CN107108482B - 化学发泡剂和可热膨胀的热塑性组合物 - Google Patents

化学发泡剂和可热膨胀的热塑性组合物 Download PDF

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CN107108482B
CN107108482B CN201580069777.6A CN201580069777A CN107108482B CN 107108482 B CN107108482 B CN 107108482B CN 201580069777 A CN201580069777 A CN 201580069777A CN 107108482 B CN107108482 B CN 107108482B
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thermally expandable
expandable composition
composition according
carbamate
activator
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CN107108482A (zh
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N·波德鲁
R·徐-拉伯
U·布尔克哈德特
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Sika Technology AG
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    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
    • C08J9/08—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing carbon dioxide
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    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C271/00—Derivatives of carbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
    • C07C271/06—Esters of carbamic acids
    • C07C271/08—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms
    • C07C271/10—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C271/16—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms to carbon atoms of hydrocarbon radicals substituted by singly-bound oxygen atoms
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    • C07C269/00—Preparation of derivatives of carbamic acid, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
    • C07C269/02—Preparation of derivatives of carbamic acid, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups from isocyanates with formation of carbamate groups
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    • C07C269/00—Preparation of derivatives of carbamic acid, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
    • C07C269/04—Preparation of derivatives of carbamic acid, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups from amines with formation of carbamate groups
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    • C07C271/08—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms
    • C07C271/10—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C271/12—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals
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    • C07C271/08—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms
    • C07C271/10—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C271/20—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms to carbon atoms of hydrocarbon radicals substituted by nitrogen atoms not being part of nitro or nitroso groups
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    • C07C271/08—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms
    • C07C271/24—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atom of at least one of the carbamate groups bound to a carbon atom of a ring other than a six-membered aromatic ring
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    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/04—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms
    • C07D295/12—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly or doubly bound nitrogen atoms
    • C07D295/125—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly or doubly bound nitrogen atoms with the ring nitrogen atoms and the substituent nitrogen atoms attached to the same carbon chain, which is not interrupted by carbocyclic rings
    • C07D295/13—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly or doubly bound nitrogen atoms with the ring nitrogen atoms and the substituent nitrogen atoms attached to the same carbon chain, which is not interrupted by carbocyclic rings to an acyclic saturated chain
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    • C07D295/16—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms acylated on ring nitrogen atoms
    • C07D295/20—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms acylated on ring nitrogen atoms by radicals derived from carbonic acid, or sulfur or nitrogen analogues thereof
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    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/16—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms acylated on ring nitrogen atoms
    • C07D295/20—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms acylated on ring nitrogen atoms by radicals derived from carbonic acid, or sulfur or nitrogen analogues thereof
    • C07D295/215—Radicals derived from nitrogen analogues of carbonic acid
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    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/02—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by the reacting monomers or modifying agents during the preparation or modification of macromolecules
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
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    • C08J2201/00—Foams characterised by the foaming process
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    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
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    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
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    • C08J2325/02—Homopolymers or copolymers of hydrocarbons
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    • E—FIXED CONSTRUCTIONS
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    • E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
    • E04B1/62—Insulation or other protection; Elements or use of specified material therefor
    • E04B1/74—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
    • E04B1/88—Insulating elements for both heat and sound

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Acoustics & Sound (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CN201580069777.6A 2014-12-19 2015-12-18 化学发泡剂和可热膨胀的热塑性组合物 Expired - Fee Related CN107108482B (zh)

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Application Number Priority Date Filing Date Title
EP14199411 2014-12-19
EP14199411.1 2014-12-19
PCT/EP2015/080639 WO2016097365A1 (en) 2014-12-19 2015-12-18 Chemical blowing agent and thermally expandable thermoplastic composition

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CN107108482A CN107108482A (zh) 2017-08-29
CN107108482B true CN107108482B (zh) 2020-07-14

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US (1) US20170342230A1 (enExample)
EP (1) EP3233790B1 (enExample)
JP (1) JP6709222B2 (enExample)
CN (1) CN107108482B (enExample)
WO (1) WO2016097365A1 (enExample)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109476866B (zh) * 2016-07-20 2022-05-31 Sika技术股份公司 制备可热膨胀材料的方法
EP3583161B1 (en) 2017-02-17 2021-09-01 Zephyros Inc. Activatable polymer composition comprising at least two carboxylic acids as blowing agent
US12173132B2 (en) * 2017-08-08 2024-12-24 Sika Technology Ag Foam with improved expansion behaviour when used in thin layers
CN116102765B (zh) * 2018-06-15 2024-03-29 陶氏环球技术有限责任公司 含有甲苯磺酰基的化学发泡剂
WO2026027577A1 (en) * 2024-07-29 2026-02-05 Sika Technology Ag Thermally expandable composition comprising a polymeric foaming agent

Citations (2)

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US3425964A (en) * 1964-10-09 1969-02-04 Nat Starch Chem Corp Latent curing agents for thermosetting polymers
US5266133A (en) * 1993-02-17 1993-11-30 Sika Corporation Dry expansible sealant and baffle composition and product

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GB1228474A (enExample) * 1968-06-27 1971-04-15
JP3903825B2 (ja) * 2002-03-29 2007-04-11 Ｊｓｒ株式会社 エチレン系共重合ゴム組成物、スポンジ用ゴム組成物およびスポンジ製品
JP2008239753A (ja) * 2007-03-27 2008-10-09 Sumitomo Chemical Co Ltd ゴム発泡体およびシール材
KR101368585B1 (ko) * 2009-06-15 2014-02-28 제이에스알 가부시끼가이샤 감방사선성 수지 조성물, 레지스트 패턴 형성 방법, 화합물 및 중합체
EP2546276A1 (de) * 2011-07-15 2013-01-16 Sika Technology AG Härter für Epoxidharze
DE102012205057A1 (de) * 2012-03-29 2013-10-02 Henkel Ag & Co. Kgaa Thermisch expandierbare Zubereitungen
EP2895548B1 (de) * 2012-09-11 2017-01-04 Sika Technology AG Thermoplastisches schäumungsagenz

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US3425964A (en) * 1964-10-09 1969-02-04 Nat Starch Chem Corp Latent curing agents for thermosetting polymers
US5266133A (en) * 1993-02-17 1993-11-30 Sika Corporation Dry expansible sealant and baffle composition and product

Non-Patent Citations (4)

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Title
Design of a Neutral Macrocyclic Ionophore: Synthesis and Binding Properties for Nitrate and Bromide Anions;Rainer Herges et al.;《European Journal of the Organic Chemsitry》;20021231;第3004-3014页 *
Enantiomerically Pure Isophorone Diamine [3-(Aminomethyl)-3,5,5-trimethylcyclohexylamine]: A Chiral 1,4-Diamine Building Block Made Available on Large Scale;Albrecht Berkessel et al.;《The Journal of Organic Chemistry》;20061115;第71卷;第9312-9318页 *
Mild and High-Yielding Molybdenum(VI) Dichloride Dioxide-Catalyzed Formation of Mono-, Di-, Tri-, and Tetracarbamates from Alcohols and Aromatic or Aliphatic Isocyanates;Christian Stock et al.;《Advanced Synthesis & Catalysis》;20120806;第354卷;第2309-2330页 *
Molecular Imprinting of Carboxylic Acids Employing Novel Functional Macroporous Polymers;David Spivak et al.;《The Journal of Organic Chemistry》;19990606;第64卷;第4627-4634页 *

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US20170342230A1 (en) 2017-11-30
EP3233790B1 (en) 2019-06-26
WO2016097365A1 (en) 2016-06-23
EP3233790A1 (en) 2017-10-25
JP6709222B2 (ja) 2020-06-10
JP2018506601A (ja) 2018-03-08

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