CN101810171A - Novel environmentally-friendly corrosion-resistance peracetic acid disinfectant - Google Patents

Novel environmentally-friendly corrosion-resistance peracetic acid disinfectant Download PDF

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Publication number
CN101810171A
CN101810171A CN 201010150527 CN201010150527A CN101810171A CN 101810171 A CN101810171 A CN 101810171A CN 201010150527 CN201010150527 CN 201010150527 CN 201010150527 A CN201010150527 A CN 201010150527A CN 101810171 A CN101810171 A CN 101810171A
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Prior art keywords
peracetic acid
disinfectant
gram
resistance
acid disinfectant
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CN 201010150527
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CN101810171B (en
Inventor
屈庆
李蕾
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Yunnan University YNU
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Yunnan University YNU
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Abstract

The invention relates to a novel environmentally-friendly corrosion-resistance peracetic acid disinfectant, and belongs to the technical field of disinfection product preparation. 100 ml of the novel environmentally-friendly corrosion-resistance peracetic acid disinfectant comprises: 0.1 to 0.5 gram of peracetic acid solution, 0.05 to 0.1 gram of stabilizer sodium ethylenediamine tetracetate, 0.1 to 0.2 gram of surfactant sodium citrate, 0.1 to 0.2 gram of quaternary ammonium salt, 0.005 to 0.02 gram of sodium molybdate, and the balance of water. The disinfectant has broad-spectrum sterilization performance, so that the stability of conventional peracetic acid is obviously improved; additives of the disinfectant obviously inhibit the corrosion of the peracetic acid on metal materials, can be suitable for quick and effective sterilization and disinfection in schools, hospitals, factories, mines and other public places, and also can be used for environment disinfection and sterilization of SARS (Severe Acute Respiratory Syndromes), A(H1N1) and other communicable diseases. The disinfectant has no pollution after use, and is safe and convenient to use.

Description

A kind of novel environment friendly and erosion-resisting peroxyacetic acid disinfectant
Technical field:
The present invention relates to a kind of novel environment friendly and erosion-resisting peroxyacetic acid disinfectant, belong to the sterile products preparing technical field.
Background technology:
The bacterium of public place and virus cause much infecting the inducement of communicable disease often, and the disinfection of carrying out the public place can suppress propagation, the diffusion of disease in the crowd preferably.Chlorine and chlorine-containing disinfectant have very strong mutagenesis, and along with social development, the people's environmental protection and the safety meaning also improve day by day, and ozone, hydrogen peroxide and Peracetic acid etc. are considered to replace the good selection of chlorine and chlorine-containing disinfectant.Wherein, Peracetic acid has efficiently, fast, the sterilizing performance of wide spectrum, its volatilization easily in addition, decompose, its catabolite is nontoxic low fatty acid, water and oxygen, adopts peracetic acid disinfectant can not stay any harmful substance.Therefore the antiseptic property of Peracetic acid and superior Environmental compatibility thereof also obtain paying attention to day by day.Yet the easy decomposability and the severe corrosive of the peroxyacetic acid disinfectant that tradition is used have not only limited its use field, have also brought great loss and hidden danger to society, people are promoted the use of it hang back.
Summary of the invention:
The objective of the invention is to overcome the deficiency of prior art, and provide a kind of cheap, configuration is simple, safe in utilization and novel environment friendly and erosion-resisting peroxyacetic acid disinfectant easily.
Peroxyacetic acid disinfectant of the present invention, its composition comprise following component and concentration (g/100ml): stoste (peracetic acid soln) 0.1-0.5; Stabilizing agent (sodium ethylene diamine tetracetate) 0.05-0.1; Surfactant (sodium citrate) 0.1-0.2; Quaternary ammonium salt 0.1-0.2; Sodium molybdate 0.005-0.02, surplus is a water.
Peracetic acid soln is that active component plays sterilization in the present composition, the preferred 0.1-0.5g/100ml of its mass concentration.
Described component sodium ethylene diamine tetracetate mainly plays stabilization, the preferred 0.05-0.1g/100ml of its mass concentration;
Described component surfactant sodium citrate mainly plays stabilization, the preferred 0.1-0.2g/100ml of its mass concentration;
Described component sodium molybdate mainly plays the anticorrosive effect to metal material, the preferred 0.005-0.02g/100ml of its mass concentration;
Described component quaternary ammonium salt mainly plays collaborative erosion-resisting effect to metal material, the preferred 0.1-0.2g/100ml of its mass concentration;
The preparation method is easy for present composition disinfectant.The steps include: that it is 0.1-0.5g/100ml that commercial common peroxyacetic acid disinfectant water is diluted to concentration by weight percentage, shady place left standstill 8 minutes; Sodium molybdate and sodium ethylene diamine tetracetate adding wherein are configured to homogeneous solution, and shady place leaves standstill 5 minutes, and is stand-by; Sodium citrate, doped quaternary ammonium salt are added wherein successively, and shady place stirred 4 minutes gently, and shady place left standstill 60 minutes; Get high stable, anticorrosive peroxyacetic acid disinfectant.The quality index of described peroxyacetic acid disinfectant is: not stratified, the no crystallization of outward appearance, free from admixture; Color and luster is a colourless transparent liquid; Can store 6 months in the dark environment.
Characteristics of the present invention are: cheap, configuration is simple, and safe in utilization and convenient, bactericidal property, stability with wide spectrum obviously strengthen, and have obviously suppressed Peracetic acid to the Corrosion of Metallic Materials effect, can be widely used in various public places disinfection.
Embodiment:
The present invention does to set forth further by following examples, but does not limit the scope of the invention.
Embodiment one:
It is 0.1g/100ml that commercial common peroxyacetic acid disinfectant water is diluted to concentration by weight percentage, and shady place left standstill 8 minutes; Sodium molybdate 0.005g/100ml and sodium ethylene diamine tetracetate 0.05g/100ml adding wherein are configured to homogeneous solution, and shady place leaves standstill 5 minutes, and is stand-by; Sodium citrate 0.1g/100ml, doped quaternary ammonium salt 0.1g/100ml are added wherein successively, and shady place stirred 4 minutes gently, and shady place left standstill 60 minutes; Get high stable, anticorrosive peroxyacetic acid disinfectant.Peroxyacetic acid disinfectant quality index after production is finished is: not stratified, the no crystallization of outward appearance, free from admixture; Color and luster is a colourless transparent liquid; Can store 6 months in the dark environment.
Embodiment two:
Commercial common peroxyacetic acid disinfectant water is diluted to 0.3g/100ml by weight percentage, and shady place left standstill 8 minutes; Sodium molybdate 0.01g/100ml and sodium ethylene diamine tetracetate 0.07g/100ml adding wherein are configured to homogeneous solution, and shady place leaves standstill 5 minutes, and is stand-by; Sodium citrate 0.15g/100ml, doped quaternary ammonium salt 0.14g/100ml are added wherein successively, and shady place stirred 4 minutes gently, and shady place left standstill 60 minutes; Get high stable, anticorrosive peroxyacetic acid disinfectant.Peroxyacetic acid disinfectant quality index after production is finished is: not stratified, the no crystallization of outward appearance, free from admixture; Color and luster is a colourless transparent liquid; Can store 6 months in the dark environment.
Embodiment three:
Commercial common peroxyacetic acid disinfectant water is diluted to 0.5g/100ml by weight percentage, and shady place left standstill 8 minutes; Sodium molybdate 0.02g/100ml and sodium ethylene diamine tetracetate 0.1g/100ml adding wherein are configured to homogeneous solution, and shady place leaves standstill 5 minutes, and is stand-by; Sodium citrate 0.2g/100ml, doped quaternary ammonium salt 0.2g/100ml are added wherein successively, and shady place stirred 4 minutes gently, and shady place left standstill 60 minutes; Get high stable, anticorrosive peroxyacetic acid disinfectant.Peroxyacetic acid disinfectant quality index after production is finished is: not stratified, the no crystallization of outward appearance, free from admixture; Color and luster is a colourless transparent liquid; Can store 6 months in the dark environment.
Application shows:
Adding ingredient has obviously improved the stability and the corrosion inhibition of Peracetic acid, adding ingredient to common iron, 4 hours inhibition of fine copper reach 98% respectively, more than 97%; There is not corrosion to aluminium base.Adding ingredient can not weaken peroxyacetic acid disinfectant to bacterium and the viral killing action that has rapidly and efficiently simultaneously.This kind of disinfectant uses the back contamination-free to leave over, and fine with environment compatibility, corrosivity is very low, and is safe in utilization, convenient.Can be widely used in the daily sterilizing of public places such as school, hospital, factories and miness, office, army; The environment sterilizing that also can be used for popular phase of special disease such as SARS (SARS), H1N1 and other various communicable diseases.

Claims (1)

1. a novel environment friendly and erosion-resisting peroxyacetic acid disinfectant, it is characterized in that described peroxyacetic acid disinfectant comprises following components in weight percentage: peracetic acid soln 0.1-0.5g/100ml, stabilizing agent sodium ethylene diamine tetracetate 0.05-0.1g/100ml, surfactant sodium citrate 0.1-0.2g/100ml, quaternary ammonium salt 0.1-0.2g/100ml, sodium molybdate 0.005-0.02g/100ml, surplus are water.
CN2010101505274A 2010-04-20 2010-04-20 Novel environmentally-friendly corrosion-resistance peracetic acid disinfectant Expired - Fee Related CN101810171B (en)

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CN101810171B CN101810171B (en) 2012-11-07

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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102090393A (en) * 2010-12-29 2011-06-15 广东环凯微生物科技有限公司 Stable peroxyacetic acid disinfectant
CN102415380A (en) * 2011-10-18 2012-04-18 中国人民解放军疾病预防控制所 Low-corrosion peracetic acid solid generating agent as well as preparation method and application thereof
CN102488705A (en) * 2011-12-08 2012-06-13 施耐克江苏生物制药有限公司 Skin mucous membrane disinfectant for killing virus
CN102511478A (en) * 2011-11-01 2012-06-27 苏州晶瑞化学有限公司 Stable peroxyacetic acid solution
CN102613179A (en) * 2012-03-12 2012-08-01 河北科技大学 Sterilizing agent for preventing and curing diseases of vegetables and fruits and preparation method thereof
CN102696599A (en) * 2012-06-05 2012-10-03 上海利康消毒高科技有限公司 Concentrated compound peroxyacetic acid and quaternary ammonium salt disinfection solution
CN103651351A (en) * 2013-12-09 2014-03-26 山东华亚环保科技有限公司 Sterilizing algicide for circulating cooling water
WO2015103955A1 (en) * 2014-01-09 2015-07-16 南通思锐生物科技有限公司 Disinfecting detergent
CN106857513A (en) * 2017-01-11 2017-06-20 北京长江脉医药科技有限责任公司 A kind of unitary Peracetic acid solid particle disinfectant
CN111436434A (en) * 2020-05-20 2020-07-24 成都百士洁生物科技有限公司 Green environment-friendly peroxyacetic acid disinfectant as well as preparation method and application thereof
CN112913840A (en) * 2021-01-06 2021-06-08 海韵一剑大卫生科技有限公司 Ultralow-temperature peracetic acid disinfectant and preparation method thereof

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
《J Appl Electrochem》 20091231 Qing Qu, et al. Effect of sodium molybdate on the corrosion behavior of cold rolled steel in peracetic acid solution 569-576 1 第39卷, *
《医学动物防制》 20080930 谭伟龙等 过氧乙酸杀菌剂研究进展 641-643 1 第24卷, 第9期 *

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102090393B (en) * 2010-12-29 2013-06-12 广东环凯微生物科技有限公司 Stable peroxyacetic acid disinfectant
CN102090393A (en) * 2010-12-29 2011-06-15 广东环凯微生物科技有限公司 Stable peroxyacetic acid disinfectant
CN102415380B (en) * 2011-10-18 2014-05-07 中国人民解放军疾病预防控制所 Low-corrosion peracetic acid solid generating agent as well as preparation method and application thereof
CN102415380A (en) * 2011-10-18 2012-04-18 中国人民解放军疾病预防控制所 Low-corrosion peracetic acid solid generating agent as well as preparation method and application thereof
CN102511478A (en) * 2011-11-01 2012-06-27 苏州晶瑞化学有限公司 Stable peroxyacetic acid solution
CN102511478B (en) * 2011-11-01 2013-01-09 苏州晶瑞化学有限公司 Stable peroxyacetic acid solution, preparation method thereof and stabilizer for preparation
CN102488705A (en) * 2011-12-08 2012-06-13 施耐克江苏生物制药有限公司 Skin mucous membrane disinfectant for killing virus
CN102613179A (en) * 2012-03-12 2012-08-01 河北科技大学 Sterilizing agent for preventing and curing diseases of vegetables and fruits and preparation method thereof
CN102696599A (en) * 2012-06-05 2012-10-03 上海利康消毒高科技有限公司 Concentrated compound peroxyacetic acid and quaternary ammonium salt disinfection solution
CN103651351A (en) * 2013-12-09 2014-03-26 山东华亚环保科技有限公司 Sterilizing algicide for circulating cooling water
WO2015103955A1 (en) * 2014-01-09 2015-07-16 南通思锐生物科技有限公司 Disinfecting detergent
JP2016532634A (en) * 2014-01-09 2016-10-20 南通思▲鋭▼生物科技有限公司 Formulation for sterilization cleaning
US10226048B2 (en) 2014-01-09 2019-03-12 Nantong Sirui Bio-Technology Co., Ltd Disinfecting detergent
CN106857513A (en) * 2017-01-11 2017-06-20 北京长江脉医药科技有限责任公司 A kind of unitary Peracetic acid solid particle disinfectant
CN111436434A (en) * 2020-05-20 2020-07-24 成都百士洁生物科技有限公司 Green environment-friendly peroxyacetic acid disinfectant as well as preparation method and application thereof
CN112913840A (en) * 2021-01-06 2021-06-08 海韵一剑大卫生科技有限公司 Ultralow-temperature peracetic acid disinfectant and preparation method thereof

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