CN106699475A - Total nutrient and loosed soil type multifunctional fertilizer specially used for peanuts and production method thereof - Google Patents
Total nutrient and loosed soil type multifunctional fertilizer specially used for peanuts and production method thereof Download PDFInfo
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- CN106699475A CN106699475A CN201710101273.9A CN201710101273A CN106699475A CN 106699475 A CN106699475 A CN 106699475A CN 201710101273 A CN201710101273 A CN 201710101273A CN 106699475 A CN106699475 A CN 106699475A
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
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Abstract
The invention discloses a total nutrient and loosed soil type multifunctional fertilizer specially used for peanuts. The fertilizer is characterized by being prepared from the following raw materials in parts by weight: 23-26 parts of urea, 25-27 parts of monoammonium phosphate, 23-27 parts of potassium chloride, 3-5 parts of a silicon calcium magnesium fertilizer, 11-16 parts of clay, 1-2 parts of humic acid, 1-2 parts of polyacrylamide and 1-2 parts of a microelement auxiliary. The fertilizer product pays attention to a peanut growth soil environment, is beneficial to acicula formation and ovary enlargement of peanuts, and effectively improves the peanut yield.
Description
Technical field
The invention belongs to technical field of fertilizers, and in particular to a kind of full nutrient, the type that loosens the soil multifunctional peanut special fertilizer and its
Manufacture method.
Background technology
Peanut is China's abundance, a kind of edible extensive nut, belongs to Rosales, pulse family annual herb plant, preferably
Warmer climate, the Sandy land of moderate rainfall, the season of growth is more long, and early-maturing variety 120-130 can be divided into according to breeding time length
My god, medium variety 145 days or so, late variety 165 days or so.
China's peanut cultivation area maintains more than 60,000,000 mu, more than 13,000,000 tons of total output, with agriculture natural throughout the year
It is divided into six big main producing regions based on area, respectively northern major peanut area, southern spring and autumn Liang Shu peanut area, Yangtze river basin spring and summer peanut
Jiao Zuo areas, Yunnan-Guizhou Plateau peanut area, northeast Han Shu peanuts area and western inland peanut area.It is concentrated mainly on Shandong, Henan, river
North, Anhui and Liaoning etc. save, and account for more than the 60% of national peanut yield.
Peanut breeding time is broadly divided into seeding stage, Seedling Stage, floricome phase, five breeding times of fruiting period and swollen fruiting period.Formed
It is N 6.01-7.23Kg, P that 100Kg Pod Yields absorb N P and K amount2O5 1.21-1.84Kg、K2O 4.38-5.21Kg, N:
P2O5:K2O≈1:0.22:0.68.Additionally, Ca is the fourth element of peanut, 100kg pods inhale calsequestrin 1.5-3.5kg.Molybdenum and
Boron element is the catalyst and energy source during peanut rhizobium fixed nitrogen, and lacking molybdenum rhizobium can lose nitrogen fixing capacity, and boron deficiency is led
Cause colored and unreal.
Peanut had not only been afraid of arid but also had been afraid of accumulated water, and drought and water shortage can influence normal plants.Reduction spends number, fruit pin to bury tired
Difficulty, even if having played pin, ovary can not expand.Peanut is the drought-enduring crop of comparing, but Flood resistance is poor, and field ponding is excessive, soil
Earth lacks air, causes root system development bad, and root nodule is few, and nitrogen fixing capacity is weak, and plant jaundice is short and small, and Flower node is improved, lower pin
Difficulty, setting percentage, plumpness reduction, decayed fruit is increased, and has a strong impact on peanut yield and quality.
Current fertilizer specially for peanut is a large amount of soil is become hardened using inorganic salts with N P and K, organic matter as Main way,
Soil fertility weakens, and soil granular structure destruction is serious.Application of organic fertilizers nutrient content is low, it is impossible to which meeting peanut needs fertilizer, and peanut is given birth to
Environmental concern long it is less.
The content of the invention
To make up the deficiencies in the prior art, the present invention provide a kind of full nutrient, the type that loosens the soil multifunctional peanut special fertilizer and its
Manufacture method.
The present invention is achieved through the following technical solutions:
A kind of full nutrient, the type that loosens the soil multifunctional peanut special fertilizer, it is characterized in that:Raw material including following parts by weight:
Urea 23-26 parts
MAP 25-27 parts
Potassium chloride 23-27 parts
Silicon-calcium-magnesium fertilizer 3-5 parts
Clay 11-16 parts
Humic acid 1-2 parts
Polyacrylamide 1-2 parts
Micro- auxiliary agent 1-2 parts
The auxiliary agent is EDTA Chelated Manganeses, EDTA chelated zincs, EDTA chelated irons, boric acid, ammonium heptamolybdate, ferrous sulfate heptahydrate, one
It is several in water zinc sulphate, anhydrous cupric sulfate.
Full nutrient of the invention, the type that loosens the soil multifunctional peanut special fertilizer,
Nitrogen content >=46.2% in the urea;
Potassium content >=60% in the potassium chloride;
Effective silicon >=20%, calcium content >=20%, content of magnesium >=8.0% in the silicon-calcium-magnesium fertilizer;
Above-mentioned content is mass content;In terms of nitrogen, in terms of potassium oxide, calcium content is with calcium oxide for potassium content for wherein nitrogen content
Meter, content of magnesium is in terms of magnesia.
Further, full nutrient of the invention, the type that loosens the soil multifunctional peanut special fertilizer,
EDTA Chelated Manganeses contain manganese >=13%;
EDTA chelated zincs contain zinc >=15%;
EDTA chelated iron iron content >=13%;
Boric acid boracic >=17%;
Ammonium heptamolybdate contains molybdenum >=54%;
Ferrous sulfate heptahydrate iron content >=20%;
Monohydrate zinc sulphate contains zinc >=33%;
Anhydrous cupric sulfate cupric >=40%;
The humic acid content of organic matter >=50%.
A kind of full nutrient of the invention, the manufacture method of the type that loosens the soil multifunctional peanut special fertilizer, comprise the following steps:
(1)Clay, silicon-calcium-magnesium fertilizer, humic acid, polyacrylamide and micro- auxiliary agent are well mixed to obtain auxiliary agent group;
(2)Urea, MAP, potassium chloride, clay and auxiliary agent group are sent into comminutor, steam is passed through and is granulated;
(3)Particle enters baking roller and a chill roles after granulation, and flue-gas temperature is controlled at 500-600 DEG C;
(4)One it is cold after material sieved, finished product enter two dry roller and two chill roles, flue-gas temperature control in 200-300
DEG C, sieve after cooling;
(5)Material after cooling is packed after coating, face powder metering, as fertilizer specially for peanut.
A kind of full nutrient of the invention, the manufacture method of the type that loosens the soil multifunctional peanut special fertilizer, step(2)Middle comminutor goes out
Material mouth temperature control is at 65-80 DEG C.
A kind of full nutrient of the invention, the manufacture method of the type that loosens the soil multifunctional peanut special fertilizer, step(3)In a cold rear thing
Material temperature control is at 55-75 DEG C.
A kind of full nutrient of the invention, the manufacture method of the type that loosens the soil multifunctional peanut special fertilizer, step(4)In two cold rear things
Material temperature control is at 30-45 DEG C.
The beneficial effects of the invention are as follows:
(1)Product of the present invention focuses on peanut growth soil environment, adds high molecular reactive polyacrylamide, beneficial to pin under peanut and
Ovary increasing, improves peanut yield.
(2)High molecular reactive polyacrylamide stability is strong, can arbitrary proportion be dissolved in water, it is adaptable to acid, neutral, alkali
The various soil such as property, viscosity, sand.Can effectively nurse one's health, improve soil granular structure, eliminate soil hardening, enhancing soil oozes
Saturating ability, improves soil buffer performance, while having water conservation and hydrophobic function.
(3)Product of the present invention is, according to the rich scarce situation of national soil nutrient soil fertility, fertile critical period and maximum to be needed with reference to peanut
The Nutrient Absorption phase is formulated, and accomplishes that what different zones peanut can be real adds to lacked element, realizes that nutrient is comprehensive, loosen the soil type
Fertilizer specially for peanut.
(4)Auxiliary agent group is formulated by weight, has facilitation, the nutrient of stable equilibrium, it is ensured that nutrient between nutrient
Validity.
(5)Nitrogenous fertilizer is combined with acid amides state with ammonium nitrogen, and ammonium nitrogen can directly be absorbed by peanut, and amidonitrogen needs inverted
Could be absorbed by peanut, meet the regulation of fertilizer requirement of plant growth, improve crop quality and yield.Nonirrigated farmland using effect more preferably, is accorded with
Close the demand of water-saving agriculture.
(6)The present invention with the addition of plant growth necessary to the trace element such as zinc, manganese, boron, molybdenum, iron, crop photosynthesis can be increased
Effect, improves the activity of enzyme, enhancing root of the crop, stem, the resistance against diseases of leaf, and then improve the yield and quality of crop.
(7)Present invention addition activation mineral sources humic acid, energy improved soil structure, stimulation Peanut Root System grow, enhancing flower
Raw resistance and improving quality, have certain preventive and therapeutic effect for peanut continuous cropping disease.
Specific embodiment
With reference to specific embodiment, the present invention is further detailed explanation.
Embodiment 1
A kind of full nutrient, the type that loosens the soil multifunctional peanut special fertilizer, including following parts by weight raw material:27 parts of urea, phosphoric acid one
27 parts of ammonium, 25 parts of potassium chloride, 10 parts of clay, 3 parts of silicon-calcium-magnesium fertilizer(Effective silicon >=20%, calcium oxide >=20%, magnesia >=8.0%)、
5 parts of clay, 1 part of humic acid, 1 part of polyacrylamide, monohydrate zinc sulphate contain zinc >=33%, and ammonium heptamolybdate contains molybdenum >=54%, and boric acid contains
Boron >=17% is total 1 part.
A kind of full nutrient of the present embodiment, the manufacture method of the type that loosens the soil multifunctional peanut special fertilizer, comprise the following steps:
(1)Weigh 3 parts of silicon-calcium-magnesium fertilizer, 5 parts of clay, 1 part of humic acid, 1 part of polyacrylamide, sulfuric acid monohydrate respectively by weight
Total 1 part of zinc, ammonium heptamolybdate, three kinds of raw materials of boric acid are well mixed to obtain auxiliary agent group.
(2)Weigh 27 parts of urea, 27 parts of MAP, 25 parts of potassium chloride, 10 parts of clay and auxiliary agent group respectively by weight
11 parts feed intake entering comminutor, are passed through steam and are granulated, control material temperature and moisture, discharging opening temperature of charge
Control is at 70 DEG C.
(3)Enter one after granulation and dry roller and a chill roles, flue-gas temperature is controlled in 550 DEG C, a cold rear temperature of charge control
System is at 65 DEG C.
(4)One cold rear material is sieved, and finished product enters two and dries cold with two, and flue-gas temperature is controlled in 250 DEG C, discharging opening thing
Material temperature control sieves after cooling at 40 DEG C
(5)Material after cooling is packed after coating, face powder metering, as fertilizer specially for peanut.
The product specification that the present embodiment is obtained is N-P2O5—K2O(15.4-12.0-15.0)。
Embodiment 2
A kind of full nutrient, the type that loosens the soil multifunctional peanut special fertilizer, including following parts by weight raw material:26 parts of urea, phosphoric acid one
27 parts of ammonium, 26 parts of potassium chloride, 11 parts of clay, 4 parts of silicon-calcium-magnesium fertilizer(Effective silicon >=20%, calcium oxide >=20%, magnesia >=8.0%)、
5 parts of clay, 1 part of humic acid, 1 part of polyacrylamide, EDTA chelated zincs contain zinc >=15%, and ammonium heptamolybdate contains molybdenum >=54%, and boric acid contains
Boron >=17% is total 1 part.
A kind of full nutrient of the present embodiment, the manufacture method of the type that loosens the soil multifunctional peanut special fertilizer, comprise the following steps:
(1)Weigh 3 parts of silicon-calcium-magnesium fertilizer, 5 parts of clay, 1 part of humic acid, 1 part of polyacrylamide, sulfuric acid monohydrate respectively by weight
Total 1 part of zinc, ammonium heptamolybdate, three kinds of raw materials of boric acid are well mixed to obtain auxiliary agent group.
(2)Weigh 27 parts of urea, 27 parts of MAP, 25 parts of potassium chloride, 10 parts of clay and auxiliary agent group respectively by weight
11 parts feed intake entering comminutor, are passed through steam and are granulated, control material temperature and moisture, discharging opening temperature of charge
Control is at 65 DEG C.
(3)Enter one after granulation and dry roller and a chill roles, flue-gas temperature is controlled in 500 DEG C, a cold rear temperature of charge control
System is at 55 DEG C.
(4)One cold rear material is sieved, and finished product enters two and dries cold with two, and flue-gas temperature is controlled in 300 DEG C, discharging opening thing
Material temperature control is sieved after cooling at 30 DEG C.
(5)Material after cooling is packed after coating, face powder metering, as fertilizer specially for peanut.
The product specification that the present embodiment is obtained is N-P2O5—K2O(15.0-12.1-15.6)。
Embodiment 3
A kind of full nutrient, the type that loosens the soil multifunctional peanut special fertilizer, including following parts by weight raw material:28 parts of urea, phosphoric acid one
26 parts of ammonium, 24 parts of potassium chloride, 11 parts of clay, 3 parts of silicon-calcium-magnesium fertilizer(Effective silicon >=20%, calcium oxide >=20%, magnesia >=8.0%)、
5 parts of clay, 1 part of humic acid, 1 part of polyacrylamide agent, monohydrate zinc sulphate contain zinc >=33%, and ammonium heptamolybdate contains molybdenum >=54%, seven water
Ferrous sulfate iron content >=20% is total 1 part.
A kind of full nutrient of the present embodiment, the manufacture method of the type that loosens the soil multifunctional peanut special fertilizer, comprise the following steps:
(1)Weigh 3 parts of silicon-calcium-magnesium fertilizer, 5 parts of clay, 1 part of humic acid, 1 part of polyacrylamide, sulfuric acid monohydrate respectively by weight
Total 1 part of zinc, ammonium heptamolybdate, three kinds of raw materials of boric acid are well mixed to obtain auxiliary agent group.
(2)Weigh 27 parts of urea, 27 parts of MAP, 25 parts of potassium chloride, 10 parts of clay and auxiliary agent group respectively by weight
11 parts feed intake entering comminutor, are passed through steam and are granulated, control material temperature and moisture, discharging opening temperature of charge
Control is at 80 DEG C.
(3)Enter one after granulation and dry roller and a chill roles, flue-gas temperature is controlled in 600 DEG C, a cold rear temperature of charge control
System is at 75 DEG C.
(4)One cold rear material is sieved, and finished product enters two and dries cold with two, and flue-gas temperature is controlled at 200-300 DEG C, discharging
Mouth temperature of charge control is sieved after cooling at 45 DEG C.
(5)Material after cooling is packed after coating, face powder metering, as fertilizer specially for peanut.
The product specification that the present embodiment is obtained is N-P2O5—K2O(15.0-12.1-15.6)。
Embodiment 4
A kind of full nutrient, the type that loosens the soil multifunctional peanut special fertilizer, including following parts by weight raw material:28 parts of urea, phosphoric acid one
27 parts of ammonium, 26 parts of potassium chloride, 8 parts of clay, 3 parts of silicon-calcium-magnesium fertilizer(Effective silicon >=20%, calcium oxide >=20%, magnesia >=8.0%)、
5 parts of clay, 1 part of humic acid, 1 part of polyacrylamide, monohydrate zinc sulphate contain zinc >=33%, and ammonium heptamolybdate contains molybdenum >=54%, EDTA chelas
Close manganese total 1 part containing manganese >=13%.
A kind of full nutrient of the present embodiment, the manufacture method of the type that loosens the soil multifunctional peanut special fertilizer, comprise the following steps:
(1)Weigh 3 parts of silicon-calcium-magnesium fertilizer, 5 parts of clay, 1 part of humic acid, 1 part of polyacrylamide, sulfuric acid monohydrate respectively by weight
Total 1 part of zinc, ammonium heptamolybdate, three kinds of raw materials of boric acid are well mixed to obtain auxiliary agent group.
(2)Weigh 27 parts of urea, 27 parts of MAP, 25 parts of potassium chloride, 10 parts of clay and auxiliary agent group respectively by weight
11 parts feed intake entering comminutor, are passed through steam and are granulated, control material temperature and moisture, discharging opening temperature of charge
Control is at 75 DEG C.
(3)Enter one after granulation and dry roller and a chill roles, flue-gas temperature is controlled in 560 DEG C, a cold rear temperature of charge control
System is at 60 DEG C.
(4)One cold rear material is sieved, and finished product enters two and dries cold with two, and flue-gas temperature is controlled in 260 DEG C, discharging opening thing
Material temperature control is sieved after cooling at 40 DEG C.
(5)Material after cooling is packed after coating, face powder metering, as fertilizer specially for peanut.
The product specification that the present embodiment is obtained is N-P2O5—K2O(15.8-12.3-15.6)。
Manure trial
Experiment address:Shandong Province Junan County Ban Quan towns.
Experiment soil nutrient:Soil types is cinnamon soil, and soil nutrient content is organic matter 0.86%, alkali-hydrolyzable nitrogen 28.4mg/
Kg, rapid available phosphorus 10.6mg/Kg, available potassium 35.9mg/Kg.
For examination peanut varieties:Mountain flower No. 9.
Test process:Peanut experiment sets 6 treatment altogether, each 3 repetition for the treatment of, random district's groups arrangement.Risen by 80 centimetres
Ridge, ridge is high 25 centimetres, 150 centimetres of ridge face width, sows 2 row peanuts, and 30 centimetres of line-spacing is covered with 80 centimetres of plastic membranes.
Treatment 1(N1):Blank, does not apply fertilizer.
Treatment 2(N2):Habits fertilization, every mu of 50 kilograms of base organic fertilizer, commercially available 40 kilograms of 15-15-15 chloros fertilizer, after
Every mu of phase imposes 10 kilograms of high tower 32-4-4 fertilizer.
Treatment 3(N3):Every mu of 50 kilograms of base organic fertilizer, special fertilizer prepared by embodiment 1(15.4-12.0-15.0)40
Kilogram, every mu of later stage imposes 10 kilograms of high tower 32-4-4 fertilizer.
Treatment 4(N4):Every mu of 50 kilograms of base organic fertilizer, special fertilizer prepared by embodiment 2(15.0-12.1-15.6)40
Kilogram, every mu of later stage imposes 10 kilograms of high tower 32-4-4 fertilizer.
Treatment 5(N5):Every mu of 50 kilograms of base organic fertilizer, special fertilizer prepared by embodiment 3(15.7-12.1-14.6)40
Kilogram, every mu of later stage imposes 10 kilograms of high tower 32-4-4 fertilizer.
Treatment 6(N6):Every mu of 50 kilograms of base organic fertilizer, special fertilizer prepared by embodiment 4(15.8-12.3-15.6)40
Kilogram, every mu of later stage imposes 10 kilograms of high tower 32-4-4 fertilizer.
In the dibbling of April 20 in 2016, August was harvested peanut on the 26th within 2016, and growth period is 129 days, and July 10 topdressed one
Secondary, fertilizing type is ditch spread.Other field management measures such as irrigation, weeding, prevention and control of plant diseases, pest control are consistent between each treatment.Peanut growth
Each treatment plant height of measurement in phase, determines each treatment plant height, all kinds of fruits quality, hundred benevolence quality, kernel percent, yield respectively during results.
The peanut plant height of each treatment is measured, peanut all kinds of fruits quality, hundred benevolence quality, the yield of each treatment is measured, it is as a result as follows
Shown in table:
Preferably, 50.2 kilograms are higher by than blank, than general with N3 treatment fertilizer efficiency effect in the present invention as can be seen from the above table
Logical chloro 15-15-15 fertilizer is higher by 25.8 kilograms kilograms, and fertilizer prepared by the present invention is all remarkably higher than blank and common chlorine
Base(15-15-15), common organic fertilizer.
Claims (7)
1. a kind of full nutrient, the type that loosens the soil multifunctional peanut special fertilizer, it is characterised in that:Raw material including following parts by weight:
Urea 23-26 parts
MAP 25-27 parts
Potassium chloride 23-27 parts
Silicon-calcium-magnesium fertilizer 3-5 parts
Clay 11-16 parts
Humic acid 1-2 parts
Polyacrylamide 1-2 parts
Micro- auxiliary agent 1-2 parts
The micro- auxiliary agent is EDTA Chelated Manganeses, EDTA chelated zincs, EDTA chelated irons, boric acid, ammonium heptamolybdate, seven water sulfuric acid
It is several in ferrous iron, monohydrate zinc sulphate, anhydrous cupric sulfate.
2. a kind of full nutrient according to claim 1, the type that loosens the soil multifunctional peanut special fertilizer, it is characterised in that:
Nitrogen content >=46.2% in the urea;
Potassium content >=60% in the potassium chloride;
Effective silicon >=20%, calcium content >=20%, content of magnesium >=8.0% in the silicon-calcium-magnesium fertilizer;
Above-mentioned content is mass content;In terms of nitrogen, in terms of potassium oxide, calcium content is with calcium oxide for potassium content for wherein nitrogen content
Meter, content of magnesium is in terms of magnesia.
3. a kind of full nutrient according to claim 1, the type that loosens the soil multifunctional peanut special fertilizer, it is characterised in that:
EDTA Chelated Manganeses contain manganese >=13%;
EDTA chelated zincs contain zinc >=15%;
EDTA chelated iron iron content >=13%;
Boric acid boracic >=17%;
Ammonium heptamolybdate contains molybdenum >=54%;
Ferrous sulfate heptahydrate iron content >=20%;
Monohydrate zinc sulphate contains zinc >=33%;
Anhydrous cupric sulfate cupric >=40%;
The humic acid content of organic matter >=50%.
4. a kind of full nutrient according to claim any one of 1-3, the manufacture method of the type that loosens the soil multifunctional peanut special fertilizer,
It is characterized in that:Comprise the following steps:
(1)Clay, silicon-calcium-magnesium fertilizer, humic acid, polyacrylamide and micro- auxiliary agent are well mixed to obtain auxiliary agent group;
(2)Urea, MAP, potassium chloride, clay and auxiliary agent group are sent into comminutor, steam is passed through and is granulated;
(3)Particle enters baking roller and a chill roles after granulation, and flue-gas temperature is controlled at 500-600 DEG C;
(4)One it is cold after material sieved, finished product enter two dry roller and two chill roles, flue-gas temperature control in 200-300
DEG C, sieve after cooling;
(5)Material after cooling is packed after coating, face powder metering, as fertilizer specially for peanut.
5. a kind of full nutrient according to claim 4, the manufacture method of the type that loosens the soil multifunctional peanut special fertilizer, its feature exist
In:Step(2)Middle comminutor discharging opening temperature control is at 65-80 DEG C.
6. a kind of full nutrient according to claim 4, the manufacture method of the type that loosens the soil multifunctional peanut special fertilizer, its feature exist
In:Step(3)In a cold rear temperature of charge control at 55-75 DEG C.
7. a kind of full nutrient according to claim 4, the manufacture method of the type that loosens the soil multifunctional peanut special fertilizer, its feature exist
In:Step(4)In two cold rear temperature of charge controls at 30-45 DEG C.
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CN108976070A (en) * | 2017-06-02 | 2018-12-11 | 深圳市芭田生态工程股份有限公司 | Fertilizer specially for peanut and preparation method thereof |
CN108164370A (en) * | 2018-02-09 | 2018-06-15 | 河南心连心化肥有限公司 | A kind of special base fertilizer of peanut suitable for peanut uptake characters |
CN109438121A (en) * | 2018-12-05 | 2019-03-08 | 史丹利农业集团股份有限公司 | A kind of multifunction soil conditioning-type protecting field speciality fertilizers on commercial crops and the preparation method and application thereof |
CN112110767A (en) * | 2020-09-22 | 2020-12-22 | 史丹利农业集团股份有限公司 | Organic-inorganic compound fertilizer containing active factors and preparation and application thereof |
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