CN106783576B - Secondary corrosion table-board process for high-voltage-resistance semiconductor discrete device chip - Google Patents

Secondary corrosion table-board process for high-voltage-resistance semiconductor discrete device chip Download PDF

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CN106783576B
CN106783576B CN201611183968.8A CN201611183968A CN106783576B CN 106783576 B CN106783576 B CN 106783576B CN 201611183968 A CN201611183968 A CN 201611183968A CN 106783576 B CN106783576 B CN 106783576B
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corrosion
silicon wafer
mesa
etching
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CN106783576A (en
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苏舟
徐敏丽
高广亮
刘帅
陈浩
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Jinzhou Liaojing Electronic Technology Co ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic System or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/30Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
    • H01L21/302Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to change their surface-physical characteristics or shape, e.g. etching, polishing, cutting
    • H01L21/306Chemical or electrical treatment, e.g. electrolytic etching
    • H01L21/30604Chemical etching
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic System or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/30Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
    • H01L21/302Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to change their surface-physical characteristics or shape, e.g. etching, polishing, cutting
    • H01L21/306Chemical or electrical treatment, e.g. electrolytic etching
    • H01L21/30604Chemical etching
    • H01L21/30608Anisotropic liquid etching

Abstract

A secondary mesa etching process for a high-voltage-resistance semiconductor discrete device chip comprises the following steps: carrying out primary corrosion on the surface of a silicon wafer with an oxide layer on the surface, wherein the primary corrosion depth is 75-85 mu m; carrying out secondary corrosion on the silicon wafer subjected to the primary corrosion V-shaped groove through a photoetching mask, wherein the secondary corrosion depth is 7-10 mu m, and the width of the secondary corrosion table top is larger than that of the primary corrosion table top; and after the two mesa etchings are finished, performing glass passivation. Through the secondary corrosion of the mesa, small-angle steps caused by different corrosion rates of silicon and silicon dioxide at the position close to the surface of the silicon wafer are removed, a physical buffer area is formed at the joint of the surface of the silicon wafer and the mesa of the V-shaped groove by the fused passivation process of filling glass powder in the groove, the contact area of the glass powder and the corrosion mesa is increased, the contact capacity is increased, the dielectric strength is improved, and the surface leakage is reduced, so that the excellent high-temperature and high-pressure performance and high reliability of the high-pressure-resistant semiconductor discrete device chip are ensured.

Description

Secondary corrosion table-board process for high-voltage-resistance semiconductor discrete device chip
Technical Field
The invention relates to a secondary mesa etching process for a high-voltage-resistance semiconductor discrete device chip.
The invention relates to a processing method of a semiconductor device, in particular to a secondary mesa etching process of a high-voltage-resistance semiconductor discrete device chip.
Background
A traditional mesa semiconductor discrete device chip adopts a one-step V-shaped groove etching process, and the etching depth is generally 80-90 mu m. Because the corrosion rates of silicon dioxide and silicon are different, small-angle steps are formed on the interface of the silicon dioxide and the silicon in the corrosion process, the filling effect of the subsequent glass powder on the V-shaped groove is influenced, and the position, close to the surface of the silicon wafer, of the V-shaped groove cannot be completely filled and covered by the glass powder, so that when a product is subjected to voltage test, sparks are easily generated on the edge of the V-shaped groove, the breakdown voltage of the product is reduced due to the increase of surface leakage, and the reliability of the product is influenced.
Disclosure of Invention
The invention aims to solve the problems in the prior art and provides a secondary mesa etching process for a high-voltage-resistance semiconductor discrete device chip, which enlarges the contact area between glass powder and an etched mesa, increases the contact capacity, improves the dielectric strength and reduces the surface electric leakage, thereby ensuring the excellent high-temperature and high-voltage performance and high reliability of the high-voltage-resistance semiconductor discrete device chip.
The technical solution of the invention is as follows:
a secondary mesa etching process for a high-voltage-resistance semiconductor discrete device chip comprises the following steps:
1. carrying out primary corrosion on the surface of a silicon wafer with an oxide layer on the surface, wherein the primary corrosion depth is 75-85 mu m;
2. carrying out secondary corrosion on the silicon wafer subjected to the primary corrosion V-shaped groove through a photoetching mask, wherein the secondary corrosion depth is 7-10 mu m, and the width of the secondary corrosion table top is larger than that of the primary corrosion table top;
3. and after the two mesa etchings are finished, performing glass passivation.
Furthermore, the time for the first etching is 3-4 min, and the time for the second etching is 0.5-0.8 min.
Furthermore, the width difference between the secondary etching table and the primary etching table is 60-80 μm.
Further, a knife scraping method is adopted during glass passivation, and the process steps are as follows:
1. powder scraping, namely coating a proper amount of glass powder slurry on the surface of a silicon wafer by using a clean glass rod, uniformly scraping and coating the surface of the silicon wafer in a groove by using a single-sided blade at an angle of 45 degrees with the horizontal direction, and repeatedly scraping and coating for 15-20 times until the groove is full; then, baking the silicon wafer on an electric furnace of 300-500W for 3-5 min until the glass powder is dried to be white;
2. sintering at low temperature, namely sintering the silicon chip subjected to powder scraping at 480-520 ℃ for 20-30 minutes at low temperature, and introducing N2 as protective gas in the sintering process;
3. powder wiping: placing the silicon wafer sintered at low temperature on a clean and flat glass plate, and wiping off glass powder on the surface of the silicon wafer lightly and flatly by using an eraser;
4. and (3) high-temperature sintering: sintering the silicon wafer subjected to powder wiping at the high temperature of 720-880 ℃ for 15-20 minutes, and introducing N2 or O2 as a protective gas in the sintering process;
5. the above process is repeated two to three times.
The invention has the beneficial effects that: through the secondary corrosion of the mesa, small-angle steps caused by different corrosion rates of silicon and silicon dioxide at the position close to the surface of the silicon wafer are removed, a physical buffer area is formed at the joint of the surface of the silicon wafer and the mesa of the V-shaped groove by the fused passivation process of filling glass powder in the groove, the contact area of the glass powder and the corrosion mesa is increased, the contact capacity is increased, the dielectric strength is improved, and the surface leakage is reduced, so that the excellent high-temperature and high-pressure performance and high reliability of the high-pressure-resistant semiconductor discrete device chip are ensured.
Drawings
FIG. 1 is a schematic view of a primary etched mesa structure of a silicon wafer;
FIG. 2 is a schematic diagram of a secondary etched mesa structure of a silicon wafer;
FIG. 3 is a schematic diagram of a silicon wafer etching mesa after being filled with glass powder.
In the figure: 1-silicon chip, 2-oxide layer, 3-primary corrosion table, 4-secondary corrosion table and 5-fused glass powder.
Detailed Description
The invention is described in detail below with reference to the accompanying drawings:
example 1
The secondary mesa etching process for the high-voltage-resistance semiconductor discrete device chip comprises the following steps:
1. as shown in figure 1, a silicon wafer 1 with an oxide layer 2 on the surface is subjected to one V-shaped groove corrosion by mixed acid solution, and the thickness dsio of the oxide layer on the surface of the silicon wafer2The thickness is 0.5 mu m, the mixed acid solution is a mixed solution of nitric acid, hydrofluoric acid and glacial acetic acid, the volume ratio is 5:3:2, a container for containing the mixed acid solution is placed in the mixed ice-water solution, the silicon wafer is corroded in the mixed acid solution for 3min at the timing, the corrosion depth of the measuring groove reaches 75 mu m, the width reaches 180 mu m, and a primary corrosion table top 3 is formed.
2. As shown in fig. 2, after a silicon wafer 1 forming a primary etching mesa 3 is subjected to photoetching mask, a V-shaped groove is subjected to secondary etching by using a mixed acid solution, wherein the mixed acid solution is a mixed solution of nitric acid, hydrofluoric acid and glacial acetic acid, the volume ratio is 5:3:2, a container containing the mixed acid solution is placed in the mixed ice-water solution, the silicon wafer is subjected to timed etching for 0.5min in the mixed acid solution, the etching depth of the measuring groove reaches 7 micrometers, the width of the groove surface reaches 240 micrometers, and a secondary etching mesa 4 is formed. The difference between the width of the secondary etching mesa 4 and the width of the primary etching mesa 3 was 60 μm.
3. As shown in fig. 3, a doctor blade glass passivation process is used, and the V-shaped groove after the secondary etching is filled with glass powder to perform fused passivation to form fused glass powder 5.
The specific process comprises the following steps: powder scraping → low temperature sintering → powder scraping → high temperature sintering.
And (3) powder scraping, namely coating a proper amount of glass powder slurry on the surface of the silicon wafer by using a clean glass rod, uniformly scraping and coating the silicon wafer in the groove by using a single-sided blade at an angle of 45 degrees with the horizontal direction, and repeatedly scraping and coating for 15 times until the groove is full. Then the silicon chip is placed on a 300W electric furnace to be baked for 5min, and the glass powder is dried to be white.
And (3) low-temperature sintering: and sintering the silicon chip subjected to powder scraping at 480 ℃ for 30 minutes at low temperature, wherein N2 is introduced as protective gas in the sintering process.
Powder wiping: and (3) placing the silicon wafer sintered at low temperature on a clean and flat glass plate, and lightly and flatly wiping the glass powder on the surface of the silicon wafer by using an eraser without wiping the glass powder in the groove.
And (3) high-temperature sintering: and sintering the silicon wafer subjected to powder wiping at the high temperature of 720 ℃ for 20 minutes, wherein N2 or O2 is introduced as protective gas in the sintering process.
The above process was repeated two times.
Example 2
The secondary mesa etching process for the high-voltage-resistance semiconductor discrete device chip comprises the following steps:
1. as shown in figure 1, the surface of a silicon wafer with an oxide layer 2 on the surface is subjected to one V-shaped groove corrosion by using a mixed acid solution, and the thickness dsio of the oxide layer on the surface of the silicon wafer20.65 μm, mixed acid solution of nitric acid, hydrofluoric acid and glacial acetic acid at volume ratio of 5:3:2, placing the container in ice-water mixture, and placing silicon wafer in the containerEtching for 4min in the mixed acid solution, measuring the etching depth of the groove to 85 μm and the etching width to 200 μm, and forming a primary etching table top 3.
2. As shown in fig. 2, after a silicon wafer 1 forming a primary etching mesa 3 is subjected to photoetching mask, a V-shaped groove is subjected to secondary etching by using a mixed acid solution, wherein the mixed acid solution is a mixed solution of nitric acid, hydrofluoric acid and glacial acetic acid, the volume ratio is 5:3:2, a container containing the mixed acid solution is placed in the mixed ice-water solution, the silicon wafer is subjected to chronoetching for 48 seconds in the mixed acid solution, the etching depth of the measuring groove reaches 10 micrometers, the width of the groove surface reaches 280 micrometers, and a secondary etching mesa 4 is formed. The difference between the width of the secondary etching mesa 4 and the width of the primary etching mesa 3 was 80 μm.
3. As shown in fig. 3, a doctor blade glass passivation process is used, and the V-shaped groove after the secondary etching is filled with glass powder to perform fused passivation to form fused glass powder 5.
The specific process comprises the following steps: powder scraping → low temperature sintering → powder scraping → high temperature sintering.
And (3) powder scraping, namely coating a proper amount of glass powder slurry on the surface of the silicon wafer by using a clean glass rod, uniformly scraping and coating the silicon wafer in the groove by using a single-sided blade at an angle of 45 degrees with the horizontal direction, and repeatedly scraping and coating for 20 times until the groove is full. Then the silicon chip is placed on a 500W electric furnace to be baked for 3min, and the glass powder is dried to be white.
And (3) low-temperature sintering, namely sintering the silicon chip subjected to powder scraping at 520 ℃ for 20 minutes, and introducing N2 as protective gas in the sintering process.
Powder wiping: and (3) placing the silicon wafer sintered at low temperature on a clean and flat glass plate, and lightly and flatly wiping the glass powder on the surface of the silicon wafer by using an eraser without wiping the glass powder in the groove.
And (3) high-temperature sintering: and sintering the silicon wafer subjected to powder wiping at 880 ℃ for 15 minutes, wherein N2 or O2 is introduced as protective gas during sintering.
This process was repeated three times.
Example 3
The secondary mesa etching process for the high-voltage-resistance semiconductor discrete device chip comprises the following steps:
1.3 DD1 in two-piece taking process55I products are respectively marked as a silicon chip I and a silicon chip II, and the thickness dsio of the oxide layers on the surfaces of the two silicon chips2Are all 0.55 μm.
2. And carrying out one-time V-shaped groove corrosion on the two silicon wafers after the mesa photoetching. Placing a container containing a mixed solution of nitric acid, hydrofluoric acid and glacial acetic acid in a volume ratio of 5:3:2 in an ice-water mixed solution, placing two silicon wafers on a wafer frame, placing the wafer frame into an etching solution for timing etching, taking out the silicon wafers after timing for 3min and 40 sec, and measuring the depth and width of a V-shaped groove, wherein the depth of the groove surface mesa of the two silicon wafers is 81 micrometers, and the width of the groove surface mesa of the two silicon wafers is 192 micrometers.
3. And (3) placing the silicon wafer I in high-purity water to be cleaned, cleaning and processing the silicon wafer II, and then carrying out secondary groove photoetching on a mask.
4. And carrying out secondary V-shaped groove corrosion on the silicon wafer II subjected to the secondary groove mask photoetching. And placing a container containing a mixed solution of nitric acid, hydrofluoric acid and glacial acetic acid in a volume ratio of 5:3:2 in an ice-water mixed solution, placing a silicon wafer II on a wafer frame, placing the silicon wafer II in an etching solution for timing etching, taking out the silicon wafer after timing for 35 seconds, and measuring the depth and the width of a V-shaped groove, wherein the depth of the groove surface of the secondary V-shaped groove of the silicon wafer II is 8.5 micrometers, and the width of the table surface of the groove surface is 270 micrometers.
5. And (3) cleaning the silicon wafer I and the silicon wafer II after the V-shaped groove is corroded, filling glass powder into the V-shaped groove by adopting a scraping glass passivation process, and performing fusion passivation.
The specific process comprises the following steps: powder scraping → low temperature sintering → powder scraping → high temperature sintering.
And (3) powder scraping, namely coating a proper amount of glass powder slurry on the surface of the silicon wafer by using a clean glass rod, uniformly scraping and coating the silicon wafer in the groove by using a single-sided blade at an angle of 45 degrees with the horizontal direction, and repeatedly scraping and coating for 18 times until the groove is full. Then the silicon chip is placed on a 350W electric furnace to be baked for 4min, and the glass powder is dried to be white.
And (3) low-temperature sintering, namely sintering the silicon chip subjected to powder scraping at 510 ℃ for 25 minutes, wherein N2 is introduced as protective gas in the sintering process.
Powder wiping: and (3) placing the silicon wafer sintered at low temperature on a clean and flat glass plate, and lightly and flatly wiping the glass powder on the surface of the silicon wafer by using an eraser without wiping the glass powder in the groove.
And (3) high-temperature sintering: and sintering the silicon wafer subjected to powder wiping at 820 ℃ for 18 minutes, wherein N2 is introduced as a protective gas during sintering.
This process was repeated three times.
6. After glass passivation, 10 dies are respectively extracted from the silicon wafer I and the silicon wafer II to carry out BVCBO test, and the test results of the BVCBO values are shown in a table 1: unit (V)
Figure BDA0001185878010000061
Note: test condition ICB 1mA
Description of the drawings: when the silicon wafer I is tested, sparks are generated on the edge of the V-shaped groove on the surface of the chip obviously, but the phenomenon is not generated on the silicon wafer II, and the BVCBO value of the silicon wafer II is 80-100V higher than that of the silicon wafer I.
7. Finishing the chip production flow by the silicon chip I and the silicon chip II, respectively selecting 10 branch tube cores for packaging, and then carrying out product parameter test, wherein the test values of BVCBO and ICBO are selected and recorded in a table 2:
Figure BDA0001185878010000071
note: and (3) testing conditions are as follows: BVCBO: ICB 1mA requires BVCBO >1100V
ICBO VCB 100V ICBO <100 μ A
The above-described embodiments are intended to illustrate rather than to limit the invention, and any modifications and variations of the present invention are within the spirit of the invention and the scope of the appended claims.

Claims (4)

1. A secondary mesa etching process for a high-voltage-resistance semiconductor discrete device chip is characterized by comprising the following steps:
1.1) carrying out primary corrosion on the surface of a silicon wafer with an oxide layer on the surface, wherein the primary corrosion depth is 75-85 μm;
1.2) carrying out secondary corrosion on the silicon wafer subjected to the primary corrosion V-shaped groove through a photoetching mask, wherein the secondary corrosion depth is 7-10 mu m, and the width of the secondary corrosion table top is larger than that of the primary corrosion table top;
1.3) and after the two mesa etchings are finished, performing glass passivation.
2. The secondary etching mesa process of the chip of the high-voltage semiconductor discrete device as claimed in claim 1, wherein the time for the primary etching is 3min to 4min, and the time for the secondary etching of the mesa is 0.5min to 0.8 min.
3. The secondary etching mesa process of the chip of the high-voltage semiconductor discrete device as claimed in claim 1, wherein the difference between the widths of the secondary etching mesa and the primary etching mesa is 60 μm to 80 μm.
4. The secondary etching mesa process of high voltage semiconductor discrete device chip as claimed in claim 1, wherein a knife-scraping method is adopted during glass passivation, and the process steps are as follows:
4.1) scraping powder, namely coating a proper amount of glass powder slurry on the surface of a silicon wafer by using a clean glass rod, uniformly scraping and coating the glass powder slurry in a groove by using a single-sided blade at an angle of 45 degrees with the horizontal direction, and repeatedly scraping and coating for 15-20 times until the groove is full; then, the silicon chip is placed on an electric furnace of 300W-500W to be baked for 3 min-5 min until the glass powder is dried to be white;
4.2) low-temperature sintering, namely sintering the silicon chip subjected to powder scraping at 480-520 ℃ for 20-30 minutes, and introducing N2 as a protective gas in the sintering process;
4.3), powder scraping: placing the silicon wafer sintered at low temperature on a clean and flat glass plate, and wiping off glass powder on the surface of the silicon wafer lightly and flatly by using an eraser;
4.4), high-temperature sintering: sintering the silicon wafer subjected to powder wiping at the high temperature of 720-880 ℃ for 15-20 minutes, and introducing N2 or O2 as protective gas in the sintering process;
4.5) repeating the above process for two times to three times.
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CN101393929A (en) * 2008-11-10 2009-03-25 吉林华微电子股份有限公司 Thyristor for terminal semi-conductor discrete device with dual positive oblique angle slots and manufacturing method thereof
CN104269356A (en) * 2014-09-29 2015-01-07 西安卫光科技有限公司 Method for manufacturing 50A high-current fast recovery diode
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