CN106631164A - Glass-ceramic tile preparation method - Google Patents
Glass-ceramic tile preparation method Download PDFInfo
- Publication number
- CN106631164A CN106631164A CN201510718598.2A CN201510718598A CN106631164A CN 106631164 A CN106631164 A CN 106631164A CN 201510718598 A CN201510718598 A CN 201510718598A CN 106631164 A CN106631164 A CN 106631164A
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- CN
- China
- Prior art keywords
- ceramic tile
- glass
- base substrate
- preparation
- devitrified glass
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
- C04B41/5023—Glass-ceramics
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Finishing Walls (AREA)
Abstract
The invention relates to a glass-ceramic tile preparation method, which comprises: A, spreading a powder material in the mold cavity of the lower mold of a stamping mold, carrying out stamping pressing by using an upper mold to obtain a billet having an edge enclosing ring structure, and transferring the billet so as to be spare, wherein the stamping surface of the upper mold is provided with a boss, the area of the boss is smaller than the material distribution area of the mold cavity of the lower mold, and the edge enclosing ring circles the surface of the billet to form a material distribution cavity; B, drying the billet obtained in the step A, and arranging glass-ceramic molten block or flaky glass-ceramic in the material distribution cavity; C, placing the billet obtained in the step B into a kiln, and firing to obtain a billet having a glass-ceramic layer; and D, polishing and burnishing, wherein the fired ceramic tile is subjected to polishing and burnishing to obtain the glass-ceramic tile. According to the glass-ceramic tile prepared through the method of the present invention, the thickness of the glass-ceramic layer is increased, and the three-dimensional color decoration effect of the surface of the glass-ceramic tile is improved.
Description
Technical field
The present invention relates to architectural pottery technical field, more particularly to a kind of preparation method of devitrified glass ceramic tile.
Background technology
Devitrified glass ceramic tile, its is glittering and translucent, with growing and change unusual imitative bag reason, color naturally
The exterior decorative effect of color distinct level, it is easy to clean, good physical and chemical performance, with more higher than stone material
Weather proofing, against weather;Its mechanical strength is big, toughness is strong, impact resistance is good, resistance to chemical attack
Performance is high, and comprehensive acid-fast alkali-proof performance is better than pure crystallizing glass sheet material, and devitrified glass ceramic tile is also reduction plate
The weight of material provides possibility with the application for widening skyscraper, therefore is favored by building materials market deeply.
But at present because four sides of ceramic tile blank are typically single plane, therefore cloth is carried out in glass-ceramic layer
When, when carrying out the Laminited charity of glass ceramics frit, can be affected by the proportion of liquid or mobility,
And cause the finite thickness of the glass-ceramic layer of current devitrified glass ceramic tile, its thickness generally all in below 3mm,
And its surface smoothness is not enough, therefore the mirror effect of the devitrified glass ceramic tile of production and third dimension is spent thoroughly at present
Not strong, decorative effect is single, there are water ripples.
The content of the invention
It is an object of the invention to propose a kind of preparation of the devitrified glass ceramic tile for increasing glass-ceramic layer thickness
Method.
It is that, up to this purpose, the present invention is employed the following technical solutions:.
A kind of preparation method of devitrified glass ceramic tile, comprises the following steps:
A, powder is layed in the die cavity of lower mould of stamping mold, is obtained by upper punch pressure compacting and there is surrounding edge
The base substrate of ring structure, the stamping surface of the upper mould is provided with boss, and the area of the boss is less than the lower mould
Die cavity cloth area, the surrounding edge ring the base substrate surface loop around formed distribution cavity, shift base substrate
It is standby;
It is micro- to its cloth intracavity charity glass ceramics frit or lamellar after B, the body drying for obtaining step A
Crystal glass;
The base substrate kiln-firing of C, the glass ceramics frit of charity for being obtained step B, burns till with crystallite
The base substrate of glassy layer;
D, polishing grinding:By the ceramic tile after burning till, polishing is polished, obtains devitrified glass ceramic tile.
Illustrate further, the base substrate to suppressing carries out pattern decorative makes base substrate obtain pattern texture, described
Pattern decorative is the superposition of one or more decorating methods, and the decorating method is silk-screen, cylinder, ink-jet,
Cloth glaze, cloth slurry etc., carry out again charity clear frit or transparent glass-ceramics frit after pattern decorative.
Further illustrate, the height of the distribution cavity is 3-10mm.
Preferably, the polishing grinding of step D also includes cutting action, will burn till enclosing for the ceramic tile of acquisition
The cutting of side ring structure is removed.
Further illustrate, the charity of the glass ceramics frit is more than two-layer or two-layer.
Further illustrate, the glass ceramics frit is the devitrified glass of transparent glass ceramics frit or colour
Frit.
Further illustrate, the sheet-like crystallite glass contains crystallize body.
Preferably, the base substrate after the compacting of step A is before into step B, by throwing blank process or roll process
The surface of the base substrate is provided with textured pattern.
Preferably, the glass ceramics frit in step B is transparent glass ceramics frit, in step A
The stamping surface of the upper mould of the stamping mold for using is additionally provided with textured pattern.
Further illustrate, the distribution cavity is provided with boundary projection, and forms multiple by the boundary bulge clearance
Cloth point chamber.
Beneficial effects of the present invention:The present invention in the production of devitrified glass ceramic tile, the base substrate for using have enclose
Side ring and cloth cavity configuration, the thickness of the glass ceramics frit of institute's charity is surround the distribution cavity for being formed by surrounding edge ring
Interior height is determined, because liquid is restricted to cloth intracavity, different from common no surrounding edge ring and cloth
The base substrate of cavity configuration, often because the proportion or mobility of liquid, cause the thickness of glass-ceramic layer cannot
Paving is thick, and instant invention overcomes its defect, increases the charity thickness of the prepared glass-ceramic layer for obtaining.By
In the thicker of glass-ceramic layer, then the mirror effect of ceramic tile and saturating degree third dimension are stronger, described so as to enhance
The thickness of the glass-ceramic layer of microcrystal glass plate ceramic tile, and the water ripples defect of ceramic tile is also slighter;With micro-
The charity thickness of crystal glass frit increases, and also improves the three-dimensional polychromy on the surface of devitrified glass ceramic tile.
Description of the drawings
Fig. 1 is the structural representation of the stamping mold of one embodiment of the invention and base substrate;
Fig. 2 is a kind of structural representation of devitrified glass ceramic tile of the invention;
Fig. 3 is the structural representation of the devitrified glass ceramic tile of various embodiments of the present invention;
Fig. 4 is flow chart prepared by a kind of production of devitrified glass ceramic tile of one embodiment of the invention;
Fig. 5 is flow chart prepared by a kind of production of devitrified glass ceramic tile of one embodiment of the invention;
Wherein:Stamping mold 1, lower mould 11, upper mould 12, base substrate 2, surrounding edge ring 21, distribution cavity 22, point
Boundary's projection 23, cloth point chamber 24, textured pattern 25, glass-ceramic layer 3.
Specific embodiment
Further illustrate technical scheme below in conjunction with the accompanying drawings and by specific embodiment.
As shown in figure 1, a kind of preparation method of devitrified glass ceramic tile, comprises the following steps:
A, powder is layed in the die cavity of lower mould 11 of stamping mold 1, is obtained by the punching press of upper mould 12 compacting
Base substrate 2 with the structure of surrounding edge ring 21, the stamping surface of the upper mould 12 is provided with boss, the face of the boss
Product is less than the cloth area of the die cavity of the lower mould 11, surface loop of the surrounding edge ring 21 in the base substrate 2
Around distribution cavity 22 is formed, transfer base substrate 2 is standby;
B, by step A obtain base substrate 2 be dried after, into its distribution cavity 22 charity glass ceramics frit or
Sheet-like crystallite glass;
The kiln-firing of base substrate 2 of C, the glass ceramics frit of charity 3 for being obtained step B, burns till and has
The base substrate of glass-ceramic layer 3;
D, polishing grinding:By the ceramic tile after burning till, polishing is polished, obtains devitrified glass ceramic tile.
In the production of devitrified glass ceramic tile, the base substrate 2 for using has surrounding edge ring 21 and distribution cavity 22 to the present invention
Structure, the thickness of the glass ceramics frit of institute's charity is surround the height in the distribution cavity 22 for being formed by surrounding edge ring 21
Degree is determined, because liquid is restricted in distribution cavity 22, different from common no surrounding edge ring and distribution cavity knot
The base substrate of structure, often because the proportion or mobility of liquid, causing the thickness of glass-ceramic layer 3 cannot spread
Thickness, and instant invention overcomes its defect, increases the charity thickness of the prepared glass-ceramic layer 3 for obtaining.By
In the thicker of glass-ceramic layer 3, then the mirror effect of ceramic tile and saturating degree third dimension are stronger, so as to enhance
The thickness of the glass-ceramic layer 3 of microcrystal glass plate ceramic tile is stated, and the water ripples defect of ceramic tile is also slighter;With
The charity thickness of glass ceramics frit increases, and also improves the three-dimensional illuminated effect on the surface of devitrified glass ceramic tile
Really.
Further description, the height of the distribution cavity 22 is 3-10mm.The setting of the height of distribution cavity 22
The thickness of glass-ceramic layer 3 is determined, therefore the height of distribution cavity is set in 3-10mm, it is ensured that crystallite glass
The charity thickness of glass frit, so as to improve the saturating degree third dimension and decorative effect of devitrified glass ceramic tile.
Further description, the polishing grinding of step D also includes cutting action, will burn till acquisition
The structure of surrounding edge ring 21 cutting of ceramic tile is removed.Can be prepared into after the structure of surrounding edge ring 21 is cut micro- with market
The similar ceramic tile of crystal glass ceramic tile structure, difference be the present invention prepare ceramic tile, its glass-ceramic layer 3
Thickness it is bigger than the thickness of original devitrified glass ceramic tile, and product qualified rate of its production is higher, reduces
The appearance of substandard products.
Further description, the charity of the glass ceramics frit is more than two-layer or two-layer.By crystallite glass
Glass frit with Laminited ground charity in the distribution cavity 22, with the increase of the glass ceramics frit charity number of plies,
Then increase the thickness of glass-ceramic layer 3, so as to improve the three-dimensional polychromy of devitrified glass ceramic tile.
Further description, the glass ceramics frit is the crystallite of transparent glass ceramics frit or colour
Glass frit can obtain transparent glass-ceramics layer 3 from charity transparent glass-ceramics frit, make devitrified glass ceramic tile
With certain three-dimensional transparent effect, the decorative effect of devitrified glass ceramic tile is improved.
The sheet-like crystallite glass contains crystallize body, when carrying out cloth chamber using sheet-like crystallite glass, can be layered cloth
Material, the crystallize composition inside the devitrified glass of its lamellar can when every layer of devitrified glass between with crystallize texture
The connection of shape so as to which the decorative effect of glass-ceramic layer more enriches, can form cotton-shaped texture.
Further description, step A compacting after base substrate 2 before into step B, by pattern decorative
The surface of the base substrate 2 is provided with textured pattern 25.
The pattern decorative is the superposition of one or more decorating methods, the decorating method be silk-screen, cylinder,
Ink-jet, cloth glaze, cloth slurry etc., carry out again charity clear frit or transparent glass-ceramics frit after pattern decorative.
Further description, the glass ceramics frit in step B is transparent glass ceramics frit,
The stamping surface of the upper mould 12 of the stamping mold 1 used in step A is additionally provided with textured pattern.By upper mould
Process after the textured pattern design of 12 stamping surfaces or compacting, makes the surface of base substrate 2 have textured pattern, with reference to
Certain thickness transparent glass-ceramics layer 3, the enhanced visual effect for burning till rear brick face, abundant devitrified glass
The decorative effect of ceramic tile.
The distribution cavity 22 is partitioned into multiple cloth point chambers 24 by boundary raised 23, the boundary raised 23
Height is highly consistent with surrounding edge ring 21.Boundary raised 23 is provided with the inside of distribution cavity 22 form multiple cloth
Material point chamber 24, is capable of achieving the cloth of different cavity, realizes the devitrified glass ceramic tile with splicing effect, in addition,
Also its stitching portion can be cut, brick body is split, be suitable for it is various sizes of install and use, point
The design of boundary's projection 23 makes its cutting not affect brick face decorative effect.
Embodiment 1
As shown in figure 4, a kind of preparation method of nontransparent devitrified glass ceramic tile:
A, as shown in figure 1, powder is layed in the die cavity of lower mould 11 of stamping mold 1, by upper mould 12
Punching press compacting obtains the base substrate 2 with the structure of surrounding edge ring 21, and the stamping surface of the upper mould 12 is provided with boss,
, less than the cloth area of the die cavity of the lower mould 11, the surrounding edge ring 21 is in the base for the area of the boss
Around distribution cavity 22 is formed, the height of its distribution cavity 22 is 6mm to the surface loop of body 2, and transfer base substrate 2 is standby;
B, by step A obtain base substrate 1 be dried after, 2 layers of charity is nontransparent micro- into its distribution cavity 22
Crystal glass frit, wherein per layer of thickness is 3mm;
The kiln-firing of base substrate 2 of C, the nontransparent glass ceramics frit 3 of the charity for being obtained step B,
Burn till the base substrate with glass-ceramic layer 3;
D, polishing grinding:By the ceramic tile after burning till, polishing is polished, obtains nontransparent devitrified glass porcelain
Brick, as shown in Figure 2.
Embodiment 2
A kind of preparation method of the transparent devitrified glass ceramic tile with textured pattern:
A, powder is layed in the die cavity of lower mould 11 of stamping mold 1, the stamping mold 1 for using it is upper
The stamping surface of mould 12 is provided with textured pattern, is obtained by the punching press of upper mould 12 compacting and there is surrounding edge ring 21 to tie
The base substrate 2 of structure, the stamping surface of the upper mould 12 is provided with boss, and the area of the boss is less than the lower mould
The cloth area of 11 die cavity, the surrounding edge ring 21 the base substrate 2 surface loop around formed distribution cavity 22,
The height of its distribution cavity 22 is 8mm, and the surface of the base substrate 2 is provided with textured pattern by roll process
25, transfer base substrate 2 is standby;
B, by step A obtain base substrate 1 be dried after, 2 layers of transparent crystallite of charity into its distribution cavity 22
Glass frit, wherein per layer of thickness is 4mm;
The kiln-firing of base substrate 2 of C, the glass ceramics frit of charity 3 for being obtained step B, burns till and has
The base substrate of glass-ceramic layer 3;
D, polishing grinding:By the ceramic tile after burning till, polishing is polished, obtains transparent with textured pattern
Devitrified glass ceramic tile.
Embodiment 3
A kind of preparation method of the devitrified glass ceramic tile with splicing effect:
A, powder is layed in the die cavity of lower mould 11 of stamping mold 1, the stamping mold 1 for using it is upper
The stamping surface of mould 12 is provided with textured pattern, is obtained by the punching press of upper mould 12 compacting and there is surrounding edge ring 21 to tie
The base substrate 2 of structure, the stamping surface of the upper mould 12 is provided with boss, and the area of the boss is less than the lower mould
The cloth area of 11 die cavity, the surrounding edge ring 21 the base substrate 2 surface loop around formed distribution cavity 22,
The height of its distribution cavity 22 is 8mm, and the distribution cavity 22 is partitioned into the cloth of contoured shape by boundary raised 23
Divide chamber 24, the height of the boundary raised 23 is highly consistent with surrounding edge ring 21, by roll process in institute
The surface for stating base substrate 2 is provided with textured pattern 25, and transfer base substrate 2 is standby;
B, the base substrate 1 that step A is obtained is dried after, the charity sheet-like crystallite glass into its cloth point chamber 24;
The kiln-firing of base substrate 2 of C, the glass ceramics frit of charity 3 for being obtained step B, burns till and has
The base substrate of glass-ceramic layer 3;
D, polishing grinding:By the ceramic tile after burning till, polishing is polished, obtains the crystallite with splicing effect
Glass ceramic tile.
Supplementary notes, the boundary raised 23, can be with addition to the cloth point chamber 24 for being partitioned into contoured shape
The cloth point chamber 24 of the various shapes such as grid, hydrosphere, polygon is formed, it is combined with the textured pattern 25,
The devitrified glass ceramic tile with splicing effect is realized, the multiformity of the decoration of devitrified glass ceramic tile is increased, such as
Shown in Fig. 3.By the preparation of a ceramic tile, when follow-up paving is used, segmentation can be carried out to it and be used, be adapted to
Property is strong.
Embodiment 4
As shown in figure 5, a kind of preparation method of the transparent devitrified glass ceramic tile without surrounding edge ring 21:
A, powder is layed in the die cavity of lower mould 11 of stamping mold 1, is obtained by the punching press of upper mould 12 compacting
Base substrate 2 with the structure of surrounding edge ring 21, the stamping surface of the upper mould 12 is provided with boss, the face of the boss
Product is less than the cloth area of the die cavity of the lower mould 11, surface loop of the surrounding edge ring 21 in the base substrate 2
Around distribution cavity 22 is formed, the height of its distribution cavity 22 is 10mm, and transfer base substrate 2 is standby;
B, by step A obtain base substrate 1 be dried after, 5 layers of transparent crystallite of charity into its distribution cavity 22
Glass frit, wherein per layer of thickness is 2mm;
The kiln-firing of base substrate 2 of C, the glass ceramics frit of charity 3 for being obtained step B, burns till and has
The base substrate of glass-ceramic layer 3;
D, cutting and polishing grinding:By the ceramic tile after burning till, its surrounding edge ring 21 is cut into removal, then carried out
Polishing grinding, obtains the transparent devitrified glass ceramic tile without surrounding edge ring 21, as shown in Figure 2.
The know-why of the present invention is described above in association with specific embodiment.These descriptions are intended merely to explain this
The principle of invention, and can not by any way be construed to limiting the scope of the invention.Based on herein
Explain, those skilled in the art associates other tools of the present invention by need not paying performing creative labour
Body embodiment, these modes are fallen within protection scope of the present invention.
Claims (9)
1. a kind of preparation method of devitrified glass ceramic tile, it is characterised in that:Comprise the following steps:
A, powder is layed in the die cavity of lower mould of stamping mold, is obtained by upper punch pressure compacting and there is surrounding edge
The base substrate of ring structure, the stamping surface of the upper mould is provided with boss, and the area of the boss is less than the lower mould
Die cavity cloth area, the surrounding edge ring the base substrate surface loop around formed distribution cavity, shift base substrate
It is standby;
After B, the body drying for obtaining step A, to its cloth intracavity charity glass ceramics frit or lamellar
Devitrified glass;
The base substrate kiln-firing of C, the glass ceramics frit of charity for being obtained step B, burns till with micro-
The base substrate of crystal glass layer;
D, polishing grinding:By the ceramic tile after burning till, polishing is polished, obtains devitrified glass ceramic tile.
2. a kind of preparation method of devitrified glass ceramic tile according to claim 1, it is characterised in that:It is described
The height of distribution cavity is 3-10mm.
3. a kind of preparation method of devitrified glass ceramic tile according to claim 1, it is characterised in that:It is described
The polishing grinding of step D also includes cutting action, the surrounding edge ring structure for burning till the ceramic tile of acquisition is cut and is removed.
4. a kind of preparation method of devitrified glass ceramic tile according to claim 1, it is characterised in that:It is described
Glass ceramics frit charity is more than two-layer or two-layer.
5. a kind of preparation method of devitrified glass ceramic tile according to claim 1, it is characterised in that:It is described
Glass ceramics frit is the glass ceramics frit of transparent glass ceramics frit or colour.
6. a kind of preparation method of devitrified glass ceramic tile according to claim 1, it is characterised in that:It is described
Sheet-like crystallite glass contains crystallize body.
7. a kind of preparation method of devitrified glass ceramic tile according to claim 5, it is characterised in that:Step
Base substrate after A compactings before into step B, by throwing blank process or roll process on the surface of the base substrate
It is provided with textured pattern.
8. a kind of preparation method of devitrified glass ceramic tile according to claim 5, it is characterised in that:It is described
Glass ceramics frit in step B is transparent glass ceramics frit, the stamping mold used in step A
The stamping surface of upper mould is additionally provided with textured pattern.
9. a kind of preparation method of devitrified glass ceramic tile according to claim 1, it is characterised in that:It is described
Distribution cavity is provided with boundary projection, and forms multiple cloth point chambers by the boundary bulge clearance.
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CN201510718598.2A CN106631164A (en) | 2015-10-28 | 2015-10-28 | Glass-ceramic tile preparation method |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN108298953A (en) * | 2018-01-31 | 2018-07-20 | 佛山市金牛陶瓷有限公司 | The reeded polished bricks production technology of burnishing surface band, mould structure and polished bricks |
CN110156494A (en) * | 2019-06-17 | 2019-08-23 | 佛山市东鹏陶瓷有限公司 | A kind of preparation method of microcrystal composite board |
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CN1537709A (en) * | 2003-04-17 | 2004-10-20 | 潮 何 | Production technology of polished brick with embedded pattern polished brick manufactural using said technology |
CN102775074A (en) * | 2012-08-13 | 2012-11-14 | 广东金牌陶瓷有限公司 | Method for producing microcrystal glass ceramics composite board |
CN104261882A (en) * | 2014-09-23 | 2015-01-07 | 佛山市禾才科技服务有限公司 | Green brick of one-step sintered glass-ceramic composite board |
CN104291877A (en) * | 2014-09-23 | 2015-01-21 | 佛山市禾才科技服务有限公司 | Preparation method of single fired glass ceramic composite board |
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Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN1537709A (en) * | 2003-04-17 | 2004-10-20 | 潮 何 | Production technology of polished brick with embedded pattern polished brick manufactural using said technology |
CN102775074A (en) * | 2012-08-13 | 2012-11-14 | 广东金牌陶瓷有限公司 | Method for producing microcrystal glass ceramics composite board |
CN104261882A (en) * | 2014-09-23 | 2015-01-07 | 佛山市禾才科技服务有限公司 | Green brick of one-step sintered glass-ceramic composite board |
CN104291877A (en) * | 2014-09-23 | 2015-01-21 | 佛山市禾才科技服务有限公司 | Preparation method of single fired glass ceramic composite board |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN108298953A (en) * | 2018-01-31 | 2018-07-20 | 佛山市金牛陶瓷有限公司 | The reeded polished bricks production technology of burnishing surface band, mould structure and polished bricks |
CN110156494A (en) * | 2019-06-17 | 2019-08-23 | 佛山市东鹏陶瓷有限公司 | A kind of preparation method of microcrystal composite board |
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Application publication date: 20170510 |