CN106024865A - Mesa diode processing technology - Google Patents

Mesa diode processing technology Download PDF

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Publication number
CN106024865A
CN106024865A CN201610566729.4A CN201610566729A CN106024865A CN 106024865 A CN106024865 A CN 106024865A CN 201610566729 A CN201610566729 A CN 201610566729A CN 106024865 A CN106024865 A CN 106024865A
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CN
China
Prior art keywords
glass
silicon chip
mesa
glass paste
silicon
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Pending
Application number
CN201610566729.4A
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Chinese (zh)
Inventor
王志敏
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Rugao Dachang Electronics Co Ltd
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Rugao Dachang Electronics Co Ltd
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Priority to CN201610566729.4A priority Critical patent/CN106024865A/en
Publication of CN106024865A publication Critical patent/CN106024865A/en
Pending legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/02Semiconductor bodies ; Multistep manufacturing processes therefor
    • H01L29/06Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions
    • H01L29/0684Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions characterised by the shape, relative sizes or dispositions of the semiconductor regions or junctions between the regions
    • H01L29/0688Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions characterised by the shape, relative sizes or dispositions of the semiconductor regions or junctions between the regions characterised by the particular shape of a junction between semiconductor regions
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/66007Multistep manufacturing processes
    • H01L29/66075Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
    • H01L29/66083Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by variation of the electric current supplied or the electric potential applied, to one or more of the electrodes carrying the current to be rectified, amplified, oscillated or switched, e.g. two-terminal devices
    • H01L29/6609Diodes
    • H01L29/66136PN junction diodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/86Types of semiconductor device ; Multistep manufacturing processes therefor controllable only by variation of the electric current supplied, or only the electric potential applied, to one or more of the electrodes carrying the current to be rectified, amplified, oscillated or switched
    • H01L29/861Diodes
    • H01L29/8613Mesa PN junction diodes

Abstract

The invention discloses a mesa diode processing technology comprising the following steps: completing diffusion film making; photo-etching a trench for the first time; corroding a circular groove mesa for the first time; photo-etching the trench for the second time; corroding the circular groove mesa for the second time; growing a silicon dioxide film on the circular groove mesa and cleaning the silicon dioxide film; applying glass powder; baking glass powder; performing glass passivation; and corroding and cleaning the surface. According to the invention, mixed acid corrosive liquid is prepared with nitric acid, hydrofluoric acid and glacial acetic acid according to the volume ratio of 5:3:1, photo-etched silicon wafers are corroded in the mixed acid corrosive liquid to corrode out PN junction mesa grooves of chips, and the geometrical shape of the mesa diode PN junctions is corroded into a circular shape. As the circular shape has a smooth curved surface, highest breakdown voltage is achieved. Thus, the breakdown voltage effect of devices is improved effectively.

Description

A kind of processing technique of mesa diode
Technical field
The present invention relates to semiconductor electronic component technical field, the processing of a kind of mesa diode Technique.
Background technology
Mesa diode, although the manufacture method of PN junction is identical with diffused, but, only retain PN junction And the part of necessity, unnecessary portion medicine is eroded.Its remaining part just presents appearance Face shape, thus gain the name.The mesa of initial production, makes quasiconductor materials'use diffusion method. Therefore, again this mesa is called diffused-mesa.PN junction geometry and semiconductor surface electric field pair The impact of breakdown voltage is the most notable.The adverse effect to breakdown voltage due to corner angle electric field and surface field, High-voltage diode does not the most use planar structure to commonly use mesa structure.At present, existing general table top knot Structure diode PN junction geometry is poor to the breakdown voltage effect improving device.
Summary of the invention
It is an object of the invention to provide the processing technique of a kind of mesa diode, to solve existing one As the mesa structure diode PN junction geometry poor problem of breakdown voltage effect to improving device.
For achieving the above object, the present invention provides following technical scheme: the processing of a kind of mesa diode Technique, this processing technique comprises the following steps:
Diffusion sheet completes → and the corrosion circular trough table top → secondary lithographic trenches of secondary lithographic trenches → once → Anticaustic circular trough table top → circular trough table top growth silicon dioxide film and cleaning treatment → coating glass dust → bakee glass dust → glassivation → surface corrosion cleaning.
S1, will diffuse out the silicon chip of PN junction according to the dimensions of required chip carry out gluing, front baking, Exposure, development and the photoetching process of post bake, carry out photoetching round shape figure;
S2, by volume, by nitric acid: Fluohydric acid.: glacial acetic acid=5:3:1 is configured to nitration mixture corrosive liquid, Then silicon chip after photoetching is put in nitration mixture corrosive liquid and corrode, corrode the PN junction table top ditch each chip Groove, keeps each chip chamber to connect and not dialysis, then carries out cleaning of removing photoresist;
S2, preparation glass paste solvent: ethyl cellulose and diluent are placed in the ratio of 1g:10ml In beaker, heated and stirred is dissolved, and makes glass paste solvent;
S2, preparation glass paste: pour glass paste solvent and lead glass frit into eggplant in 3ml:5g ratio Shape bottle is stirred;
S3, the glass paste being stirred drips to corrode the silicon chip surface of groove, with rustless steel spoon at silicon On sheet apply, make glass paste uniformly fill in groove, then with rustless steel scraper by unnecessary glass paste from silicon Sheet surface scrapes gently, subsequently this silicon chip is put into quartz boat;
S4, glass pre-burning: push fire door and dry 12-18 minute, push calcined temperature and be 420-480 DEG C, push away Entering burn-in time is 25-28 minute, burning-off photoresist layer simultaneously;Calcined temperature is transferred to 565~575 DEG C, The quartz boat that will be equipped with coated glass paste silicon chip puts into pre-burning in quartz ampoule, and the time is 25 minutes;
Silicon chip after S5, wiping pre-burning: by the glass dust wiped clean of the silicon chip surface after pre-burning, and note In groove, glass paste is not wiped;
S6, glass burn till: the silicon chip wiped through Watch glass brush is carried out glass and burns till, deluster simultaneously Photoresist, firing temperature is 830-840 DEG C, and firing time is 12-18 minute, is cooled to 500-550 DEG C, Time is 30 minutes, and being naturally cooling to less than 200 DEG C can come out of the stove;
S7, re-operate one time again according to the order of S5 to S8;
S8, after cleaned for the silicon chip after glassivation, nickel plating or gold-plated alloying, carry out scribing, make The chip of silicon rectification device.
Compared with prior art, the method have the advantages that this invention, will by by volume Nitric acid: Fluohydric acid.: glacial acetic acid=5:3:1 is configured to nitration mixture corrosive liquid, is then put into by silicon chip after photoetching Nitration mixture corrosive liquid corrodes, corrodes the PN junction mesa trench each chip, by mesa structure diode PN junction geometry is corroded and circular shape, and circle has mild curved surfaces, can have the highest hitting Wear voltage, effectively raise the breakdown voltage effect of device.
Detailed description of the invention
Technical scheme in the embodiment of the present invention will be clearly and completely described below, it is clear that institute The embodiment described is only a part of embodiment of the present invention rather than whole embodiments.Based on this Embodiment in bright, those of ordinary skill in the art are obtained under not making creative work premise Every other embodiment, broadly falls into the scope of protection of the invention.
The present invention provides a kind of technical scheme: the processing technique of a kind of mesa diode, this processing technique Comprise the following steps:
Diffusion sheet completes → and the corrosion circular trough table top → secondary lithographic trenches of secondary lithographic trenches → once → Anticaustic circular trough table top → circular trough table top growth silicon dioxide film and cleaning treatment → coating glass dust → bakee glass dust → glassivation → surface corrosion cleaning, the thickness of circular trough table top growth silicon dioxide film Degree is 1.5-2 nanometer.
S1, will diffuse out the silicon chip of PN junction according to the dimensions of required chip carry out gluing, front baking, Exposure, development and the photoetching process of post bake, carry out photoetching round shape figure;
S2, by volume, by nitric acid: Fluohydric acid.: glacial acetic acid=5:3:1 is configured to nitration mixture corrosive liquid, Then silicon chip after photoetching is put in nitration mixture corrosive liquid and corrode, corrode the PN junction table top ditch each chip Groove, keeps each chip chamber to connect and not dialysis, then carries out cleaning of removing photoresist;
S2, preparation glass paste solvent: ethyl cellulose and diluent are placed in the ratio of 1g:10ml In beaker, heated and stirred is dissolved, and makes glass paste solvent;
S2, preparation glass paste: pour glass paste solvent and lead glass frit into eggplant in 3ml:5g ratio Shape bottle is stirred;
S3, the glass paste being stirred drips to corrode the silicon chip surface of groove, with rustless steel spoon at silicon On sheet apply, make glass paste uniformly fill in groove, then with rustless steel scraper by unnecessary glass paste from silicon Sheet surface scrapes gently, subsequently this silicon chip is put into quartz boat;
S4, glass pre-burning: push fire door and dry 12-18 minute, push calcined temperature and be 420-480 DEG C, push away Entering burn-in time is 25-28 minute, burning-off photoresist layer simultaneously;Calcined temperature is transferred to 565~575 DEG C, The quartz boat that will be equipped with coated glass paste silicon chip puts into pre-burning in quartz ampoule, and the time is 25 minutes;
Silicon chip after S5, wiping pre-burning: by the glass dust wiped clean of the silicon chip surface after pre-burning, and note In groove, glass paste is not wiped;
S6, glass burn till: the silicon chip wiped through Watch glass brush is carried out glass and burns till, deluster simultaneously Photoresist, firing temperature is 830-840 DEG C, and firing time is 12-18 minute, is cooled to 500-550 DEG C, Time is 30 minutes, and being naturally cooling to less than 200 DEG C can come out of the stove;
S7, re-operate one time again according to the order of S5 to S8;
S8, after cleaned for the silicon chip after glassivation, nickel plating or gold-plated alloying, carry out scribing, make The chip of silicon rectification device.
Although an embodiment of the present invention has been shown and described, for those of ordinary skill in the art Speech, it is possible to understand that these embodiments can be carried out without departing from the principles and spirit of the present invention Multiple change, revising, replace and modification, the scope of the present invention is limited by claims and equivalent thereof Fixed.

Claims (1)

1. the processing technique of a mesa diode, it is characterised in that: this processing technique includes following step Rapid:
Diffusion sheet completes → and the corrosion circular trough table top → secondary lithographic trenches of secondary lithographic trenches → once → Anticaustic circular trough table top → circular trough table top growth silicon dioxide film and cleaning treatment → coating glass dust → bakee glass dust → glassivation → surface corrosion cleaning.
S1, will diffuse out the silicon chip of PN junction according to the dimensions of required chip carry out gluing, front baking, Exposure, development and the photoetching process of post bake, carry out photoetching round shape figure;
S2, by volume, by nitric acid: Fluohydric acid.: glacial acetic acid=5:3:1 is configured to nitration mixture corrosive liquid, Then silicon chip after photoetching is put in nitration mixture corrosive liquid and corrode, corrode the PN junction table top ditch each chip Groove, keeps each chip chamber to connect and not dialysis, then carries out cleaning of removing photoresist;
S2, preparation glass paste solvent: ethyl cellulose and diluent are placed in the ratio of 1g:10ml In beaker, heated and stirred is dissolved, and makes glass paste solvent;
S2, preparation glass paste: pour glass paste solvent and lead glass frit into eggplant in 3ml:5g ratio Shape bottle is stirred;
S3, the glass paste being stirred drips to corrode the silicon chip surface of groove, with rustless steel spoon at silicon On sheet apply, make glass paste uniformly fill in groove, then with rustless steel scraper by unnecessary glass paste from silicon Sheet surface scrapes gently, subsequently this silicon chip is put into quartz boat;
S4, glass pre-burning: push fire door and dry 12-18 minute, push calcined temperature and be 420-480 DEG C, push away Entering burn-in time is 25-28 minute, burning-off photoresist layer simultaneously;Calcined temperature is transferred to 565~575 DEG C, The quartz boat that will be equipped with coated glass paste silicon chip puts into pre-burning in quartz ampoule, and the time is 25 minutes;
Silicon chip after S5, wiping pre-burning: by the glass dust wiped clean of the silicon chip surface after pre-burning, and note In groove, glass paste is not wiped;
S6, glass burn till: the silicon chip wiped through Watch glass brush is carried out glass and burns till, deluster simultaneously Photoresist, firing temperature is 830-840 DEG C, and firing time is 12-18 minute, is cooled to 500-550 DEG C, Time is 30 minutes, and being naturally cooling to less than 200 DEG C can come out of the stove;
S7, re-operate one time again according to the order of S5 to S8;
S8, after cleaned for the silicon chip after glassivation, nickel plating or gold-plated alloying, carry out scribing, make The chip of silicon rectification device.
CN201610566729.4A 2016-07-19 2016-07-19 Mesa diode processing technology Pending CN106024865A (en)

Priority Applications (1)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106783576A (en) * 2016-12-20 2017-05-31 锦州辽晶电子科技有限公司 High-voltage semiconductor discrete device chip anticaustic mesa technology
CN109302159A (en) * 2018-08-01 2019-02-01 河源市众拓光电科技有限公司 A kind of method of compound substrate and compound substrate production thin film bulk acoustic wave resonator
CN109309014A (en) * 2017-07-26 2019-02-05 天津环鑫科技发展有限公司 Improve the glass firing process of product electrical parameter
CN111739798A (en) * 2020-05-21 2020-10-02 如皋市大昌电子有限公司 Cleaning and packaging method for diode high-voltage silicon stack
CN112086368A (en) * 2020-08-05 2020-12-15 如皋市大昌电子有限公司 Preparation process of plastic-sealed high-voltage silicon stack of quick switch
CN112909078A (en) * 2021-02-08 2021-06-04 临沂卓芯电子有限公司 High-voltage ultrafast recovery diode chip and manufacturing method thereof
CN113066719A (en) * 2021-03-18 2021-07-02 吉林华微电子股份有限公司 Silicon wafer manufacturing method and silicon wafer
CN114388372A (en) * 2021-05-19 2022-04-22 上海音特电子有限公司 Technological method for power semiconductor PN junction protection

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Publication number Priority date Publication date Assignee Title
CN101038892A (en) * 2007-04-25 2007-09-19 天津中环半导体股份有限公司 Knife scraping method glass passivation process for silicon current rectifier
CN101478006A (en) * 2009-01-19 2009-07-08 西安电子科技大学 Terahertz GaN Gunn diode based on conducting type SiC substrate and manufacturing process thereof
CN102129987A (en) * 2010-12-30 2011-07-20 常州星海电子有限公司 Process for passivating bidirectional trigger diode scrapped glass
US9368650B1 (en) * 2015-07-16 2016-06-14 Hestia Power Inc. SiC junction barrier controlled schottky rectifier

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101038892A (en) * 2007-04-25 2007-09-19 天津中环半导体股份有限公司 Knife scraping method glass passivation process for silicon current rectifier
CN101478006A (en) * 2009-01-19 2009-07-08 西安电子科技大学 Terahertz GaN Gunn diode based on conducting type SiC substrate and manufacturing process thereof
CN102129987A (en) * 2010-12-30 2011-07-20 常州星海电子有限公司 Process for passivating bidirectional trigger diode scrapped glass
US9368650B1 (en) * 2015-07-16 2016-06-14 Hestia Power Inc. SiC junction barrier controlled schottky rectifier

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106783576A (en) * 2016-12-20 2017-05-31 锦州辽晶电子科技有限公司 High-voltage semiconductor discrete device chip anticaustic mesa technology
CN106783576B (en) * 2016-12-20 2021-01-26 锦州辽晶电子科技有限公司 Secondary corrosion table-board process for high-voltage-resistance semiconductor discrete device chip
CN109309014A (en) * 2017-07-26 2019-02-05 天津环鑫科技发展有限公司 Improve the glass firing process of product electrical parameter
CN109302159A (en) * 2018-08-01 2019-02-01 河源市众拓光电科技有限公司 A kind of method of compound substrate and compound substrate production thin film bulk acoustic wave resonator
CN111739798A (en) * 2020-05-21 2020-10-02 如皋市大昌电子有限公司 Cleaning and packaging method for diode high-voltage silicon stack
CN112086368A (en) * 2020-08-05 2020-12-15 如皋市大昌电子有限公司 Preparation process of plastic-sealed high-voltage silicon stack of quick switch
CN112909078A (en) * 2021-02-08 2021-06-04 临沂卓芯电子有限公司 High-voltage ultrafast recovery diode chip and manufacturing method thereof
CN112909078B (en) * 2021-02-08 2022-11-29 临沂卓芯电子有限公司 High-voltage ultrafast recovery diode chip and manufacturing method thereof
CN113066719A (en) * 2021-03-18 2021-07-02 吉林华微电子股份有限公司 Silicon wafer manufacturing method and silicon wafer
CN114388372A (en) * 2021-05-19 2022-04-22 上海音特电子有限公司 Technological method for power semiconductor PN junction protection

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