CN106977304A - A kind of biological organic fertilizer and its application based on spent bleaching clay - Google Patents

A kind of biological organic fertilizer and its application based on spent bleaching clay Download PDF

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Publication number
CN106977304A
CN106977304A CN201710299601.0A CN201710299601A CN106977304A CN 106977304 A CN106977304 A CN 106977304A CN 201710299601 A CN201710299601 A CN 201710299601A CN 106977304 A CN106977304 A CN 106977304A
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China
Prior art keywords
bleaching clay
spent bleaching
organic fertilizer
biological organic
plant growth
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Inventor
许海
高素萍
谢爱军
杨乐
李晓艳
俞泳宏
刘锡林
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Gansu tiannongyihe Agriculture Co., Ltd
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Shanghai Kunpeng Environmental Protection Technology Co Ltd
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Priority to CN201710299601.0A priority Critical patent/CN106977304A/en
Publication of CN106977304A publication Critical patent/CN106977304A/en
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05DINORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
    • C05D5/00Fertilisers containing magnesium
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F17/00Preparation of fertilisers characterised by biological or biochemical treatment steps, e.g. composting or fermentation
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/80Soil conditioners
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/40Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse

Abstract

The invention provides a kind of biological organic fertilizer based on spent bleaching clay, its composition of raw materials includes 50 70 parts of spent bleaching clay, 10 15 parts of humic acid, 0.5 2 parts of composite bacteria liquid, 0.5 1 parts of complex enzyme, 0.01 0.1 parts of 5 10 parts of aluminium-magnesium silicate and plant growth regulator, composite bacteria liquid are that pseudomonad, bacillus subtilis, white-rot fungi, Bacillus cereus, bacillus thuringiensis are 1: 1.3 1.6: 0.5 1.1: 0.3 0.6: 0.2 0.4 mixing composition by nutrient solution volume ratio;Complex enzyme is amylase, lipase, lignoenzyme according to the mixing composition of mass ratio 1: 1.4 1.6: 0.3 0.8;Plant growth regulator is brassin lactones and one or more combinations in the basic element of cell division, Thidiazuron, gibberellic acid, heteroauxin, methyl α-naphthyl acetate.Biological organic fertilizer of the present invention is, with preventing and treating soil pests, degraded Pesticide Residue in Soil and chemical residual, to have a variety of functions such as solidification and stabilization, comprehensive improvement excellent effect to the heavy metal ion in soil, and without root, burn seedlings problem is burnt, cost is relatively low.

Description

A kind of biological organic fertilizer and its application based on spent bleaching clay
Technical field
The present invention relates to a kind of biological organic fertilizer based on spent bleaching clay and its application.
Background technology
In agricultural planting, there are two common hang-ups, one is the harm of root nematode and soil-borne disease to crop, two being Fertilizer, a large amount of of agricultural chemicals use, the huge economic losses for making agricultural product chemical residual exceeded and causing.Further, since industry " three It is useless " to discharge and cross decontaminated water field irrigation, the polluted soil in agricultural sludge area because city development construction is migrated, great Liang Shi With the calcium superphosphate chemical fertilizer of the impurity containing Cd and containing animal wastes higher Zn, the Heavy Metal Accumulation such as Cd, Hg and Zn in soil is dirty Contaminate thing exceeded for a long time, be also exactly persistence organic pollutant present in agricultural chemicals and common organic fertilizer, have a strong impact on the mankind It is healthy.
For problem above, existing conventional modification method has chemical modifying, physically improved, organic fertilizer improvement and life Thing improvement etc..The kind of soil conditioner has such as mineral substance, organic matter, artificial synthesized high-molecular compound, beneficial microbe Preparation, sulphur-bentonite etc..These modifying agents are generally common liquid fertilizer, farm manure or organic matter, nutrient content than relatively low, Though certain nutrient can be supplemented for soil, have ignored the improvement of soil physico-chemical property, nutrient is difficult release, neither take stopgap measures nor Effect a permanent cure.Effective microorganism preparation species is various, and the improved effect of most of microbial bacterial agents reported or produced is general, mainly It is that microbial bacterial agent is difficult to survive and breed to limit its effect performance, some microbial bacterias under alkaline land soil environment Although agent effect is preferably, expensive.
CN106278705A discloses a kind of alkaline land improving fertilizer special for organic and its preparation method and application, organic fertilizer by Following components in percentage by weight is constituted:Edible oil and fat decolouring spent bleaching clay 90%~92%, middle micro- 1%~6%, it is saline and alkaline Ground improved materials 2%~9%;Middle trace element is consisted of the following components in percentage by weight:Potassium sulfate 35~65%, ammonium sulfate 30~60%, zinc sulfate 1~4%, borax 0.5~2%;Alkaline land improving material is consisted of the following components in percentage by weight: Desulfurization gypsum powder 70~100%, sofril 0~30%.The preparation method of organic fertilizer is:By edible oil and fat decolouring spent bleaching clay, in Trace element and alkaline land improving material are mixed evenly according to described percentage by weight, then pH of the addition by dilution The acid conditioner of value, is uniformly mixed, and the pH value of adjustment mixture is 3~4, obtains alkaline land improving fertilizer special for organic, pH value Acid conditioner is consisted of the following components in percentage by weight:Gustatory production wastewater 60~80%, steel and iron industry H2SO4Pickling is given up Liquid 10~20%, steel and iron industry HCL pickle liquors 10~20%, the consumption of pH value acidity conditioner is the 5- of total weight of the mixture 20%.The organic fertilizer of the patent uses edible oil and fat decolouring spent bleaching clay in alkaline land improving first, but it is not to edible The content of grease is illustrated in grease-decolor spent bleaching clay.Meanwhile, it uses steel and iron industry hydrochloric acid and sulphur pickle liquor to adjust pH, Because containing Cr inside iron and steel pickling waste liquid, this can cause substantial amounts of Cr to enter soil, cause the secondary pollution of soil, and past Hydrochloric acid and sulfuric acid waste are added in spent bleaching clay, the microorganism in spent bleaching clay is all killed, the growing environment of microorganism is destroyed, given up Excess oil in carclazyte can not be decomposed by the microorganisms, while the nutriment that plant easily absorbs can not be converted it into, be given up Macronutrient in carclazyte can not be absorbed and used by plants.In addition, spent bleaching clay addition is up to more than 90%, and grease is not Through consumption, containing substantial amounts of nutrient, single fertilization is excessive, can cause the excessive growth of plant, hinders flower_bud formation and blooms, In addition it is formulated and is unfavorable for soil granular on the whole and is formed.For summary, although the organic fertilizer of the patent uses spent bleaching clay for raw material, But spent bleaching clay is not utilized well, while it does not have for the harm of root nematode and soil-borne pathogen in soil There is improving effect, it is impossible to improve the cold-resistant of crop, the resistance such as disease-resistant.
CN105622297A discloses a kind of composite microbial manure using spent clay mineral as primary raw material, the fertilizer Each component is counted by weight is respectively:60-90 parts of spent clay mineral, 5-8 parts of pH adjusting agent, 10-15 parts of humic acid is combined micro- 0.15-1 parts of biological inoculum, wherein pH adjusting agent are plant ash or calcium hydroxide.Complex microorganism bacterial classification includes bacillus subtilis Bacterium and bacillusmusilaginosiengineering.Fertilizer disclosed in the patent is mixed in proportion by material component, and the patent is mainly utilized The materials such as the protein, organic matter, the amino acid that contain in spent clay mineral for soil provide nutrition and regulation soil texture and Be conducive to microorganism to grow simultaneously, promote the activity of microorganism.However, the fertilizer of the patent is after use, due to spent clay ore deposit The substantial amounts of organic principle contained in thing, these organic principles do not become thoroughly decomposed completely, can be produced in soil it is secondary become thoroughly decomposed, produce Heat amount, easily causes the problems such as burning root, burn seedlings;In addition, the organic principle contained in spent clay mineral is not plant growth The nutrient that can directly utilize, to meet the nutrition required for earlier plant growth, generally also needs to add nutrition in addition again Composition, utilization ratio is low, and cost is high.It does not improve work for the root nematode in soil and the harm of soil-borne pathogen yet simultaneously With, it is impossible to improve the cold-resistant of crop, the resistance such as disease-resistant.
CN105580843A discloses a kind of gemma medicine fertilizer containing brassin lactones, and it is mainly by brassin lactones 0.0005-0.005wt%, bacillus bacterium solution 90-99wt%, emulsifying agent 0.25-2.5wt%, solvent 0.75-7.5wt% groups Into, the synergy of the patent utilization brassin lactones and bacillus, with nutrition adjustment, the multi-efficiency such as sterilization can show Write and promote plant growth, improve yield, improving quality improves crops itself cold-resistant, the ability of drought resisting.However, medicine fertilizer is main Crop surface is put on, is more to be used as a kind of medicine, does not possess effect of improved soil structure, it is impossible to solidified earth Heavy metal in earth, it is impossible to which the nutritional ingredient required for long term growth is provided for soil.
The content of the invention
The technical problems to be solved by the invention are to overcome the deficiencies in the prior art there is provided a kind of biology based on spent bleaching clay Organic fertilizer.The biological organic fertilizer of the present invention has insect in preventing and treating soil simultaneously, controls the population quantity of soil soil-borne pathogen, Can be degraded Pesticide Residue in Soil and chemical residual, improve the resistance of crop, while having one to the heavy metal ion in soil Determine solidification and stabilization effect, be a kind of multifunctional biological fertilizer.The biological organic fertilizer comprehensive improvement excellent effect of the present invention, nothing Root, burn seedlings problem are burnt, while cost is relatively low.
The present invention is to solve the above problems, the technical scheme taken is as follows:
A kind of biological organic fertilizer based on spent bleaching clay, in parts by weight, the composition of raw materials of the biological organic fertilizer is comprising useless 50-70 parts of carclazyte, 10-15 parts of humic acid, 0.5-2 parts of composite bacteria liquid, 0.5-1 parts of complex enzyme, 5-10 parts of aluminium-magnesium silicate and plant 0.01-0.1 parts of thing growth regulator, the composite bacteria liquid is pseudomonad, bacillus subtilis, white-rot fungi, waxy brood cell Bacillus, bacillus thuringiensis are 1: 1.3-1.6: 0.5-1.1: 0.3-0.6: 0.2-0.4 mixing composition by nutrient solution volume ratio; The complex enzyme is amylase, lipase, lignoenzyme according to the mixing composition of mass ratio 1: 1.4-1.6: 0.3-0.8;It is described to plant Thing growth regulator is brassin lactones and one in the basic element of cell division, Thidiazuron, gibberellic acid, heteroauxin, methyl α-naphthyl acetate Plant or a variety of combinations.
Preferably, the composite bacteria liquid is pseudomonad, bacillus subtilis, white-rot fungi, Bacillus cereus, Su Yun Golden bacillus is 1: 1.5: 0.7: 0.4: 0.3 mixing composition by nutrient solution volume ratio.
Preferably, the complex enzyme is amylase, lipase, lignoenzyme according to the mixing composition of mass ratio 1: 1.5: 0.6.
Preferably, the weight ratio of the spent bleaching clay, composite bacteria liquid and plant growth regulator is 1: 0.01-0.04: 0.001-0.004。
Further, the plant growth regulator can be one kind in following (a)~(e):
(a) brassin lactones mix composition for 1: 50-350 in mass ratio with the basic element of cell division;
(b) brassin lactones mix composition for 1: 1-10 in mass ratio with Thidiazuron;
(c) brassin lactones mix composition with gibberellic acid in mass ratio 1: 10-50;
(d) brassin lactones mix composition with heteroauxin in mass ratio 1: 1-10;
(e) brassin lactones mix composition with methyl α-naphthyl acetate in mass ratio 1: 1-100.
Above-mentioned (a), brassin lactones and the basic element of cell division act synergistically, with individually using brassin lactones compared with, can be with Addition is reduced, and helps to increase crop yield, has significant synergy, wherein brassin lactones to improving crop quality It is 1: 50-200 with basic element of cell division preferred mass ratio.
Above-mentioned (b), brassin lactones and the basic element of cell division act synergistically, with individually using brassin lactones compared with, can be with Addition is reduced, and helps to significantly reduce the hardenability of crop carpopodium, the plantation of grape is particularly suitable for.
Above-mentioned (c), brassin lactones act synergistically with gibberellic acid, compared with individually using brassin lactones, can reduce Addition, and help to increase chlorophyll content of plant, protect green anti-old, promote well developed root system, promote crop to the effective of fertilizer Absorb, supplemental crop inferior position part well grows, strengthen the absorption of plant pair fertilizer, adjust the balance of plant internal water, from And improve drought resisting and the winter resistance of plant.
Above-mentioned (d) and (e), compared with individually using brassin lactones, can reduce addition, and help to increase plant Chlorophyll content, improves crop photosynthesis efficiency, can increase crop yield again, so as to improve economic and social benefit.
Preferably, the biological organic fertilizer, which is made by the steps, obtains:Spent bleaching clay is first subjected to sterilization treatment, by corruption Grow acid and aluminium-magnesium silicate is added in the spent bleaching clay after sterilizing, stir, then add complex enzyme, stir, its secondary control Temperature processed is added between 28-35 DEG C, then by composite bacteria liquid and plant growth regulator, is stirred, and control temperature is in 28-35 Composting is carried out between DEG C.Wherein the composting time is preferably 4~6 days, and turning 1 to 2 time preferably during composting.
The preparation method of the biological organic fertilizer based on spent bleaching clay of the present invention includes:By formula rate, first spent bleaching clay is entered Row sterilization treatment, humic acid and aluminium-magnesium silicate are added in the spent bleaching clay after sterilizing, stirs, then adds complex enzyme, Stir, its secondary control temperature is added between 28-35 DEG C, then by composite bacteria liquid and plant growth regulator, is stirred, Control temperature between 28-35 DEG C, composting 4~6 days is produced.
The biological organic fertilizer based on spent bleaching clay of the present invention can be applied to the plantation of various crops.Applicable crop is for example Ginseng, corn, wheat, grape etc..
According to the present invention, the spent bleaching clay is that grease-decolor processing is useless white.In oil and fat refining process, typically add atlapulgite Decolourized, the oil that the carclazyte being separated after grease-decolor processing contains 20-30%.Contain 20-30%'s for these The carclazyte of oil, some producers can carry out secondary deep squeezing, obtain miscella and oil-containing 5-8% oil-containing spent bleaching clay.The present invention Can be using these spent bleaching clays containing oily 20-30% spent bleaching clay or oil-containing 5-8%.However, as the preferred scheme of the present invention, It is preferred to use the spent bleaching clay that oil content is 12wt%-15wt%, on the one hand, show by inventor's lot of experiments, oil-containing The breeding that rate can be good at described complex microorganism for 10wt%-18wt% spent bleaching clay provides good growing environment, The spent bleaching clay for being 5-8% with oil content is mixed with microorganism, not enough supports the growth of long-term microorganism, it is necessary to additionally add battalion again The normal growth that material just can guarantee that microorganism is supported, is such as mixed with without the spent bleaching clay of after-treatment with microorganism, in a short time Substantial amounts of organic matter is difficult to become thoroughly decomposed completely.On the other hand, inventor is had found by the spent bleaching clay containing 20-30% after decolouring The spent bleaching clay that oil content is 12-15% can be obtained by normal temperature physical squeezing.It is therefore especially preferred that 12-15% spent bleaching clay is made For the raw material of the present invention, it is possible to achieve (inventor had found by containing after decolouring minimization of cost in oil and fat refining process 20-30% spent bleaching clay can obtain the spent bleaching clay that oil content is 12-15% by normal temperature physical squeezing, usually using oil weight 2- 5% carclazyte is decolourized, the general grease for being adsorbed with 20-50% in the spent bleaching clay after decolouring, then again to decolouring after Spent bleaching clay carry out after-treatment, the content of reduction the inside grease, the handling process of existing market mainly has solvent extraction, height The treated spent bleaching clay of warm physical squeezing method, wherein solvent extraction, oil content inside it than relatively low, substantially grease all by Extract, but using and wasting for substantial amounts of solvent can be caused, simultaneously because using a large amount of solvents, increasing substantial amounts of be processed into This, causes processing spent bleaching clay economic benefit not high;Spent bleaching clay is handled by high-temperature physics milling process, the oil content inside it is general In 5-8% or so, this method needs to use heated by natural gas, can also increase processing cost, can be big using normal temperature physical squeezing Width reduces cost) while obtain optimal effect.
According to the present invention, in each component that composition above-mentioned raw materials are formulated, the component such as plant growth regulator and spent bleaching clay can Individually packaging, according to the inventive method is made fertilizer, then used using preceding.
The preparation method of the complex microbial inoculum is:By pseudomonad, bacillus subtilis, white-rot fungi, waxy Then bacillus, the bacterium powder of bacillus thuringiensis will respectively through respective nutrient solution is made after activation and domestication culture Nutrient solution is well mixed to be produced.Pseudomonad, bacillus subtilis, white-rot fungi, Bacillus cereus, bacillus thuringiensis Bacterium powder be it is known, can by commercially available, what activation and domestication and culture method were advised according to known program or producer Mode is carried out.
Compared with prior art, beneficial effects of the present invention are as follows:
The bio-fertilizer of each component organic assembling formation of the present invention, collects the advantage of existing all organic fertilizers, and overcome each Deficiency, full-featured, improved effect is good, and maximizing utilizes waste resource, and cost is relatively low.
1st, specific complex enzyme is added in the present invention, shortens decomposed period, being prevented effectively from prior art organic fertilizer can not fill Divide the problems such as burning root for becoming thoroughly decomposed and in turn resulting in for the second time in the soil for becoming thoroughly decomposed and bringing, burn seedlings.
2nd, compound bacteria of the present invention is pseudomonad, bacillus subtilis, white-rot fungi, Bacillus cereus, the golden buds of Su Yun Spore bacillus mixes according to certain ratio;This combination can secrete a variety of enzymes and hormone, be conducive to microorganism by grease Breaks down proteins change into amino acid so as to be more beneficial for the absorption of plant, while bacillus subtilis, Bacillus cereus The hormone produced with bacillus thuringiensis being capable of purification soil environment, the root system of cover crop, and make leaf portion bacterium and fungi Disease is significantly reduced, and in the brassin in tens kinds of fungies of suppression, bacterium and Disease, with plant growth regulator Ester acts synergistically, and mitigates the generation of soil-borne disease to greatest extent, mitigates harm of the soil disease to plant growth, improves crops Cold-resistant, the resistance such as disease-resistant.This five kinds of bacteriums are under certain proportion simultaneously, pseudomonad and white rot fungus secretion hormone and Enzyme, can have good degradation to chemical fertilizer, agricultural chemicals in soil.On the one hand aluminium-magnesium silicate can adjust spent bleaching clay in formula PH, on the other hand can adsorb the heavy metal in soil, substantial amounts of AL by ion exchange3+Enter soil, AL3+Exist with water AL (OH) is formed in soil3Colloid, promotes the crumb structure of soil to be formed, and chesson can reach water conservation loam, while greatly The air of amount enters soil, is conducive to the breeding of microorganism, and accelerates degraded speed of the microorganism to agricultural chemicals and chemical residual Degree and degradation efficiency.
3rd, whole raw materials used in the present invention are converted into after applying to improve nutrient for plant growth Product free amino acid, do not result in the secondary pollution of soil, and wherein realize the resource reutilization of spent bleaching clay, contribute to Environmental pollution is reduced, demand of the various crops to amino acid is fully met, the yield and quality requirement of crops is improved.
4th, plant growth regulator be brassin lactones with selected from the basic element of cell division, Thidiazuron, gibberellic acid, heteroauxin, Acted synergistically between one or more combinations in methyl α-naphthyl acetate, various plants conditioning agent, can not only reduce consumption, increase is planted Thing chlorophyll content, improves crop photosynthesis efficiency, can increase brassin in crop yield, and plant growth regulator again Also there is the effect cooperateed between lactone and compound bacteria, can significantly mitigate the generation of soil-borne disease, mitigate soil disease to making The harm of thing growth, the resistance such as the cold-resistant of raising crops, disease-resistant.
Embodiment
Below in conjunction with specific embodiment, the present invention will be further described in detail, and unreceipted condition is in embodiment The conventional condition in this area.When addressing the consumption or dosage of material or content, unless stated otherwise, weight is referred both to.Below The composite bacteria liquid used in embodiment, preparation method is as follows:Microbial bacteria passes through commercially available and preceding according to known using Program or producer suggestion mode enter line activating and domestication cultivate, then by pseudomonad, bacillus subtilis, white-rot fungi, Bacillus cereus, the nutrient solution of bacillus thuringiensis are compounded together according to volume ratio 1: 1.5: 0.7: 0.4: 0.3, control Temperature is at 28-32 DEG C.Complex enzyme used is amylase, lipase, lignoenzyme according to mass ratio 1 in following examples: 1.5: 0.6 mixing compositions.The preparation method of biological organic fertilizer is:Spent bleaching clay is first subjected to sterilization treatment, then by humic acid and Aluminium-magnesium silicate is added in spent bleaching clay and stirred, and complex enzyme is added in spent bleaching clay, is stirred, and then controls temperature to exist Between 28-35 DEG C, then composite bacteria liquid and plant growth regulator be added in well mixed spent bleaching clay it be stirred for uniform, control Temperature processed is kept 3 days between 28-35 DEG C, then carries out turning once, continues to be kept for 3 days.It is that difference has in table 1 below The composition of machine fertilizer composition of raw materials.
Table 1
Embodiment 1 uses the application experiment of the bio-organic fertilizer of different plant growth regulator
Following plant growth regulator group is respectively adopted and prepares biological according to the formula of table 11 and above-mentioned preparation method Organic fertilizer, whole raw materials are commercially available in addition to spent bleaching clay, and spent bleaching clay is that the spent bleaching clay that self-produced oil content is about 13-14% is (de- The spent bleaching clay of oil-containing 20-30% after color is obtained by normal temperature physical squeezing).
Plant growth regulator group 1-7:Brassin lactones and the basic element of cell division in mass ratio 1: 45,1: 50,1: 100,1 : 200,1: 300,1: 350 and 1: 380 composition;
Plant growth regulator group 8-12:Brassin lactones are 1: 0.8,1: 1,1: 5,1 in mass ratio with Thidiazuron: 10th, 1: 11 mixing composition;
Plant growth regulator group 13-19:Brassin lactones are 1: 9,1: 10,1: 20,1 in mass ratio with gibberellic acid: 30th, 1: 40,1: 50 and 1: 55 mixing composition;
Plant growth regulator group 20-22:Brassin lactones are 1: 1,1: 5 and 1: 10 in mass ratio with heteroauxin Mixing composition;
Plant growth regulator group 23-25:Brassin lactones are 1: 1,1: 50 and 1: 100 in mass ratio with methyl α-naphthyl acetate Mixing composition.
Plant growth regulator group 26:Brassin lactones;
Plant growth regulator group 27:The basic element of cell division;
Plant growth regulator group 28:Thidiazuron;
Plant growth regulator group 29:Gibberellic acid;
Plant growth regulator group 30:Heteroauxin;
Plant growth regulator group 31:Methyl α-naphthyl acetate.
1. practice ground situation:Tianjin Wuqing District chrysanthemum shop township, is experimental field Acid soil, marks off 32 areas It is 0.1 mu of region.
2. for studying thing:Corn, in late April, 2015 sowing, late August harvest.
3. supply method for testing:Fertilizer is respectively applied to corn planting fertilising, experiment is made using commercially available special compound fertilizer for corns For control.Using field (corn) cell, before corn seeding, with reference to site preparation, disposably spread manuer in holes 30-40 kgs/acre, during sowing Notice that seed and fertilizer separate 5-7 centimetres, in order to avoid regular job is pressed in burn seedlings, field management and water management, soil items are referred to Mark and the indices of crop are detected, wherein, disease incidence is referring to table 2 in the indices and planting process of corn. According to results showed that in the proportion of the present invention, plant modifying agent is brassin lactones and other plant conditioning agent Combination when, significantly higher crop yield and quality are resulted in, while disease incidence has some improvement.
Table 2
Embodiment 2
This example provides a kind of biological organic fertilizer, and its composition of raw materials is referring to the formula of table 12, and wherein spent bleaching clay oil content is about 13- 14%, plant growth regulator is that brassin lactones mix composition with the basic element of cell division in mass ratio 1: 100.Each component is independently wrapped Dress.Before use, organic fertilizer is made according to the above-mentioned method of the present invention.
Embodiment 3
This example provides a kind of biological organic fertilizer, and its composition of raw materials is referring to the formula of table 13, and wherein spent bleaching clay oil content is about 13- 14%, plant growth regulator is that brassin lactones mix composition with Thidiazuron in mass ratio 1: 5.Each component independent packaging.Make With preceding, organic fertilizer is made according to the inventive method.
Embodiment 4
This example provides a kind of biological organic fertilizer, its composition of raw materials referring to the formula of table 11, unlike, wherein spent bleaching clay oil-containing Rate is about 6-8%, and plant growth regulator is that brassin lactones mix composition with the basic element of cell division in mass ratio 1: 100.Use Before, organic fertilizer is made according to the above-mentioned method of the present invention.
Embodiment 5
This example provides a kind of biological organic fertilizer, and its composition of raw materials is referring to the formula of table 12, and wherein spent bleaching clay oil content is about 20- 22%, plant growth regulator is that brassin lactones mix composition with the basic element of cell division in mass ratio 1: 100.Each component is independently wrapped Dress.Before use, organic fertilizer is made according to the above-mentioned method of the present invention.
Embodiment 6
This example provides a kind of biological organic fertilizer, and its composition of raw materials is referring to the formula of table 14, and wherein spent bleaching clay oil content is about 13- 14%, plant growth regulator is that brassin lactones mix composition with gibberellic acid in mass ratio 1: 30.Each component independent packaging.Make With preceding, organic fertilizer is made according to the inventive method.
Embodiment 7
This example provides a kind of biological organic fertilizer, and its composition of raw materials is referring to the formula of table 15, and it is about 13- that wherein spent bleaching clay, which closes oil cut rate, 14%, plant growth regulator is that brassin lactones mix composition with heteroauxin in mass ratio 1: 5.Each component independent packaging. Before use, organic fertilizer is made according to the inventive method.
Embodiment 8
This example provides a kind of biological organic fertilizer, and its composition of raw materials is referring to the formula of table 11, and it is about 13- that wherein spent bleaching clay, which closes oil cut rate, 14%, plant growth regulator is that brassin lactones mix composition with methyl α-naphthyl acetate in mass ratio 1: 50.Each component independent packaging.Make With preceding, organic fertilizer is made according to the inventive method.
Comparative example 1
A kind of biological organic fertilizer of this example offer, its basic be the same as Example 2, unlike, wherein composite bacteria liquid is withered grass bud Spore bacillus, white-rot fungi, Bacillus cereus, the nutrient solution of bacillus thuringiensis are answered according to volume ratio 1: 0.4: 0.3: 0.15 With composition.
Comparative example 2
A kind of biological organic fertilizer of this example offer, its basic be the same as Example 2, unlike, the composite bacteria liquid is false unit cell Bacterium, bacillus subtilis, Bacillus cereus, bacillus thuringiensis are 1: 1.4: 0.5: 0.2 mixing by nutrient solution volume ratio Composition.
Comparative example 3
A kind of biological organic fertilizer of this example offer, its basic be the same as Example 2, unlike, wherein being adjusted without plant growth Save agent.
Comparative example 4
A kind of biological organic fertilizer of this example offer, its basic be the same as Example 2, unlike, wherein plant growth regulator is complete Portion is brassin lactones.
Embodiment 9
Application test is carried out using embodiment 2-8 and comparative example 1-4 organic fertilizer, it is specific as follows:
1. practice ground situation:Tianjin Wuqing District chrysanthemum shop township, is experimental field Acid soil.
2. for studying thing:Wheat, in late September, 2015 sowing, in late May, 2016 harvest.
3. supply method for testing:Each example fertilizer is respectively applied to wheat planting fertilising, experiment uses Commercial wheat specific complex Fertilizer is used as control.Using field (wheat) cell, before wheat cultivation, with reference to site preparation, 50-60 kgs/acre of single fertilization, field Between management and water management press regular job, the indices of soil indices and crop are detected, wherein, in soil Heavy metal ion content and residues of pesticides are referring to table 3, and the yield and insect pest situation of wheat are referring to table 4.In addition, using comparative example In the experiment of 1-4 organic fertilizer, it was observed that a certain proportion of burn seedlings phenomenon.
Table 3
Table 4
Sequence number Wheat yield (kg/ mus) Locust insect pest rate % Rust diseases rate % Lodging ratio %
Embodiment 2 612.8 6.3 5.6 0.4
Embodiment 3 599.6 6.7 5.9 0.3
Embodiment 4 436.7 16.9 14.6 4.3
Embodiment 5 458.2 15.3 13.9 5.1
Embodiment 6 606.5 6.2 5.7 0.5
Embodiment 7 604.9 5.9 5.6 0.4
Embodiment 8 610.3 6.1 5.9 0.6
Comparative example 1 422.5 17.6 15.3 10.6
Comparative example 2 399.9 18.6 14.9 10.1
Comparative example 3 402.3 18.2 16.1 12.6
Comparative example 4 437.6 18.5 14.8 13.1
It is commercially available 510.2 12.9 10.8 6.4

Claims (10)

1. a kind of biological organic fertilizer based on spent bleaching clay, it is characterised in that:In parts by weight, the raw material of the biological organic fertilizer is matched somebody with somebody Side includes 50-70 parts of spent bleaching clay, 10-15 parts of humic acid, 0.5-2 parts of composite bacteria liquid, 0.5-1 parts of complex enzyme, aluminium-magnesium silicate 5-10 Part and 0.01-0.1 part of plant growth regulator, the composite bacteria liquid be pseudomonad, bacillus subtilis, white-rot fungi, Bacillus cereus, bacillus thuringiensis are 1: 1.3-1.6: 0.5-1: 1: 0.3-0.6 by nutrient solution volume ratio:0.2-0.4 Mixing composition;The complex enzyme is amylase, lipase, lignoenzyme according to the mixing group of mass ratio 1: 1.4-1.6: 0.3-0.8 Into;The plant growth regulator is brassin lactones with being selected from the basic element of cell division, Thidiazuron, gibberellic acid, heteroauxin, naphthalene second One or more combinations in acid.
2. the biological organic fertilizer according to claim 1 based on spent bleaching clay, it is characterised in that:The composite bacteria liquid is false single Born of the same parents bacterium, bacillus subtilis, white-rot fungi, Bacillus cereus, bacillus thuringiensis are 1: 1.5 by nutrient solution volume ratio: 0.7: 0.4: 0.3 mixing composition.
3. the biological organic fertilizer according to claim 1 based on spent bleaching clay, it is characterised in that:The complex enzyme is starch Enzyme, lipase, lignoenzyme are mixed according to mass ratio 1: 1.5: 0.6 and constituted.
4. the biological organic fertilizer according to claim 1 based on spent bleaching clay, it is characterised in that:The spent bleaching clay is de- for grease Color handles spent bleaching clay, and its oil content is 12wt%-15wt%.
5. the biological organic fertilizer according to claim 1 based on spent bleaching clay, it is characterised in that:The spent bleaching clay, compound bacteria The weight ratio of liquid and plant growth regulator is 1: 0.01-0.04: 0.001-0.004.
6. the biological organic fertilizer according to claim 1 based on spent bleaching clay, it is characterised in that:The plant growth regulator One kind in following (a)~(e):
(a) brassin lactones mix composition for 1: 50-350 in mass ratio with the basic element of cell division;
(b) brassin lactones mix composition for 1: 1-10 in mass ratio with Thidiazuron;
(c) brassin lactones mix composition with gibberellic acid in mass ratio 1: 10-50;
(d) brassin lactones mix composition with heteroauxin in mass ratio 1: 1-10;
(e) brassin lactones mix composition with methyl α-naphthyl acetate in mass ratio 1: 1-100.
7. the biological organic fertilizer according to claim 1 based on spent bleaching clay, it is characterised in that:The biological organic fertilizer passes through Following steps are prepared:Spent bleaching clay is first subjected to sterilization treatment, humic acid and aluminium-magnesium silicate are added to useless white after sterilizing In soil, stir, then add complex enzyme, stir, its secondary control temperature is between 28-35 DEG C, then by composite bacteria liquid Add, stir with plant growth regulator, control temperature composting 4~6 days between 28-35 DEG C.
8. the preparation method of the biological organic fertilizer based on spent bleaching clay as any one of claim 1 to 7, its feature exists In this method includes:By formula rate, spent bleaching clay is first subjected to sterilization treatment, humic acid and aluminium-magnesium silicate are added to sterilizing In spent bleaching clay afterwards, stir, then add complex enzyme, stir, its secondary control temperature is between 28-35 DEG C, then incites somebody to action Composite bacteria liquid and plant growth regulator are added, and are stirred, and control temperature is between 28-35 DEG C, and composting 4~6 days is produced.
9. the preparation method of the biological organic fertilizer according to claim 8 based on spent bleaching clay, it is characterised in that:In the heap Turning 1 to 2 time during system.
10. the biological organic fertilizer based on spent bleaching clay as any one of claim 1 to 7 is in ginseng, corn, wheat, Portugal Application in grape plantation.
CN201710299601.0A 2017-05-02 2017-05-02 A kind of biological organic fertilizer and its application based on spent bleaching clay Pending CN106977304A (en)

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CN107857626A (en) * 2017-12-20 2018-03-30 漳州迈威特生物科技有限公司 A kind of application bio-feritlizer and preparation technology
CN110526422A (en) * 2019-09-16 2019-12-03 德蓝水技术股份有限公司 A kind of petrochemical wastewater special bio growth-promoting agent
CN114586780A (en) * 2021-04-02 2022-06-07 多农多收技术研究(江苏)有限公司 Product for relieving crop phytotoxicity and rapidly recovering growth and preparation and use methods thereof
CN115349519A (en) * 2022-08-30 2022-11-18 山东大成生物化工有限公司 Brassinolide-gibberellic acid-bacillus aryabhattai compound pesticide fertilizer and preparation method and application thereof

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