CN106748229A - A kind of bioorganic pesticide fertilizer and its composting method with the Java brucea dregs of fat as raw material - Google Patents

A kind of bioorganic pesticide fertilizer and its composting method with the Java brucea dregs of fat as raw material Download PDF

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Publication number
CN106748229A
CN106748229A CN201611261812.7A CN201611261812A CN106748229A CN 106748229 A CN106748229 A CN 106748229A CN 201611261812 A CN201611261812 A CN 201611261812A CN 106748229 A CN106748229 A CN 106748229A
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parts
pesticide fertilizer
bioorganic pesticide
dregs
fat
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徐汉虹
孙郑
毛根林
张志祥
刘牛
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South China Agricultural University
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South China Agricultural University
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05CNITROGENOUS FERTILISERS
    • C05C5/00Fertilisers containing other nitrates
    • C05C5/02Fertilisers containing other nitrates containing sodium or potassium nitrate
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05CNITROGENOUS FERTILISERS
    • C05C9/00Fertilisers containing urea or urea compounds
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F17/00Preparation of fertilisers characterised by biological or biochemical treatment steps, e.g. composting or fermentation
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/60Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/80Soil conditioners
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/40Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Health & Medical Sciences (AREA)
  • Soil Sciences (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Biochemistry (AREA)
  • Biotechnology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Molecular Biology (AREA)
  • Fertilizers (AREA)

Abstract

The invention discloses a kind of bioorganic pesticide fertilizer and its composting method, belong to fertilizer preparing technical field.The bioorganic pesticide fertilizer includes following raw material:70 90 parts of chicken manure, 30 50 parts of the Java brucea dregs of fat, 20 40 parts of waste residue, 20 35 parts of tea seed cake, 10 20 parts of derris root powder, 5 10 parts of biological bacteria, micro- 13 parts, 13 parts of additive, the bioorganic pesticide fertilizer are made by crushing and screening, stirring mixing, fermentation, ageing, drying and other steps.Bioorganic pesticide fertilizer of the invention can not only effectively prevention and control soil pest and disease damage, and can be balanced nutritious, strengthen the immunity of crops, improve crop yield;Bioorganic pesticide fertilizer ecological, environmental protective of the invention, can improve soil texture, environmentally safe.

Description

A kind of bioorganic pesticide fertilizer and its composting method with the Java brucea dregs of fat as raw material
Technical field
The invention belongs to fertilizer preparing technical field, and in particular to a kind of bioorganic pesticide with the Java brucea dregs of fat as raw material Fertilizer and its composting method.
Background technology
China is a large agricultural country, and agricultural chemicals and chemical fertilizer play highly important effect in agricultural production, with life The raising of the gentle health perception of running water, people pay much attention to the security of agricultural product, to nuisanceless, pollution-free food demand by Year increases.
But because unreasonable and excessive use the to soil causes China certain areas to there is different degrees of soil hardening, The problems such as salination, soil physico-chemical property is caused to change, soil-borne disease is serious, particularly in the facilities vegetable with high added value The field such as plantation and Chinese herbal medicine plantation.The continuous cropping of crop and continuous cropping provide hotbed for the development of pest and disease damage, largely use high poison Agricultural chemicals destroys ecology while enhancing disease pest resistance, generates residues of pesticides, and a large amount of and unreasonable of chemical fertilizer use Destroy soil physico-chemical property.
Java brucea is the primary species of China, and botanical pesticide is can be used for according to the study, its effective active composition(Java brucea is bitter Element and active component)It is present in complete stool.Java brucea is mainly used in pharmacy industry at present, by the way that brucea fruit oil is obtained by extraction, then enters Row deep processing.And the remaining Java brucea dregs of fat are particularly suitable for organic rich in nutrient and fractions of active ingredient such as organic matters The fermentation of medicine fertilizer.Therefore the production of bioorganic pesticide fertilizer is carried out using the Java brucea dregs of fat, economy and society effect can be not only obtained Benefit, has also accepted Java brucea upstream industry, reduces production cost, realizes the resources effective utilization of discarded object.
The use of bioorganic pesticide fertilizer, improves soil physico-chemical property, is effectively improved the soil salinization, optimizes soil micro- Biology community structure, by collective effects such as the Java brucea dregs of fat and tea seed cake, derris root powder, biological bacterias, effectively contains soil-borne disease Generation, improve the immunity of crop, finally improve crop yield, improve crop quality.
The content of the invention
The purpose of the present invention is directed to defect of the prior art and deficiency, there is provided one kind can effectively prevention and control soil disease Insect pest, and can be balanced nutritious, strengthen the immunity of crops, improve bioorganic pesticide fertilizer and its composting side of crop yield Method.
The purpose of the present invention is realized by following scheme.
A kind of bioorganic pesticide fertilizer, it is characterised in that in units of weight portion, including following raw material:Chicken manure 70-90 parts, 30-50 parts of the Java brucea dregs of fat, waste residue 20-40 parts, tea seed cake 20-35 parts, 10-20 parts of derris root powder, biological bacteria 5-10 parts, micro unit It is plain 1-3 parts, additive 1-5 parts.
Preferably, described bioorganic pesticide fertilizer, it is characterised in that in units of weight portion, including following raw material:Chicken manure 75-85 parts, 35-45 parts of the Java brucea dregs of fat, waste residue 25-35 parts, tea seed cake 25-35 parts, 12-20 parts of derris root powder, biological bacteria 8-10 Part, 2-3 parts, additive 2-3 parts of trace element.
Preferably, described bioorganic pesticide fertilizer, it is characterised in that in units of weight portion, including following raw material:Chicken manure 80 parts, 40 parts of the Java brucea dregs of fat, 30 parts of waste residue, 30 parts of tea seed cake, 15 parts of derris root powder, 8 parts of biological bacteria, trace element 2 parts, addition 2 parts of agent.
Specifically, the waste residue includes print chinaberry slag, bagasse, marc, edible fungi residues, sugar residue, bean dregs, acid-sludge, starch One or more in slag, manioc waste, citric acid waste, soy sauce residues, residue of monosodium glutamate, soybean residue.
Specifically, the biological bacteria includes that nitrogen-fixing bacteria, bacillus, ferment bacterium, saccharomycete, actinomyces, rhizobium, phosphorus are thin One or more in bacterium, B. mucilaginocus, phosphate solubilizing bacteria, chaetomium thermophilum, streptomycete and Paecilomyces lilacinus.
Further, described biological bacteria includes bacillus subtilis, become thoroughly decomposed composite bacteria agent and other functions strain, described The composite bacteria agent that becomes thoroughly decomposed including in bacillus, nitrogen-fixing bacteria, ferment bacterium, saccharomycete, actinomyces, chaetomium thermophilum and streptomycete One or more mixture, described other functions microbial inoculum includes rhizobium, phosphobacteria, B. mucilaginocus, phosphate solubilizing bacteria, pale purple One or more mixture of Paecilomyces varioti.
Specifically, the trace element includes one or more in iron, boron, manganese, copper, zinc, molybdenum, magnesium, rare earth metal.
Specifically, the additive include gypsum, lime, carbohydrate, soap powder, charcoal, activated carbon, calcium lignosulfonate, One or more in ethylenediamine tetra-acetic acid, amino acid, inorganic fertilizer.
The present invention also provides a kind of preparation method of bioorganic pesticide fertilizer, comprises the following steps.
S1:By the Java brucea dregs of fat, waste residue, tea seed cake, derris root powder after crushing and screening after, be stirred with chicken manure, it is stirred Addition, biological bacteria, additive in journey, regulation water content to 50%-65%, pH to 6.5-8, C/N=25:1~30:1、C/P=80:1~ 120:1, obtain mixture.
S2:Mixture is carried out into aerobic fermentation at 50-70 DEG C, ripening 7-15 days after fermenting 15-30 days.
S3:The mixture of step S2 compostings is sieved and is crushed, add additive, trace element to mix, dry, life is obtained Thing organic medical fertilizer.
Compared with prior art, the advantage of the invention is that.
(1) bioorganic pesticide fertilizer in the present invention, makes full use of organic solid castoff resource, has accepted Java brucea product Industry chain, increased economic benefit, reduce production cost, realize that waste material is efficiently utilized.
(2) medicine fertilizer production process green of the invention, environmental protection, energy-conservation, efficient, low-carbon (LC).
(3) pesticide-fertilizer product comprehensive nutrition of the invention, equilibrium, added without any chemical pesticide and hormone, using safety, There is good preventive and therapeutic effect to various soil-borne diseases and subterranean pest-insect.
(4) medicine fertilizer of the invention fundamentally improves soil physico-chemical property, optimizes structure of soil microbial community, fertilizer efficiency And drug effect is efficiently, persistently.
(5) the inducible crop of the bacillus subtilis that the present invention is used produces Resistant reaction, is so as to reduce disease pest Evil, the mode of action is novel effectively.
Specific embodiment
The above of the invention is described in further details by the following examples, but this should not be interpreted as this Invention.
The scope of above-mentioned theme is only limitted to following embodiment, and all technologies realized based on the above of the present invention are belonged to The scope of the present invention, under the scope for not departing from the principle of the invention, various changes and modifications of the present invention are possible, these change and Improve in category the scope of protection of the invention.
Embodiment 1.
A kind of bioorganic pesticide fertilizer, in units of weight portion, including following raw material:90 parts of chicken manure, 40 parts of the Java brucea dregs of fat, 20 parts of bagasse, 10 parts of edible fungi residues, 10 parts of bean dregs, 20 parts of tea seed cake, 10 parts of derris root powder, 5 parts of bacillus subtilis, urea 1 Part, 1 part of magnesium elements.
The preparation method of the bioorganic pesticide fertilizer, comprises the following steps.
S1:By the Java brucea dregs of fat of aforementioned proportion, bagasse, edible fungi residues, bean dregs, tea seed cake, derris root powder through broken sieve After point, it is stirred with chicken manure, addition bacillus subtilis, carbohydrate, urea in whipping process, regulation water content to 50%-65%, PH to 6.5-8, C/N=25:1~30:1、C/P=80:1~120:1, obtain mixture.
S2:Solid state fermentation is carried out by trough composting system, using temperature and humidity in Sensor monitoring fermentation process Change.When temperature is more than 70 DEG C, carry out turning over polishing working, make material fast cooling.Control bottom ventilation, makes heap body maintain 50 DEG C high temperature above more than 7 days, until heap temperature is gradually reduced, fermentation process probably continues 15~30 days, depending on concrete condition It is fixed;Treat that heap temperature drops to less than 40 DEG C, ageing(Secondary fermentation)Treatment 7-15 days, heap temperature is usually no more than 50 DEG C, certain rate of venting is maintained, treat that heap temperature is dropped to close to room temperature, stop fermentation.
S3:The mixture of composting is sieved and is crushed, add magnesium elements to mix, material is removed into superfluous water by dryer Point, it is 30% or so to control moisture content, and pack is obtained bioorganic pesticide fertilizer.
Field test:Trial crops are cabbage heart, are carried out in Guangzhou Vegetable park, and phyllotreta striolata occurs tight in the field area Weight, each experimental plot area 20m2, to test and set treatment and compare, control is divided into common organic fertilizer control and blank. Bioorganic pesticide fertilizer of the invention is applied in treatment, and amount of application is 500kg/ mus, and the common organic fertilizer of market purchase is applied in control, Amount of application is suitable with the contained nutrient of medicine fertilizer applied, and is mixed with top layer 30cm soil, disposably applies, Routine Management. Each treatment sets 3 repetitions.Soil sampling uses Tullgren soil animal separatory funnel isolation technics phyllotreta striolatas larva simultaneously Carry out statistical analysis.
Field test effect:Test process area compared with experimental control area, cabbage heart field soil phyllotreta striolata larva insect population Number reduces by 70%, and yield of flowering Chinese cabbage increases by 25% relative to control, reaches the pole level of signifiance.Common organic fertilizer group control is relative Unobvious in blank prevention effect, yield increases by 10% with respect to blank.
Embodiment 2.
A kind of bioorganic pesticide fertilizer, in units of weight portion, including following raw material:70 parts of chicken manure, 30 parts of the Java brucea dregs of fat, 10 parts of bagasse, 10 parts of edible fungi residues, 20 parts of tea seed cake, 20 parts of derris root powder, 8 parts of bacillus subtilis, 2 parts of phosphate solubilizing bacteria, carbohydrate 2 Part, 2 parts of potassium nitrate, 1 part of boron element.
The preparation method of the bioorganic pesticide fertilizer, comprises the following steps.
S1:By the Java brucea dregs of fat of aforementioned proportion, bagasse, edible fungi residues, tea seed cake, derris root powder after crushing and screening after, It is stirred with chicken manure, bacillus subtilis, carbohydrate, potassium nitrate, regulation water content to 50%-65%, pH is added in whipping process To 6.5-8, C/N=25:1~30:1、C/P=80:1~120:1, obtain mixture.
S2:Solid state fermentation is carried out by trough composting system, the change of temperature and humidity in monitoring fermentation process.Work as temperature During more than 70 DEG C, carry out turning over polishing working, make material fast cooling.Control bottom ventilation, makes heap body maintain 50 DEG C of high temperature above 7 More than it, until heap temperature is gradually reduced, fermentation process probably continues 15~30 days, is determined on a case-by-case basis;Treat heap body temperature Degree drops to less than 40 DEG C, ageing(Secondary fermentation)Treatment 7-15 days, heap temperature is usually no more than 50 DEG C, maintains certain Rate of venting, treats that heap temperature is dropped to close to room temperature, stops fermentation.
S3:The mixture of composting is sieved and is crushed, add boron element to mix, material is removed into superfluous water by dryer Point, it is 30% or so to control moisture content, and pack is obtained bioorganic pesticide fertilizer.
Field test:Trial crops are tomato, are carried out in Yongzhou City Dongan County vegetable cultivation base, and the canopy area is due to length There is serious, each experimental plot area 50m in year plantation capsicum and tomato, root-knot nematode2, test and set treatment and compare, control It is divided into common organic fertilizer control and blank.Bioorganic pesticide fertilizer of the invention is applied in treatment, and amount of application is 800kg/ mus, The common organic fertilizer of market purchase is applied in control, and amount of application is suitable with nutrient contained by the medicine fertilizer applied, and top layer 30cm soil is mixed, and is disposably applied, Routine Management.Each treatment sets 3 repetitions.Sampled using 5 methods, result of the test Use root knot exponential representation.
Field test effect:Test process area root knot index is 0-1, and check plot root knot index is 2-4, and yield of hot pepper is relative Increase by 26% in control, reach the pole level of signifiance.Common organic fertilizer group control is not obvious relative to blank prevention effect, Yield increases by 10% with respect to blank.
Embodiment 3.
A kind of bioorganic pesticide fertilizer, in units of weight portion, including following raw material:80 parts of chicken manure, 40 parts of the Java brucea dregs of fat, 20 parts of print chinaberry slag, 10 parts of edible fungi residues, 30 parts of tea seed cake, 15 parts of derris root powder, 5 parts of bacillus subtilis, 1 part of carbohydrate, potassium nitrate 1 Part, 1 part of boron element, 1 part of Zn-ef ficiency.
The preparation method of the bioorganic pesticide fertilizer, comprises the following steps.
S1:By the Java brucea dregs of fat of aforementioned proportion, print chinaberry slag, edible fungi residues, tea seed cake, derris root powder after crushing and screening after, It is stirred with chicken manure, bacillus subtilis, carbohydrate, potassium nitrate, regulation water content to 50%-65%, pH is added in whipping process To 6.5-8, C/N=25:1~30:1、C/P=80:1~120:1, obtain mixture.
S2:Solid state fermentation is carried out by trough composting system, the change of temperature and humidity in monitoring fermentation process.Work as temperature When degree is more than 70 DEG C, carry out turning over polishing working, make material fast cooling.Control bottom ventilation, makes heap body maintain 50 DEG C of high temperature above More than 7 days, until heap temperature is gradually reduced, fermentation process probably continued 15~30 days, is determined on a case-by-case basis;Treat heap body temperature Degree drops to less than 40 DEG C, adds phosphate solubilizing bacteria, ageing(Secondary fermentation)Treatment 7-15 days, heap temperature is usually no more than 50 DEG C, certain rate of venting is maintained, treat that heap temperature is dropped to close to room temperature, stop fermentation.
S3:The mixture of composting is sieved and is crushed, add boron element to mix, material is removed into superfluous water by dryer Point, it is 30% or so to control moisture content, and pack is obtained bioorganic pesticide fertilizer.
Field test:Trial crops are tomato, are carried out in Yongzhou City Dongan County vegetable cultivation base, and the canopy area tomato is withered There is serious, full canopy withered total crop failure when falling ill most heavy in disease of withering.Each experimental plot area 50m2, experiment sets treatment and compares, right Compareed and blank according to common organic fertilizer is divided into.Bioorganic pesticide fertilizer of the invention is applied in treatment, and amount of application is 800kg/ The common organic fertilizer of market purchase is applied in mu, control, and amount of application is suitable with nutrient contained by the medicine fertilizer applied, and top layer 30cm soil is mixed, and is disposably applied, Routine Management.Each treatment sets 3 repetitions.
Field test effect:Compared with check plot, treatment region tomato wilt incidence reduces by 55% in test process area, kind Eggplant biomass of individual tree improves 18%, and tomato always increases production 32%, reaches the pole level of signifiance.The relative blank of organic fertilizer control is prevented Control tomato wilt effect not notable, biomass of individual tree improves 8%.

Claims (8)

1. a kind of bioorganic pesticide fertilizer, it is characterised in that in units of weight portion, including following raw material:Chicken manure 70-90 parts, crow 30-50 parts of the courage dregs of fat, waste residue 20-40 parts, tea seed cake 20-35 parts, 10-20 parts of derris root powder, biological bacteria 5-10 parts, trace element 1-3 parts, additive 1-3 parts.
2. bioorganic pesticide fertilizer according to claim 1, it is characterised in that in units of weight portion, including following raw material: Chicken manure 75-85 parts, 35-45 parts of the Java brucea dregs of fat, waste residue 25-35 parts, tea seed cake 25-35 parts, 12-20 parts of derris root powder, biological bacteria 8-10 parts, 2-3 parts, additive 2-3 parts of trace element.
3. bioorganic pesticide fertilizer according to claim 2, it is characterised in that in units of weight portion, including following raw material: 80 parts of chicken manure, 40 parts of the Java brucea dregs of fat, 30 parts of waste residue, 30 parts of tea seed cake, 15 parts of derris root powder, 8 parts of biological bacteria, trace element 2 parts, 2 parts of additive.
4. the bioorganic pesticide fertilizer according to claim any one of 1-3, it is characterised in that the waste residue include print chinaberry slag, Bagasse, marc, edible fungi residues, sugar residue, bean dregs, acid-sludge, fecula, manioc waste, citric acid waste, soy sauce residues, residue of monosodium glutamate, beans One or more in rotten slag.
5. the bioorganic pesticide fertilizer according to claim any one of 1-3, it is characterised in that the biological bacteria includes fixed nitrogen Bacterium, bacillus, ferment bacterium, saccharomycete, actinomyces, rhizobium, phosphobacteria, B. mucilaginocus, phosphate solubilizing bacteria, chaetomium thermophilum and strepto- One or more in bacterium.
6. the bioorganic pesticide fertilizer according to claim any one of 1-3, it is characterised in that the trace element include iron, One or more in boron, manganese, copper, zinc, molybdenum, magnesium, rare earth metal.
7. the bioorganic pesticide fertilizer according to claim any one of 1-3, it is characterised in that the additive include gypsum, In lime, carbohydrate, soap powder, charcoal, activated carbon, calcium lignosulfonate, ethylenediamine tetra-acetic acid, amino acid, inorganic fertilizer one Plant or various.
8. the preparation method of a kind of bioorganic pesticide fertilizer according to claim any one of 1-7, it is characterised in that including with Lower step:
S1:By the Java brucea dregs of fat, waste residue, tea seed cake, derris root powder after crushing and screening after, be stirred with chicken manure, in whipping process Add biological bacteria, additive, regulation water content to 50%-65%, pH to 6.5-8, C/N=25:1~30:1、C/P=80:1~120:1, Obtain mixture;
S2 :Mixture is carried out into aerobic fermentation at 50-70 DEG C, ripening 7-15 days after fermenting 15-30 days;
S3:The mixture of step S2 compostings is sieved and is crushed, add mixing, dry, system after additive, trace element, biological bacteria Obtain bioorganic pesticide fertilizer.
CN201611261812.7A 2016-12-31 2016-12-31 A kind of bioorganic pesticide fertilizer and its composting method with the Java brucea dregs of fat as raw material Pending CN106748229A (en)

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CN110041116A (en) * 2019-03-01 2019-07-23 张宏亮 A kind of dedicated new bio-fertilizer of fruit trees flower plants vegetables and preparation method thereof
CN110128202A (en) * 2019-05-31 2019-08-16 襄阳农博源农业有限公司 A kind of biological organic fertilizer and preparation method thereof

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CN110041116A (en) * 2019-03-01 2019-07-23 张宏亮 A kind of dedicated new bio-fertilizer of fruit trees flower plants vegetables and preparation method thereof
CN110128202A (en) * 2019-05-31 2019-08-16 襄阳农博源农业有限公司 A kind of biological organic fertilizer and preparation method thereof

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Application publication date: 20170531