CN107107248A - 用于制造夹层板的方法 - Google Patents

用于制造夹层板的方法 Download PDF

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Publication number
CN107107248A
CN107107248A CN201580069297.XA CN201580069297A CN107107248A CN 107107248 A CN107107248 A CN 107107248A CN 201580069297 A CN201580069297 A CN 201580069297A CN 107107248 A CN107107248 A CN 107107248A
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China
Prior art keywords
semi
metal
finished product
metal level
sandwich plate
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Granted
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CN201580069297.XA
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CN107107248B (zh
Inventor
T·孚罗里西
S·林德纳
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Outokumpu Oyj
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Outokumpu Oyj
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    • B23K11/10Spot welding; Stitch welding
    • B23K11/11Spot welding
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    • B23K11/067Resistance welding; Severing by resistance heating using roller electrodes for welding three-dimensional seams
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    • BPERFORMING OPERATIONS; TRANSPORTING
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Abstract

本发明涉及一种用于制造夹层板的方法,所述夹层板作为半成品,其中,至少一个非金属材料层(2、12)位于至少两个金属层(1、3;11、13)之间。金属层(1、3;11、13)中的至少一个成形为三维层(3、13),且金属层(1、3;11、13)形成为直接机械接触,使得所述半成品能够电阻焊,以便在随后的制造过程中将所述半成品连接到解决方案的期望组合上。

Description

用于制造夹层板的方法
技术领域
本发明涉及一种用于制造作为半成品的夹层板的方法,其中,非金属材料层以使得后续加工业可直接使用该半成品进行焊接处理的方式定位在各金属层之间的凹陷空间中,金属层中的一个金属层大体上是平坦的金属层,而另一个金属层是三维外形的金属层。
背景技术
夹层板结构可由各种各样的金属材料、聚合物材料或复合材料制成。人们发现许多夹层板结构能够减轻重量以及噪音,并为结构载荷支承提供足够的刚度和强度。为了用作多功能结构而评估了芯相对密度为2至10%和单元尺寸在毫米范围内的夹层板。格子支承结构的敞开和三维孔隙网络创造了同时支承高应力以及交叉流动热交换的机会。由于上述优点,特别是轻质和刚硬的特性,夹层板结构为广泛的加工业(如汽车工程,商用、农用以及铁路车辆、船舶和建筑结构或集装箱工程)所关注。但是复杂的制造过程经常是必不可少的,而不能使用用于单块金属薄板(如钢材)的已被认可和训练有素的经济高效和处理高效的方法。对于焊接工艺(如电阻焊)来说尤其如此。
对于通常的电阻焊和具体地作为电阻焊工艺的一种方法的点焊来说,要使用物理学中电阻加热的焦耳定律。这意味着将电能转换为欧姆电阻,然后进一步转化为热能。这对于点焊工艺来说意味着电流在电路中流动。机器部件由铜制成,以便以低电阻和低热损失来良好地传输电流。在从铜到金属薄板的过渡点,在薄板之间以及从第二薄板到铜之间,电流的能量转变为欧姆电阻。由于两个薄板之间的过渡电阻迄今为最高这一效应,热能在这一点也是最高的。最后,在这一点处的热能达到了薄板的熔化温度,并产生了焊点或所谓焊点熔核。热能的公式为:Q=Is2*t*R,其中Is为焊接电流,t=焊接时间,R=所有电阻之和。当使用现有的夹层板结构时,存在至少一种绝缘的非金属材料。因此,电路不闭合,因而无法产生将薄板熔合在一起的热能。
在WO公开2014009114A1、2014001152A9和2013156167A1或塔塔钢材数据表《unique and durable composite solution that delivers light-weight products and design innovation》(—提供轻质产品和设计创新的独特耐用复合材料解决方案)中提到了具有平整顺序的不同层的典型夹层板。此外,WO公开2008125228A1和2004002646A1描述了一种方法,该方法用于制造不同层黏合在一起的金属夹层结构。所有这些WO公开具有相同缺点,即在金属外层之间具有绝缘材料,从而导致不适宜电阻焊。
日本公开H01-127125描述了一种用于制造包含两个薄板金属层和一个波纹元件的夹层板的方法。点焊用于将第一薄板金属层装配到波纹带材的一个表面上。然后,进行粘合带处理。一对压辊机用于通过加压和黏合将第二薄板金属层装配到波纹带材的第二表面上。所得到的半成品的缺点是,随后的加工业(如车身制造商)无法将这种夹层产品用于进一步的电阻焊处理,以便将这种夹层板与其他车身薄板、板材或成形部件接合在一起。原因是所提到的带材在电阻焊处理中充当电路的绝缘体。不能产生焊点熔核,因此无法建立连接。
日本专利公开H0278541A描述了一种如何生产夹层结构的方法,在该夹层结构中,凹陷部产生在一个金属薄板的外表面上、在通过插入树脂形成的叠层中。其实现的方式的是,突出部的尖端与另一金属薄板的内表面之间的距离被以该距离给定。这意味着,尽管使用了赋形的外层钢制薄板,但最后在两个金属薄板之间存在限定的绝缘间隙,从而导致了电阻焊不适宜的配置。
美国专利申请2013-273387涉及夹层金属薄板的高频焊接。因此,包括至少两个金属薄板和布置在两个金属薄板之间的薄板(其由具有不同于两个金属薄板的组成的材料组成)的第一复合薄板金属部件被焊接到由固体金属材料或其它复合材料构成的第二薄板金属部件上,所述第二薄板金属部件具有至少两个金属薄板和布置在所述金属薄板之间的薄板(其由具有不同于两个金属薄板的组成的材料组成)。
WO公开2011082128A1中提到了如何用电阻点焊焊接夹层板的方法,其中,夹层板的复合芯材由两个金属外层层叠。产生特定电阻焊适宜性的目标通过在芯层中具有多根与外层薄钢板电连通的钢纤维来解决。一个缺点是焊接结果的重现性和重复性。当后续制造商想要使用焊接参数时,不能保证具有正确和足够数量的接触着的钢纤维。存在着很大的如下危险性:在钢纤维与钢外层的接触区域中产生焊接飞溅并燃烧其周围的非金属部件。除了软化和移置非金属中间层之外,也在以下出版物中和在其中详细描述的内容中提及了作为解决该目标的一种方式。
为了绕过电阻焊不适宜的夹层结构的缺点,有不同的专利描述了如下处理和方法,所述处理和方法涉及如何使在初始的半成品交货状态配置下不可焊的夹层结构在特定的进一步处理中可焊。一个例子是日本公开2006305591A,其中两个金属外层在两者的表面上叠覆有热塑性树脂绝缘板板。使两个金属层直接接触的目的通过软化树脂绝缘板和通过将其向外推出焊接位置来解决。两个焊接电极必须处于加热状态,这要大量成本、对制造商而言需要特殊设备、并且在随后的加工业中实施。DE公开102011054362A1公开了另一特定方式,该特定方式涉及如何在部件制造过程中利用额外的处理步骤来使电阻焊不适宜的夹层产品在特定配置下可焊。解决该任务是通过在第一处理步骤中加热塑料芯层,然后在第二处理步骤中用至少一个电极将力赋予夹层表面。软化的非金属中间层将从该力加载位置移开,并且两个金属外层开始接触。两个步骤都是部件制造过程中的额外处理步骤,需要额外的生产时间、增加制造成本并降低时钟周期。此外,所提到的是,该解决方案仅适用于部件的特定边界区域。相同的额外处理步骤由DE公开102011109708A1解决,其也描述了随后处理,以使在初始状态下两个金属外层不直接接触的夹层结构可焊。FR公开2709083A1描述了一种典型夹层板,其具有两个金属外层薄板和隔离了两个外层的非金属芯材。为了达到特定的可焊性,使用了类似于DE公开102011054362A1中的相同方法,以软化和移开在薄板的边界区域处的非金属芯料。
在WO公开2012150144A1中描述了另一种产生用于电阻焊不适宜夹层板的电路的粗放且复杂的方法。这里的任务是用额外的机器部件构建电桥,以便绕过绝缘聚合物材料并实现夹层板与其它薄板的可焊性。需要额外的时间来安装非常大量的硬件(其限制了对薄板的易接近性)并使其定位于正确的位置。这使生产成本增加。特别是对于所形成的大部件而言,产生具有不明确电流的问题的电接触将是成问题的。
还有其它文献来源,例如寻求其他接合方法来代替电阻焊的论文。AlexanderKempf于2004年在亚琛工业大学撰写了题目为《夹层材料的机械接合方法研究》的论文。在Gunther Lange的题目为《具有聚合物芯材的三层奥氏体夹层复合材料的成形行为研究》的论文(TU Clausthal,2005)中,给出了可能的接合方法的概述:仅描述了利用钎焊、黏合或激光束进行的搭接接合。没有提及电阻焊工艺或全熔透焊接工艺。
基于这些出版物,夹层板(其为两个大体上平坦的金属层与非金属中间层的组合)业已公知。但是,在初始的半成品和交货状态下未给出电阻焊适宜性的严重缺点没有得到解决。随后的部件制造业不能使用其现有的电阻焊机,或者通过线性接触焊方法(如激光束或等离子焊)来创建完全穿透。这种夹层板的缺点在于,非金属层电隔离了金属层。这使得难于将夹层与其他材料焊接起来并将它们集成到多材料设计的部件中。
发明内容
本发明的目的是防止现有技术的一些缺点,并实现一种改进方法,该改进方法用于制造具有至少两个金属层和在金属层之间的至少一个非金属层的半成品夹层板。在该方法中,金属层之间的机械接触通过使用三维金属薄板作为至少一个金属层并且将非金属材料填充到形成于金属层之间的凹陷空间中来施行。现在,在随后的制造过程(如车身工程)中,能够采用本发明将初始交货状态的夹层板直接用于后续的焊接处理,特别是电阻焊处理,即夹层板的金属层实现为直接机械接触,以使电阻焊适宜性成为可能。本发明的另一个好处是夹层板的所选设置:与夹层板包括两个(金属)外层和两个粘合层以便将两个外层与中间定位的芯材黏合在一起的现有技术相反,本发明以最简单的方式仅使用了两个金属层(其中,一个金属层大体上是平的而另一个金属层大体上是三维的),以及一个非金属粘合层(其填充在这两个金属层之间的凹陷空间中)。结果,本发明的夹层板能够使用较为简单的生产线来制造、增加时钟频率、且其较为便宜,因为与现有技术的夹层板相比节省了两层。本发明的重要特征被列入所附权利要求。
根据本发明,夹层板由至少两个金属层和至少一个非金属层制成,当至少一个金属层成形为三维物体时,所述至少一个非金属层位于形成在两个金属层之间的凹陷空间中。将非金属复合材料填充到在两个金属层之间形成的凹陷空间中,填充度最大为60%,优选地最大为90%,最优选地最大为基本100%。为了施加非金属材料,使用一个或多个精细喷嘴来保证期望的填充度。在本发明中,可以使用刮刀从潜在接触区域消减非金属材料,但这不是优选的。三维金属层能够可选地加热到最多80℃,以增加填充的非金属材料的流动行为。有利地,得到证实的粘度大约为10000mPas。为了清楚起见,当谈到本说明书中的金属层时,将二维的金属层称为第一金属层,将三维的金属层称为第二金属层。
根据本发明的非金属层基本上位于第二金属层的谷中。第二金属层的金属峰表面基本上与第一金属层直接机械接触。第一金属层与第二金属层之间的直接机械接触还确保了电接触。电接触进一步使得能够具有电路并因此能够通过电阻点焊或其他焊接工艺将该夹层板与其它薄板、板或成形件接合,以便将半成品连接到解决方案的期望组合的结构上。与所选择的非金属材料结合的三维层的形式和在金属层之间形成的凹陷空间中的非金属材料的填充度使得这些夹层板具有它们的机械特征、刚度特征、声音特征、接合特征和处理特征。
根据本发明的夹层板的制造中的第一和第二金属层有利地由相同的材料(例如不锈钢、碳钢、铜、铝、镁)制成,但是第一和第二金属层也可由不同的金属材料、不同的金属或不同的金属组合物制成。当使用不同的金属或不同的金属组合物时,这些金属的组合可进一步改变夹层板的行为。例如,具有不同热膨胀系数的金属的组合在本发明的一些解决方案中是有利的。通过使用具有两种不同热膨胀系数的两种金属可影响夹层板的热膨胀,并且三维薄板的表面将避免夹层板的焊接区域的破坏。此外,具有两个不同金属层的本发明的夹层板可用作多材料设计的车身的湿腐蚀区域中的部件桥。例如,中柱脚由不锈钢制成,摇杆轨道由铝制成,夹层板可用作这两个部件之间的连接。夹层板的铝侧焊接在铝摇杆轨道上,而不锈钢夹层与不锈钢中柱焊接。因此,不同部件之间没有接触腐蚀和电化学电势桥。唯一的电势桥此时在夹层板中,但是非金属层隔离了很大的区域,而剩余的金属接触与部件尺寸相比较小(线性或点接触)。
本发明所制夹层板中的第二金属层是波纹状金属件、在第二金属层的表面上呈瘤、疙瘩形状的金属件、或任何其他的三维金属件,其可与大体上平坦的二维第一金属层机械连接。第二金属层的适宜形状例如可在WO公开2014/096180中找到。第二金属层的形式还决定夹层板的阻尼、噪声、振动、刚度(特别是屈曲刚度)和可焊性。疙瘩和瘤外形的薄板导致与方向无关的刚度,但是仅适于利用电阻点焊进行焊接(因点状接触)。波纹状外形的薄板具有与方向相关的刚度,但是使得在电阻滚缝焊等所有连续焊接工艺下都可焊(因线性接触)。在第二金属层的形状为波纹状并视利用夹层板的解决方案而定的情况下,第二金属层可具有大体上正弦波的形状,或者第二层可具有这样的波纹带材的形状,其中带材的彼此相邻的两个部分彼此大体上垂直。其它形状的波纹带材也可用于根据本发明制造的夹层板中的第二层。
本发明的夹层板中的两个金属层之间的非金属层有利地由聚合物材料、树脂材料、冷或热固的一种或两种组分的粘合胶(例如用于汽车行业的抗碰撞单组分粘合胶或含有树脂和硬化剂的双组分夹层粘合材料)制成。非金属中间层的重要特性是施加时的粘度和固化和发泡的方式。在不破坏金属接触面积的情况下达到限定的填充度的良好粘度为约10000mPas。依赖于非金属材料,施加前预热该非金属材料可以是适合的,以达到正确的施加粘度。固化和发泡的方式取决于所选择的粘合物:一种方式是使用与水喷雾接触而发生反应的密封剂,另一种方式是使用对温度起反应的双组分粘合材料。典型的夹层粘合材料(例如与硬化剂组合的双组分聚氨酯粘合物)也是可以和适宜的。在将树脂与固化剂混合之后,给出限定的施加时间以施加所有夹层。
当根据本发明的方法制造夹层板时,由连续金属件或金属层元件组成的第二金属层优选地置于大体上水平的位置。自然,可采用在大体上水平的位置与大体上竖直的位置之间的任何位置。在第二金属层被放置在大体上水平的位置的情况下,用于非金属层的材料被嵌入到形成在金属层之间的如下部分上的凹陷空间中,所述部分相对于第二金属层的表面的竖直方向位于较低的位置。用于非金属层的材料的总量使得在金属层之间形成的凹陷空间的最多60%、优选地最多90%、最优选地最多100%被填充有用于非金属层的材料。利用限定的填充度,可改变夹层板的重量、刚度、疲劳、噪声和阻尼特性,从而符合期望的解决方案。第二金属层的表面的上部(在竖直方向上)不具有非金属层材料。在夹层板的制造中,第二金属层的表面上无非金属层的区域实现了金属层之间的机械接触。
第一金属层被传递用于制造根据本发明的夹层板,使得第一金属层在第二金属层上方、因而也在非金属层上方。第一金属层与第二金属层之间的相互位置有利地使得非金属层相对于这两个金属层横向地布置。机械接触实现于第一金属层与第二金属层之间。机械接触在第二金属层的上表面的特定区域上实现(该区域没有被非金属层覆盖,第二金属层的沿竖直方向的最上部能够中断非金属层材料),或借助于位于第二金属层的上部的特定构件实现。
本发明的夹层板中的第一金属层和第二金属层通过黏合与金属接触的组合来彼此附接,使得焊接(以便将半成品连接到解决方案的期望组合的结构上)到其他薄板、板或成形件上之举将聚焦在第一金属层与第二金属层彼此具有结构性机械接触的点上。两个金属表面之间的机械接触使得能够使用让所述表面之间具有电路的不同种类的方式。
将第一金属层和第二金属层焊接(以便将半成品连接到解决方案的期望组合的结构上)到其它金属薄板、板或成形件上之举可通过作为电阻焊工艺的电焊、凸焊、扣板焊或滚缝焊来进行。也可利用其他焊接工艺(例如微等离子焊和激光微焊)以及缝焊工艺(例如电子束焊和激光束焊)。
根据本发明的夹层板还被构造成使得夹层板可接合到期望的材料件上,以便将夹层板连接到诸如车身的完整结构上。夹层板用于随后的制造过程,例如客车、商用车、农用车或铁路车辆的车身工程,特别是用于湿区域部件或诸多部件如汽车顶盖、通风帽/前壁、槽道、立柱镶嵌物、前盖或用于噪音相关应用场合(如集装箱)。
附图说明
参照以下附图更详细地描述本发明,附图中:
图1由侧视图以示意性方式示出了本发明的一个优选实施例,而
图2由侧视图以示意性方式示出了本发明的另一优选实施例。
具体实施方式
如图1所示的是平坦金属层1、聚合物层2和三维金属层3。聚合物层2位于形成在金属层1与3之间的凹陷空间中。
在图2中,平坦金属层11、聚合物层12和三维金属层13与结合图1的描述所描述的层类似。由金属层11和13与聚合物层构成的夹层通过电阻点焊15焊接到金属薄板14上。

Claims (21)

1.一种用于制造夹层板的方法,所述夹层板作为半成品,其中,至少一个非金属材料层(2、12)位于至少两个金属层(1、3;11、13)之间,其特征在于,所述至少两个金属层(1、3;11、13)中的至少一个被成形为三维层(3、13),且所述至少两个金属层(1、3;11、13)被形成为直接机械接触,使得所述半成品能够电阻焊,以便在随后的制造过程中将所述半成品连接到解决方案的期望组合上。
2.如权利要求1所述的方法,其特征在于,所述非金属材料层(2、12)以可改变的填充度定位在形成于所述至少两个金属层之间的凹陷空间中,所述填充度最大为60%,优选地最大为90%,最优选地最大为基本100%。
3.如前述权利要求中任一项所述的方法,其特征在于,所述三维层(3、13)是波纹状金属带材。
4.如前述权利要求中任一项所述的方法,其特征在于,所述三维层(3、13)是在该三维层的表面上呈瘤、疙瘩形状的金属件。
5.如前述权利要求1至4中任一项所述的方法,其特征在于,所述至少两个金属层(1、3;11、13)由相同的金属制成。
6.如前述权利要求1至4中任一项所述的方法,其特征在于,所述至少两个金属层(1、3;11、13)由不同的金属材料制成。
7.如权利要求6所述的方法,其特征在于,所述至少两个金属层(1、3;11、13)由具有两种不同热膨胀系数的金属制成,所述具有两种不同热膨胀系数的金属影响所述夹层板的热膨胀。
8.如前述权利要求中任一项所述的方法,其特征在于,所述至少两个金属层(1、3;11、13)由不锈钢制成。
9.如前述权利要求1至7中任一项所述的方法,其特征在于,所述至少两个金属层(1、3;11、13)由碳钢制成。
10.如前述权利要求1至7中任一项所述的方法,其特征在于,所述至少两个金属层(1、3;11、13)由铜制成。
11.如前述权利要求1至7中任一项所述的方法,其特征在于,所述至少两个金属层(1、3;11、13)由铝制成。
12.如前述权利要求1至7中任一项所述的方法,其特征在于,所述至少两个金属层(1、3;11、13)由镁制成。
13.如前述权利要求中任一项所述的方法,其特征在于,所述非金属材料层(2、12)由聚合物材料制成。
14.如前述权利要求1至12中任一项所述的方法,其特征在于,所述非金属材料层(2、12)由树脂材料制成。
15.如前述权利要求1至12中任一项所述的方法,其特征在于,所述非金属材料层(2、12)由冷或热固的一种或两种组分的粘合胶制成。
16.如前述权利要求1至12中任一项所述的方法,其特征在于,所述非金属材料层(2、12)由包含树脂和硬化剂的双组分夹层粘合材料制成。
17.如前述权利要求1至16中任一项所述的方法,其特征在于,半成品夹层板在随后的制造过程中通过焊接接合,以便将所述半成品连接到解决方案的期望组合上。
18.如前述权利要求1至16中任一项所述的方法,其特征在于,半成品夹层板在随后的制造过程中通过电阻点焊接合,以便将所述半成品连接到解决方案的期望组合上。
19.如前述权利要求1至16中任一项所述的方法,其特征在于,半成品夹层板在随后的制造过程中通过电阻滚焊接合,以便将所述半成品连接到解决方案的期望组合上。
20.如前述权利要求1至16中任一项所述的方法,其特征在于,半成品夹层板在随后的制造过程中通过激光或电子束焊接合,以便将所述半成品连接到解决方案的期望组合上。
21.根据前述权利要求1至16中任一项所述的方法,其特征在于,半成品夹层板在随后的制造过程中通过微等离子焊接合,以便将所述半成品连接到解决方案的期望组合上。
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