CN106948029A - 一种复合纤维 - Google Patents

一种复合纤维 Download PDF

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CN106948029A
CN106948029A CN201710306106.8A CN201710306106A CN106948029A CN 106948029 A CN106948029 A CN 106948029A CN 201710306106 A CN201710306106 A CN 201710306106A CN 106948029 A CN106948029 A CN 106948029A
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冯志容
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    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/10Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one other macromolecular compound obtained by reactions only involving carbon-to-carbon unsaturated bonds as constituent
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/07Addition of substances to the spinning solution or to the melt for making fire- or flame-proof filaments
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • D01F1/103Agents inhibiting growth of microorganisms
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/14Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/18Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from other substances

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Artificial Filaments (AREA)

Abstract

本发明公开了一种复合纤维,它涉及复合纤维技术领域。所述的复合纤维由以下重量份数的原料制成:聚乙烯醇纤维6‑11份、海泡石纤维2‑8份、改性碳纤维20‑30份,竹纤维10‑15份,抗菌微粒2‑4份、碳酸钠7‑9份、氧化钡5‑9份、纳米二氧化钛3‑9份,聚乳酸15‑30份,钛酸酯偶联剂3‑8份,二盐基邻苯二甲酸铅1‑3份,抗氧剂0.5‑1份和阻燃高分子材料3‑8份。此种复合纤维具有很好的强度和耐高温阻燃性能,同时纤维之间排布均匀,强度和力学性能优异,相容性好,碳纤维和竹纤维在体系中分散均匀,同时,拉伸强度高、弹性系数高、吸收冲击能量大,制备过程简单。

Description

一种复合纤维
技术领域
本发明涉及一种复合纤维,属于复合纤维技术领域。
背景技术
目前全球石油资源越来越短缺,环境日益恶化,各类以石油基树脂制造的有机 维材料的生产成本不断增涨且生产污染大,然而各个领域对纤维材料的需求却日趋强烈。复合纤维制造技术可以获得兼有两种聚合物特性的双组分纤维、永久卷曲纤维、超细纤维、空心纤维、异形细纤维等多种改性纤维。但现有的复合纤维普遍存在结构不均匀,强度不够等缺陷,不能够满足使用需求。
发明内容
针对上述问题,本发明要解决的技术问题是提供一种复合纤维。
本发明的复合纤维由以下重量份数的原料制成:聚乙烯醇纤维 6-11 份、海泡石纤维 2-8 份、改性碳纤维 20-30 份,竹纤维 10-15 份,抗菌微粒2-4份、碳酸钠 7-9 份、氧化钡 5-9 份、纳米二氧化钛 3-9 份,聚乳酸 15-30 份,钛酸酯偶联剂 3-8 份,二盐基邻苯二甲酸铅 1-3 份,抗氧剂 0.5-1 份和阻燃高分子材料3-8份。
进一步优选,所述的复合纤维由以下重量份数的原料制成:聚乙烯醇纤维 6 份、海泡石纤维 6 份、改性碳纤维 25 份,竹纤维 12份,抗菌微粒2份、碳酸钠 8份、氧化钡8份、纳米二氧化钛 7份,聚乳酸25份,钛酸酯偶联剂8份,二盐基邻苯二甲酸铅3份,抗氧剂 1份和阻燃高分子材料5份。
作为优选,所述的抗氧剂为抗氧剂 TNP。
作为优选,所述的阻燃高分子为聚间苯二甲 酰间苯二胺、聚芳砜酰胺或含砜基聚苯并咪唑中的一种。
作为优选,所述的抗菌微粒为纳米银抗菌颗粒。
本发明的有益效果:此种复合纤维具有很好的强度和耐高温阻燃性能,同时纤维之间排布均匀,强度和力学性能优异,相容性好,碳纤维和竹纤维在体系中分散均匀,同时,拉伸强度高、弹性系数高、吸收冲击能量大, 而且制备过程简单,方便工业化生产。
具体实施方式:
本具体实施方式采用以下技术方案:所述的复合纤维由以下重量份数的原料制成:聚乙烯醇纤维 6-11 份、海泡石纤维 2-8 份、改性碳纤维 20-30 份,竹纤维 10-15 份,抗菌微粒2-4份、碳酸钠 7-9 份、氧化钡 5-9 份、纳米二氧化钛 3-9 份,聚乳酸 15-30 份,钛酸酯偶联剂 3-8 份,二盐基邻苯二甲酸铅 1-3 份,抗氧剂 0.5-1 份和阻燃高分子材料3-8份。
进一步优选,所述的复合纤维由以下重量份数的原料制成:聚乙烯醇纤维 6 份、海泡石纤维 6 份、改性碳纤维 25 份,竹纤维 12份,抗菌微粒2份、碳酸钠 8份、氧化钡8份、纳米二氧化钛 7份,聚乳酸25份,钛酸酯偶联剂8份,二盐基邻苯二甲酸铅3份,抗氧剂 1份和阻燃高分子材料5份。
作为优选,所述的抗氧剂为抗氧剂 TNP。
作为优选,所述的阻燃高分子为聚间苯二甲 酰间苯二胺、聚芳砜酰胺或含砜基聚苯并咪唑中的一种。
作为优选,所述的抗菌微粒为纳米银抗菌颗粒。
实施例1:复合纤维由以下重量份数的原料制成:聚乙烯醇纤维 6份、海泡石纤维2份、改性碳纤维 20份,竹纤维 10 份,抗菌微粒2份、碳酸钠 7份、氧化钡 5份、纳米二氧化钛 3份,聚乳酸 15 份,钛酸酯偶联剂 3份,二盐基邻苯二甲酸铅 1份,抗氧剂 0.5份和阻燃高分子材料3份;
实施例2:复合纤维由以下重量份数的原料制成:聚乙烯醇纤维 6 份、海泡石纤维 6份、改性碳纤维 25 份,竹纤维 12份,抗菌微粒2份、碳酸钠 8份、氧化钡8 份、纳米二氧化钛 7份,聚乳酸25份,钛酸酯偶联剂8份,二盐基邻苯二甲酸铅3份,抗氧剂 1 份和阻燃高分子材料5份。
实施例3:复合纤维由以下重量份数的原料制成:聚乙烯醇纤维11 份、海泡石纤维8 份、改性碳纤维 30 份,竹纤维 15 份,抗菌微粒4份、碳酸钠 9 份、氧化钡9 份、纳米二氧化钛 9 份,聚乳酸 30 份,钛酸酯偶联剂8 份,二盐基邻苯二甲酸铅 3 份,抗氧剂 1 份和阻燃高分子材料8份。
以上显示和描述了本发明的基本原理和主要特征和本发明的优点。本行业的技术人员应该了解,本发明不受上述实施例的限制,上述实施例和说明书中描述的只是说明本发明的原理,在不脱离本发明精神和范围的前提下,本发明还会有各种变化和改进,这些变化和改进都落入要求保护的本发明范围内。本发明要求保护范围由所附的权利要求书及其等效物界定。

Claims (5)

1.一种复合纤维,其特征在于:所述的复合纤维由以下重量份数的原料制成:聚乙烯醇纤维 6-11 份、海泡石纤维 2-8 份、改性碳纤维 20-30 份,竹纤维 10-15 份,抗菌微粒2-4份、碳酸钠 7-9 份、氧化钡 5-9 份、纳米二氧化钛 3-9 份,聚乳酸 15-30 份,钛酸酯偶联剂 3-8 份,二盐基邻苯二甲酸铅 1-3 份,抗氧剂 0.5-1 份和阻燃高分子材料3-8份。
2.按照权利要求1所述的一种复合纤维,其特征在于:所述的复合纤维由以下重量份数的原料制成:聚乙烯醇纤维 6 份、海泡石纤维 6 份、改性碳纤维 25 份,竹纤维 12份,抗菌微粒2份、碳酸钠 8份、氧化钡8 份、纳米二氧化钛 7份,聚乳酸25份,钛酸酯偶联剂8份,二盐基邻苯二甲酸铅3份,抗氧剂 1 份和阻燃高分子材料5份。
3.按照权利要求1所述的一种复合纤维,其特征在于:所述的抗氧剂为抗氧剂 TNP。
4.按照权利要求1所述的一种复合纤维,其特征在于:所述的阻燃高分子为聚间苯二甲酰间苯二胺、聚芳砜酰胺或含砜基聚苯并咪唑中的一种。
5.按照权利要求1所述的一种复合纤维,其特征在于:所述的抗菌微粒为纳米银抗菌颗粒。
CN201710306106.8A 2017-05-04 2017-05-04 一种复合纤维 Pending CN106948029A (zh)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108867035A (zh) * 2018-07-04 2018-11-23 合肥远科服装设计有限公司 一种阻燃性能可改善的针织面料及其制备方法
CN110587757A (zh) * 2019-08-15 2019-12-20 阜阳创启工艺品有限公司 一种使用柳木皮下脚料制备高强度改性纤维的方法
CN111979625A (zh) * 2020-08-25 2020-11-24 湖南尚珂伊针纺有限公司 一种化纤复合纤维及其加工方法

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103451770A (zh) * 2013-09-04 2013-12-18 东华大学 一种绿色低碳阻燃假发纤维的制备方法
CN104018243A (zh) * 2014-05-05 2014-09-03 东华大学 一种阻燃纤维及其制备方法
CN104356584A (zh) * 2014-10-29 2015-02-18 昆山艾士比高分子科技有限公司 一种纤维复合材料
CN104404650A (zh) * 2014-11-04 2015-03-11 张桂华 一种复合纤维
CN105483861A (zh) * 2015-12-30 2016-04-13 王丽萍 一种高性能复合纤维材料

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103451770A (zh) * 2013-09-04 2013-12-18 东华大学 一种绿色低碳阻燃假发纤维的制备方法
CN104018243A (zh) * 2014-05-05 2014-09-03 东华大学 一种阻燃纤维及其制备方法
CN104356584A (zh) * 2014-10-29 2015-02-18 昆山艾士比高分子科技有限公司 一种纤维复合材料
CN104404650A (zh) * 2014-11-04 2015-03-11 张桂华 一种复合纤维
CN105483861A (zh) * 2015-12-30 2016-04-13 王丽萍 一种高性能复合纤维材料

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108867035A (zh) * 2018-07-04 2018-11-23 合肥远科服装设计有限公司 一种阻燃性能可改善的针织面料及其制备方法
CN110587757A (zh) * 2019-08-15 2019-12-20 阜阳创启工艺品有限公司 一种使用柳木皮下脚料制备高强度改性纤维的方法
CN111979625A (zh) * 2020-08-25 2020-11-24 湖南尚珂伊针纺有限公司 一种化纤复合纤维及其加工方法

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Application publication date: 20170714