CN106611797A - Power device with local metal service life control and manufacturing method thereof - Google Patents

Power device with local metal service life control and manufacturing method thereof Download PDF

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Publication number
CN106611797A
CN106611797A CN201510695743.XA CN201510695743A CN106611797A CN 106611797 A CN106611797 A CN 106611797A CN 201510695743 A CN201510695743 A CN 201510695743A CN 106611797 A CN106611797 A CN 106611797A
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Prior art keywords
power device
substrate
energy level
deep
deep energy
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Inventor
吴迪
刘钺杨
何延强
董少华
曹功勋
刘江
金锐
温家良
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State Grid Corp of China SGCC
State Grid Shanghai Electric Power Co Ltd
Smart Grid Research Institute of SGCC
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State Grid Corp of China SGCC
State Grid Shanghai Electric Power Co Ltd
Smart Grid Research Institute of SGCC
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Priority to CN201510695743.XA priority Critical patent/CN106611797A/en
Publication of CN106611797A publication Critical patent/CN106611797A/en
Pending legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/86Types of semiconductor device ; Multistep manufacturing processes therefor controllable only by variation of the electric current supplied, or only the electric potential applied, to one or more of the electrodes carrying the current to be rectified, amplified, oscillated or switched
    • H01L29/861Diodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic System or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/26Bombardment with radiation
    • H01L21/263Bombardment with radiation with high-energy radiation
    • H01L21/268Bombardment with radiation with high-energy radiation using electromagnetic radiation, e.g. laser radiation
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/02Semiconductor bodies ; Multistep manufacturing processes therefor
    • H01L29/06Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions
    • H01L29/0684Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions characterised by the shape, relative sizes or dispositions of the semiconductor regions or junctions between the regions
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/02Semiconductor bodies ; Multistep manufacturing processes therefor
    • H01L29/12Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed
    • H01L29/16Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed including, apart from doping materials or other impurities, only elements of Group IV of the Periodic System
    • H01L29/167Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed including, apart from doping materials or other impurities, only elements of Group IV of the Periodic System further characterised by the doping material
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/66007Multistep manufacturing processes
    • H01L29/66075Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
    • H01L29/66083Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by variation of the electric current supplied or the electric potential applied, to one or more of the electrodes carrying the current to be rectified, amplified, oscillated or switched, e.g. two-terminal devices
    • H01L29/6609Diodes

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  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • High Energy & Nuclear Physics (AREA)
  • Electromagnetism (AREA)
  • Optics & Photonics (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Thyristors (AREA)

Abstract

The invention relates to a power device with local metal service life control and a manufacturing method thereof. The power device comprises a substrate and a PN junction together formed by P+ areas formed on the substrate; an oxide layer grows on a substrate N- layer; the P+ area is internally provided with a deep energy level doping layer; diffusion of deep energy level impurities totally depends on temperature, and the temperature decides the diffusion speed and the solid solubility in silicon. When thermal diffusion is carried out on the deep energy level impurities, one-side annealing, such as, laser annealing is adopted, the laser annealing local temperature is distributed in an axial range of a chip, and thus, limited depth knot pushing for the deep energy level impurities can be realized. The technical scheme provided by the invention can realize local metal service life control.

Description

A kind of power device with local metal life control and preparation method thereof
Technical field
The present invention relates to a kind of power device and preparation method thereof, and in particular to a kind of power device with local metal life control Part and preparation method thereof.
Background technology
With the development of Power Electronic Technique, various frequency changer circuits, the application of chopper circuit constantly expand, these power electronics electricity The IGCT of the employing commutation cutoff that the loop in road has, some employings have the novel power transistor of self-switching-off capability, this Two kinds of devices are required for a fast recovery diode in parallel therewith.The process conditions of early stage require to be introduced into few in being combined The heart carries out semiconductor device manufacture, but so the device of manufacture has slower switching speed, it is difficult to meet the need to frequency applications Ask.In order to meet power electronic system to high frequency performance requirement, either switching tube, or the diode of afterflow, it is required for Complex centre is introduced into lattice with controlled method, minority carrier life time is reduced, the switching speed of device is improved.If had more to device The requirement of high frequency, then need to introduce more complex centres while being optimized in structure.
Complex centre is introduced in the devices, generally adopts two ways at present.The first is that the impurity that deep energy level is presented in silicon is entered Row thermal diffusion;Second is that, by high-energy particle bombardment silicon crystal, the lattice that hole and interstitial atom form are produced in crystal is damaged Wound.The first generally adopts heavy metal gold or platinum, due to its diffusion velocity it is fast, it is impossible to precise control depth, therefore for the global longevity Life control mode.The second way is usually electron irradiation, hydrogen injection or helium injection.Electron irradiation usually runs through mode, i.e., Complex centre distribution in the devices is constant, therefore is still global life control.Hydrogen injects and helium injection can be by control Implantation Energy processed realizes that limited depth injects, and realizes life control, i.e., the Localized Lifetime Control generally said, office in most effective region Domain lifetime control techniques are the conventional life control modes of high side device.
Global life control mode is typically unfavorable to the switching characteristic of device, is unfavorable for improving the compromise characteristic of device, at present Deep energy level heavy metal doping way because implementation method be limited, fail to realize Localized Lifetime Control, be commonly used to low side device. And existing Localized Lifetime Control means depend on the high ion implantation device of price, higher processing cost is generally meant that, it is existing Stage energetic ion injection device is both needed to from external import.See from the market, it is rare to adopt Localized Lifetime control less than 1200V devices Mode processed, high cost are main causes.Additionally need and be concerned with, no matter the complex centre which kind of mode is introduced, during which is compound The heart and produces center if located in space-charge region in reverse bias operation, near forbidden band central authorities level of energy Complex centre, then mean bigger reverse leakage.Now, gold, hydrogen and helium are unfavorable, and platinum is optimum.Because mixing platinum Complex centre has most obvious low drain electrical dominance away from forbidden band centre position, in all life control modes, so platinum device has Beneficial to higher junction temperature limit is obtained, higher voltage is applied to.It should be noted that for fast recovery diode, complex centre away from From PN junction more close to, be more conducive to compromise characteristic raising, therefore, under identical levels of leakage, if using the side of local platinum Formula carries out life control, and platinum can be entered in space-charge region, and its compromise characteristic can be better than the core using hydrogen or helium Localized Lifetime Control Piece.
The content of the invention
To solve above-mentioned deficiency of the prior art, it is an object of the invention to provide a kind of power with local metal life control Device and preparation method thereof, realizes metal Localized Lifetime Control.
The purpose of the present invention is realized using following technical proposals:
The present invention provides a kind of power device with local metal life control, and the power device includes substrate and formed thereon The PN junction that collectively forms of P+ areas, the growth on the substrate N- layers has oxide layer;Which thes improvement is that, in P+ areas It is provided with deep energy level doped layer;
N-type silicon substrate of the substrate for Uniform Doped, the N-type silicon substrate include the substrate N- layers being sequentially distributed and lining Bottom N+ layers;
Further, the impurity that the deep energy level doped layer is mixed is gold or platinum, and its dosage is 1 × 1012cm-2~1 × 1016cm-2
Further, the oxide layer forms active area window, and on the active area window, knot forms P+ areas.
Further, the deep energy level doped layer is distributed in power device axial range, for realizing power device local metal Life control.
The present invention also provides a kind of manufacture method of the power device with local metal life control, and which thes improvement is that, institute The method of stating comprises the steps:
A, initial oxidation:In H2And O2Atmosphere, at 900 DEG C -1100 DEG C, the N-type silicon substrate to the Uniform Doped after cleaning Oxidation 1-10 hours, in 8000-20000 angstrom of oxide layer of its superficial growth;
B, formation active area:In the N-type silicon substrate of Uniform Doped gluing, expose, develop, etch and remove photoresist to forming active Area's window;
C, formation PN junction:300-500 angstrom of oxide layer is grown on active area window as masking layer, dosage is subsequently carried out for 1 ×1013cm-2~1 × 1015cm-2Boron ion injection, form boron ion implanted layer, and the knot shape under 1200 DEG C, nitrogen atmosphere Into the P+ areas of 1-20um;
D, enter dense boron in surfaces of active regions after-teeming:20-50 kiloelectron-volt of energy, implantation dosage 1e13cm-2~1e15cm-2, At 900 DEG C, constant temperature is annealed into line activating for 1 hour;
E, minority carrier life time control is carried out, realizes that deep-level impurity is combined with N-type silicon substrate using deposit, evaporation or injection mode, Limited depth deep-level impurity knot is realized using one side annealing way, deep energy level doped layer is formed;
F, generation metal electrode:P areas surface using evaporation or splash-proofing sputtering metal aluminum, photoetching, etch, removing photoresist forms with alloy Surface metal electrode;
G, surface passivation:By SiN, SiO2, polyimides PI thin film forms surface passivation, and by photoetching, etching is formed Emitter stage aluminum lead PAD region;
H, back metal;Routinely technique forms back metal, forms Al/Ti/Ni/Ag or Ti/Ni/Ag back metal electrodes.
Further, in step E, one side annealing way includes laser annealing mode and electron beam annealing mode.
The excellent effect that has of technical scheme that the present invention is provided is:
1. deep-level impurity Localized Lifetime Control is realized using one side annealing, processing cost is reduced compared with energetic ion injects, Product can realize on low-voltage-grade, enhance product performance, it is to avoid equipment dependence;
2. life control means are enriched, can be applied on gated device, local doping can avoid the reliability for affecting grid oxygen;
3. the Localized Lifetime Control means realization of the platinum of Low dark curient, on the basis of more excellent compromise characteristic, advantageously reduces device leakage Electricity, improves device working junction temperature;
4. low-voltage-grade devices field, the Localized Lifetime Control means of gold, can continue to improve gold doping device compromise characteristic, realize Device performance is more excellent, and the knot severity control of gold is applied also for high pressure field outside space-charge region such as;
5. largely or entirely without deep-level impurity, what is reduced for carrier capture coefficient is raised with temperature answers device for drift region Conjunction center, can optimize its forward voltage drop temperature coefficient, beneficial to parallel connection;
6. by adjusting optical maser wavelength, life control depth can be adjusted flexibly, technique difficulty of processing is low.
Description of the drawings
Fig. 1 is the substrate N- layers that the present invention is provided;
Fig. 2 is the N- material piece field oxides that the present invention is provided;
Fig. 3 is the material piece for providing chip profile figure after active area chemical wet etching of the invention;
Fig. 4 is that the material piece active area for providing of the invention knot after B injections forms P+ areas;
Fig. 5 is that the material piece that the present invention is provided has local metal life control chip profile figure one;
Fig. 6 is that the material piece that the present invention is provided has local metal life control chip profile figure two;
Wherein:1. substrate N- layers are represented;2. oxide layer is represented;3. P+ layers are represented;4. deep energy level doped layer is represented.
Specific embodiment
Below in conjunction with the accompanying drawings the specific embodiment of the present invention is described in further detail.
The following description and drawings fully illustrate specific embodiments of the present invention, to enable those skilled in the art to put into practice it .Other embodiments can include structure, logic, electric, process and other changes.Embodiment only generation The possible change of table.Unless explicitly requested, otherwise individually component and function are optional, and the order for operating can change. The part of some embodiments and feature can be included in or replace part and the feature of other embodiments.The enforcement of the present invention The scope of scheme includes the gamut of claims, and all obtainable equivalent of claims.Herein, These embodiments of the present invention individually or generally can be represented with term " invention " that it is convenient that this is used for the purpose of, and And if in fact disclosing the invention more than, the scope for being not meant to automatically limit the application is any single invention or sends out Bright design.
The technical problem to be solved in the present invention is that:For the technical problem that prior art is present, the present invention proposes a kind of new Method, so as to realize metal Localized Lifetime Control.
To solve above-mentioned technical problem, the present invention is employed the following technical solutions:
The present invention provides a kind of power device with local metal life control, and the power device includes substrate and formed thereon The PN junction that collectively forms of P+ areas, the growth on the substrate N- layers has oxide layer;Deep energy level doped layer is provided with P+ areas;
N-type silicon substrate of the substrate for Uniform Doped, the N-type silicon substrate include the substrate N- layers being sequentially distributed and lining Bottom N+ layers.
The diffusion of deep-level impurity places one's entire reliance upon temperature, and temperature determines its diffusion velocity and the solid solubility in silicon.To deep energy When level impurity carries out thermal diffusion, annealed using one side, such as laser annealing mode is carried out, using the local Temperature Distribution of laser annealing The limited depth knot of deep-level impurity is realized in chip axial range, thus, you can realize device local metal life control. The impurity that the deep energy level doped layer is mixed is gold or platinum, and its dosage is 1 × 1012cm-2~1 × 1016cm-2.The oxide layer is formed Active area window, on the active area window, knot forms P+ areas.The deep energy level doped layer is distributed in power device axial direction model In enclosing, for realizing power device local metal life control.
The present invention also provides a kind of manufacture method of the power device with local metal life control, comprises the steps:
1. initial oxidation:After cleaning to the N-type silicon substrate (see figure 1) of Uniform Doped, using the side of high-temperature oxydation Method, silicon chip surface grow oxide layer 2, thickness 8000-20000A, as shown in Figure 2;
2. active area is formed:By gluing, expose, development, etching is removed photoresist, and forms active area window as shown in Figure 3;
3. PN junction is formed:To prevent implant damage, growth 300-500A oxide layers from subsequently carrying out boron injection as masking layer, Dosage is 1e13-1e15, knot 1-20um under 1200 DEG C of nitrogen, sees Fig. 4;
4. to prevent, active area concentration is too low to there is Ohmic contact problem, and surface is mended dense boron and activated;
5. minority carrier life time control is carried out, realizes that deep-level impurity is combined with silicon using deposit, evaporation or injection mode, using laser Annealing way realizes limited depth deep-level impurity knot, sees Fig. 5 or Fig. 6;
6. metal electrode:Usual manner evaporates or sputters AL, by photoetching, etches, removes photoresist, and alloy forms surface metal Deposit;
7. surface passivation:Surface passivation is formed by conventional methods;
8. back metal:Routinely technique forms back metal, forms Al/Ti/Ni/Ag or Ti/Ni/Ag back metal electrodes.
The annealing way that the present invention is provided is annealed for one side, is explained merely with laser annealing herein, other achievable lists The mode of face annealing is also included, such as electron beam etc.;The present invention mainly by fast recovery diode FRD flow processs illustrating, but Method is equally applicable to the power device that other need Localized Lifetime Control;According to device application and parameter request, deep-level impurity Gold or platinum are not limited only to, other elements, such as palladium etc. can be also included.Actual deep energy level complex centre depth is according to device parameters need Ask, there may be two kinds of forms of Fig. 5 and Fig. 6.
Above example is only to illustrate technical scheme rather than a limitation, although reference above-described embodiment is to the present invention Be described in detail, those of ordinary skill in the art still can to the present invention specific embodiment modify or Person's equivalent, these any modification or equivalents without departing from spirit and scope of the invention are applying for pending this Within bright claims.

Claims (7)

1. a kind of power device with local metal life control, the power device include the PN junction that substrate and the P+ areas for being formed thereon collectively form, and the growth on the substrate N- layers has oxide layer;Characterized in that, being provided with deep energy level doped layer in P+ areas;
N-type silicon substrate of the substrate for Uniform Doped, the N-type silicon substrate include the substrate N- layers being sequentially distributed and substrate N+ layers.
2. power device as claimed in claim 1, it is characterised in that the impurity that the deep energy level doped layer is mixed is gold or platinum, its dosage is 1 × 1012cm-2~1 × 1016cm-2
3. power device as claimed in claim 2, it is characterised in that the impurity that the deep energy level doped layer is mixed is palladium, and its dosage is 1 × 1012cm-2~1 × 1016cm-2
4. power device as claimed in claim 1, it is characterised in that the oxide layer forms active area window, on the active area window, knot forms P+ areas.
5. power device as claimed in claim 1, it is characterised in that the deep energy level doped layer is distributed in power device axial range, for realizing power device local metal life control.
6. a kind of manufacture method of the power device with local metal life control as any one of claim 1-5, it is characterised in that methods described comprises the steps:
A, initial oxidation:In H2And O2Atmosphere, at 900 DEG C -1100 DEG C, the N-type silicon substrate oxidation 1-10 hours to the Uniform Doped after cleaning, in 8000-20000 angstrom of oxide layer of its superficial growth;
B, formation active area:In the N-type silicon substrate of Uniform Doped gluing, expose, develop, etch and remove photoresist to forming active area window;
C, formation PN junction:300-500 angstrom of oxide layer is grown on active area window as masking layer, dosage is subsequently carried out for 1 × 1013cm-2~1 × 1015cm-2Boron ion injection, formed boron ion implanted layer, and under 1200 DEG C, nitrogen atmosphere knot formed 1-20um P+ areas;
D, enter dense boron in surfaces of active regions after-teeming:20-50 kiloelectron-volt of energy, implantation dosage 1e13cm-2~1e15cm-2, at 900 DEG C, constant temperature is annealed into line activating for 1 hour;
E, minority carrier life time control is carried out, realize that deep-level impurity is combined with N-type silicon substrate using deposit, evaporation or injection mode, limited depth deep-level impurity knot, formation deep energy level doped layer are realized using one side annealing way;
F, generation metal electrode:P areas surface using evaporation or splash-proofing sputtering metal aluminum, photoetching, etch, remove photoresist and alloy formed surface metal electrode;
G, surface passivation:By SiN, SiO2, polyimides PI thin film forms surface passivation, and by photoetching, etching forms emitter stage aluminum lead PAD region;
H, back metal;Routinely technique forms back metal, forms Al/Ti/Ni/Ag or Ti/Ni/Ag back metal electrodes.
7. manufacture method as claimed in claim 6, it is characterised in that in step E, one side annealing way includes laser annealing mode and electron beam annealing mode.
CN201510695743.XA 2015-10-23 2015-10-23 Power device with local metal service life control and manufacturing method thereof Pending CN106611797A (en)

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Cited By (4)

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CN107946723A (en) * 2017-11-22 2018-04-20 中航(重庆)微电子有限公司 A kind of new low loss RF microstrip structure production method
CN108831834A (en) * 2018-06-22 2018-11-16 重庆平伟实业股份有限公司 The forming method of power semiconductor
CN111106012A (en) * 2019-12-20 2020-05-05 电子科技大学 Method for realizing local service life control of semiconductor device
CN115775836A (en) * 2022-12-19 2023-03-10 扬州国宇电子有限公司 Mesa structure fast recovery diode and preparation method thereof

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CN102569067A (en) * 2012-02-17 2012-07-11 北京时代民芯科技有限公司 Method for manufacturing planar high-voltage ultrafast soft recovery diode
CN103618006A (en) * 2013-10-30 2014-03-05 国家电网公司 A fast recovery diode and a manufacturing method thereof
CN104157569A (en) * 2014-08-26 2014-11-19 清华大学 Technology for manufacturing fast recovery diode
CN104952936A (en) * 2014-03-25 2015-09-30 国家电网公司 Fast recovery diode and manufacturing method thereof

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CN1471146A (en) * 2003-06-18 2004-01-28 北京工业大学 Method for manufacturnig silicon high-speed semiconductor switch device
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107946723A (en) * 2017-11-22 2018-04-20 中航(重庆)微电子有限公司 A kind of new low loss RF microstrip structure production method
CN108831834A (en) * 2018-06-22 2018-11-16 重庆平伟实业股份有限公司 The forming method of power semiconductor
CN111106012A (en) * 2019-12-20 2020-05-05 电子科技大学 Method for realizing local service life control of semiconductor device
CN111106012B (en) * 2019-12-20 2022-05-17 电子科技大学 Method for realizing local service life control of semiconductor device
CN115775836A (en) * 2022-12-19 2023-03-10 扬州国宇电子有限公司 Mesa structure fast recovery diode and preparation method thereof
CN115775836B (en) * 2022-12-19 2023-09-05 扬州国宇电子有限公司 Mesa structure fast recovery diode and preparation method thereof

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