CN106833671A - Alkaline land modifying agent and saline and alkali land improvement method based on spent bleaching clay and phosphatization slag - Google Patents
Alkaline land modifying agent and saline and alkali land improvement method based on spent bleaching clay and phosphatization slag Download PDFInfo
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- CN106833671A CN106833671A CN201710041747.5A CN201710041747A CN106833671A CN 106833671 A CN106833671 A CN 106833671A CN 201710041747 A CN201710041747 A CN 201710041747A CN 106833671 A CN106833671 A CN 106833671A
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- bleaching clay
- modifying agent
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K17/00—Soil-conditioning materials or soil-stabilising materials
- C09K17/40—Soil-conditioning materials or soil-stabilising materials containing mixtures of inorganic and organic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09C—RECLAMATION OF CONTAMINATED SOIL
- B09C1/00—Reclamation of contaminated soil
- B09C1/08—Reclamation of contaminated soil chemically
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09C—RECLAMATION OF CONTAMINATED SOIL
- B09C2101/00—In situ
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2101/00—Agricultural use
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2109/00—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE pH regulation
Abstract
The present invention relates to a kind of alkaline land modifying agent based on spent bleaching clay and phosphatization slag, by weight percentage, its composition of raw materials includes spent bleaching clay 40 55%, complex micro organism fungicide 0.5 2%, phosphatization slag 20 25%, soluble calcium salt 10 15% and plant ash 4 29.5%, and described complex micro organism fungicide is that bacillus subtilis, bacillus licheniformis, bacillus laterosporus, Streptomyces jingyangensis, bacillusmusilaginosiengineering are 1 by nutrient solution volume ratio:1.2‑1.6:0.5‑0.7:1.2‑1.5:The mixture of 0.6 0.9 compositions.The improvement in salt-soda soil particularly heavy metal pollution salt-soda soil can be effectively realized using modifying agent of the present invention and with reference to modification method of the present invention, the improvement requirement in salt-soda soil is fundamentally solved, while low cost of the present invention, is capable of achieving resource reutilization, environmental pollution is reduced.
Description
Technical field
The present invention relates to a kind of soil conditioner, more particularly to a kind of alkaline land modifying agent.
Background technology
The salinization of soil is destroyed than larger to soil physico-chemical property, and pole is unfavorable for the growth of many crops, easily causes work
Thing is short of seedling or dead, so as to hinder the development of agricultural economy.Salt-soda soil is more due to salt content, and organic quality is few, and acid-base value is high, makes
Agron suffers leaching loss, and soil texture is destroyed, and is sticked when showing as wet, and hard when doing, native table often has white salinity accumulation,
Ventilation, it is permeable bad, serious meeting cause plant wilt, poisoning and rotten death.In addition, surface soil alkalinity is too big, soil is had influence on
The validity of the nutrients such as phosphorus, iron, manganese, boron, zinc in earth, easily causes a large amount of nitrogen, phosphorus, potassium essential element and iron, calcium, boron
Deng the shortage of trace element.According to statistics, Chinese saline-alkali soil area there are about more than 20 ten thousand square kilometres, constitute about China's territory total area
2.1%.Up to the present China about also have 80% or so saline-alkali soil not to be developed.It is increasingly tight in land resource
The today opened, the exploitation of large area saline-alkali wasteland and the preventing and treating of the salinization of soil have become influence China's economy and society
The major issue of sustainable development.
Existing conventional modification method has chemical modifying, physically improved, organic fertilizer improvement and biological modification etc..Soil
The kind of modifying agent has such as mineral substance, organic matter, artificial synthesized macromolecular compound, effective microorganism preparation, sulphur-bentonite
Deng.These modifying agents are generally common liquid body fertilizer material ﹑ farm manures or organic matter, and nutrient content is than relatively low, though can be supplemented for soil
Certain nutrient, but the improvement of soil physico-chemical property is have ignored, nutrient is difficult release, neither takes stopgap measures nor effects a permanent cure.Beneficial micro- life
Thing type of preparation is various, and the improved effect of most of microbial bacterial agents reported or produced is general, mainly microbial bacterial agent
Be difficult to survive and breed under alkaline land soil environment and played so as to limit its effect, although some microbial bacterial agent effects compared with
It is good, but it is expensive.
CN106278705A discloses a kind of alkaline land improving fertilizer special for organic and its preparation method and application, organic fertilizer by
Following components in percentage by weight is constituted：Edible oil and fat decolouring spent bleaching clay 90%~92%, middle micro- 1%~6%, it is saline and alkaline
Ground improved materials 2%~9%；Middle trace element is consisted of the following components in percentage by weight：Potassium sulfate 35~65%, ammonium sulfate
30~60%, zinc sulfate 1~4%, borax 0.5~2%；Alkaline land improving material is consisted of the following components in percentage by weight：
Desulfurization gypsum powder 70~100%, sofril 0~30%.The preparation method of organic fertilizer is：By edible oil and fat decolourize spent bleaching clay, in
, according to described percentage by weight mixing and stirring, the pH of dilution is passed through in then addition for trace element and alkaline land improving material
The acid conditioner of value, is uniformly mixed, and the pH value for adjusting mixture is 3~4, obtains alkaline land improving fertilizer special for organic, pH value
Acid conditioner is consisted of the following components in percentage by weight：Gustatory production wastewater 60~80%, steel and iron industry H2SO4 pickling are given up
Liquid 10~20%, steel and iron industry HCL pickle liquors 10~20%, the consumption of pH value acidity conditioner is the 5- of total weight of the mixture
20%.The organic fertilizer of the patent uses edible oil and fat decolouring spent bleaching clay in alkaline land improving first, but it is not to edible
The content of grease is illustrated in grease-decolor spent bleaching clay.Meanwhile, it uses steel and iron industry hydrochloric acid and sulphur pickle liquor regulation pH,
Because Cr is contained in iron and steel pickling waste liquid the inside, this can cause substantial amounts of cr to enter soil, cause the secondary pollution of soil, and past
Hydrochloric acid and sulfuric acid waste are added in spent bleaching clay, the microorganism in spent bleaching clay are all killed, destroy the environment of the growth of microorganism,
Unnecessary grease in spent bleaching clay can not be decomposed by the microorganisms, while the nutrients that plant easily absorbs can not be converted it into
Matter, the macronutrient in spent bleaching clay can not be absorbed and used by plants.Additionally, spent bleaching clay addition is up to more than 90%, and
, without consumption, containing substantial amounts of nutrient, single fertilization is excessive, can cause the excessive growth of plant, hinders flower_bud formation for grease
With bloom, be formulated be unfavorable on the whole that soil granular is formed in addition.For summary, although the organic fertilizer of the patent is using spent bleaching clay
It is raw material, but but spent bleaching clay is not utilized well, it is impossible to fundamentally solves the improvement requirement in salt-soda soil.
CN103320137B discloses a kind of composite microbiological bacteriocin saline-alkali soil improver, and described modifying agent includes micro- life
Thing, organic liquor and matrix.Described microorganism includes bacillus subtilis (Bacillussubtilis) and bacillus megaterium
(Bacillusmegaterium), the ratio of weight and number of described bacillus subtilis and bacillus megaterium is：Withered grass gemma
Bacillus 60~80；Bacillus megaterium 20~40, the bacillus subtilis is that the bacillus subtilis is bacillus subtilis
Bacterium CGMCC7296, bacillus subtilis CGMCC7297, the mixture of bacillus subtilis CGMCC7298；The huge gemma
Bacillus is CGMCC 7337.Described organic liquor includes the protease that described microbial bacterial agent fermentation is produced, lipase, α-
Amylase, amino acid.Described matrix includes chicken manure or cow dung, lignite, ground phosphate rock, medical stone.Described chicken manure or cow dung pass through
Cross 200~400 DEG C of high-temperature sterilizations；Described lignite is containing 20% humic acid；The ground phosphate rock, medical stone are more than 300 mesh.
The patent formulation is complicated, production inconvenience, with the addition of the nutriment that a large amount of growth of microorganism need, relatively costly, and salt-soda soil
Hardened environment under, growth of microorganism and breeding are limited, and regulation effect is not good.
The content of the invention
An object of the present invention is to provide a kind of improved alkaline land modifying agent based on spent bleaching clay and phosphatization slag, and this changes
Good dose can effectively realize alkaline land improving, the improvement requirement in salt-soda soil fundamentally be solved, while low cost of the present invention.
The present invention also provides a kind of modification method in salt-soda soil simultaneously, and the method is easy to operate and can effectively realize salt-soda soil
Improvement.
To achieve the above object, a kind of technical scheme that the present invention takes is as follows for the present invention：
A kind of alkaline land modifying agent based on spent bleaching clay and phosphatization slag, by weight percentage, its composition of raw materials includes useless
Carclazyte 40-55%, complex micro organism fungicide 0.5-2%, phosphatization slag 20-25%, soluble calcium salt 10-15% and plant ash 4-
29.5%, described complex micro organism fungicide is bacillus subtilis, bacillus licheniformis, bacillus laterosporus, Jingyang strepto-
Bacterium, bacillusmusilaginosiengineering are 1 by nutrient solution volume ratio:1.2-1.6:0.5-0.7:1.2-1.5:The mixing of 0.6-0.9 compositions
Thing.
Preferably, complex micro organism fungicide is bacillus subtilis, bacillus licheniformis, bacillus laterosporus, Jingyang chain
Mould, the volume ratio of bacillusmusilaginosiengineering nutrient solution are 1:1.4-1.5:0.5-0.6:1.2-1.3:It is mixed that 0.8-0.9 is constituted
Compound.Most preferably, bacillus subtilis, bacillus licheniformis, bacillus laterosporus, Streptomyces jingyangensis, gel-shaped gemma bar
The volume ratio of bacteria culture fluid is 1:1.5:0.6:1.3:0.8.
According to the present invention, the spent bleaching clay is useless white grease-decolor treatment.In oil and fat refining process, typically add atlapulgite
Decolourized, the oil that the carclazyte being separated after grease-decolor treatment contains 20-30%.Contain 20-30%'s for these
The carclazyte of oil, some producers can carry out secondary deep squeezing, obtain the oil-containing spent bleaching clay of miscella and oil-containing 5-8%.The present invention
Can be using the spent bleaching clay of these spent bleaching clays or oil-containing 5-8% containing 20-30% oil.However, as preferred scheme of the invention,
It is preferred that it is the spent bleaching clay of 12wt%-15wt% to use oil content, on the one hand, show by inventor's lot of experiments, oil-containing
Rate provides good growing environment for the breeding that the spent bleaching clay of 10wt%-18wt% can be good at described complex microorganism,
Mixed with microorganism with the spent bleaching clay that oil content is 5-8%, not enough support the growth of long-term microorganism, it is necessary to additionally add battalion again
The normal growth that material just can guarantee that microorganism is supported, is such as mixed with microorganism with the spent bleaching clay without after-treatment, applied
To in alkaline land soil, microbes have little time to decompose, and cause substantial amounts of grease to be full of in soil, can so cause substantial amounts of
Air can not come in, and cause microorganism and be unable to normal growth.On the other hand, inventor is had found by by containing after decolouring
The spent bleaching clay of 20-30% can obtain the spent bleaching clay that oil content is 12-15% by normal temperature physical squeezing.It is therefore especially preferred that 12-
15% spent bleaching clay is used as raw material of the invention, it is possible to achieve minimization of cost is (in oil and fat refining process, usually using oil weight 2-
5% carclazyte is decolourized, by the general grease for being adsorbed with 20-50% in the spent bleaching clay after decolouring, then again to decolouring after
Spent bleaching clay carry out after-treatment, reduce the content of the inside grease, the handling process of existing market mainly has solvent extraction, height
The treated spent bleaching clay of warm physical squeezing method, wherein solvent extraction, oil content inside it than relatively low, substantially grease all by
Extract, but using and wasting for substantial amounts of solvent can be caused, simultaneously because using a large amount of solvents, increasing substantial amounts of being processed into
This, causes treatment spent bleaching clay economic benefit not high；Spent bleaching clay is processed by high-temperature physics milling process, the oil content inside it is general
In 5-8% or so, this method needs to use heated by natural gas, can also increase processing cost, can be big using normal temperature physical squeezing
Width reduces cost) while obtain optimal effect.
Further, soluble calcium salt is preferably calcium lignosulfonate and/or calcium citrate.
According to the present invention, each component for constituting above-mentioned raw materials formula is individually packed.
The present invention also provides a kind of saline and alkali land improvement method, and it uses the present invention above-mentioned based on spent bleaching clay and phosphatization slag
Alkaline land modifying agent, and comprise the following steps：
(1) complex micro organism fungicide agent is added in spent bleaching clay, controls temperature to be kept for 3-5 weeks for 28-35 DEG C, make micro- life
Thing is bred, and obtains modifying agent component A；
(2) soluble calcium salt and phosphatization slag it are uniformly sprinkling upon saline and alkaline the earth's surface, then as modifying agent B component
Water is turned over and spread, is kept for 5-15 days；
(3) modifying agent component A is uniformly sprinkling upon the saline and alkaline the earth's surface processed by step (2), and is turned over, make to mix
Close uniform, kept for 5-10 days；
(4) plant ash is uniformly sprinkling upon the saline and alkaline the earth's surface processed by step (3), and is turned over, keep 5-10
My god.
The preparation method of the complex microbial inoculum is：By bacillus subtilis, bacillus licheniformis, side spore gemma bar
Bacterium, Streptomyces jingyangensis, the bacterium powder of bacillusmusilaginosiengineering are made respective nutrient solution after being cultivated respectively through activation and domestication, so
Nutrient solution is well mixed afterwards is obtained final product.Bacillus subtilis, bacillus licheniformis, bacillus laterosporus, Streptomyces jingyangensis, jelly
The bacterium powder of sample bacillus has learned that, can activate and domestication and culture method is according to simultaneously known journey by commercially available
Sequence or the mode of producer's suggestion are carried out.
Preferably, in every gram of modifying agent component A, bacillus subtilis, bacillus licheniformis, bacillus laterosporus,
Streptomyces jingyangensis, the viable count of bacillusmusilaginosiengineering are respectively greater than 3.5x108、2.7x108、3.5x107、3.0x108With
2.0x108。
Further, in step (1), during holding, 3-4 ventilation is stirred weekly.And preferably kept for 3 weeks.
Further, in step (2), ploughed depth is 18-25cm, preferably from about 20cm.Water is spread so that soil layer of turning over is wet
Profit.Preferably, kept for 5-10 days in the step.
Further, in step (3), ploughed depth is 18-25cm, preferably from about 20cm.Preferably, kept in the step
5-7 days.
Compared with prior art, beneficial effects of the present invention are as follows：
(1) spent bleaching clay can be neutralized in acidity with the salt-soda soil in alkalescence, coordinate the use of microorganism, can be effective
Reduce the pH value of alkaline land soil, at the same spent bleaching clay can be microorganism in the soil provide nutrient required for breeding and
Do not result in excessive fertilization and cause plant excessive growth simultaneously.
(2) present invention pass through experimental studies have found that, by bacillus subtilis, bacillus licheniformis, bacillus laterosporus, river rising in Ningxia and flowing into central Shaanxi
After positive streptomycete, bacillusmusilaginosiengineering mix in specific proportions, can be reached in the environment in salt-soda soil in the presence of spent bleaching clay
To symplastic growth and breeding, if lacking jelly bacillus, bacillus licheniformis, bacillus laterosporus and Jingyang in microbial inoculum
Streptomycete cannot survive discovery substantially, if removing bacillus licheniformis, be had when mix bacterium agent is mixed substantial amounts of miscellaneous
Bacterium produces, so as to suppress the growth of beneficial bacterium in microbial inoculum, causes the quality of microbial inoculum between a batch unstable, causes to saline and alkaline
Ground repairing effect does not reach requirement, the compounding of this several microbial inoculum, it is possible to increase its collaboration resistance alkali ability, can be in salt-soda soil soil
Fermented well in earth, support the growth in saline and alkaline aerial plant.
(3) phosphatization slag is added in inventive formulation, on the one hand salt-soda soil pH, regulation soil can be reduced using phosphatization slag is acid
Earth acid-base property, on the other hand can play solidification and static stabilization to heavy metal in soil, while under microbial action, can
To provide trace element needed for a large amount of plants；Plant ash is added in formula can provide a large amount of potassium elements for plant growth, can be with
Promote soil spherulitic texture to be formed, be effectively improved alkaline land soil structure, whole component synergies significantly improve salt-soda soil soil
Matter.
(5) whole raw materials used in the present invention or the direct nutrient or last being converted into of providing can be plant
Thing growth improves the product of nutrient, does not result in the secondary pollution of soil, and it is sharp again wherein to realize the resource of spent bleaching clay
With, contribute to reduce environmental pollution.
Specific embodiment
Below in conjunction with specific embodiment, the present invention will be further described in detail, and unreceipted condition is in embodiment
The conventional condition in this area.When the consumption or dosage or content of material is addressed, unless stated otherwise, weight is referred both to.Below
The complex micro organism fungicide used in embodiment, preparation method is as follows：Microbial bacteria by commercially available, and using it is preceding according to
Known program or producer suggestion mode enter line activating and domestication cultivate, then by bacillus subtilis, bacillus licheniformis,
Bacillus laterosporus, Streptomyces jingyangensis, bacillusmusilaginosiengineering nutrient solution are according to volume ratio 1:1.5:0.6:1.3:0.8 compounding exists
Together, control temperature is at 28-32 DEG C.
Embodiment 1
This example provides a kind of alkaline land modifying agent, and by weight percentage, its composition of raw materials includes spent bleaching clay 50%, is combined
Microbial bacterial agent 2%, phosphatization slag 20%, calcium lignosulfonate 15%, plant ash 13%, wherein spent bleaching clay oil content are for about 13-
14%.Each component independent packaging.
Embodiment 2
This example provides a kind of alkaline land modifying agent, and by weight percentage, its composition of raw materials includes spent bleaching clay 42%, is combined
Microbial bacterial agent 1%, phosphatization slag 25%, calcium lignosulfonate 10%, plant ash 22%, wherein spent bleaching clay oil content are for about 13-
14%.Each component independent packaging.
Embodiment 3
This example provides a kind of alkaline land modifying agent, and by weight percentage, its composition of raw materials includes spent bleaching clay 45%, is combined
Microbial bacterial agent 1.5%, phosphatization slag 22.5%, calcium lignosulfonate 12%, plant ash 19%, wherein spent bleaching clay oil content is for about
13-14%.Each component independent packaging.
Embodiment 4
This example provides a kind of alkaline land modifying agent, its substantially with embodiment 1, unlike, wherein spent bleaching clay oil content is
About 6-8%.
Embodiment 5
This example provides a kind of alkaline land modifying agent, its substantially with embodiment 1, unlike, wherein spent bleaching clay oil content is
About 20-22%.
Comparative example 1
This example provides a kind of alkaline land modifying agent, its substantially with embodiment 1, unlike, wherein complex micro organism fungicide
It is bacillus subtilis, bacillus licheniformis, bacillus laterosporus, Streptomyces jingyangensis in proportion 1:1.5:0.6:1.3 mixing groups
Into.
Comparative example 2
This example provides a kind of alkaline land modifying agent, its substantially with embodiment 1, unlike, wherein complex micro organism fungicide
It is bacillus subtilis, bacillus laterosporus, Streptomyces jingyangensis, jelly bacillus in proportion 1:0.6:1.3:0.8 mixing group
Into.
Comparative example 3
This example provides a kind of alkaline land modifying agent, and by weight percentage, its composition of raw materials includes spent bleaching clay 50%, is combined
Microbial bacterial agent 2%, phosphatization slag 15%, calcium lignosulfonate 13%, plant ash 20%, wherein spent bleaching clay oil content are for about 13-
14%.Each component independent packaging.
Embodiment 6
Alkaline land improving experiment is carried out using the modifying agent of embodiment 1-5 and comparative example 1-3, it is specific as follows：
1. salt-soda soil situation is tested：Lan Yu forts village of Datong City, Shanxi Province Tianzhen County San Shipu townshiies moderate salt affected soil, its pH
Salt-soda soil is divided into 9 homalographic regions, 0.05 mu of each region by value 8.5 or so.
2. for studying thing：Corn, in late April, 2016 sowing, late August harvests.
3. method for testing is supplied：First salt-soda soil is improved, then long-term cropping on the soil after improvement, wherein improvement side
Method is as follows：Complex microbial inoculum in each formula is added in spent bleaching clay, control temperature is for about 30-32 DEG C and is kept for 3 weeks, obtains
To modifying agent component A, wherein viable count is surveyed, as a result referring to table 1；Using the calcium lignosulfonate in each formula and phosphatization slag as changing
Good dose of B component, it is uniformly sprinkling upon saline and alkaline the earth's surface, is then carried out turning over 20cm and is spread water (wetting), is kept for 7 days,
Then modifying agent component A is uniformly sprinkling upon saline and alkaline the earth's surface, and is turned over, make to be well mixed, kept for 7 days, will finally matched somebody with somebody
Plant ash in side is uniformly sprinkling upon saline and alkaline the earth's surface, and carries out the 20cm that turns over, and is kept for 7 days, and the betterment of land is to complete.Detection soil
Earth indices, as a result referring to table 2, wherein heavy metal index is referring to table 3.
Table 1
Table 2
Table 3
| Sequence number | Cadmium (mg/L) | Zinc (mg/L) | Lead (mg/L) | Mercury (mg/L) | Copper (mg/L) |
| Blank soil | 0.3896 | 2.7698 | 1.1236 | 0.0769 | 0.6789 |
| Embodiment 1 | Do not detect | 0.2356 | Do not detect | Do not detect | 0.1112 |
| Embodiment 2 | Do not detect | 0.1024 | Do not detect | Do not detect | Do not detect |
| Embodiment 3 | 0.1586 | 0.2236 | Do not detect | 0.0059 | 0.2893 |
| Embodiment 4 | 0.2012 | 1.1068 | 0.5668 | 0.0287 | 0.2587 |
| Embodiment 5 | 0.1009 | 1.0598 | 0.4659 | 0.0199 | 0.1998 |
| Comparative example 1 | 0.2156 | 1.4254 | 0.8546 | 0.0412 | 0.4995 |
| Comparative example 2 | 0.2689 | 1.3665 | 0.8854 | 0.0549 | 0.4612 |
| Comparative example 3 | 0.2095 | 0.8658 | 0.5378 | 0.0367 | 0.2982 |
General planting and fertilizing management further are carried out according to conventional crop to the soil after the completion of improvement, is broadcast in corn
Before kind, with reference to site preparation, commercially available 15-25 kgs/acre of common organic fertilizer of disposably spreading manuer in holes notices that seed and fertilizer separate 5- during sowing
7 centimetres, in order to avoid regular job is pressed in burn seedlings, field management and water management, the indices to crop detect, as a result referring to
Table 4.
Table 4
| Sequence number | Plant height (cm) | Spike length (cm) | Fringe is thick (cm) | Tassel row number (OK) | Effective fringe (grain) | Per mu yield (kg) |
| Blank soil | 240.7 | 19.36 | 3.89 | 9.36 | 1635 | 790 |
| Embodiment 1 | 275.5 | 24.26 | 5.96 | 16.78 | 3494 | 1516 |
| Embodiment 2 | 272.6 | 23.56 | 5.56 | 17.21 | 3463 | 1548 |
| Embodiment 3 | 271.8 | 23.79 | 5.90 | 16.87 | 3454 | 1542 |
| Embodiment 4 | 262.8 | 21.50 | 5.12 | 15.67 | 2956 | 1312 |
| Embodiment 5 | 263.5 | 20.99 | 5.63 | 15.45 | 3012 | 1321 |
| Comparative example 1 | 261.6 | 21.15 | 4.96 | 11.23 | 3004 | 1005 |
| Comparative example 2 | 265.6 | 20.21 | 4.56 | 11.21 | 2368 | 1023 |
| Comparative example 3 | 254.4 | 21.69 | 4.39 | 10.96 | 2165 | 969 |
Above result of the test shows, successfully realizes changing salt-soda soil using the modifying agent and modification method of inventive formulation
Good, improved effect is notable.
Claims (10)
1. a kind of alkaline land modifying agent based on spent bleaching clay and phosphatization slag, it is characterised in that：By weight percentage, it is described saline and alkaline
The composition of raw materials of ground modifying agent includes spent bleaching clay 40-55%, complex micro organism fungicide 0.5-2%, phosphatization slag 20-25%, solvable
Property calcium salt 10-15% and plant ash 4-29.5%, described complex micro organism fungicide is bacillus subtilis, lichens gemma bar
Bacterium, bacillus laterosporus, Streptomyces jingyangensis, bacillusmusilaginosiengineering are 1 by nutrient solution volume ratio:1.2-1.6:0.5-0.7:
1.2-1.5:The mixture of 0.6-0.9 compositions.
2. the alkaline land modifying agent based on spent bleaching clay and phosphatization slag according to claim 1, it is characterised in that：Described answers
Conjunction microbial bacterial agent is bacillus subtilis, bacillus licheniformis, bacillus laterosporus, Streptomyces jingyangensis, gel-shaped gemma bar
The volume ratio of bacteria culture fluid is 1:1.4-1.5:0.5-0.6:1.2-1.3:The mixture of 0.8-0.9 compositions.
3. the alkaline land modifying agent based on spent bleaching clay and phosphatization slag according to claim 1, it is characterised in that：It is described useless white
Soil processes spent bleaching clay for grease-decolor, and its oil content is 12wt%-15wt%.
4. the alkaline land modifying agent based on spent bleaching clay and phosphatization slag according to claim 1, it is characterised in that：It is described solvable
Property calcium salt be calcium lignosulfonate and/or calcium citrate.
5. a kind of saline and alkali land improvement method, it is characterised in that：The method is using such as any one of Claims 1-4 claim
The described alkaline land modifying agent based on spent bleaching clay and phosphatization slag, and comprise the following steps：
(1) complex micro organism fungicide agent is added in spent bleaching clay, controls temperature to be kept for 3-5 weeks for 28-35 DEG C, make microorganism numerous
Grow, obtain modifying agent component A；
(2) it is uniformly sprinkling upon saline and alkaline the earth's surface as modifying agent B component for soluble calcium salt and phosphatization slag, is then carried out
Water is turned over and spread, is kept for 5-15 days；
(3) modifying agent component A is uniformly sprinkling upon the saline and alkaline the earth's surface processed by step (2), and is turned over, make mixing equal
It is even, kept for 5-10 days；
(4) plant ash is uniformly sprinkling upon the saline and alkaline the earth's surface processed by step (3), and is turned over, kept for 5-10 days.
6. saline and alkali land improvement method according to claim 5, it is characterised in that：The preparation of the complex micro organism fungicide agent
Method is：By bacillus subtilis, bacillus licheniformis, bacillus laterosporus, Streptomyces jingyangensis, bacillusmusilaginosiengineering bacterium
Then be well mixed for nutrient solution and obtain final product by powder respectively through respective nutrient solution is made after activation and domestication culture.
7. saline and alkali land improvement method according to claim 5, it is characterised in that：In step (1), during holding, often
Stir 3-4 ventilation week.
8. saline and alkali land improvement method according to claim 5, it is characterised in that：In step (2), ploughed depth is 18-
25cm。
9. saline and alkali land improvement method according to claim 5, it is characterised in that：In step (3), ploughed depth is 18-
25cm。
10. the alkaline land modifying agent based on spent bleaching clay and phosphatization slag as described in any one of Claims 1-4 claim exists
Application in heavy metal pollution alkaline land improving.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710041747.5A CN106833671A (en) | 2017-01-20 | 2017-01-20 | Alkaline land modifying agent and saline and alkali land improvement method based on spent bleaching clay and phosphatization slag |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201710041747.5A CN106833671A (en) | 2017-01-20 | 2017-01-20 | Alkaline land modifying agent and saline and alkali land improvement method based on spent bleaching clay and phosphatization slag |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108085017A (en) * | 2017-12-29 | 2018-05-29 | 薛彦芳 | A kind of salt-soda soil soil conditioner and preparation method thereof |
| CN110790614A (en) * | 2019-12-04 | 2020-02-14 | 吉林大学 | Alkaline soil conditioner for phosphated residues and preparation method and application thereof |
| CN111587282A (en) * | 2018-02-11 | 2020-08-25 | 北京紫光英力化工技术有限公司 | Use of biobased sulfonates as nutrient sources and conditioners |
| CN112877075A (en) * | 2021-01-18 | 2021-06-01 | 周玉玲 | Saline soil conditioner and saline soil improvement method |
| CN113121288A (en) * | 2019-12-31 | 2021-07-16 | 北京紫光英力化工技术有限公司 | Fertilizer containing bio-based sulfonate and application thereof in sand stabilization and soil improvement |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104355943A (en) * | 2014-11-12 | 2015-02-18 | 山西省农业科学院农业环境与资源研究所 | Special saline-alkali-soil improvement fertilizer prepared by modification with flue gas desulfurization gypsum and preparation method thereof |
| CN104788265A (en) * | 2015-04-30 | 2015-07-22 | 山西省农业科学院农业环境与资源研究所 | Saline-alkali soil biological improved fertilizer based on high-sulfur gangue and preparation method thereof |
| CN105103757A (en) * | 2015-08-28 | 2015-12-02 | 贵州开磷集团股份有限公司 | Method for improving saline and alkaline land by using ardealite, tetrametilenpentaurea and biological bacteria |
| CN105622297A (en) * | 2016-03-21 | 2016-06-01 | 上海鲲鹏环保科技有限公司 | Compound microbial fertilizer taking waste clay minerals as main raw material |
-
2017
- 2017-01-20 CN CN201710041747.5A patent/CN106833671A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104355943A (en) * | 2014-11-12 | 2015-02-18 | 山西省农业科学院农业环境与资源研究所 | Special saline-alkali-soil improvement fertilizer prepared by modification with flue gas desulfurization gypsum and preparation method thereof |
| CN104788265A (en) * | 2015-04-30 | 2015-07-22 | 山西省农业科学院农业环境与资源研究所 | Saline-alkali soil biological improved fertilizer based on high-sulfur gangue and preparation method thereof |
| CN105103757A (en) * | 2015-08-28 | 2015-12-02 | 贵州开磷集团股份有限公司 | Method for improving saline and alkaline land by using ardealite, tetrametilenpentaurea and biological bacteria |
| CN105622297A (en) * | 2016-03-21 | 2016-06-01 | 上海鲲鹏环保科技有限公司 | Compound microbial fertilizer taking waste clay minerals as main raw material |
Non-Patent Citations (3)
| Title |
|---|
| 关坪: "《环境保护管理与污染治理》", 31 August 1995, 国防工业出版社 * |
| 吕春娟: "《农村水土保持》", 30 September 2006, 中国社会出版社 * |
| 张立新: "山西省天镇县盐碱地现状及改良途径", 《中国农业信息》 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108085017A (en) * | 2017-12-29 | 2018-05-29 | 薛彦芳 | A kind of salt-soda soil soil conditioner and preparation method thereof |
| CN111587282A (en) * | 2018-02-11 | 2020-08-25 | 北京紫光英力化工技术有限公司 | Use of biobased sulfonates as nutrient sources and conditioners |
| CN110790614A (en) * | 2019-12-04 | 2020-02-14 | 吉林大学 | Alkaline soil conditioner for phosphated residues and preparation method and application thereof |
| CN113121288A (en) * | 2019-12-31 | 2021-07-16 | 北京紫光英力化工技术有限公司 | Fertilizer containing bio-based sulfonate and application thereof in sand stabilization and soil improvement |
| CN112877075A (en) * | 2021-01-18 | 2021-06-01 | 周玉玲 | Saline soil conditioner and saline soil improvement method |
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