CN106495613A - A kind of heat preservation decoration integrative tapestry brick and preparation method thereof - Google Patents
A kind of heat preservation decoration integrative tapestry brick and preparation method thereof Download PDFInfo
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- CN106495613A CN106495613A CN201610959101.0A CN201610959101A CN106495613A CN 106495613 A CN106495613 A CN 106495613A CN 201610959101 A CN201610959101 A CN 201610959101A CN 106495613 A CN106495613 A CN 106495613A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
- E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
- E04F13/0875—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements having a basic insulating layer and at least one covering layer
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
- E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
- E04F13/14—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements stone or stone-like materials, e.g. ceramics concrete; of glass or with an outer layer of stone or stone-like materials or glass
- E04F13/141—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements stone or stone-like materials, e.g. ceramics concrete; of glass or with an outer layer of stone or stone-like materials or glass with an outer layer of concrete
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/27—Water resistance, i.e. waterproof or water-repellent materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/30—Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values
- C04B2201/32—Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values for the thermal conductivity, e.g. K-factors
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Architecture (AREA)
- Ceramic Engineering (AREA)
- Structural Engineering (AREA)
- Civil Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Finishing Walls (AREA)
Abstract
The invention discloses a kind of heat preservation decoration integrative flexible clay facing tile and preparation method thereof, the invention belongs to new decorative material for building field, it includes porcelain tendre finish coat and heat-insulation layer.Component of the described porcelain tendre finish coat comprising following weight portion：10～25 parts of 8～15 parts of emulsion, 15～25 parts of breeze, 5～15 parts of cement, 40～60 parts of quartz sand, 5～15 parts of fire retardant, 0.5～2 part of inorganic pigment and water；Described heat-insulation layer is by the component of the following weight portion containing glass fiber reticular cloth：10～25 parts of 8～15 parts of emulsion, 15～25 parts of breeze, 15～25 parts of cement, 20～50 parts of insulation material, 5～15 parts of fire retardant, 0.5～2 part of inorganic pigment and water.Porcelain tendre finish coat hydrophobicity is strong, resistance to soiling is good, and porcelain tendre finish coat connects into an entirety with insulation interlayer by grout material, and heat preservation decoration integrative tapestry brick light weight, with decoration and heat insulation function, is a kind of insulation and decoration construction material of excellent combination property.
Description
Technical field
The present invention relates to new decorative material for building technical field, more particularly to a kind of heat preservation decoration integrative tapestry brick and
Its preparation method.
Background technology
Flexible clay facing tile, also known as bright and beautiful clay (brocade:Rich color, clay:Fine and glossy clay).It is with color modified inorganic mineral powder
Expect for primary raw material, add a small amount of high molecular weight water soluble polymer, through specific technique make with flexible light
Matter building decoration, this respect are different from porcelain tendre, are the substitution material of preferable traditional decoration building materials porcelain face brick, it is adaptable to coagulation
The energy-conservation of the various newly-built bodies of wall such as soil, building block, external thermal insulation system and existing building and facing transformation.
Flexible clay facing tile can be combined with the various External Thermal Insulation Technology for External for commercially using at present, need not change exterior wall
The original technology way of external thermal insulation, directly pastes in outer thermal-insulating and anti-cracking overcoat.Compared to traditional porcelain face brick outer heat preservation system
Way, flexible clay facing tile have three advantages：
One be safe and reliable from heavy and light, system, it is to avoid as porcelain face brick and the warm and humid shear stress of protective facing are big
The risk for dropping；
Two is that steam permeability is extremely strong, and water proofing property is again splendid, had both overcome rainwater and has penetrated into external wall outer insulation within the walls, and had prevented again
Condensed water occurs freeze thawing to be damaged；
Three is the arrangement of reinforcement quantity that can reduce structure foundation wall, simplifies external wall outer insulation way, simplifies surface brick adherence operation, not only
Work efficiency more than 50% can be improved, and comprehensive cost reduces by more than 30%, remarkable in economical benefits.
Compared to other same type of material, flexible clay facing tile has two big advantages：One is that water repellent and steam permeability are good, generically
Say, be exactly that aqueous water enters not going, vaporous water can be out, it can be ensured that whole body of wall has respiratory.Two is at flexible clay facing tile
Glue is not returned under hot environment, and in the hot water more than 85 DEG C, brew is not returned white and can still be restored to the original state after 96 hours, automatically cleaning
Ability is strong, and the punching of wind water can be bright and clean such as fresh.
Patent 201310143356.6 discloses a kind of flexible clay facing tile, is made up of the material of following weight parts proportioning, water
Mud 35-45, flyash 5-10, fineness are 60 mesh or so quartz sand 20-30, and fineness is 100 mesh or so quartz sand 5-15, wooden
Matter cellulose 1-3, silicon powder 1-5, Pulvis Talci 3-8, calcium oxide 1-5, sodium silicate 1-3, press down alkaline agent 0.5-1, acrylic acid
Rubber powder 2-3, iron oxide pigment 2-5.28 will be added water by every 100 weight portion after material mixing in above-mentioned formula, generally spend
Ionized water, powder is put in water, slurry is broken into homogenizer, by about three kilograms of every square of materials, first by 2/3rds
Slurry uniformly scratch on mould, spread at least one of which 4# alkali resistant glass fibre open weave cloth, then by remaining 1/3rd slurry
On uniform blade coating, finally remove scratch with row brush.
Patent 201310143356.6 discloses a kind of flexible clay facing tile, is made up of the material of following weight parts proportioning, water
Mud 35-45, flyash 5-10, fineness are 60 mesh or so quartz sand 20-30, and fineness is 100 mesh or so quartz sand 5-15, wooden
Matter cellulose 1-3, silicon powder 1-5, Pulvis Talci 3-8, calcium oxide 1-5, sodium silicate 1-3, press down alkaline agent 0.5-1, acrylic acid
Rubber powder 2-3, iron oxide pigment 2-5.28 will be added water by every 100 weight portion after material mixing in above-mentioned formula, generally spend
Ionized water, powder is put in water, slurry is broken into homogenizer, by about three kilograms of every square of materials, first by 2/3rds
Slurry uniformly scratch on mould, spread at least one of which 4# alkali resistant glass fibre open weave cloth, then by remaining 1/3rd slurry
On uniform blade coating, finally remove scratch with row brush.
Patent 201410639871.8 disclose one kind extensively can substitute ceramic tile be applied to architecture inside and outside decoration use
Colour tapestry brick, the flexible colored finish brick include components by weight percent be polymer emulsion 10-20%, firming agent 1-2%, increasing
Modeling agent 1.5-2.5%, thickening agent 0.2-0.5%, colorful quartz sands 60-75% and water 12-14% are mixed through raw material, are criticized
Molding, cutting is scraped, is dried at 45-90 DEG C and is formed, wherein polymer emulsion is pure-acrylic emulsion or silicone acrylic emulsion, and firming agent is first
Phenylene diisocyanate, methyl diphenylene diisocyanate or aliphatic poly cyanate, thickening agent are cellulose etherses or polyurethane
Class thickening agent, colorful quartz sands are the colorful quartz sands that fineness of the natural colorful mineral through crushing, sieving is 140-40 mesh.
The colored flexible clay facing tile of the present invention, have the advantages that formula is simple, with low cost, rich color, resistance to water and flexibility are good,
It is that a kind of ceramic tile that substitutes is applied to the ideal material of architecture inside and outside decoration.
But above-mentioned flexible clay facing tile is all single face brick, all undesirable in terms of wall insulation performance, answer actual
Heat-insulation layer also individually will be laid with, and one side complex procedures are on the other hand relatively costly.
Content of the invention
In order to solve the deficiency that existing building and ornament materials are present, present invention aim at providing a kind of new insulation
Decoration integrated flexible clay facing tile and preparation method thereof.
The present invention is adopted the technical scheme that：
The heat preservation decoration integrative flexible clay facing tile of the present invention is made up of porcelain tendre finish coat and heat-insulation layer, described porcelain tendre
Finish coat is grouped into by the group of following weight portion：8～15 parts of emulsion, 15～25 parts of breeze, 5～15 parts of cement, quartz sand 40
10～25 parts of～60 parts, 5～15 parts of fire retardant, 0.5～2 part of inorganic pigment and water；Described heat-insulation layer is by containing glass fiber net
The group of the following weight portion of lattice cloth is grouped into：8～15 parts of emulsion, 15～25 parts of breeze, 15～25 parts of cement, insulation material 20～
10～25 parts of 50 parts, 5～15 parts of fire retardant, 0.5～2 part of inorganic pigment and water.
It is preferred that：The heat preservation decoration integrative flexible clay facing tile of the present invention is made up of porcelain tendre finish coat and heat-insulation layer, described
Porcelain tendre finish coat be to be grouped into by the group of following weight portion：10 parts of emulsion, 20 parts of breeze, 10 parts of cement, 50 parts of quartz sand, resistance
20 parts of 10 parts of agent of combustion, 1 part of inorganic pigment and water；Described heat-insulation layer is by the component of the following weight portion containing glass fiber reticular cloth
Composition：20 parts of 10 parts of emulsion, 20 parts of breeze, 20 parts of cement, 35 parts of insulation material, 10 parts of fire retardant, 1 part of inorganic pigment and water.
Described emulsion be organosilicon modified acrylic ester elastic emulsion, solid content is 50%, glass transition temperature for-
5～25 DEG C.
Described breeze is the one kind in Kaolin, volcanic ash, flyash or calcium powder.
Described cement is the one kind being numbered in 325,425,525 or 625 white portland cement.
Described quartz sand, its particle diameter are 50～400 mesh.
Described fire retardant is the one kind in antimony oxide, tripolycyanamide and APP.
Described inorganic pigment be white carbon black, titanium white, titan yellow, iron oxide red, iron oxide yellow, barba hispanica, cadmium red, in cadmium yellow one
Plant or two kinds.
Described glass fiber reticular cloth is the glass fiber reticular cloth through fire retardant process.
Described insulation material is haydite, expanded perlite granule, hard polyurethane foam granule and polystyrene foam
One kind in granule.
The preparation method of the heat preservation decoration integrative flexible clay facing tile of the present invention is comprised the following steps that：
(1) preparation of porcelain tendre finish coat：
Weigh breeze, cement and quartz sand by weight, be added in kneader, mix homogeneously obtains mixed powder；By weight
Amount part weighs emulsion, fire retardant, inorganic pigment and water, is added in stirred tank, stirs, obtains mixed emulsion；Again will mixing
Powder is added in mixed emulsion, is sufficiently stirred for, and obtains slurry；Finally slurry is poured in mould, is done in 40～90 DEG C of baking ovens
Dry 1～3h, obtains porcelain tendre finish coat；
(2) preparation of heat preservation decoration integrative tapestry brick：
Weigh breeze, cement and insulation material by weight, be added in kneader, mix homogeneously obtains mixed powder；Press
Weight portion weighs emulsion, fire retardant, inorganic pigment and water, is added in stirred tank, stirs, obtains mixed emulsion；Again will be mixed
Close powder to be added in mixed emulsion, be sufficiently stirred for, obtain slurry；Finally slurry is poured into porcelain tendre decorative layer that step (1) is obtained
Surface, after laying grid cloth, dries 2～6h in 40～90 DEG C of baking ovens, and the dried rear demoulding obtains heat preservation decoration integrative decorations
Face brick.
The preparation method of the heat preservation decoration integrative flexible clay facing tile of the present invention includes slurry preparation, porcelain tendre finish coat and guarantor
Warm formable layer.The preparation method of the present invention is simple, energy-conserving and environment-protective.Porcelain tendre finish coat hydrophobicity is strong, resistance to soiling is good, porcelain tendre finish coat
One entirety is connected into by grout material with insulation interlayer, heat preservation decoration integrative tapestry brick light weight, with decoration and insulation work(
Can, it is a kind of insulation and decoration construction material of excellent combination property.
The positive effect of the present invention is as follows：
1. the porcelain tendre finish coat for being prepared using organosilicon modified acrylic ester elastic emulsion have good pollution resistance,
Water proofing property and weatherability；Heat preservation decoration integrative flexible clay facing tile antidetonation, cracking resistance and good freeze-thaw resistance are given simultaneously；
2. Kaolin, volcanic ash and flyash are not only used as powder stuffing, and produced by cement hydration process
Hydraulicity gel rubber material can be formed under the excitation of calcium hydroxide, improve the strong of heat preservation decoration integrative flexible clay facing tile
Degree；
3. heat preservation decoration integrative flexible clay facing tile good flame resistance, meets the environmental requirement of halogen-free flameproof, reaches fire retardant etc.
Level；
4. the porcelain tendre decorative layer of heat preservation decoration integrative flexible clay facing tile is passed through in porcelain tendre layer and heat-insulation layer with insulation interlayer
Emulsion, breeze and cement realize effectively boning, so as to form a complete body, the construction of heat preservation decoration integrative flexible clay facing tile
Simply, low cost；
5. flame-proof glass fibre grid cloth improves the intensity of heat-insulation layer as reinforcing material, and then improves heat insulation decoration integrated
Change the overall intensity of flexible clay facing tile, improve its safety in utilization；
6. heat preservation decoration integrative flexible clay facing tile is compared with conventional vacuum integrated board, thin have the advantages that light weight, body, whole
Body weight can reduce more than half, and heat conductivity is less than 0.1W/m.K, and compound insulating material is required.
Specific embodiment
The following examples are that the present invention is described in further detail.
Embodiment 1
The preparation method of the heat preservation decoration integrative flexible clay facing tile of the present invention, comprises the following steps that：
(1) preparation of porcelain tendre finish coat：
Weigh 40 parts of 20 parts of Kaolin, 8 parts of 325 white portland cement and 50 mesh quartz sands by weight, be added to kneading
In machine, mix homogeneously obtains mixed powder；Organosilicon-modified acrylic that glass transition temperature be -5 DEG C is weighed by weight
15 parts of 10 parts of ester emulsion, 5 parts of antimony oxide, 1 part of titan yellow and water, are added in stirred tank, stir, obtain mixed emulsion；
Again mixed powder is added in mixed emulsion, is sufficiently stirred for, obtain slurry；Finally slurry is poured in mould, in 40 DEG C of baking ovens
In dry 3h, obtain porcelain tendre finish coat；
(2) preparation of heat preservation decoration integrative flexible clay facing tile：
Weigh 40 parts of 20 parts of Kaolin, 15 parts of 325 white portland cement and expanded perlite granule by weight, be added to
In kneader, mix homogeneously obtains mixed powder；Weigh that glass transition temperature is -5 DEG C by weight organic-silicon-modified third
15 parts of 10 parts of olefin(e) acid ester emulsion, 5 parts of antimony oxide, 1 part of titan yellow and water, are added in stirred tank, stir, and obtain mixing breast
Liquid；Again mixed powder is added in mixed emulsion, is sufficiently stirred for, obtain slurry；Finally by slurry pour that step (1) obtains into soft
Porcelain decor surface, lay one layer through the glass fiber reticular cloth that fire retardant was processed after, dry 6h in 70 DEG C of baking ovens, dried after
The demoulding, obtains heat preservation decoration integrative flexible clay facing tile.
Embodiment 2-6
As shown in table 1, concrete preparation method is with embodiment 1 for the technological parameter of composition of raw materials and preparation.
Table 1
Above-described embodiment gained sample is surveyed according to GB/T3810.13-2006 test pollution resistances, GB/8624-2006 respectively
Examination anti-flammability, GB/T3810.12-2006 test freeze-thaw resistances, GB/T1865-1997 test resistances to ag(e)ing and GB/T10294-
2008 test heat conductivitys.
Table 2
As can be seen from Table 2, the heat preservation decoration integrative flexible clay facing tile that the present invention is prepared has excellent anti-soil
Property, freeze-thaw resistance, anti-flammability and ageing-resistant performance, heat conductivity meets the requirement of thermal insulation decorative material less than 0.1W/m.K.This
The weight of the heat preservation decoration integrative flexible clay facing tile that invention is prepared is light compared with conventional vacuum ornament materials, easy for installation, into
This low, energy-conserving and environment-protective, is a kind of environmental protection thermal insulation decorative material.
Although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
Understanding can carry out multiple changes, modification, replacement to these embodiments without departing from the principles and spirit of the present invention
And modification, the scope of the present invention be defined by the appended.
Claims (10)
1. a kind of heat preservation decoration integrative flexible clay facing tile, it is characterised in that：It is made up of porcelain tendre finish coat and heat-insulation layer, institute
The porcelain tendre finish coat that states is grouped into by the group of following weight portion：8～15 parts of emulsion, 15～25 parts of breeze, 5～15 parts of cement,
10～25 parts of 40～60 parts of quartz sand, 5～15 parts of fire retardant, 0.5～2 part of inorganic pigment and water；Described heat-insulation layer is by containing
The group for having the following weight portion of glass fiber reticular cloth is grouped into：8～15 parts of emulsion, 15～25 parts of breeze, 15～25 parts of cement, insulation
10～25 parts of 20～50 parts of material, 5～15 parts of fire retardant, 0.5～2 part of inorganic pigment and water.
2. heat preservation decoration integrative flexible clay facing tile as claimed in claim 1, it is characterised in that：It is by porcelain tendre finish coat and
Heat-insulation layer is constituted, and described porcelain tendre finish coat is grouped into by the group of following weight portion：10 parts of emulsion, 20 parts of breeze, cement 10
Part, 50 parts of quartz sand, 10 parts of fire retardant, 1 part of inorganic pigment and 20 parts of water；Described heat-insulation layer is by containing glass fiber reticular cloth
The group of following weight portion is grouped into：10 parts of emulsion, 20 parts of breeze, 20 parts of cement, 35 parts of insulation material, 10 parts of fire retardant, inorganic
20 parts of 1 part of pigment and water.
3. heat preservation decoration integrative flexible clay facing tile as claimed in claim 1 or 2, it is characterised in that：Described emulsion is have
Machine fluorine-silicon modified acrylic ester elastomer emulsion, solid content is 50%, and glass transition temperature is -5～25 DEG C.
4. heat preservation decoration integrative flexible clay facing tile as claimed in claim 1 or 2, it is characterised in that：Described breeze is height
One kind in ridge soil, volcanic ash, flyash or calcium powder.
5. heat preservation decoration integrative flexible clay facing tile as claimed in claim 1 or 2, it is characterised in that：Described cement is mark
Number for 325,425,525 or 625 white portland cement in one kind.
6. heat preservation decoration integrative flexible clay facing tile as claimed in claim 1 or 2, it is characterised in that：Described quartz sand, its
Particle diameter is 50～400 mesh.
7. heat preservation decoration integrative flexible clay facing tile as claimed in claim 1 or 2, it is characterised in that：Described fire retardant is
One kind in antimony oxide, tripolycyanamide and APP；Described inorganic pigment is white carbon black, titanium white, titan yellow, ferrum oxide
One or two in red, iron oxide yellow, barba hispanica, cadmium red, cadmium yellow.
8. heat preservation decoration integrative flexible clay facing tile as claimed in claim 1 or 2, it is characterised in that：Described fiberglass mesh
Cloth is the glass fiber reticular cloth through fire retardant process.
9. heat preservation decoration integrative flexible clay facing tile as claimed in claim 1 or 2, it is characterised in that：Described insulation material
For the one kind in haydite, expanded perlite granule, hard polyurethane foam granule and polystyrene foam particles.
10. a kind of method of the heat preservation decoration integrative flexible clay facing tile prepared as described in any one of claim 1-9, its feature
It is：Methods described is comprised the following steps that：
(1) preparation of porcelain tendre finish coat：
Weigh breeze, cement and quartz sand by weight, be added in kneader, mix homogeneously obtains mixed powder；By weight
Emulsion, fire retardant, inorganic pigment and water is weighed, is added in stirred tank, is stirred, obtain mixed emulsion；Again by mixed powder
It is added in mixed emulsion, is sufficiently stirred for, obtains slurry；Finally slurry is poured in mould, dry 1 in 40～90 DEG C of baking ovens～
3h, obtains porcelain tendre finish coat；
(2) preparation of heat preservation decoration integrative tapestry brick：
Weigh breeze, cement and insulation material by weight, be added in kneader, mix homogeneously obtains mixed powder；By weight
Part weighs emulsion, fire retardant, inorganic pigment and water, is added in stirred tank, stirs, obtains mixed emulsion；Again by mixed powder
Material is added in mixed emulsion, is sufficiently stirred for, is obtained slurry；Finally slurry is poured into porcelain tendre decor surface that step (1) is obtained,
After laying grid cloth, 2～6h is dried in 40～90 DEG C of baking ovens, the dried rear demoulding obtains heat preservation decoration integrative tapestry brick.
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| CN108218328A (en) * | 2017-12-07 | 2018-06-29 | 福建省梭普新材料科技有限公司 | A kind of environment-friendly type porcelain tendre and preparation method thereof |
| CN108505705A (en) * | 2018-03-29 | 2018-09-07 | 安徽巨力新型环保材料有限公司 | Soft stone insulation and decoration integrated plate |
| CN108863217A (en) * | 2018-07-10 | 2018-11-23 | 合沐佳成都新材料有限公司 | A kind of inorganic porcelain tendre and preparation method thereof |
| CN109734396A (en) * | 2019-02-22 | 2019-05-10 | 中洁环保新能源科技（西安）有限公司 | A kind of preparation method of ecosystem self-heat conserving and decorating integrative materials for wall |
| CN110066142A (en) * | 2019-04-19 | 2019-07-30 | 江苏苏美材料股份有限公司 | A kind of porcelain tendre of the anti-accumulation of salt in the surface soil of environmental protection |
| CN110437691A (en) * | 2018-05-03 | 2019-11-12 | 徐庆明 | Aqueous inorganic miberal powder insulating mold coating |
| CN110450272A (en) * | 2019-08-29 | 2019-11-15 | 湖北垚美软瓷有限公司 | A kind of multi-use architecture energy-saving flexible house decorative material surface detail processing method |
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| CN108218328A (en) * | 2017-12-07 | 2018-06-29 | 福建省梭普新材料科技有限公司 | A kind of environment-friendly type porcelain tendre and preparation method thereof |
| CN108505705A (en) * | 2018-03-29 | 2018-09-07 | 安徽巨力新型环保材料有限公司 | Soft stone insulation and decoration integrated plate |
| CN110437691A (en) * | 2018-05-03 | 2019-11-12 | 徐庆明 | Aqueous inorganic miberal powder insulating mold coating |
| CN108863217A (en) * | 2018-07-10 | 2018-11-23 | 合沐佳成都新材料有限公司 | A kind of inorganic porcelain tendre and preparation method thereof |
| CN109734396A (en) * | 2019-02-22 | 2019-05-10 | 中洁环保新能源科技（西安）有限公司 | A kind of preparation method of ecosystem self-heat conserving and decorating integrative materials for wall |
| CN110066142A (en) * | 2019-04-19 | 2019-07-30 | 江苏苏美材料股份有限公司 | A kind of porcelain tendre of the anti-accumulation of salt in the surface soil of environmental protection |
| CN110450272A (en) * | 2019-08-29 | 2019-11-15 | 湖北垚美软瓷有限公司 | A kind of multi-use architecture energy-saving flexible house decorative material surface detail processing method |
| CN110450272B (en) * | 2019-08-29 | 2021-05-18 | 湖北垚美软瓷有限公司 | Method for processing surface patterns of multifunctional building energy-saving flexible interior decoration material |
| CN111187032A (en) * | 2019-12-03 | 2020-05-22 | 万卓（武汉）新材料有限公司 | High-performance sound-absorbing damping soft porcelain decorative material and preparation method thereof |
| CN113831075A (en) * | 2020-06-08 | 2021-12-24 | 湖北垚美软瓷有限公司 | Soft porcelain building decoration material and preparation method thereof |
| CN111926986A (en) * | 2020-08-05 | 2020-11-13 | 安徽恒创环保建材有限公司 | Heat-insulating and sound-insulating brick for building |
| CN113603445A (en) * | 2021-09-13 | 2021-11-05 | 广西柔石新型建材有限公司 | Composite building decorative surface sheet and preparation method thereof |
| CN114163175A (en) * | 2021-11-23 | 2022-03-11 | 博亿格装饰材料(宁波)有限公司 | Soft porcelain tile and preparation method thereof |
| CN114163175B (en) * | 2021-11-23 | 2023-01-31 | 博亿格装饰材料(宁波)有限公司 | Soft porcelain tile and preparation method thereof |
| CN114873952A (en) * | 2022-05-31 | 2022-08-09 | 南通大学 | Alkali-free soft porcelain capable of fixing carbon and preparation method thereof |
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