CN106518061A - 大红色氧化锆陶瓷及其制作方法 - Google Patents
大红色氧化锆陶瓷及其制作方法 Download PDFInfo
- Publication number
- CN106518061A CN106518061A CN201610921882.4A CN201610921882A CN106518061A CN 106518061 A CN106518061 A CN 106518061A CN 201610921882 A CN201610921882 A CN 201610921882A CN 106518061 A CN106518061 A CN 106518061A
- Authority
- CN
- China
- Prior art keywords
- parts
- hours
- large red
- red zirconia
- oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 title claims abstract description 76
- 239000000919 ceramic Substances 0.000 title claims abstract description 39
- 238000002360 preparation method Methods 0.000 title abstract description 8
- 239000000975 dye Substances 0.000 claims abstract description 28
- 238000004519 manufacturing process Methods 0.000 claims abstract description 20
- 239000000843 powder Substances 0.000 claims abstract description 15
- 238000005245 sintering Methods 0.000 claims abstract description 10
- 238000003756 stirring Methods 0.000 claims abstract description 10
- 229910052761 rare earth metal Inorganic materials 0.000 claims abstract description 5
- 150000002910 rare earth metals Chemical class 0.000 claims abstract description 5
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 25
- 229910001928 zirconium oxide Inorganic materials 0.000 claims description 25
- 239000002994 raw material Substances 0.000 claims description 22
- 238000000034 method Methods 0.000 claims description 18
- 239000000463 material Substances 0.000 claims description 17
- 238000001816 cooling Methods 0.000 claims description 16
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 claims description 12
- 239000004033 plastic Substances 0.000 claims description 11
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 9
- 239000004568 cement Substances 0.000 claims description 9
- 238000000227 grinding Methods 0.000 claims description 9
- 239000001257 hydrogen Substances 0.000 claims description 9
- 229910052739 hydrogen Inorganic materials 0.000 claims description 9
- 239000001301 oxygen Substances 0.000 claims description 9
- 229910052760 oxygen Inorganic materials 0.000 claims description 9
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 claims description 6
- 229910000420 cerium oxide Inorganic materials 0.000 claims description 6
- 229910000423 chromium oxide Inorganic materials 0.000 claims description 6
- ZXGIFJXRQHZCGJ-UHFFFAOYSA-N erbium(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Er+3].[Er+3] ZXGIFJXRQHZCGJ-UHFFFAOYSA-N 0.000 claims description 6
- VQCBHWLJZDBHOS-UHFFFAOYSA-N erbium(III) oxide Inorganic materials O=[Er]O[Er]=O VQCBHWLJZDBHOS-UHFFFAOYSA-N 0.000 claims description 6
- 239000004200 microcrystalline wax Substances 0.000 claims description 6
- 238000000465 moulding Methods 0.000 claims description 6
- PLDDOISOJJCEMH-UHFFFAOYSA-N neodymium(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Nd+3].[Nd+3] PLDDOISOJJCEMH-UHFFFAOYSA-N 0.000 claims description 6
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims description 6
- 239000012188 paraffin wax Substances 0.000 claims description 6
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims description 5
- DCXXMTOCNZCJGO-UHFFFAOYSA-N Glycerol trioctadecanoate Natural products CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 claims description 5
- 229920005669 high impact polystyrene Polymers 0.000 claims description 3
- 239000004797 high-impact polystyrene Substances 0.000 claims description 3
- 238000007731 hot pressing Methods 0.000 claims description 3
- 238000000462 isostatic pressing Methods 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 239000000758 substrate Substances 0.000 claims description 3
- 238000003825 pressing Methods 0.000 claims description 2
- 229940116364 hard fat Drugs 0.000 claims 1
- 239000001993 wax Substances 0.000 claims 1
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- RUDFQVOCFDJEEF-UHFFFAOYSA-N yttrium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Y+3].[Y+3] RUDFQVOCFDJEEF-UHFFFAOYSA-N 0.000 abstract 3
- 238000000498 ball milling Methods 0.000 abstract 1
- 238000005238 degreasing Methods 0.000 abstract 1
- 230000002708 enhancing effect Effects 0.000 abstract 1
- 229910010293 ceramic material Inorganic materials 0.000 description 11
- 238000005516 engineering process Methods 0.000 description 4
- 239000003086 colorant Substances 0.000 description 2
- 239000012620 biological material Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000012776 electronic material Substances 0.000 description 1
- 238000013467 fragmentation Methods 0.000 description 1
- 238000006062 fragmentation reaction Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/48—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on zirconium or hafnium oxides, zirconates, zircon or hafnates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/63—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
- C04B35/632—Organic additives
- C04B35/634—Polymers
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/63—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
- C04B35/638—Removal thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/64—Burning or sintering processes
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3224—Rare earth oxide or oxide forming salts thereof, e.g. scandium oxide
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3224—Rare earth oxide or oxide forming salts thereof, e.g. scandium oxide
- C04B2235/3225—Yttrium oxide or oxide-forming salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3224—Rare earth oxide or oxide forming salts thereof, e.g. scandium oxide
- C04B2235/3227—Lanthanum oxide or oxide-forming salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3224—Rare earth oxide or oxide forming salts thereof, e.g. scandium oxide
- C04B2235/3229—Cerium oxides or oxide-forming salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
- C04B2235/3244—Zirconium oxides, zirconates, hafnium oxides, hafnates, or oxide-forming salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
- C04B2235/658—Atmosphere during thermal treatment
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
- C04B2235/658—Atmosphere during thermal treatment
- C04B2235/6582—Hydrogen containing atmosphere
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
- C04B2235/658—Atmosphere during thermal treatment
- C04B2235/6583—Oxygen containing atmosphere, e.g. with changing oxygen pressures
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
- C04B2235/66—Specific sintering techniques, e.g. centrifugal sintering
- C04B2235/661—Multi-step sintering
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Composite Materials (AREA)
- Compositions Of Oxide Ceramics (AREA)
Abstract
本发明提供一种大红色氧化锆陶瓷及其制作方法。本发明的大红色氧化锆陶瓷，其原料组分包括氧化锆、氧化钇、及稀土染色剂，通过稀土染色剂对氧化锆及氧化钇进行染色，与现有技术相比，能够实现陶瓷的大红色外观，大大提升了产品的市场竞争力，增强了产品的适用性。本发明的大红色氧化锆陶瓷的制作方法，对组分为氧化锆、氧化钇、及稀土染色剂的原料进行球磨搅拌，制成陶瓷粉末，并经过高压成型、排胶脱脂、及烧结的步骤，制得大红色氧化锆陶瓷，制程简单，生产效率高，产品良率高，同时稀土染色剂对氧化锆及氧化钇进行染色，与现有技术相比，能够实现陶瓷的大红色外观，大大提升了产品的市场竞争力，增强了产品的适用性。
Description
技术领域
本发明涉及陶瓷制造技术领域，尤其涉及一种大红色氧化锆陶瓷及其制作方法。
背景技术
陶瓷材料在人类生活和现代化建设中是不可缺少的一种材料。传统的陶瓷材料具有硬度高、耐腐蚀性强、耐磨性强、绝缘性强、热导率低、热稳定性好等优点，但其抗拉强度较低，塑性和韧性很差，容易产生碎裂。随着材料科学的不断发展，各种新型的陶瓷材料相继产生，很大程度上改善了传统陶瓷材料的不足。
氧化锆(ZrO2)作为一种新型陶瓷材料，除了具有传统的陶瓷材料的优点外，还同时具有较好的韧性，是耐火材料、高温结构材料、生物材料、和电子材料的重要原料，在工业生产中得到了广泛应用。
随着生活水平的提高，人们对生活品质及外在形象的要求也越来越高，而且人们对审美要求也日趋多样化，导致人们对日常生活中使用的产品的外观的重视程度也逐渐增加，外形美观已经成为产品品质的重要的考量内容。然而现有的陶瓷材料的颜色一般较为单一，且多为白、灰等颜色，当将陶瓷材料应用于产品的外观部分，尤其是当将陶瓷材料应用于穿戴用品及便携产品时，例如手表表带、饰品、手机外壳等，虽然具有较好的使用性能，但陶瓷材料的颜色会影响产品的美观度，无法满足不同用户的不同类型的审美需求，降低了产品的市场竞争力。
发明内容
本发明的目的在于提供一种大红色氧化锆陶瓷，能够实现陶瓷的大红色外观，提升产品的市场竞争力。
本发明的另一目的在于提供一种大红色氧化锆陶瓷的制作方法，制程简单，生产效率高，产品良率高，且能够实现陶瓷的大红色外观，提升产品的市场竞争力。
为实现上述目的，本发明首先提供一种大红色氧化锆陶瓷，其包括原料组分及其重量份如下：氧化锆90-94份、氧化钇4-5份、及稀土染色剂0.05-1份，所述稀土染色剂选自氧化铬、氧化镧、氧化钕、氧化铈、氧化铒。
所述稀土染色剂选自氧化铬、氧化镧、氧化钕、氧化铈、氧化铒中的两种或两种以上。
所述原料组分及其重量份如下：氧化锆92份、氧化钇4.5份、及稀土染色剂0.5份。
本发明还提供一种大红色氧化锆陶瓷的制作方法，包括如下步骤：
步骤1、提供原料，该原料组分及其重量份如下：氧化锆90-94份、氧化钇4-5份、及稀土染色剂0.05-1份；
步骤2、将各原料组分球磨搅拌，制成陶瓷粉末；
步骤3、高压成型；
步骤4、排胶脱脂；
步骤5、烧结。
步骤2中，球磨搅拌时间为48-90小时，陶瓷粉末的粒径为0.5-5μm。
步骤3中，对陶瓷粉末添加石蜡、微晶蜡、硬脂蜡及塑胶，并混合均匀，然后采用干压、热压、或等静压成型。
所述步骤3的各材料含量按重量份计分别如下：以陶瓷粉末为1000份，石蜡11－17份，微晶蜡11－17份，硬脂蜡1－3份，塑胶65－75份；所述塑胶选用PE、PP、HIPS、PET其中的一种或其组合。
步骤4中，排胶脱脂的温度小于或等于500℃，其中坯体在温度达到100℃之前脱脂，在温度达到200℃之后排塑。
步骤5的烧结包括氧气烧、真空烧及氢气烧，其中氧气烧用12-24小时从常温加热1450-1520℃，并保温1-2小时，然后自然冷却；真空烧用6-12小时从常温加热到1350-1450℃，保温3-6小时，然后自然冷却；氢气烧用4-6小时从常温加热到800-1200℃，保温1-2小时，然后自然冷却。
步骤5中，氧气烧用13小时从常温加热1500℃，并保温2小时，然后自然冷却；真空烧用6小时从常温加热到1350℃，保温4小时，然后自然冷却；氢气烧用4小时从常温加热到800℃，保温1小时，然后自然冷却。
本发明的有益效果：本发明的大红色氧化锆陶瓷，其原料组分包括氧化锆、氧化钇、及稀土染色剂，通过稀土染色剂对作为陶瓷主体材料的氧化锆及氧化钇进行染色，与现有技术相比，能够实现陶瓷的大红色外观，大大提升了产品的市场竞争力，增强了产品的适用性。本发明的大红色氧化锆陶瓷的制作方法，对组分为氧化锆、氧化钇、及稀土染色剂的原料进行球磨搅拌，制成陶瓷粉末，并经过高压成型、排胶脱脂、及烧结的步骤，制得大红色氧化锆陶瓷，制程简单，生产效率高，产品良率高，同时稀土染色剂对作为陶瓷主体材料的氧化锆及氧化钇进行染色，与现有技术相比，能够实现陶瓷的大红色外观，大大提升了产品的市场竞争力，增强了产品的适用性。
具体实施方式
本发明提供一种大红色氧化锆陶瓷，其包括原料组分及其重量份如下：氧化锆90-94份、氧化钇4-5份、及稀土染色剂0.05-1份，所述稀土染色剂选自氧化铬、氧化镧、氧化钕、氧化铈、氧化铒。
本发明的大红色氧化锆陶瓷，其原料组分中的氧化锆、及氧化钇为陶瓷主体材料，而稀土染色剂能够对作为陶瓷主体材料的氧化锆及氧化钇进行染色，与现有技术中陶瓷材料仅能呈现白、灰几种颜色相比，能够实现陶瓷的大红色外观，当所述大红色氧化锆陶瓷应用于产品的外观部分时，能够大大提升产品的市场竞争力，并增强了产品的适用性。
具体地，所述稀土染色剂选自氧化铬、氧化镧、氧化钕、氧化铈、氧化铒中的两种或两种以上。
优选地，所述原料组分及其重量份如下：氧化锆92份、氧化钇4.5份、及稀土染色剂0.5份。
基于上述大红色氧化锆陶瓷，本发明还提供一种大红色氧化锆陶瓷的制作方法，包括如下步骤：
步骤1、提供原料，该原料组分及其重量份如下：氧化锆90-94份、氧化钇4-5份、及稀土染色剂0.05-1份。
优选地，所述原料组分及其重量份如下：氧化锆92份、氧化钇4.5份、及稀土染色剂0.5份。
步骤2、将各原料组分球磨搅拌，制成陶瓷粉末。
具体地，步骤2中，球磨搅拌时间为48-90小时，陶瓷粉末的粒径为0.5-5μm。
步骤3、高压成型。
具体地，步骤3中，对陶瓷粉末添加石蜡、微晶蜡、硬脂蜡及塑胶，并混合均匀，然后采用干压、热压、或等静压成型。
进一步地，所述步骤3的各材料含量按重量份计分别如下：以陶瓷粉末为1000份，石蜡11－17份，微晶蜡11－17份，硬脂蜡1－3份，塑胶65－75份；所述塑胶选用PE、PP、HIPS、PET其中的一种或其组合。
步骤4、排胶脱脂。
具体地，步骤4中，排胶脱脂的温度小于或等于500℃，其中坯体在温度达到100℃之前脱脂，在温度达到200℃之后排塑。
步骤5、烧结。
具体地，步骤5的烧结包括氧气烧、真空烧及氢气烧，其中氧气烧用12-24小时从常温加热1450-1520℃，并保温1-2小时，然后自然冷却；真空烧用6-12小时从常温加热到1350-1450℃，保温3-6小时，然后自然冷却；氢气烧用4-6小时从常温加热到800-1200℃，保温1-2小时，然后自然冷却。
优选地，步骤5中，氧气烧用13小时从常温加热1500℃，并保温2小时，然后自然冷却；真空烧用6小时从常温加热到1350℃，保温4小时，然后自然冷却；氢气烧用4小时从常温加热到800℃，保温1小时，然后自然冷却。
本发明的大红色氧化锆陶瓷的制作方法，对组分为氧化锆、氧化钇、及稀土染色剂的原料进行球磨搅拌，制成陶瓷粉末，并经过高压成型、排胶脱脂、及烧结的步骤，制得大红色氧化锆陶瓷，制程简单，生产效率高，产品良率高，同时稀土染色剂对作为陶瓷主体材料的氧化锆及氧化钇进行染色，与现有技术中陶瓷材料仅能呈现白、灰几种颜色相比，能够实现陶瓷的大红色外观，当所述大红色氧化锆陶瓷应用于产品的外观部分时，能够大大提升产品的市场竞争力，并增强了产品的适用性。
综上所述，本发明的大红色氧化锆陶瓷，其原料组分包括氧化锆、氧化钇、及稀土染色剂，通过稀土染色剂对作为陶瓷主体材料的氧化锆及氧化钇进行染色，与现有技术相比，能够实现陶瓷的大红色外观，大大提升了产品的市场竞争力，增强了产品的适用性。本发明的大红色氧化锆陶瓷的制作方法，对组分为氧化锆、氧化钇、及稀土染色剂的原料进行球磨搅拌，制成陶瓷粉末，并经过高压成型、排胶脱脂、及烧结的步骤，制得大红色氧化锆陶瓷，制程简单，生产效率高，产品良率高，同时稀土染色剂对作为陶瓷主体材料的氧化锆及氧化钇进行染色，与现有技术相比，能够实现陶瓷的大红色外观，大大提升了产品的市场竞争力，增强了产品的适用性。
以上所述，对于本领域的普通技术人员来说，可以根据本发明的技术方案和技术构思作出其他各种相应的改变和变形，而所有这些改变和变形都应属于本发明后附的权利要求的保护范围。
Claims (10)
1.一种大红色氧化锆陶瓷，其特征在于，其包括原料组分及其重量份如下：氧化锆90-94份、氧化钇4-5份、及稀土染色剂0.05-1份，所述稀土染色剂选自氧化铬、氧化镧、氧化钕、氧化铈、氧化铒。
2.如权利要求1所述的大红色氧化锆陶瓷，其特征在于，所述稀土染色剂选自氧化铬、氧化镧、氧化钕、氧化铈、氧化铒中的两种或两种以上。
3.如权利要求1所述的大红色氧化锆陶瓷，其特征在于，所述原料组分及其重量份如下：氧化锆92份、氧化钇4.5份、及稀土染色剂0.5份。
4.一种大红色氧化锆陶瓷的制作方法，包括如下步骤：
步骤1、提供原料，该原料组分及其重量份如下：氧化锆90-94份、氧化钇4-5份、及稀土染色剂0.05-1份；
步骤2、将各原料组分球磨搅拌，制成陶瓷粉末；
步骤3、高压成型；
步骤4、排胶脱脂；
步骤5、烧结。
5.如权利要求4所述的大红色氧化锆陶瓷的制作方法，其特征在于，步骤2中，球磨搅拌时间为48-90小时，陶瓷粉末的粒径为0.5-5μm。
6.如权利要求4所述的大红色氧化锆陶瓷的制作方法，其特征在于，步骤3中，对陶瓷粉末添加石蜡、微晶蜡、硬脂蜡及塑胶，并混合均匀，然后采用干压、热压、或等静压成型。
7.如权利要求6所述的大红色氧化锆陶瓷的制作方法，其特征在于，所述步骤3的各材料含量按重量份计分别如下：以陶瓷粉末为1000份，石蜡11－17份，微晶蜡11－17份，硬脂蜡1－3份，塑胶65－75份；所述塑胶选用PE、PP、HIPS、PET其中的一种或其组合。
8.如权利要求4所述的大红色氧化锆陶瓷的制作方法，其特征在于，步骤4中，排胶脱脂的温度小于或等于500℃，其中坯体在温度达到100℃之前脱脂，在温度达到200℃之后排塑。
9.如权利要求4所述的大红色氧化锆陶瓷的制作方法，其特征在于，步骤5的烧结包括氧气烧、真空烧及氢气烧，其中氧气烧用12-24小时从常温加热1450-1520℃，并保温1-2小时，然后自然冷却；真空烧用6-12小时从常温加热到1350-1450℃，保温3-6小时，然后自然冷却；氢气烧用4-6小时从常温加热到800-1200℃，保温1-2小时，然后自然冷却。
10.如权利要求9所述的大红色氧化锆陶瓷的制作方法，其特征在于，步骤5中，氧气烧用13小时从常温加热1500℃，并保温2小时，然后自然冷却；真空烧用6小时从常温加热到1350℃，保温4小时，然后自然冷却；氢气烧用4小时从常温加热到800℃，保温1小时，然后自然冷却。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610921882.4A CN106518061A (zh) | 2016-10-21 | 2016-10-21 | 大红色氧化锆陶瓷及其制作方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610921882.4A CN106518061A (zh) | 2016-10-21 | 2016-10-21 | 大红色氧化锆陶瓷及其制作方法 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106518061A true CN106518061A (zh) | 2017-03-22 |
Family
ID=58292163
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610921882.4A Pending CN106518061A (zh) | 2016-10-21 | 2016-10-21 | 大红色氧化锆陶瓷及其制作方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106518061A (zh) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107937982A (zh) * | 2017-11-30 | 2018-04-20 | 冯春生 | 大红色立方氧化锆晶体 |
| CN108314449A (zh) * | 2018-02-06 | 2018-07-24 | 厦门嘉联科技开发有限公司 | 一种彩色氧化锆陶瓷手机背板的制造工艺 |
| CN108424109A (zh) * | 2018-03-27 | 2018-08-21 | 焦作市维纳科技有限公司 | 一种透明中国红立方锆宝石及其制备方法 |
| CN109400148A (zh) * | 2018-11-01 | 2019-03-01 | 山东国瓷功能材料股份有限公司 | 一种大红色氧化锆陶瓷以及制备方法与应用 |
| CN112062557A (zh) * | 2019-06-11 | 2020-12-11 | 比亚迪股份有限公司 | 氧化锆陶瓷及其制备方法和应用 |
| CN113480309A (zh) * | 2021-08-03 | 2021-10-08 | 无锡乾鹏医疗科技有限公司 | 一种红色氧化锆陶瓷及其制备方法 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1374273A (zh) * | 2001-03-08 | 2002-10-16 | 贵研铂业股份有限公司 | 氧化锆系列陶瓷粉末生产方法 |
| JP2007015882A (ja) * | 2005-07-06 | 2007-01-25 | Ngk Insulators Ltd | 電子部品用焼成治具 |
| CN101020607A (zh) * | 2006-08-16 | 2007-08-22 | 邓湘凌 | 银白色氧化锆陶瓷制品及其制造方法 |
| CN102153346A (zh) * | 2010-12-08 | 2011-08-17 | 赣州科盈结构陶瓷有限公司 | 稀土复合氧化锆陶瓷健身球及其制备方法 |
| CN103073286A (zh) * | 2011-11-18 | 2013-05-01 | 常熟市创新陶瓷有限公司 | 一种复合稳定氧化锆陶瓷及其制造方法 |
-
2016
- 2016-10-21 CN CN201610921882.4A patent/CN106518061A/zh active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1374273A (zh) * | 2001-03-08 | 2002-10-16 | 贵研铂业股份有限公司 | 氧化锆系列陶瓷粉末生产方法 |
| JP2007015882A (ja) * | 2005-07-06 | 2007-01-25 | Ngk Insulators Ltd | 電子部品用焼成治具 |
| CN101020607A (zh) * | 2006-08-16 | 2007-08-22 | 邓湘凌 | 银白色氧化锆陶瓷制品及其制造方法 |
| CN102153346A (zh) * | 2010-12-08 | 2011-08-17 | 赣州科盈结构陶瓷有限公司 | 稀土复合氧化锆陶瓷健身球及其制备方法 |
| CN103073286A (zh) * | 2011-11-18 | 2013-05-01 | 常熟市创新陶瓷有限公司 | 一种复合稳定氧化锆陶瓷及其制造方法 |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107937982A (zh) * | 2017-11-30 | 2018-04-20 | 冯春生 | 大红色立方氧化锆晶体 |
| CN108314449A (zh) * | 2018-02-06 | 2018-07-24 | 厦门嘉联科技开发有限公司 | 一种彩色氧化锆陶瓷手机背板的制造工艺 |
| CN108424109A (zh) * | 2018-03-27 | 2018-08-21 | 焦作市维纳科技有限公司 | 一种透明中国红立方锆宝石及其制备方法 |
| CN109400148A (zh) * | 2018-11-01 | 2019-03-01 | 山东国瓷功能材料股份有限公司 | 一种大红色氧化锆陶瓷以及制备方法与应用 |
| CN109400148B (zh) * | 2018-11-01 | 2021-11-16 | 山东国瓷功能材料股份有限公司 | 一种大红色氧化锆陶瓷以及制备方法与应用 |
| CN112062557A (zh) * | 2019-06-11 | 2020-12-11 | 比亚迪股份有限公司 | 氧化锆陶瓷及其制备方法和应用 |
| CN113480309A (zh) * | 2021-08-03 | 2021-10-08 | 无锡乾鹏医疗科技有限公司 | 一种红色氧化锆陶瓷及其制备方法 |
| CN113480309B (zh) * | 2021-08-03 | 2022-07-12 | 无锡乾鹏医疗科技有限公司 | 一种红色氧化锆陶瓷及其制备方法 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106518061A (zh) | 大红色氧化锆陶瓷及其制作方法 | |
| CN102417346B (zh) | 青花坭兴陶的制备工艺 | |
| CN100398489C (zh) | 可切削着色氧化锆陶瓷及其用途 | |
| CN106045563A (zh) | 一种淡蓝色钧瓷及其烧制方法 | |
| CN104671780A (zh) | 一种粉红色氧化锆陶瓷的制备方法 | |
| CN111205089B (zh) | 一种高透波绿色氧化锆陶瓷及其制备方法和制得的产品 | |
| CN103449809A (zh) | 一种氧化锆陶瓷质棋子及其制备方法 | |
| CN106045468A (zh) | 仿宋代哥窑开片青瓷配方及制造工艺 | |
| CN101020607A (zh) | 银白色氧化锆陶瓷制品及其制造方法 | |
| CN103183526A (zh) | 一种铁锈釉料及其产品的制作方法 | |
| CN104478482A (zh) | 一种南宋官窑米黄釉料变配方及制作工艺 | |
| CN114368966A (zh) | 一种氧化锆基全瓷义齿及其制备方法 | |
| CN101857369B (zh) | 古亚金釉及其制备方法 | |
| CN109400150B (zh) | 一种高强度粉红色氧化锆陶瓷粉体及其制备方法和应用 | |
| CN103467047A (zh) | 一种地板砖及其制作方法 | |
| CN107805046A (zh) | 一种无开片汝瓷餐具及汝瓷餐具无开片制作方法 | |
| CN102659401B (zh) | 灰白色氧化锆陶瓷的制作方法 | |
| CN101935233B (zh) | 一种低温银白色金属光泽釉及其制备方法 | |
| CN101401676A (zh) | 陶瓷首饰的制作方法 | |
| CN107365147A (zh) | 一种钧瓷及其制备方法 | |
| CN103360115B (zh) | 一种金酱釉料及其产品的制作方法 | |
| CN105439641B (zh) | 金黄乌滴还原窑变釉及用其制备的金黄乌滴还原窑变釉陶瓷制品及制备方法 | |
| CN106619140A (zh) | 一种氧化铝全瓷牙科修复材料及其制备方法 | |
| CN106830931B (zh) | 一种聚硅氮烷制备金色手机陶瓷外壳的方法 | |
| CN106083200A (zh) | 龙泉宋代哥窑青瓷釉及用该釉制作龙泉宋代哥窑青瓷产品的方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20180608 Address after: 518102 Guangdong Shenzhen Baoan District Xixiang street, Hengzhou Hengfeng Industrial Town, C5 building, eighth story. Applicant after: Shenzhen Hongtong New Material Co., Ltd. Address before: 518000 Guangdong, Shenzhen, Baoan District Xixiang, Hengzhou Industrial Park, C5, 7 building. Applicant before: Deng Xiangling |
|
| TA01 | Transfer of patent application right | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170322 |
|
| RJ01 | Rejection of invention patent application after publication |