CN106857513A - A kind of unitary Peracetic acid solid particle disinfectant - Google Patents

A kind of unitary Peracetic acid solid particle disinfectant Download PDF

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Publication number
CN106857513A
CN106857513A CN201710017133.3A CN201710017133A CN106857513A CN 106857513 A CN106857513 A CN 106857513A CN 201710017133 A CN201710017133 A CN 201710017133A CN 106857513 A CN106857513 A CN 106857513A
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China
Prior art keywords
sodium
acid
peracetic acid
unitary
solid particle
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CN201710017133.3A
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Chinese (zh)
Inventor
戴彦榛
史瑞雪
王舒萌
王玉路
李芳�
李欢欢
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Changjiangmai Medicine Science & Technology Co Ltd Beijing
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Changjiangmai Medicine Science & Technology Co Ltd Beijing
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Priority to CN201710017133.3A priority Critical patent/CN106857513A/en
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/16Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group; Thio analogues thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/12Powders or granules

Abstract

It is a kind of be obtained in that be more easy to storage transport, the peracetic acid soln that makes preparation is more stable, corrosivity is smaller, reliable unitary Peracetic acid solid particle disinfectant safe and convenient to use, is made up of inorganic peroxide, tetraacetyl ethylene diamine, surfactant, pH value conditioning agent, stabilizer, corrosion inhibiter, peroxyacetic acid concentration indicator.

Description

A kind of unitary Peracetic acid solid particle disinfectant
Technical field
The present invention relates to a kind of unitary Peracetic acid solid particle disinfectant.
Background technology
Used as traditional pasteurization material, chlorine-containing disinfecting material effects mechanism is hydrolysis generation hypochlorous acid molecule, using secondary chlorine The oxidation sterilizing of acid molecule.But use chlorine-containing disinfectant sterilize when, by hypochlorous acid molecule HCIO decomposite time Chlorate ions (OCL-), easily forms carcinogen chloroform (CHCL with impurities in water3) or trichlorophenol, so seldom making now Carried out disinfection with chlorine-containing disinfectant, and generally use peroxide sterilants.
Peroxide sterilants have Strong oxdiative ability, and various microorganisms are very sensitive to it, can kill all microorganisms Go out.This kind of disinfectant is including hydrogen peroxide, Peracetic acid, chlorine dioxide and ozone etc..Their advantage is in article after sterilizing On leave no residue toxicity, non-carcinogenesis.Someone is researched and produced disinfectants with rich carboxylic macromolecular material in recent years, such as: Peroxidating acrylic acid (sodium salt), peroxidating maleic acid (sodium salt), methyl acrylic acid (sodium salt) and peroxidating fumaric acid (sodium Salt) etc..
Wherein, Peracetic acid (CH3COOOH) it is a kind of widely used quick-acting, efficient, low toxicity, broad-spectrum disinfectant, can be with Kill various bacterial propagules, mould, virus, gemma.Preventing and controlling hospital-acquired infection and large-scale infectious disease (such as atypia Property pneumonia, bird flu, H1N1) break out in played an important role.It is low with valid density;Work fast etc. Premium properties, catabolite is acetic acid and oxygen, is had no side effect.But traditional peroxyacetic acid disinfectant exists in liquid form, surely Qualitative difference, it is not easy to maintain, it is numerous dominant with recessive application risk with more explosive, severe corrosive etc..
Chinese patent literature 1 (CN1128257A) and patent document 2 (CN15422000A) disclose Peracetic acid solid The technical scheme of the preparation method of medicament.The former tetraacetyl ethylene diamine and coated place of (CN1128257A) coated treatment The sodium perborate of reason is mixed by certain molar ratio, and then the solid dissolving of the mixing is produced in a certain amount of normal-temperature water Peracetic acid, although solve and be difficult storage, transport and awkward problem, but dissolubility is poor, produces speed slowly, effectively Composition is volatile;The latter (CN15422000A) is by acetyl-containing activator, inorganic peroxide and surfactant formation of solid polycomplex Medicament, although accelerate the speed of producing of Peracetic acid, but still without solving, Stability of Acetic acid peroxide is poor, and corrosivity is high to ask Topic.
Chinese patent literature 3 (CN102415380A) disclose it is a kind of by tetraacetyl ethylene diamine, inorganic peroxide, it is cloudy from The solid producer of sub- surfactant and anticorrosive composition, in this scenario, although solve stability to a certain extent And corrosion problems, but solution ph is not controlled, peroxide need to be under weak basic condition just with acyl compounds Peracetic acid can be generated, and when alkaline too strong, the Peracetic acid fast decoupled of generation causes utilization rate relatively low.Chinese patent Document 4 (CN102964285A) disclose it is a kind of by acetylsalicylic acid, it is tetraacetyl ethylene diamine, SODIUM PERCARBONATE, surfactant, slow Erosion agent and the solid producer of pH adjusting agent composition, in this scenario, although solution ph is controlled, but it is not right Formulation technique claims, is still required without addition peroxide stabiliser, to dissolving water temperature, need to mix step, dissolving speed Degree is slow, and peroxyacetic acid concentration is not indicated.
Existing market Its Accompanying Solid Peracetic Acid propellant is generally that a certain amount of powder is loaded in mixture or two-component packaging, dissolution velocity is slow, External force is needed to mix;Peroxyacetic acid concentration is not indicated, while powder loads in mixture easily caking is unfavorable for storage, product mixing degree is not Reliability and it is unfavorable for measuring for demand hour, application place scope is limited, and corrosivity is big, there is larger damage to sterilization objects Wound.In the case where being added without peroxyacetic acid stabilizing agent, Peracetic acid is easily decomposed, and usage cycles are short.
In general, Peroxyacetic acid generator needs to solve in the presence of obvious defect.Such as:
1st, water reaction is being dissolved in using peroxide and Acyl activating thing, when preparing liquid Peracetic acid, is commonly using acyl group and live Agent is tetraacetyl ethylene diamine, density 0.9, is slightly soluble in water, needs external force to stir when preparing Peracetic acid and promotes dissolving, reaction it is slow and The water surface easily is swum in, influence is used;Simultaneously to promote its dissolving, largely using surfactant, rinsing difficulty is increased.
2nd, existing Peracetic acid solid producer is that powder and particle are loaded in mixture, therefore is difficult to mix, is not easy to determining for small demand Sample is measured, using limited;And easily moisture absorption is lumpd, it is unfavorable for preservation steady in a long-term.
3rd, Peracetic acid belongs to strong oxidizer, and the use for having larger corrosivity, poorly efficient corrosion inhibiter to metal can not be protected fully Shield is sterilized object, has severe corrosiveness to metals such as copper, carbon steels.
4th, Stability of Acetic acid peroxide is poor, easily decomposes to give off oxygen, and so as to cause the reduction of effective content, prior art is not related to And the use of peroxyacetic acid stabilizing agent, therefore its usage cycles is shorter.
5th, only have Peracetic acid growing amount to reach finite concentration, certain specified microorganisms could be reached under certain hour To sterilisation purpose, and current techniques do not refer to peroxyacetic acid concentration indicator, are unfavorable for that it is used safely.
The content of the invention
In view of above-mentioned technical problem, it is more easy to storage transport, makes preparation present invention aim at a kind of being obtained in that is provided Peracetic acid soln is more stable, corrosivity is smaller, reliable unitary Peracetic acid solid particle disinfectant safe and convenient to use.
Specifically, the present invention provides a kind of unitary Peracetic acid solid particle disinfectant, it is characterised in that by inorganic peroxy Compound, tetraacetyl ethylene diamine, surfactant, pH value conditioning agent, stabilizer, corrosion inhibiter, peroxyacetic acid concentration indicator composition.
Such as above-mentioned unitary Peracetic acid solid particle disinfectant, it is characterised in that the inorganic peroxide, four acetyl second Diamines, surfactant, pH value conditioning agent, stabilizer, corrosion inhibiter, peroxyacetic acid concentration indicator, its respective shared quality hundred Ratio is divided to be followed successively by:20%~50%: 10%~40%: 0.5%~10%: 5%~29.5%: 0.5%~15%: 0.09%~ 10%: 0.01%~0.5%.
Such as above-mentioned unitary Peracetic acid solid particle disinfectant, it is characterised in that the inorganic peroxide prioritizing selection SODIUM PERCARBONATE or sodium perborate.
Such as above-mentioned unitary Peracetic acid solid particle disinfectant, it is characterised in that the pH value conditioning agent is selected from solid acid, Optimization citric acid, tartaric acid, organic phosphoric acid, sulfamic acid etc..
Such as above-mentioned unitary Peracetic acid solid particle disinfectant, it is characterised in that the surfactant selected from it is non-from One kind or several mixtures in sub- surfactant or anion surfactant, such as:Neopelex, amino Acid surfaces activating agent, lauryl sodium sulfate, dodecyl sodium sulfate, fatty alkyl polyglycol ether and polyethylene glycol octyl group benzene Base ether etc.;The mass ratio of its shared tetraacetyl ethylene diamine is 0.5%~80%.
Such as above-mentioned unitary Peracetic acid solid particle disinfectant, it is characterised in that described stabilizer is selected from D-Glucose Sour sodium, disodium edta, inorganic phosphate, organophosphor acids and organic phosphate, silicate.Such as by hexa metaphosphoric acid Sodium, sodium pyrophosphate, sodium polyphosphate, sodium metasilicate and sodium ethylene diamine tetracetate are compounded, and its proportion of composing is:5%~30%: 10%~ 10%: 5%~25%: 5%~10%: 25%~75%
Such as above-mentioned unitary Peracetic acid solid particle disinfectant, it is characterised in that the corrosion inhibiter is selected from sodium molybdate, silicic acid Sodium, phytic acid, metal oxide, BTA, borate ester, polyethylene glycol, pentaerythrite, Sodium Benzoate, sodium polyphosphate, At least one in the methylthiazol of 2- amino -5 and imidazoline quaternary ammonium salt.Such as by sodium molybdate, sodium metasilicate, BTA, poly- second Glycol 6000 is compounded, and its proportion of composing is:10%~30%: 5%~20%: 5%~10%: 40%~80%.
Such as above-mentioned unitary Peracetic acid solid particle disinfectant, it is characterised in that the Peracetic acid containing dosis indicators by Edible pigment light blue, sodium acid carbonate, sodium chloride composition.
Such as above-mentioned unitary Peracetic acid solid particle disinfectant, it is characterised in that in addition to can be in particle shape, institute Stating Peracetic acid solid particle disinfectant can also be in forms such as tablet, pulvis or pills.
Disinfectant according to the present invention, by inorganic peroxide, tetrem involved in various combination the application Acyl ethylenediamine, surfactant, pH value conditioning agent, stabilizer, corrosion inhibiter etc., it is possible to achieve identical goal of the invention, difference rule The tablet of lattice, pulvis or pill etc..
Disinfectant according to the present invention, due to by inorganic peroxide, tetraacetyl ethylene diamine, surfactant, PH Value conditioning agent, stabilizer, corrosion inhibiter, peroxyacetic acid concentration indicator composition, so, it is more easy to storage transport.Further, by setting Put different tablet qualities, control the Peracetic acid amount of generation, different occasions, different purposes, different demands amount can be facilitated to make With.
Disinfectant according to the present invention, due to pH value conditioning agent, is not only able to adjust the pH value of use environment Section, and, the dissolving of solid particle can be accelerated in the presence of the conditioning agent of the slant acidity, mixed without external force, to water temperature It is required that low, reaction speed faster, and reduces the consumption of surfactant, beneficial to rinsing;On the other hand, due to exist efficiently, The stabilizer and corrosion inhibitor formula of low concentration, so can make preparation peracetic acid soln is more stable, corrosivity is smaller;Addition Food grade colorant is safe and reliable using being more convenient as fluoroacetic acid concentration indicator.
Specific embodiment
The present invention is described in detail below by specific embodiment.
The unitary Peracetic acid solid particle disinfectant that the present invention is provided, by inorganic peroxide, tetraacetyl ethylene diamine, table Face activating agent, pH value conditioning agent, stabilizer, corrosion inhibiter, peroxyacetic acid concentration indicator composition.It is pointed out that of the invention Peracetic acid solid particle disinfectant need dry or job shop equipped with dehumidification equipment in prepare, to ensure that this is consolidated The performance and stability of body particle reagents.
In the present invention, the granule first by tetraacetyl ethylene diamine, surfactant, pH value conditioning agent, stabilizer, Corrosion inhibiter and peroxyacetic acid concentration indicator abundant mixed pelletization in proportion, then mixed with inorganic peroxygen composition granule.Make It is preferred, the inorganic peroxide, tetraacetyl ethylene diamine, surfactant, pH value conditioning agent, stabilizer, corrosion inhibiter, mistake Fluoroacetic acid concentration indicator, its each shared mass percent be followed successively by:20%~50%: 10%~40%: 0.5%~10% : 5%~29.5%: 0.5%~15%: 0.09%~10%: 0.01%~0.5%.
In the present invention, the surfactant, corrosion inhibiter etc. can be using the examinations disclosed in patent document 1~4 Agent, as long as it meets invention thinking of the invention, you can reference is used, if it should be noted, however, that using for reference these examinations Agent in inventive formulation ratio, it is necessary to be modulated, if formula is beyond dosage range of the invention, although it can make It is standby go out disinfectant of the invention, but its stability or dissolution velocity be it cannot be guaranteed that.Formula of the invention is the present invention The classical formula that R&D team obtains by up to ten thousand experiments, but the present invention is not limited to these classics formulas, art technology Personnel should be appreciated that this point.Further, pH value conditioning agent of the invention can coordinate adhesive to use as effervesce reagent, The pH value conditioning agent not only plays a part of conditioning agent, may also operate as the effect of disintegrant, and this is in another of the application There is specific detailed description in row application, repeat no more herein.
In the present invention, the inorganic peroxide prioritizing selection SODIUM PERCARBONATE or sodium perborate.
In the present invention, the pH value conditioning agent can not only select acid regulator but also can select alkaline conditioner, lead to Cross and pH value is controlled, so that the product of different specifications can be applicable under different PH environment.
In the present invention, the surfactant is selected from nonionic surfactant or anion surfactant A kind of or several mixtures, such as:Neopelex, lauryl sodium sulfate, dodecyl sodium sulfate, fatty alkyl Polyglycol ether and Triton X-100 etc.;The mass ratio of its shared tetraacetyl ethylene diamine is 0.5%~80%.
In the present invention, described stabilizer be selected from maltonic acid sodium, disodium edta, inorganic phosphate, Organophosphor acids and organic phosphate, silicate.Such as by calgon, sodium pyrophosphate, sodium polyphosphate, sodium metasilicate and two Amine tetraacethyl sodium is compounded, and its proportion of composing is respectively (mass percent):5%~30%: 10%~10%: 5%~25%: 5%~10%: 25%~75%
In the present invention, the corrosion inhibiter is selected from sodium molybdate, sodium metasilicate, phytic acid, metal oxide, BTA, boron In esters of gallic acid, polyethylene glycol, pentaerythrite, Sodium Benzoate, sodium polyphosphate, the methylthiazol of 2- amino -5 and imidazoline quaternary ammonium salt At least one.Such as compounded by sodium molybdate, sodium metasilicate, BTA, Macrogol 6000, its proportion of composing is respectively (matter Amount percentage):10%~30%: 5%~20%: 5%~10%: 40%~80%.
In the present invention, the Peracetic acid contains dosis indicators by edible pigment light blue, sodium acid carbonate, sodium chloride group Into.
In the present invention, in addition to can be in particle shape, the Peracetic acid solid particle disinfectant can also be in The forms such as tablet, pulvis or pill.
Disinfectant according to the present invention, by inorganic peroxide, tetrem involved in various combination the application Acyl ethylenediamine, surfactant, pH value conditioning agent, stabilizer, corrosion inhibiter etc., it is possible to achieve identical goal of the invention, difference rule The tablet of lattice, pulvis or pill etc..
Disinfectant according to the present invention, due to by inorganic peroxide, tetraacetyl ethylene diamine, surfactant, PH Value conditioning agent, stabilizer, corrosion inhibiter, peroxyacetic acid concentration help of indicator particles composition, so, it is more easy to storage transport.Further, lead to Setting variable grain quality is crossed, the Peracetic acid amount of generation is controlled, different occasions, different purposes, different demands amount can be facilitated Use.
Disinfectant according to the present invention, due to the addition of pH value conditioning agent, it is possible under different PH environment It is applicable, the peracetic acid soln pH value that inventive formulation is generated can be stablized in the range of 7.0~8.0, both beneficial to Peracetic acid Quickly generate, and beneficial to peroxyacetic acid concentration stabilization keep.
Disinfectant according to the present invention, due to pH value conditioning agent, is not only able to adjust the pH value of use environment Section, and, the dissolving of solid particle can be accelerated in the presence of the conditioning agent of the slant acidity, reaction speed low to water temperature requirement Spend faster, and reduce the consumption of surfactant, beneficial to rinsing;On the other hand, due to the stabilizer that there is efficient, low concentration And corrosion inhibitor formula, so can make preparation peracetic acid soln is more stable, corrosivity is smaller;Addition food grade colorant conduct Fluoroacetic acid concentration indicator, using more convenient safe and reliable.
Below by specific embodiment, the present invention is described in detail.
Embodiment 1
First by tetraacetyl ethylene diamine 5g, neopelex 0.6g, tartaric acid 3.0g, calgon 1.0g, hydroxyl Base ethylidene diphosphonic acid 0.6g, BTA 0.2g and light blue 0.005g are mixed and are a granulated into different size particle, then with percarbonic acid Sodium particle 10g is fully mixed.
Embodiment 2
First by tetraacetyl ethylene diamine 5g, neopelex 0.6g, citric acid 3.0g, calgon 1.0g, hydroxyl Base ethylidene diphosphonic acid 0.6g, BTA 0.2g and light blue 0.005g are mixed and are a granulated into different size particle, then with percarbonic acid Sodium particle 10g is fully mixed.
Embodiment 3
First by tetraacetyl ethylene diamine 5g, fatty alkyl polyglycol ether 0.5g, tartaric acid 3.0g, calgon 1.0g, 1-hydroxy ethylidene-1,1-diphosphonic acid 0.6g, BTA 0.2g and light blue 0.005g are mixed and are a granulated into different size particle, then with cross carbon Sour sodium particle 10g is fully mixed.
Embodiment 4
First by tetraacetyl ethylene diamine 5g, fatty alkyl polyglycol ether 0.5g, tartaric acid 3.0g, calgon 1.0g, Sodium metasilicate 0.6g, BTA 0.2g and light blue 0.005g are mixed and are a granulated into different size particle, then with sodium percarbonate granules 10g is fully mixed.
Embodiment 5
First by tetraacetyl ethylene diamine 5g, fatty alkyl polyglycol ether 0.5g, tartaric acid 3.0g, calgon 1.0g, Sodium metasilicate 0.6g, borate 0.2g and light blue 0.005g are mixed and are a granulated into different size particle, then are filled with sodium percarbonate granules 10g Divide and mix.
Embodiment 6
First by tetraacetyl ethylene diamine 5g, neopelex 0.6g, citric acid 3.0g, disodium ethylene diamine tetraacetate 0.3g, calgon 0.5g, borate 0.2g, 1-hydroxy ethylidene-1,1-diphosphonic acid 0.4g, BTA 0.2g and light blue 0.005g Mixing is a granulated into different size particle, then is fully mixed with sodium percarbonate granules 10g.
Counter-example 1
Tetraacetyl ethylene diamine 5g, SODIUM PERCARBONATE 10g, neopelex 0.6g are fully mixed and formed.
Counter-example 2
Tetraacetyl ethylene diamine 5g, SODIUM PERCARBONATE 10g, citric acid 3.0g, neopelex 0.6g are fully mixed Form.
Counter-example 3
By tetraacetyl ethylene diamine 5g, SODIUM PERCARBONATE 10g, citric acid 3.0g, neopelex 0.6g, sodium molybdate 0.5g is fully mixed and formed.
According to version in 2002《Disinfection technology standard》Sterile products inspection technology specification, determines above-described embodiment gained respectively Unitary Peracetic acid solid particle disinfectant and the counter-example gained dissolution velocity of mixing powder, stability of solution, metal protection, Product stability.Its combined data is shown in Table 1.
The Its Accompanying Solid Peracetic Acid performance parameter of the different embodiments of table 1
Embodiment 1-6 gained unitary Peracetic acid solid particles are dissolved in 1L room temperature waters, are generated when 7min is completely dissolved Peroxyacetic acid concentration reaches 0.10%, 30min generation peroxyacetic acid concentrations and reaches 0.25%, and it is long to maintain more than 0.1% Up to 55h.And counter-example 1-3 dissolution times are averagely more than 26min, so as to cause Peracetic acid formation speed slow and stabilization time It is extremely short;According to version in 2002《Disinfection technology standard》Sterile products inspection technology specification, determines above-described embodiment gained bubble respectively Rise piece and counter-example to stainless steel, carbon steel, copper, aluminium metal protection, embodiment 1-6 is right to stainless steel, copper no corrosion Aluminium, carbon steel mild corrosion, show that the present invention can break through use scope and the field of peroxyacetic acid disinfectant.And counter-example to copper, Carbon steel, aluminium are all severe corrosion, are to restrict the key factor that peroxyacetic acid disinfectant is used.By embodiment 1-6 gained unitary mistakes Fluoroacetic acid solid particle and counter-example 1-3 gained powder samples were packed with reagent bottle sealing preserve respectively, using 37 DEG C/3 months Method carries out Stability Determination, as a result shows, under the same terms, the effervescent tablet Peracetic acid growing amount after experiment in 37 DEG C/3 months Averagely decline no more than 0.41%, and appearance character is basically unchanged, and the Peracetic acid growing amount of counter-example sample averagely declines Rate is all higher than 18.71%, and caking, flatulence are serious.
To sum up, although the present invention is made a detailed description for specific embodiment, but it is to be understood that these are said It is bright be it is exemplary, protection scope of the present invention is not limited only among these specific embodiments, for those skilled in the art For, the present invention can be made various changes and modifications within the scope of present inventive concept and spirit not departing from, these are repaiied Changing and changing to fall within the scope and spirit of the invention, and protection scope of the present invention is defined by the following claims.

Claims (9)

1. a kind of unitary Peracetic acid solid particle disinfectant, it is characterised in that by inorganic peroxide, tetraacetyl ethylene diamine, Surfactant, pH value conditioning agent, stabilizer, corrosion inhibiter, peroxyacetic acid concentration indicator composition.
2. unitary Peracetic acid solid particle disinfectant as claimed in claim 1, it is characterised in that the inorganic peroxide, Tetraacetyl ethylene diamine, surfactant, pH value conditioning agent, stabilizer, corrosion inhibiter, peroxyacetic acid concentration indicator, its respective institute Mass percent is accounted for be followed successively by:20%~50%: 10%~40%: 0.5%~10%: 5%~29.5%: 0.5%~15%: 0.09%~10%: 0.01%~0.5%.
3. unitary Peracetic acid solid particle disinfectant as claimed in claim 1, it is characterised in that the inorganic peroxide is excellent First select SODIUM PERCARBONATE or sodium perborate.
4. unitary Peracetic acid solid particle disinfectant as claimed in claim 1, it is characterised in that the pH value conditioning agent is selected from Solid acid, optimization citric acid, tartaric acid, organic phosphoric acid, sulfamic acid etc..
5. unitary Peracetic acid solid particle disinfectant as claimed in claim 1, it is characterised in that the surfactant is selected from One kind or several mixtures in nonionic surfactant or anion surfactant, such as:DBSA Sodium, amino acid surfactant, lauryl sodium sulfate, dodecyl sodium sulfate, fatty alkyl polyglycol ether and poly- second two Alcohol octyl phenyl ether etc.;The mass ratio of its shared tetraacetyl ethylene diamine is 0.5%~80%.
6. unitary Peracetic acid solid particle disinfectant as claimed in claim 1, it is characterised in that described stabilizer is selected from D- Sodium gluconate, disodium edta, inorganic phosphate, organophosphor acids and organic phosphate, silicate.Such as by six Sodium metaphosphate, sodium pyrophosphate, sodium polyphosphate, sodium metasilicate and disodium ethylene diamine tetraacetate are compounded, and its proportion of composing is:5%~ 30%: 10%~10%: 5%~25%: 5%~10%: 25%~75%.
7. unitary Peracetic acid solid particle disinfectant as claimed in claim 1, it is characterised in that the corrosion inhibiter is selected from molybdic acid Sodium, sodium metasilicate, phytic acid, metal oxide, BTA, borate ester, polyethylene glycol, pentaerythrite, Sodium Benzoate, poly At least one in sodium phosphate, the methylthiazol of 2- amino -5 and imidazoline quaternary ammonium salt.Such as by sodium molybdate, sodium metasilicate, the nitrogen of benzo three Azoles, Macrogol 6000 are compounded, and its proportion of composing is:10%~30%: 5%~20%: 5%~10%: 40%~80%.
8. unitary Peracetic acid solid particle disinfectant as claimed in claim 1, it is characterised in that the Peracetic acid content refers to Show that agent is made up of edible pigment light blue, sodium acid carbonate, sodium chloride.
9. unitary Peracetic acid solid particle disinfectant as claimed in claim 1, it is characterised in that except that can be in particle shape Outside, the Peracetic acid solid particle disinfectant can also be in forms such as tablet, pulvis or pills.
CN201710017133.3A 2017-01-11 2017-01-11 A kind of unitary Peracetic acid solid particle disinfectant Pending CN106857513A (en)

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Cited By (13)

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CN107410310A (en) * 2017-08-18 2017-12-01 王金强 A kind of peracetic acid in single-ingredient disinfection solution and preparation method thereof
CN109156476A (en) * 2018-10-23 2019-01-08 广州市凯迪新医学科技有限公司 Unitary package sterilization powder and preparation method thereof
CN110934141A (en) * 2018-09-21 2020-03-31 上海利康消毒高科技有限公司 Solid-state peracetic acid long-acting sterilization powder and preparation method thereof
CN111065273A (en) * 2017-08-16 2020-04-24 法国诗华大药厂 Novel disinfectant for hatcheries
CN111226978A (en) * 2020-03-18 2020-06-05 中国天辰工程有限公司 Peracetic acid disinfectant
CN111567524A (en) * 2020-04-29 2020-08-25 广西夏阳环保科技有限公司 Efficient composite peroxide disinfectant and preparation method thereof
CN111631217A (en) * 2020-07-11 2020-09-08 山东利尔康医疗科技股份有限公司 Low-odor low-corrosivity neutral peroxyacetic acid disinfectant and preparation method thereof
CN112790191A (en) * 2021-01-06 2021-05-14 海韵一剑大卫生科技有限公司 Low-temperature peracetic acid disinfectant and preparation method thereof
CN112913840A (en) * 2021-01-06 2021-06-08 海韵一剑大卫生科技有限公司 Ultralow-temperature peracetic acid disinfectant and preparation method thereof
CN114145297A (en) * 2021-12-21 2022-03-08 上海朗彤环境科技发展有限公司 Unitary peracetic acid sterilizing powder and preparation method thereof
US11330819B2 (en) * 2018-12-28 2022-05-17 Diversey, Inc. Synergistic disinfectant compositions having enhanced antimicrobial efficacy and stability, and methods of using the same
CN114631529A (en) * 2022-02-25 2022-06-17 湖北微控生物科技有限公司 Unitary stable composite peroxyacetic acid disinfectant and preparation method thereof
CN115161125A (en) * 2022-06-30 2022-10-11 金瓷科技实业发展有限公司 Biological sterilization cleaning composition and application thereof, composite biological sterilization cleaning agent and preparation method and application thereof

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