CN106632983A - 用于替代塑胶场地防水层的双组份封底材料及其制备方法 - Google Patents

用于替代塑胶场地防水层的双组份封底材料及其制备方法 Download PDF

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CN106632983A
CN106632983A CN201611270399.0A CN201611270399A CN106632983A CN 106632983 A CN106632983 A CN 106632983A CN 201611270399 A CN201611270399 A CN 201611270399A CN 106632983 A CN106632983 A CN 106632983A
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梁玲
李立强
孙清峰
李鲁中
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Shandong Inov Polyurethane Co Ltd
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Abstract

本发明属于化工技术领域，具体涉及一种用于替代塑胶场地防水层的双组份封底材料及其制备方法。用于替代塑胶场地防水层的双组份封底材料由甲组份和乙组份组成，甲组份：聚醚多元醇、催化剂、抗氧剂、紫外线吸收剂、润湿分散剂；乙组份：聚醚多元醇、异氰酸酯、填料、颜料、防尘剂。本发明产品操作时间长、固化速度适中、施工工序少、粘结性优异、环保，制备方法工艺简单、易操作。

Description

用于替代塑胶场地防水层的双组份封底材料及其制备方法
技术领域
本发明属于化工技术领域，具体涉及一种用于替代塑胶场地防水层的双组份封底材料及其制备方法。
背景技术
塑胶场地以硬度适宜、强度高、颜色艳丽美观、使用年限长等优点，自诞生之日起逐步为大家所认可，近几年铺设数量逐年提升，塑胶场地的前景也为大家所看好。如专利103013424B中所述，目前塑胶场地的施工主要分为基础施工、防水层施工、塑胶层施工这3个大部分。防水层用于塑胶场地中，可有效阻隔水气和地气的上升。在无防水层的场地，往往会因为基础水分渗透到塑胶层底部，导致塑胶层起鼓、甚至不固化，因此常规塑胶场地的施工中，防水层的制作必不可少。
专利103013424B中的产品应用有效的解决了常规封底材料固化慢、施工周期长的弊病，具有优异的施工效果，但其在不平整基础上的应用却具有局限性。以沥青基础为例，目前市场上较多沥青型塑胶基础平整度很不理想，有较多的缺陷(部分区域较整体高度低3-5mm)，由于专利103013424B产品为单组份固化产品，其一次施工厚度高于1mm以上固化速度会逐步变慢，影响施工效率，因此不适合基础明显不平整区域的铺设；如专利104497955A中的产品，其虽可一次施工较厚的厚度，但其操作时间太短(一般15-20min)；如常规环保型浆料产品，操作时间虽稍长于前者，但也一般短于30min，且粘度上升较快，摊铺后期施工效果不理想。鉴于目前国内沥青等基础的铺设水平(较多平整度不理想)，市场迫切需要一种操作时间长、固化速度适中、施工工序少、强度及粘结优异的封底材料。
发明内容
本发明的目的是提供一种用于替代塑胶场地防水层的双组份封底材料，具有操作时间长、固化速度适中、施工工序少、粘结性优异、环保的特性；本发明同时提供了用于替代塑胶场地防水层的双组份封底材料的制备方法，科学合理、简单易行。
本发明所述的用于替代塑胶场地防水层的双组份封底材料由甲组份和乙组份组成，以重量百分数计：
甲组份：
所述的甲组份中聚醚多元醇为3官能度的聚氧化丙烯三醇，数均分子量为3000-3500；优选GMN-3050S(上海高桥石油化工公司)。
所述的甲组份中催化剂为Borchi Kat22(Bayer集团公司Borchers公司生产)与Borchi Kat24(Bayer集团公司Borchers公司生产)的混合物。
所述的Borchi Kat22与Borchi Kat24的质量比为1:1。
所述的甲组份中抗氧剂为硫代二亚乙基双[3-(3,5-二叔丁基-4-羟基苯)丙酸酯]，紫外线吸收剂为2-(2H-苯并三唑基-2)-4,6-二叔戊基苯酚。
所述的甲组份中润湿分散剂为BYK-306(德国BYK化学公司生产)。
所述的乙组份中聚醚多元醇为3官能度的聚氧化丙烯三醇，数均分子量为4500-6500；优选GEP-330NY(上海高桥石油化工公司)。
所述的乙组份中异氰酸酯为二苯基甲烷二氰酸酯，优选MDI-50(烟台万华聚氨酯股份有限公司)。
所述的乙组份中填料为滑石粉，优选1250目滑石粉；颜料为氧化铁红；防尘剂为硅微粉，优选600目硅微粉。
本发明所述的用于替代塑胶场地防水层的双组份封底材料的制备方法，步骤如下：
(1)甲组份的制备：
将聚醚多元醇投入反应釜中，搅拌下依次加入抗氧剂和紫外线吸收剂，升温至90-100℃，保持此温度20min，降温至30-40℃，加入催化剂、润湿分散剂，搅拌20-30min，装桶；
(2)乙组份的制备：
将聚醚多元醇投入反应釜中，搅拌下依次加入填料、颜料、防尘剂，升温至90-100℃，真空脱水1-2h，至水分0.5-0.8‰，降温至30-40℃，加入异氰酸酯，85-90℃反应2-3h，装桶。
施工时，按照甲组份：乙组份＝1:1质量比混合搅拌均匀后刮涂于基础上(用量根据基础情况确定，一般用量为1-2kg/㎡)固化后，进行后续塑胶层的施工即可。
本发明与现有技术相比，具有如下有益效果：
(1)产品操作时间长(1.5h以上)，固化速度适中(16-24h固化)。选取合适聚醚及异氰酸酯，设计合理配方，并选取具有“前快后慢”特性的催化剂(即催化体系操作时间长，固化时间短)；同时选取合适的填料及防尘剂，同催化剂混合后粘度明显降低，一定程度上提高了操作效果，且不影响固化时间。综合两方面因素使得产品操作时间长，固化速度适中的效果。
(2)施工工序少(一次摊铺)、粘结性优异、环保。产品一次摊铺厚度可达20mm以上，可满足国内所有基础的封底；另选取优异的润湿分散剂，保证了产品同基础层及塑胶层的粘结效果优异性；本产品同时选取MDI-50等环保型原材料，制品环保无味。
(3)本发明同时提供其制备方法，工艺简单，易操作。
具体实施方式
以下结合实施例对本发明做进一步描述。
实施例中用到的所有原料除特殊说明外，均为市购。
实施例1
(1)甲组份：
在烧瓶中加入聚醚多元醇GMN-3050S 930g，搅拌下依次加入硫代二亚乙基双[3-(3,5-二叔丁基-4-羟基苯)丙酸酯]10g，2-(2H-苯并三唑基-2)-4,6-二叔戊基苯酚10g，升温至90℃，保持此温度20min，降温至30℃，加入Borchi Kat22 15g、Borchi Kat22 15g、BYK-306 20g，搅拌30min，装瓶。
(2)乙组份：
在烧瓶中加入聚醚多元醇GEP-330NY 450g，搅拌下依次加入1250目滑石粉190g、氧化铁红40g、600目硅微粉20g，升温至90℃，真空脱水2h，至水分0.5‰，降温至30℃，加入MDI-50 300g，85℃反应3h，装瓶。
(3)施工时，按照甲组份：乙组份＝1:1质量比混合搅拌均匀后刮涂于基础上(用量根据基础情况确定，一般用量为1-2kg/㎡)固化后，进行后续塑胶层的施工即可。
实施例2
(1)甲组份：
在烧瓶中加入聚醚多元醇GMN-3050S 950g，搅拌下依次加入硫代二亚乙基双[3-(3,5-二叔丁基-4-羟基苯)丙酸酯]5g，2-(2H-苯并三唑基-2)-4,6-二叔戊基苯酚5g，升温至100℃，保持此温度20min，降温至40℃，加入Borchi Kat22 5g、Borchi Kat22 5g、BYK-306 30g，搅拌20min，装瓶。
(2)乙组份：
在烧瓶中加入聚醚多元醇GEP-330NY 550g，搅拌下依次加入1250目滑石粉140g、氧化铁红50g、600目硅微粉10g，升温至100℃，真空脱水1h，至水分0.8‰，降温至40℃，加入MDI-50 250g，90℃反应2h，装瓶。
(3)施工时，按照甲组份：乙组份＝1:1质量比混合搅拌均匀后刮涂于基础上(用量根据基础情况确定，一般用量为1-2kg/㎡)固化后，进行后续塑胶层的施工即可。
实施例3
(1)甲组份：
在烧瓶中加入聚醚多元醇GMN-3050S 960g，搅拌下依次加入硫代二亚乙基双[3-(3,5-二叔丁基-4-羟基苯)丙酸酯]7g，2-(2H-苯并三唑基-2)-4,6-二叔戊基苯酚7g，升温至95℃，保持此温度20min，降温至35℃，加入Borchi Kat22 8g、Borchi Kat22 8g、BYK-30610g，搅拌25min，装瓶。
(2)乙组份：
在烧瓶中加入聚醚多元醇GEP-330NY 470g，搅拌下依次加入1250目滑石粉155g、氧化铁红100g、600目硅微粉15g，升温至95℃，真空脱水1.5h，至水分0.7‰，降温至35℃，加入MDI-50 260g，88℃反应2.5h，装瓶。
(3)施工时，按照甲组份：乙组份＝1:1质量比混合搅拌均匀后刮涂于基础上(用量根据基础情况确定，一般用量为1-2kg/㎡)固化后，进行后续塑胶层的施工即可。
将实施例1-3得到的产品与市场上常规浆料产品进行物理性能测试，结果见表1。
表1实施例1-3得到的产品与市场上常规浆料产品的物理性能测试结果
由表1可以看出，一种用于替代塑胶场地防水层的双组份封底材料操作时间明显优于常规浆料产品，固化时间适中；可施工厚度高、施工粘结强度高，施工效果优异，能很好满足市场需求。

Claims (10)

1.一种用于替代塑胶场地防水层的双组份封底材料，其特征在于由甲组份和乙组份组成，以重量百分数计：
甲组份：
乙组份：
2.根据权利要求1所述的用于替代塑胶场地防水层的双组份封底材料，其特征在于所述的甲组份中聚醚多元醇为3官能度的聚氧化丙烯三醇，数均分子量为3000-3500。
3.根据权利要求1所述的用于替代塑胶场地防水层的双组份封底材料，其特征在于所述的甲组份中催化剂为Borchi Kat22与Borchi Kat24的混合物。
4.根据权利要求3所述的用于替代塑胶场地防水层的双组份封底材料，其特征在于所述的Borchi Kat22与Borchi Kat24的质量比为1:1。
5.根据权利要求1所述的用于替代塑胶场地防水层的双组份封底材料，其特征在于所述的甲组份中抗氧剂为硫代二亚乙基双[3-(3,5-二叔丁基-4-羟基苯)丙酸酯]，紫外线吸收剂为2-(2H-苯并三唑基-2)-4,6-二叔戊基苯酚。
6.根据权利要求1所述的用于替代塑胶场地防水层的双组份封底材料，其特征在于所述的甲组份中润湿分散剂为BYK-306。
7.根据权利要求1所述的用于替代塑胶场地防水层的双组份封底材料，其特征在于所述的乙组份中聚醚多元醇为3官能度的聚氧化丙烯三醇，数均分子量为4500-6500。
8.根据权利要求1所述的用于替代塑胶场地防水层的双组份封底材料，其特征在于所述的乙组份中异氰酸酯为二苯基甲烷二氰酸酯。
9.根据权利要求1所述的用于替代塑胶场地防水层的双组份封底材料，其特征在于所述的乙组份中填料为滑石粉，颜料为氧化铁红，防尘剂为硅微粉。
10.一种权利要求1-9任一所述的用于替代塑胶场地防水层的双组份封底材料的制备方法，其特征在于步骤如下：
(1)甲组份的制备：
将聚醚多元醇投入反应釜中，搅拌下依次加入抗氧剂和紫外线吸收剂，升温至90-100℃，保持此温度20min，降温至30-40℃，加入催化剂、润湿分散剂，搅拌20-30min，装桶；
(2)乙组份的制备：
将聚醚多元醇投入反应釜中，搅拌下依次加入填料、颜料、防尘剂，升温至90-100℃，真空脱水1-2h，至水分0.5-0.8‰，降温至30-40℃，加入异氰酸酯，85-90℃反应2-3h，装桶。
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111690119A (zh) * 2020-07-27 2020-09-22 山东蓝岳新材料科技有限公司 一种聚氨酯塑胶材料及其制备方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102786658A (zh) * 2012-08-23 2012-11-21 山东东大一诺威聚氨酯有限公司 用于塑胶场地慢跑区的聚氨酯组合物及其制备方法
CN103013424A (zh) * 2012-12-21 2013-04-03 山东东大一诺威聚氨酯有限公司 用于替代塑胶场地防水层的聚氨酯粘合剂及其制备方法
CN103642381A (zh) * 2013-12-09 2014-03-19 山东一诺威聚氨酯股份有限公司 用于储罐外层防护的聚氨酯弹性体组合料及其制备方法
CN104194606A (zh) * 2014-08-13 2014-12-10 山东一诺威聚氨酯股份有限公司 用于塑胶跑道的聚氨酯双组份封底材料及其制备方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102786658A (zh) * 2012-08-23 2012-11-21 山东东大一诺威聚氨酯有限公司 用于塑胶场地慢跑区的聚氨酯组合物及其制备方法
CN103013424A (zh) * 2012-12-21 2013-04-03 山东东大一诺威聚氨酯有限公司 用于替代塑胶场地防水层的聚氨酯粘合剂及其制备方法
CN103642381A (zh) * 2013-12-09 2014-03-19 山东一诺威聚氨酯股份有限公司 用于储罐外层防护的聚氨酯弹性体组合料及其制备方法
CN104194606A (zh) * 2014-08-13 2014-12-10 山东一诺威聚氨酯股份有限公司 用于塑胶跑道的聚氨酯双组份封底材料及其制备方法

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111690119A (zh) * 2020-07-27 2020-09-22 山东蓝岳新材料科技有限公司 一种聚氨酯塑胶材料及其制备方法

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