CN106831213A - Fertilizer without pesticide residue and with excellent disease-resistant effect - Google Patents

Fertilizer without pesticide residue and with excellent disease-resistant effect Download PDF

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Publication number
CN106831213A
CN106831213A CN201710259371.5A CN201710259371A CN106831213A CN 106831213 A CN106831213 A CN 106831213A CN 201710259371 A CN201710259371 A CN 201710259371A CN 106831213 A CN106831213 A CN 106831213A
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China
Prior art keywords
fertilizer
trichoderma
organic matter
tea
fermentation
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CN201710259371.5A
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CN106831213B (en
Inventor
杨文�
潘科
吕军
陈娟
陈瑶
周玉锋
张小琴
刘忠英
孟泽洪
邹兴
周国兰
雷志伟
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Guizhou Wulian Fertilizer Co ltd
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Guizhou tea research institute
Guizhou Mingxiang Tea Technology Development Co ltd
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    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05B—PHOSPHATIC FERTILISERS
    • C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F17/00—Preparation of fertilisers characterised by biological or biochemical treatment steps, e.g. composting or fermentation
    • C05F17/50—Treatments combining two or more different biological or biochemical treatments, e.g. anaerobic and aerobic treatment or vermicomposting and aerobic treatment
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/40—Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Molecular Biology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Biochemistry (AREA)
  • Biotechnology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Fertilizers (AREA)

Abstract

The invention provides a fertilizer which has no pesticide residue and excellent disease resistance effect. Controlling fermentation temperature, oxygen-containing environment and fermentation time between trichoderma microorganisms and bacillus subtilis and organic matters without chemical pesticides and antibiotic residues, mixing the trichoderma fermentation product with polyglutamic acid for reaction, mixing the bacillus subtilis fermentation product with chitosan oligosaccharide for reaction, and mixing with a chemical fertilizer for reaction to form a complex, wherein the complex is prepared by mixing the complex with the chemical fertilizerThe medium nutrient elements are converted into the complex. Then pass through N, P in the fertilizer2O5、K2O is controlled, so that the yield and the content of nutrient components of the tea tree are increased while the normal growth of the tea tree is ensured; meanwhile, the nitrogen, phosphorus and potassium contents are reasonably configured and converted into a complex, so that the demand of each element on each production period of the tea trees can be ensured, and the disease resistance of the tea trees is improved; the incidence of tea leaf spot, tea cake disease, anthracnose, root rot and the like is reduced, and negative factors such as tea pesticide residue, harmful microorganisms, toxins and the like are effectively avoided.

Description

The excellent fertilizer of a kind of non agricultural chemical residuum, disease resisting effect
Technical field
The present invention relates to fertilizer, more particularly to the excellent fertilizer of a kind of non agricultural chemical residuum, disease resisting effect.
Background technology
Tea is the natural drink of the tool multiple nutritional components and health protection function of being only second to water in the world.China is world tea tree Plantation, product tea and tea export big country, whole nation tea place area and tea yield rank first in the world at present.In people's life water Flat continuous improvement and health perception constantly strengthen, developed country proposes and set up safety food production system and strongly limiting tealeaves has Under the increasingly advanced historical background of evil content of material, detection technique, quality and safety of tea concerns the lasting health hair of tea industry Exhibition, therefore China's quality and safety of tea standard is also strict compared with other crops.Influenceing the factor of quality and safety of tea mainly includes product Pole factor and negative factor, wherein active factor are Tea Polyphenols, theaflavin, amino acid equal size；Negative factor be residues of pesticides, Harmful microorganism, toxin, heavy metal, non-tea foreign matter and dust pollution.The main source of its Pesticide Residues is sprayed in production Agricultural chemicals and enter to move tea place with the source of organic matter fertilizer containing residues of pesticides.
It is well known that tea tree scale establishing in large scale, necessarily causes the hair of tea tree root disease and ground position disease Life is caused harm, and wherein root disease occurs more with the microbial root rot of reaping hook especially.In addition；Mineral matter element supply imbalance also may be used Physiologica disease is caused to do harm to, such as nitrogen quantity high can cause or aggravate the banded sclerotial blight of wheat, sugarcane red spot, false smut etc.；Phosphorus is There is selective inhibitory action by the Chinese medicine part of plant structure in most diseases, and low-phosphorous amount can deteriorate wheat Root rot etc.；Potassium has raising photosynthesis, thickens cell membrane, stimulates the effects such as generation lignin, cellulose, and potassium deficiency can be aggravated The harm of bacterium, fungi, virus etc.；Zinc-deficiency can cause paddy rice contracting seedling diseases；Boron deficiency can cause heartrot.Mineral matter element is supplied simultaneously Should lack of proper care can also cause the change of plant nutrient substance.The mineral matter element of plant is mainly derived from soil and artificially applying fertilizer, its Middle artificially applying fertilizer is artificial controllable factor；Artificially applying fertilizer can be chemical fertilizer and organic fertilizer, and chemical fertilizer can cause soil hardening, fertilizer efficiency profit The problems such as with rate, fertilizer efficiency time, the fertilizer efficiency of organic fertilizer is lasting, but its short-term fertilizer efficiency is poor, and large-scale cultivation in recent years, its There is heavy metal and antibiotic risk of exceeding criterion in the organic fertilizer of animal wastes, certain pollution can be caused to long-term cropping, while chemical fertilizer The long-term uncontrollable problem in the sources such as its nitrogen, phosphorus, potassium is there is also with organic fertilizer, tea tree is such as calculated before fertilising to nitrogen, phosphorus, potassium The demand in source, the content of strict control each element in fertilising, after fertilising, the burst size of each dvielement and release time are not It is controllable, can cause tea tree produce the yield and tealeaves of tealeaves contained by nutriment cannot ensure that and it is white also to increase tea tree tea Star disease, gall of tea, anthracnose, the incidence of disease of root rot, and then increase the amount of application of agricultural chemicals；Although it ensure that yield, Also result in the decline of tea leaf quality.
The content of the invention
The present invention is intended to provide the excellent fertilizer of a kind of non agricultural chemical residuum, disease resisting effect, nitrogen that it can be in conditioned fertilizer product, The burst size of phosphorus, potassium element；Reduce the incidence of disease of tea tree tea white star, gall of tea, anthracnose, root rot etc., it is to avoid agricultural chemicals is residual Stay；Tea yield is improved, increases the content of tealeaves nutriment.
Concrete scheme is as follows：
The excellent fertilizer of a kind of non agricultural chemical residuum, disease resisting effect, it is included
Microorganism：Trichoderma microorganism belonging to genus and Bacillus subtillis, and
Polyglutamic acid and chitosan oligosaccharide, and
The combination of chemical fertilizer and organic fertilizer, and
Organic fertilizer is formed by organic matter material fermentation, and further, organic matter material selection is free of chemical pesticide and antibiosis The raw material of element residual；And；
The fermentation is：Organic matter material is divided into two parts, and a organic matter material addition trichoderma microorganism belonging to genus is fermented, Obtain trichoderma fermentate；Another organic matter material addition Bacillus subtillis is fermented；Obtain Ko subtilis fermentate； And
Polyglutamic acid is first mixed and stacks 1~10h by the fertilizer in manufacturing process with the stirring of trichoderma fermentate, Obtain material A；First chitosan oligosaccharide is mixed and stack 1~10h with the stirring of Ko subtilis fermentate, material B is obtained；Then again by thing Material A, material B mix with chemical fertilizer and stack 1~100h, obtain the fertilizer.
Wherein described trichoderma microorganism is green trichoderma, Trichoderma harzianum, Trichoderma atroviride and combinations thereof.
The condition that wherein organic matter material addition trichoderma microorganism belonging to genus is fermented is：Start 1~2 day, 20~25 DEG C, aerobic fermentation, then anaerobic fermentation 20~30 days at 40~45 DEG C.
Wherein the organic matter material addition condition fermented of Bacillus subtillis is：The aerobic fermentation 21 at 20~25 DEG C ~32 days.
Organic matter >=15 weight %, 15 weight % in wherein described fertilizer >=N >=11 weight %, 7 weight % >=P2O5 >=5 weight %, 6 weight % >=K2O >=4 weight %.
Wherein described organic matter material is selected from the material being made up of the following：Without chemical pesticide and antibiotic residue Edible fungi residues, vinasse and combinations thereof.
It is further included：
Selected from the filler being made up of the following：Diatomite, kaolin and combinations thereof.
Wherein described chemical fertilizer includes nitrogen source, phosphorus source, potassium resource, zinc source, manganese source and boron source, wherein
The nitrogen source is selected from MAP, ammonium sulfate, urea, ammonium carbonate, ammonium nitrate and combinations thereof；
Phosphorus source is selected from MAP, potassium dihydrogen phosphate, sodium phosphate and combinations thereof；
The potassium resource is selected from potassium phosphate, potassium sulfate and combinations thereof；
The zinc source is zinc sulfate；
The manganese source is manganese sulfate；
The boron source is boric acid.
The component and its percentage composition of its fertilizer described further be：
Further, in order to ensure the dauer effect power of fertilizer, the bacterium in its trichoderma microorganism belonging to genus or Bacillus subtillis It is 10 to plant content7More than cfu/g.
The fertilizer that the present invention is provided is exclusively used in tea tree planting.
The principle and effect of fertilizer of the present invention be：By the fermentation temperature for controlling trichoderma microorganism belonging to genus and Bacillus subtillis Then degree, aerobic environment, fermentation time mix anti-trichoderma tunning with polyglutamic acid come the product for controlling to ferment Should, then Ko subtilis tunning and chitosan oligosaccharide hybrid reaction form complex compound with chemical fertilizer hybrid reaction again, wherein nitrogen, phosphorus, Potassium element is transformed into complex compound, then by N, the P in the fertilizer2O5、K2O is controlled, and is ensureing the same of tea tree normal growth When, increase the nutrient composition content such as its yield and Tea Polyphenols, theaflavin, amino acid, while N, P of reasonable disposition2O5、K2O content And its complex compound is translated into, and demand of each element to each production period of tea tree is ensure that, increase from mineral matter element The Disease and insect resistance of tea tree, reduces the incidence of disease of tea white star, gall of tea, anthracnose, root rot etc., is prevented effectively from tealeaves agricultural chemicals The negative factors such as residual, harmful microorganism, toxin.
Meanwhile, organic matter material of the present invention selection without agricultural chemicals, antibiotic residue makes organic fertilizer, makes the fertilizer being made Non agricultural chemical residuum, and the trichoderma microorganism belonging to genus that selects and Bacillus subtillis have certain journey to agricultural chemicals, the antibiotic etc. applied The capacity of decomposition of degree,
Specific embodiment
Be described further below technical scheme, but claimed scope be not limited to it is described.
A kind of non agricultural chemical residuum, the excellent fertilizer of disease resisting effect that the present invention is provided, its include microorganism, polyglutamic acid, The combination of chitosan oligosaccharide, chemical fertilizer and organic fertilizer, it is therein：
Microorganism is trichoderma microorganism belonging to genus and Bacillus subtillis, and trichoderma microorganism belonging to genus therein may be selected green trichoderma, breathe out Thatch trichoderma, Trichoderma atroviride and combinations thereof；In order to ensure the dauer effect power of fertilizer, its trichoderma microorganism belonging to genus or Bacillus subtillis In strain content be 107More than cfu/g；
Chemical fertilizer includes nitrogen source, phosphorus source, potassium resource, zinc source, manganese source and boron source, and wherein nitrogen source is selected from MAP, ammonium sulfate, urine Element, ammonium carbonate, ammonium nitrate and combinations thereof；Phosphorus source is selected from MAP, potassium dihydrogen phosphate, sodium phosphate and combinations thereof；Potassium resource Selected from potassium chloride, potassium phosphate, potassium sulfate and combinations thereof；Zinc source is zinc sulfate；Manganese source is manganese sulfate；Boron source is boric acid；
Organic fertilizer is that organic matter material fermentation is formed, and wherein organic matter material may be selected edible fungi residues, vinasse and combinations thereof.
In preparation method, present invention selection is；
(1) ferment：Organic matter material is divided into two parts, a organic matter material addition trichoderma microorganism belonging to genus is fermented, Obtain trichoderma fermentate；Another organic matter material addition Bacillus subtillis is fermented；Obtain Ko subtilis fermentate；
(2) just mix：First polyglutamic acid is mixed and stack 1~10h with the stirring of trichoderma fermentate, material A is obtained；First will Chitosan oligosaccharide mixes and stacks 1~10h with the stirring of Ko subtilis fermentate, obtains material B；
(3) fertilizer makes：Material A, material B are mixed with chemical fertilizer and 1~100h is stacked, the fertilizer is obtained.
It is further, and the condition that organic matter material addition trichoderma microorganism belonging to genus is fermented is：Beginning 1~2 day, 20~ 25 DEG C, aerobic fermentation, then anaerobic fermentation 20~30 days at 40~45 DEG C.Addition Bacillus subtillis is carried out organic matter material The condition of fermentation is：Aerobic fermentation 21~32 days at 20~25 DEG C.
In above-mentioned making fertilizer have organic matter >=15 weight %, 15 weight % >=N >=11 weight %, 7 weight % >= P2O5 >=5 weight %, 6 weight % >=K2O >=4 weight %.
Meanwhile, further, the fertilizer is also added with following filler：Diatomite, kaolin and combinations thereof.
Inventor is described below in the specific embodiment for making：
Embodiment 1
The present embodiment provides a kind of non agricultural chemical residuum, disease resisting effect excellent fertilizer, its raw material composition such as following table：
Table 1:The proportioning of fertilizer production raw material components
Its manufacturing process is：
(1) ferment：Organic matter material is divided into two parts of equivalent, a organic matter material addition trichoderma microorganism belonging to genus is sent out Ferment, the condition of fermentation is：Beginning 1 day, 20 DEG C, aerobic fermentation, then anaerobic fermentation 20~30 days at 40 DEG C, obtain trichoderma Fermentate；Another organic matter material addition Bacillus subtillis is fermented；The condition of fermentation is：The aerobic fermentation at 20 DEG C 21 days, obtain Ko subtilis fermentate；
(2) just mix：First polyglutamic acid is mixed and stack 1h with the stirring of trichoderma fermentate, material A is obtained；It is first that shell is few Sugar mixes and stacks 1h with the stirring of Ko subtilis fermentate, obtains material B；
(3) fertilizer makes：Material A, material B are mixed with chemical fertilizer and 1h is stacked, the fertilizer is obtained.
Embodiment 2
The present embodiment provides a kind of non agricultural chemical residuum, disease resisting effect excellent fertilizer, its raw material composition such as following table：
Table 2:The proportioning of fertilizer production raw material components
Its manufacturing process is：
(1) ferment：Organic matter material is divided into two parts of equivalent, a organic matter material addition trichoderma microorganism belonging to genus is sent out Ferment, the condition of fermentation is：Beginning 2 days, 25 DEG C, aerobic fermentation, then anaerobic fermentation 30 days at 45 DEG C, obtain trichoderma fermentation Thing；Another organic matter material addition Bacillus subtillis is fermented；The condition of fermentation is：The aerobic fermentation 32 at 25 DEG C My god, obtain Ko subtilis fermentate；
(2) just mix：First polyglutamic acid is mixed and stack 10h with the stirring of trichoderma fermentate, material A is obtained；First by shell Oligosaccharides mixes and stacks 10h with the stirring of Ko subtilis fermentate, obtains material B；
(3) fertilizer makes：Material A, material B are mixed with chemical fertilizer and 100h is stacked, the fertilizer is obtained.
Embodiment 3
The present embodiment provides a kind of non agricultural chemical residuum, disease resisting effect excellent fertilizer, its raw material composition such as following table：
The proportioning of the fertilizer production raw material components of table 3
Its manufacturing process is：
(1) ferment：Organic matter material is divided into two parts of equivalent, a organic matter material addition trichoderma microorganism belonging to genus is sent out Ferment, the condition of fermentation is：Beginning 1.5 days, 23 DEG C, aerobic fermentation, then anaerobic fermentation 25 days at 43 DEG C, obtain trichoderma hair Ferment thing；Another organic matter material addition Bacillus subtillis is fermented；The condition of fermentation is：The aerobic fermentation 26 at 23 DEG C My god, obtain Ko subtilis fermentate；
(2) just mix：First polyglutamic acid is mixed and stack 5h with the stirring of trichoderma fermentate, material A is obtained；It is first that shell is few Sugar mixes and stacks 5h with the stirring of Ko subtilis fermentate, obtains material B；
(3) fertilizer makes：Material A, material B are mixed with chemical fertilizer and 15h is stacked, the fertilizer is obtained.
Embodiment 4
The present embodiment provides a kind of non agricultural chemical residuum, disease resisting effect excellent fertilizer, its raw material composition such as following table：
The proportioning of the fertilizer production raw material components of table 4
Its manufacturing process is：
(1) ferment：Organic matter material is divided into two parts of equivalent, a organic matter material addition trichoderma microorganism belonging to genus is sent out Ferment, the condition of fermentation is：Beginning 1.5 days, 23 DEG C, aerobic fermentation, then anaerobic fermentation 25 days at 43 DEG C, obtain trichoderma hair Ferment thing；Another organic matter material addition Bacillus subtillis is fermented；The condition of fermentation is：The aerobic fermentation 26 at 23 DEG C My god, obtain Ko subtilis fermentate；
(2) just mix：First polyglutamic acid is mixed and stack 5h with the stirring of trichoderma fermentate, material A is obtained；It is first that shell is few Sugar mixes and stacks 5h with the stirring of Ko subtilis fermentate, obtains material B；
(3) fertilizer makes：Material A, material B are mixed with chemical fertilizer and 15h is stacked, the fertilizer is obtained.
Embodiment 5
The present embodiment provides a kind of non agricultural chemical residuum, disease resisting effect excellent fertilizer, its raw material composition such as following table：
The proportioning of the fertilizer production raw material components of table 5
Its manufacturing process is：
(1) ferment：Organic matter material is divided into two parts of equivalent, a organic matter material addition trichoderma microorganism belonging to genus is sent out Ferment, the condition of fermentation is：Beginning 1.5 days, 23 DEG C, aerobic fermentation, then anaerobic fermentation 25 days at 43 DEG C, obtain trichoderma hair Ferment thing；Another organic matter material addition Bacillus subtillis is fermented；The condition of fermentation is：The aerobic fermentation 26 at 23 DEG C My god, obtain Ko subtilis fermentate；
(2) just mix：First polyglutamic acid is mixed and stack 5h with the stirring of trichoderma fermentate, material A is obtained；It is first that shell is few Sugar mixes and stacks 5h with the stirring of Ko subtilis fermentate, obtains material B；
(3) fertilizer makes：Material A, material B are mixed with chemical fertilizer and 15h is stacked, the fertilizer is obtained.
It is worthy of note that, the non-limit technical scheme of above-described embodiment, the scope of protection of the invention is not limited In above-described embodiment.
In order to prove technique effect of the invention, present invention also offers test example as follows：
Test group：S1~S3：Embodiment one, embodiment three, the fertilizer of embodiment five is respectively adopted.
Control group：
D1:Using simple chemical fertilizer, wherein N content is 12 weight %, P2O5Content is 6 weight %, K2O content is 4.5 weights Amount %, zinc sulfate, manganese sulfate, boric acid content are with embodiment three.
D2：Using the combination of chemical fertilizer and organic fertilizer：Wherein the content of organic matter is 20 weight %, P2O5Content is 6 weight %, K2O content is 4.5 weight %, and zinc sulfate, manganese sulfate, boric acid content are with embodiment three；Organic matter uses bacteria residue；
D3:Using the combination of chemical fertilizer, organic fertilizer and strain：Wherein the content of organic matter is 20 weight %, P2O5Content is 6 weights Amount %, K2O content is 4.5 weight %, and, with embodiment three, the selection of strain and content are with real for zinc sulfate, manganese sulfate, boric acid content Apply example three；Organic matter uses bacteria residue；
D4:Using the combination of chemical fertilizer, organic fertilizer, polyglutamic acid and chitosan oligosaccharide：Wherein the content of organic matter be 20 weight %, P2O5Content is 6 weight %, K2O content is 4.5 weight %, and zinc sulfate, manganese sulfate, boric acid, polyglutamic acid and chitosan oligosaccharide content are same Embodiment three, organic matter uses bacteria residue；
D5:Using the combination of chemical fertilizer, organic fertilizer, microorganism, polyglutamic acid and chitosan oligosaccharide：The same embodiment of raw material usage amount Three, the places different from embodiment three are：By chemical fertilizer, organic fertilizer, microorganism, polyglutamic acid and chitosan oligosaccharide in preparation method Directly mixing, granulation drying are formed.
Each experimental group or control group are tested to 2 tea places respectively, are calculated respective yield, the incidence of disease and are made The nutrition content of finished tea, wherein finished tea make according to the manufacture craft of green tea.
(1) yield
Table 6 tests yield result
As shown in Table 6, S1, S2, S3 the spring, the summer, the yield increased group in autumn difference it is high by 16.7%, 11.8%, More than 10.2%.
(2) a situation arises for disease
Table 7：A situation arises for experiment disease
As can be seen from Table 7, S1, S2, S3 tea white star, gall of tea, anthracnose disease index than control group Low by more than 20% respectively, it shows, using fertilizer of the present invention after, can substantially mitigate the generation of disease for tea plant.
(3) quality determination result
Wherein determination of moisture is according to GB/T 8304《Tea determination of moisture》In 103 DEG C of constant weights hair determine；Water extraction according to GB/T 8305《Tea determination of extractives》；Tea Polyphenols, theaflavin, amino acid are measured according to GB/T 8302-2002, survey It is fixed, table specific as follows：
The quality determination result of table 7 (average value, %)
As can be seen from Table 8, the fertilizer plantation tea place that the present invention is provided, it is obtained in finished product green tea, and wherein water logging goes out Thing is higher than control group by more than 6.2%, and amino acid alignment is high by more than 0.8% according to group, and Tea Polyphenols is higher than control group by 4.2%, theaflavin It is higher than control group by more than 0.34% above.
Compared with D3, D4, D5 of control group by test group simultaneously, test group refers in yield, the reduction incidence of disease, morbidity Number, and the feature that had clear improvement on water extraction, Tea Polyphenols, theaflavin, amino acid content, illustrate the fertilizer of present invention offer The technique effect of simple each raw material technique effect superposition, its in raw material selection and unique manufacture craft, each material Between there occurs biochemical reaction, unexpected technique effect can be realized.
In order to further prove technique effect of the invention, present invention also offers Detecting Pesticide as follows experiment Example
Test group：S1：Using the fertilizer of real embodiment three.
Control group：D1：Using commercially available inorganic total nutrient content >=20% (N >=11%, P2O5>=5%, K2O >=4%), have The tea tree organic and inorganic compound fertilizer of machine matter content >=20%.
Test group fertilizer and control group fertilizer, trial zone and check plot spring, summer, the tealeaves dry sample of Qiu Sanji, send correlation EU criteria detection residues of pesticides are pressed by testing agency.
The Detecting Pesticide result of table 9.
As shown in Table 9, tea tree special complex fertilizer non agricultural chemical residuum of the present invention detection, and after applying this fertilizer, spring, summer, autumn Non agricultural chemical residuum detection in three season tealeaves.But control fertilizer has detected 4 kinds of residues of pesticides, and also contain disabling composition；Apply After with control fertilizer, corresponding residues of pesticides are detected in spring, summer, three season of autumn tealeaves.Result shows, special using tea tree of the present invention After composite fertilizer applies, safety guarantee can be improved for Pesticide Residues in Tea.

Claims (10)

1. the excellent fertilizer of a kind of non agricultural chemical residuum, disease resisting effect, it is included
Microorganism：Trichoderma microorganism belonging to genus and Bacillus subtillis, and
Polyglutamic acid and chitosan oligosaccharide, and
The combination of chemical fertilizer and organic fertilizer, and
Organic fertilizer is formed by organic matter material fermentation.
2. the excellent fertilizer of non agricultural chemical residuum as claimed in claim 1, disease resisting effect, wherein the trichoderma microorganism is green Trichoderma, Trichoderma harzianum, Trichoderma atroviride and combinations thereof.
3. the excellent fertilizer of non agricultural chemical residuum as claimed in claim 1, disease resisting effect, wherein the fermentation is：Organic matter is former Material is divided into two parts, and a organic matter material addition trichoderma microorganism belonging to genus is fermented, and obtains trichoderma fermentate；Another is organic Matter raw material addition Bacillus subtillis is fermented；Obtain Ko subtilis fermentate；And
Polyglutamic acid is first mixed and stacks 1~10h by the fertilizer in manufacturing process with the stirring of trichoderma fermentate, is obtained Material A；First chitosan oligosaccharide is mixed and stack 1~10h with the stirring of Ko subtilis fermentate, material B is obtained；Then again by material A, Material B mixes with chemical fertilizer and stacks 1~100h, obtains the fertilizer.
4. the excellent fertilizer of non agricultural chemical residuum as claimed in claim 3, disease resisting effect, wherein organic matter material addition wood The condition that mould microorganism belonging to genus is fermented is：Start 1~2 day, 20~25 DEG C, aerobic fermentation, the then anaerobic at 40~45 DEG C Fermentation 20~30 days；Wherein the organic matter material addition condition fermented of Bacillus subtillis is：It is aerobic at 20~25 DEG C Fermentation 21~32 days.
5. the excellent fertilizer of non agricultural chemical residuum as described in claims 1 to 3 any one, disease resisting effect, wherein the fertilizer In organic matter >=15 weight %, 15 weight % >=N >=11 weight %, 7 weight % >=P2O5>=5 weight %, 6 weight % >=K2O >=4 weight Amount %.
6. the excellent fertilizer of non agricultural chemical residuum as claimed in claim 1, disease resisting effect, wherein the organic matter material be selected from by The material of the following composition：Edible fungi residues, vinasse without chemical pesticide and antibiotic residue and combinations thereof.
7. the excellent fertilizer of non agricultural chemical residuum as claimed in claim 1, disease resisting effect, it is further included：
Selected from the filler being made up of the following：Diatomite, kaolin and combinations thereof.
8. the excellent fertilizer of non agricultural chemical residuum as claimed in claim 1, disease resisting effect, wherein the chemical fertilizer includes nitrogen source, phosphorus Source, potassium resource, zinc source, manganese source and boron source, wherein
The nitrogen source is selected from MAP, ammonium sulfate, urea, ammonium carbonate, ammonium nitrate and combinations thereof；
Phosphorus source is selected from MAP, potassium dihydrogen phosphate, sodium phosphate and combinations thereof；
The potassium resource is selected from potassium phosphate, potassium sulfate and combinations thereof；
The zinc source is zinc sulfate；
The manganese source is manganese sulfate；
The boron source is boric acid.
9. the excellent fertilizer of non agricultural chemical residuum as described in claim 1 or 8, disease resisting effect, the group of its fertilizer described further Divide and its percentage composition is：
Ingredient names Content（Weight %） Organic matter material 25-45 MAP 20-25 Ammonium sulfate 18-30 Potassium sulfate 9-15 Urea 5-10 Zinc sulfate 0.5-1 Manganese sulfate 1-3 Boric acid 1-3 Polyglutamic acid 0.01-0.03 Trichoderma microorganism belonging to genus 0.005-0.008 Bacillus subtillis 0.005-0.008 Chitosan oligosaccharide 0.005-0.008 Filler 2-7
。
10. the excellent fertilizer of a kind of non agricultural chemical residuum as described in claim 1~9, disease resisting effect, wherein the fertilizer is used for Tea tree planting.
CN201710259371.5A 2017-04-20 2017-04-20 Fertilizer without pesticide residue and with excellent disease-resistant effect Active CN106831213B (en)

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CN201710259371.5A CN106831213B (en) 2017-04-20 2017-04-20 Fertilizer without pesticide residue and with excellent disease-resistant effect

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Application Number Priority Date Filing Date Title
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CN106831213A true CN106831213A (en) 2017-06-13
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CN107857635A (en) * 2017-11-12 2018-03-30 长沙秋点兵信息科技有限公司 Nitrogen-phosphorus-potassium compound fertilizer and preparation method thereof
CN108530192A (en) * 2018-06-21 2018-09-14 安徽省神农农业技术开发有限公司 A kind of special medicated fertilizer and preparation method thereof of high effect nontoxic prevention rice green smut
CN108863585A (en) * 2018-08-13 2018-11-23 湖南泰谷生态工程有限公司 A kind of organic fertilizer and preparation method thereof for preventing and treating plant root rot
CN108863478A (en) * 2018-07-13 2018-11-23 杨丽 Organic fertilizer and preparation method thereof
CN108976032A (en) * 2018-08-31 2018-12-11 镇江鑫源达园艺科技有限公司 A kind of broccoli antibiotic fertilizer and preparation method thereof
CN109169129A (en) * 2018-09-12 2019-01-11 吉林冠州生物科技有限公司 Prolong the cultural method that the red oil of Region In Yanbian phoenix uses tree peony
CN110679433A (en) * 2019-11-11 2020-01-14 安庆师范大学 Landscape plant cultivation medium and preparation method thereof
CN111838190A (en) * 2019-04-24 2020-10-30 山东大学苏州研究院 Biocontrol microbial inoculum for preventing and treating stem base rot and gummosis as well as preparation method and application thereof
CN112759460A (en) * 2021-01-28 2021-05-07 西安众民生物化工有限公司 Sterilization regulation synergistic liquid fertilizer containing polyglutamic acid and amino-oligosaccharin
CN115281218A (en) * 2022-06-09 2022-11-04 贵州省生物技术研究所(贵州省生物技术重点实验室、贵州省马铃薯研究所、贵州省食品加工研究所) Application of trichoderma fermentation liquor extract

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CN104761373A (en) * 2015-03-31 2015-07-08 安徽中农化工国际贸易有限公司 Organic bio-bacterial manure and preparation method thereof
CN104892259A (en) * 2015-06-18 2015-09-09 张家港市五湖新材料技术开发有限公司 Special organic fertilizer for flowers
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CN106478207A (en) * 2015-08-24 2017-03-08 安徽亚环生物科技有限公司 A kind of active humic acid fertilizer based on fowl and animal excrement preparation
CN106478279A (en) * 2015-08-24 2017-03-08 安徽亚环生物科技有限公司 A kind of water solublity organic and inorganic active humic acid fertilizer and preparation method thereof

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CN104761373A (en) * 2015-03-31 2015-07-08 安徽中农化工国际贸易有限公司 Organic bio-bacterial manure and preparation method thereof
CN104892259A (en) * 2015-06-18 2015-09-09 张家港市五湖新材料技术开发有限公司 Special organic fertilizer for flowers
CN106478207A (en) * 2015-08-24 2017-03-08 安徽亚环生物科技有限公司 A kind of active humic acid fertilizer based on fowl and animal excrement preparation
CN106478279A (en) * 2015-08-24 2017-03-08 安徽亚环生物科技有限公司 A kind of water solublity organic and inorganic active humic acid fertilizer and preparation method thereof
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Publication number Priority date Publication date Assignee Title
CN107857635A (en) * 2017-11-12 2018-03-30 长沙秋点兵信息科技有限公司 Nitrogen-phosphorus-potassium compound fertilizer and preparation method thereof
CN108530192A (en) * 2018-06-21 2018-09-14 安徽省神农农业技术开发有限公司 A kind of special medicated fertilizer and preparation method thereof of high effect nontoxic prevention rice green smut
CN108863478A (en) * 2018-07-13 2018-11-23 杨丽 Organic fertilizer and preparation method thereof
CN108863585A (en) * 2018-08-13 2018-11-23 湖南泰谷生态工程有限公司 A kind of organic fertilizer and preparation method thereof for preventing and treating plant root rot
CN108976032A (en) * 2018-08-31 2018-12-11 镇江鑫源达园艺科技有限公司 A kind of broccoli antibiotic fertilizer and preparation method thereof
CN109169129A (en) * 2018-09-12 2019-01-11 吉林冠州生物科技有限公司 Prolong the cultural method that the red oil of Region In Yanbian phoenix uses tree peony
CN111838190A (en) * 2019-04-24 2020-10-30 山东大学苏州研究院 Biocontrol microbial inoculum for preventing and treating stem base rot and gummosis as well as preparation method and application thereof
CN110679433A (en) * 2019-11-11 2020-01-14 安庆师范大学 Landscape plant cultivation medium and preparation method thereof
CN112759460A (en) * 2021-01-28 2021-05-07 西安众民生物化工有限公司 Sterilization regulation synergistic liquid fertilizer containing polyglutamic acid and amino-oligosaccharin
CN115281218A (en) * 2022-06-09 2022-11-04 贵州省生物技术研究所(贵州省生物技术重点实验室、贵州省马铃薯研究所、贵州省食品加工研究所) Application of trichoderma fermentation liquor extract
CN115281218B (en) * 2022-06-09 2023-09-26 贵州省生物技术研究所(贵州省生物技术重点实验室、贵州省马铃薯研究所、贵州省食品加工研究所) Application of trichoderma fermentation liquor extract

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Address after: 564100 Tiancheng Town, Meitan County, Zunyi City, Guizhou Province

Patentee after: Guizhou Wulian fertilizer Co.,Ltd.

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