in experiment is this field unless otherwise specified
Equipment known to technical staff.
Embodiment one
By three-O- propiono-D- glucopyranose 15g, 6-O- acetyl group -2,3,4- of 6-O- acetyl group -2,3,4-, three-O-
Three-O- valeryl-D- glucopyranose 4.5g, 6-O- second of bytyry-D- glucopyranose 7.5g, 6-O- acetyl group -2,3,4-
Three-O- heptanoyl group-D- pyrans the Portugal three-O- caproyl-D- glucopyranose 9.0g, 6-O- acetyl group -2,3,4- of acyl group -2,3,4-
Three-O- isobutyryl-α-D- methyl glucopyranoside 6.0g, 6-O- acetyl group of grape sugar 3.0g, 6-O- acetyl group -2,3,4- -
Tri--O- isovaleryl-α-D- Methylpyrane glucose 9.0g, 6-O- acetyl group -2,3,4- of 2,3,4-, three-O-2- methylbutyryl
Three-O-3- methylvaleryl-α-D- Methylpyrane the Portugal base-α-D- Methylpyrane glucose 6.0g and 6-O- acetyl group -2,3,4-
Grape sugar 3.0g is stirred, and sugar ester perfume base is made；It weighs geranium oil 12.0g, caryophyllus oil 4.0g, mace oil 2.0g, smoke
Clothing grass oil 4.0g, myrcia oil 1.0g, bitter incense wood skin oil 3.0g, attar of rose 5.0g, cinnamon oil 2.0g, heliotropin 4.0g, perfume (or spice)
Orchid element 5.0g and dihydrocoumarin 8.0g, sufficiently oscillation mixed dissolution, are made auxiliary perfume base；By the sugar ester perfume base and auxiliary of preparation
After perfume base mixing, then 887.0g propylene glycol is added afterwards, sufficiently oscillation is to get to being used to heat the sugar ester essence of the cigarette that do not burn
S1。
After the sugar ester essence S1 of 6wt% is added on reconstituted tobacoo, then that comfort type fragrance is made in reconstituted tobacoo is non-ignitable
Burn cigarette D1.
Embodiment two
By three-O- propiono-D- glucopyranose 17.5g, 6-O- acetyl group -2,3,4- three of 6-O- acetyl group -2,3,4- -
O- bytyry-D- glucopyranose 10.0g, 6-O- acetyl group -2,3,4- three-O- valeryl-D- glucopyranose 7.0g, 6-O-
Three-O- caproyl-D- glucopyranose 12g, 6-O- acetyl group -2,3,4- of acetyl group -2,3,4-, three-O- heptanoyl group-D- pyrans
Three-O- isobutyryl-α-D- methyl glucopyranoside 9.0g, 6-O- acetyl of glucose 5.0g, 6-O- acetyl group -2,3,4-
Three-O- isovaleryl-α-D- Methylpyrane glucose 12.0g, 6-O- acetyl group -2,3,4- of base -2,3,4-, three-O-2- methyl fourth
Three-O-3- methylvaleryl-α-D- Methylpyrane of acyl-alpha-D- Methylpyrane glucose 9.0g and 6-O- acetyl group -2,3,4-
Glucose 4.0g is stirred, and sugar ester perfume base is made；Weigh geranium oil 15.0g, caryophyllus oil 5.0g, mace oil 4.0g,
Lavender oil 6.0g, myrcia oil 2.0g, bitter incense wood skin oil 5.0g, attar of rose 8.0g, cinnamon oil 5.0g, heliotropin 6.0g,
Vanillic aldehyde 8.0g and dihydrocoumarin 10.0g, sufficiently oscillation mixed dissolution, are made auxiliary perfume base；By the sugar ester perfume base of preparation and
After assisting perfume base mixing, then 840.5g propylene glycol is added afterwards, sufficiently oscillation is to get fragrant to the sugar ester for heating the cigarette that do not burn
Smart S2.
After the sugar ester essence S2 of 7wt% is added on reconstituted tobacoo, then that comfort type fragrance is made in reconstituted tobacoo is non-ignitable
Burn cigarette D2.
Embodiment three
By three-O- propiono-D- glucopyranose 20.0g, 6-O- acetyl group -2,3,4- three of 6-O- acetyl group -2,3,4- -
O- bytyry-D- glucopyranose 12.5g, 6-O- acetyl group -2,3,4- three-O- valeryl-D- glucopyranose 10.0g, 6-
Three-O- caproyl-D- glucopyranose 15g, 6-O- acetyl group -2,3,4- of O- acetyl group -2,3,4-, three-O- heptanoyl group-D- pyrrole
Three-O- isobutyryl-α-D- methyl glucopyranoside 10.0g, 6-O- second of glucopyranoside 6.0g, 6-O- acetyl group -2,3,4-
Three-O- isovaleryl-α-D- Methylpyrane glucose 15.0g, 6-O- acetyl group -2,3,4- of acyl group -2,3,4-, three-O-2- methyl
Three-O-3- methylvaleryl-α-D- methyl pyrrole of bytyry-α-D- Methylpyrane glucose 12.0g and 6-O- acetyl group -2,3,4-
Glucopyranoside 6.0g is stirred, and sugar ester perfume base is made；Weigh geranium oil 16.0g, caryophyllus oil 5.0g, mace oil
4.0g, lavender oil 7.0g, myrcia oil 3.0g, bitter incense wood skin oil 5.0g, attar of rose 9.0g, cinnamon oil 6.0g, heliotropin
6.0g, vanillic aldehyde 9.0g and dihydrocoumarin 11.0g, sufficiently oscillation mixed dissolution, are made auxiliary perfume base；The sugar ester of preparation is fragrant
After base and auxiliary perfume base mixing, then 812.5g propylene glycol is added afterwards, sufficiently oscillation is to get to being used to heat the sugar of the cigarette that do not burn
Ester essence S3.
After the sugar ester essence S3 of 8wt% is added on reconstituted tobacoo, then that comfort type fragrance is made in reconstituted tobacoo is non-ignitable
Burn cigarette D3.
Example IV
By three-O- propiono-D- glucopyranose 22.5g, 6-O- acetyl group -2,3,4- three of 6-O- acetyl group -2,3,4- -
O- bytyry-D- glucopyranose 15.0g, 6-O- acetyl group -2,3,4- three-O- valeryl-D- glucopyranose 12.0g, 6-
Three-O- caproyl-D- glucopyranose 18g, 6-O- acetyl group -2,3,4- of O- acetyl group -2,3,4-, three-O- heptanoyl group-D- pyrrole
Three-O- isobutyryl-α-D- methyl glucopyranoside 12.0g, 6-O- second of glucopyranoside 7.5g, 6-O- acetyl group -2,3,4-
Three-O- isovaleryl-α-D- Methylpyrane glucose 18.0g, 6-O- acetyl group -2,3,4- of acyl group -2,3,4-, three-O-2- methyl
Three-O-3- methylvaleryl-α-D- methyl pyrrole of bytyry-α-D- Methylpyrane glucose 13.5g and 6-O- acetyl group -2,3,4-
Glucopyranoside 9.0g is stirred, and sugar ester perfume base is made；It weighs geranium oil 18g, caryophyllus oil 6g, mace oil 5g, smoke clothing
Careless oil 8g, myrcia oil 4g, bitter incense wood skin oil 6g, attar of rose 10g, cinnamon oil 8g, heliotropin 8g, vanillic aldehyde 10g and dihydro
Coumarin 1 2g, sufficiently oscillation mixed dissolution, are made auxiliary perfume base；After the sugar ester perfume base of preparation and auxiliary perfume base are mixed, then after
It is added 777.5g propylene glycol, sufficiently oscillation is to get to being used to heat the sugar ester essence S4 of the cigarette that do not burn.
After the sugar ester essence S4 of 6wt% is added on reconstituted tobacoo, then that comfort type fragrance is made in reconstituted tobacoo is non-ignitable
Burn cigarette D4.
Comfort type fragrance obtained above is not burnt and cigarette D1-D4 and is not added with the blank cigarette of sugar ester essence and inserts respectively
Enter in smoke grenade, suction evaluation is carried out to cigarette, as a result referring to following table.
As can be seen from the above table, the heating of comfort type made from the disclosure is not burnt cigarette, compared with blank cigarette, fragrance with
Cigarette perfume harmony is preferable, can effectively reduce irritation, mitigates dry sensation, covers miscellaneous gas, increases sweet degree, increase oral cavity and
Nasal cavity comfort improves pleasant impression.But sugar ester essence dosage cannot be excessive, sweet sense otherwise occurs, and overweight fragrance will lead to cigarette
Perfume (or spice) is blanked, and aroma quality reduces, and flue gas concentration and the thoroughly reduction of hair property, irritation increase, and there is the problems such as residual in oral cavity.
Although some specific embodiments of the invention are described in detail by example, the skill of this field
Art personnel it should be understood that example above merely to being illustrated, the range being not intended to be limiting of the invention.The skill of this field
Art personnel are it should be understood that can without departing from the scope and spirit of the present invention modify to above embodiments.This hair
Bright range is defined by the following claims.
Claims (10)
1. a kind of for heating the sugar ester essence for the cigarette that do not burn, which is characterized in that including sugar ester perfume base and auxiliary perfume base；Its
In,
The sugar ester perfume base includes substrate agent and sugar ester, and the sugar ester includes at least five kinds of glucose tetra-esters and at least four methyl
The ratio of the quality of glucose tetra-ester, the quality sum of each sugar ester and the substrate agent is (63-127.5): (777.5-
887)；
The auxiliary perfume base includes spice oil, heliotropin, vanillic aldehyde and dihydrocoumarin；
The ratio of the quality sum of each sugar ester and the quality of the auxiliary perfume base is (63-127.5): (50-95).
2. according to claim 1 for heating the sugar ester essence of the cigarette that do not burn, which is characterized in that the substrate agent is
Propylene glycol.
3. according to claim 1 for heating the sugar ester essence for the cigarette that do not burn, which is characterized in that each sugar ester
The difference of boiling point is less than or equal to 100 DEG C, and the boiling point of each sugar ester is all larger than or is equal to 350 DEG C.
4. according to claim 1 for heating the sugar ester essence for the cigarette that do not burn, which is characterized in that the glucose four
Ester includes three-O- propiono-D- glucopyranose of 6-O- acetyl group -2,3,4-, three-O- bytyry of 6-O- acetyl group -2,3,4- -
D- glucopyranose, three-O- valeryl-D- glucopyranose of 6-O- acetyl group -2,3,4-, three-O- of 6-O- acetyl group -2,3,4-
Caproyl-D- glucopyranose and 6-O- acetyl group -2,3, tri--O- heptanoyl group-D- glucopyranose of 4-, the methyl glucoside
Four esters include three-O- isobutyryl-α-D- methyl glucopyranoside of 6-O- acetyl group -2,3,4-, 6-O- acetyl group -2,3,4-
Three-O- isovaleryl-α-D- Methylpyrane glucose, three-O-2- methylbutyryl-α-D- methyl of 6-O- acetyl group -2,3,4-
Three-O-3- methylvaleryl-α-D- Methylpyrane glucose of glucopyranose and 6-O- acetyl group -2,3,4-.
5. according to claim 4 for heating the sugar ester essence for the cigarette that do not burn, which is characterized in that the 6-O- acetyl
Three-O- propiono-D- glucopyranose of base -2,3,4-, three-O- bytyry-D- glucopyra of the 6-O- acetyl group -2,3,4-
The sugared, described three-O- valeryl-D- glucopyranose of 6-O- acetyl group -2,3,4-, the three-O- of 6-O- acetyl group -2,3,4- oneself
Acyl group-D- glucopyranose, three-O- heptanoyl group-D- glucopyranose of the 6-O- acetyl group -2,3,4-, the 6-O- acetyl
Three-O- isobutyryl-α-D- methyl glucopyranoside of base -2,3,4-, the three-O- isovaleryl of 6-O- acetyl group -2,3,4-
Base-α-D- Methylpyrane glucose, three-O-2- methylbutyryl-α-D- Methylpyrane grape of the 6-O- acetyl group -2,3,4-
The mass ratio of the sugared and described three-O-3- methylvaleryl-α-D- Methylpyrane glucose of 6-O- acetyl group -2,3,4- is (1.0-
1.5):(0.5-1.0):(0.3-0.8):(0.6-1.2):(0.2-0.5):(0.4-0.8):(0.6-1.2):(0.4-0.9):
(0.2-0.6)。
6. according to claim 1 for heating the sugar ester essence for the cigarette that do not burn, which is characterized in that the spice oil packet
Include geranium oil, caryophyllus oil, mace oil, lavender oil, myrcia oil, bitter incense wood skin oil, attar of rose and cinnamon oil.
7. according to claim 6 for heating the sugar ester essence for the cigarette that do not burn, which is characterized in that the geranium oil,
The caryophyllus oil, the mace oil, the lavender oil, the myrcia oil, the bitter incense wood skin oil, the attar of rose and
The mass ratio of the cinnamon oil is (12-18): (4-6): (2-5): (4-8): (1-4): (3-6): (5-10): (2-8).
8. according to claim 6 for heating the sugar ester essence for the cigarette that do not burn, which is characterized in that the geranium oil,
The caryophyllus oil, the mace oil, the lavender oil, the myrcia oil, the bitter incense wood skin oil, the attar of rose,
The cinnamon oil, the heliotropin, the vanillic aldehyde and the dihydrocoumarin mass ratio be (12-18): (4-6): (2-
5):(4-8):(1-4):(3-6):(5-10):(2-8):(4-8):(5-10):(8-12)。
9. a kind of for heating the reconstituted tobacoo for the cigarette that do not burn, which is characterized in that described for heating the cigarette for the cigarette that do not burn
It is described to be used for added with described in any item of the claim 1 to 8 for heating the sugar ester essence for the cigarette that do not burn on careless thin slice
The mass percentage for heating the sugar ester essence for the cigarette that do not burn is 6-8%.
The cigarette 10. one kind is not burnt, which is characterized in that including the cigarette for being used to heat the cigarette that do not burn described in claim 9
Careless thin slice.
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| CN110477439B (en) | 2022-02-25 |
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