CN103073254A - Flame-retardant flexible facing brick and preparation method thereof - Google Patents
Flame-retardant flexible facing brick and preparation method thereof Download PDFInfo
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- CN103073254A CN103073254A CN2013100469895A CN201310046989A CN103073254A CN 103073254 A CN103073254 A CN 103073254A CN 2013100469895 A CN2013100469895 A CN 2013100469895A CN 201310046989 A CN201310046989 A CN 201310046989A CN 103073254 A CN103073254 A CN 103073254A
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- flame retardant
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- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 40
- 239000003063 flame retardant Substances 0.000 title claims abstract description 40
- 238000002360 preparation method Methods 0.000 title abstract description 18
- 239000011449 brick Substances 0.000 title abstract 5
- 239000000463 material Substances 0.000 claims abstract description 32
- 238000001035 drying Methods 0.000 claims abstract description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000000835 fiber Substances 0.000 claims abstract description 14
- 239000002994 raw material Substances 0.000 claims abstract description 12
- 239000003607 modifier Substances 0.000 claims abstract description 9
- 238000002156 mixing Methods 0.000 claims abstract description 5
- 238000003756 stirring Methods 0.000 claims abstract description 5
- 238000000465 moulding Methods 0.000 claims abstract description 4
- 239000000839 emulsion Substances 0.000 claims description 43
- 239000003795 chemical substances by application Substances 0.000 claims description 39
- 239000000203 mixture Substances 0.000 claims description 31
- 239000004927 clay Substances 0.000 claims description 26
- 229920001577 copolymer Polymers 0.000 claims description 25
- 239000007787 solid Substances 0.000 claims description 22
- -1 acrylic ester Chemical class 0.000 claims description 21
- 230000003712 anti-aging effect Effects 0.000 claims description 16
- 239000004568 cement Substances 0.000 claims description 16
- 239000002002 slurry Substances 0.000 claims description 15
- 239000003638 chemical reducing agent Substances 0.000 claims description 13
- 229920001296 polysiloxane Polymers 0.000 claims description 13
- 239000013530 defoamer Substances 0.000 claims description 12
- 239000003365 glass fiber Substances 0.000 claims description 12
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical group CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 11
- 239000006185 dispersion Substances 0.000 claims description 11
- 239000002893 slag Substances 0.000 claims description 10
- 230000015271 coagulation Effects 0.000 claims description 8
- 238000005345 coagulation Methods 0.000 claims description 8
- 239000003469 silicate cement Substances 0.000 claims description 8
- 239000004575 stone Substances 0.000 claims description 8
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 7
- 239000002518 antifoaming agent Substances 0.000 claims description 7
- 239000002956 ash Substances 0.000 claims description 7
- 235000013312 flour Nutrition 0.000 claims description 7
- 239000010881 fly ash Substances 0.000 claims description 7
- 229910052710 silicon Inorganic materials 0.000 claims description 7
- 239000010703 silicon Substances 0.000 claims description 7
- 239000006004 Quartz sand Substances 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- 229920006243 acrylic copolymer Polymers 0.000 claims description 6
- 239000011507 gypsum plaster Substances 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 5
- 229920001038 ethylene copolymer Polymers 0.000 claims description 5
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 4
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 4
- 235000013339 cereals Nutrition 0.000 claims description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 4
- 239000011976 maleic acid Substances 0.000 claims description 4
- 239000011707 mineral Substances 0.000 claims description 4
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N pentanoic acid group Chemical group C(CCCC)(=O)O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 claims description 4
- 229920000570 polyether Polymers 0.000 claims description 4
- 238000005507 spraying Methods 0.000 claims description 4
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 3
- 239000004917 carbon fiber Substances 0.000 claims description 3
- HDERJYVLTPVNRI-UHFFFAOYSA-N ethene;ethenyl acetate Chemical group C=C.CC(=O)OC=C HDERJYVLTPVNRI-UHFFFAOYSA-N 0.000 claims description 3
- 239000004816 latex Substances 0.000 claims description 3
- 229920000126 latex Polymers 0.000 claims description 3
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 3
- 229920000609 methyl cellulose Polymers 0.000 claims description 3
- 239000001923 methylcellulose Substances 0.000 claims description 3
- 229920005646 polycarboxylate Polymers 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 2
- 150000001298 alcohols Chemical class 0.000 claims description 2
- 150000008431 aliphatic amides Chemical class 0.000 claims description 2
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 2
- 239000002270 dispersing agent Substances 0.000 claims description 2
- 239000000194 fatty acid Substances 0.000 claims description 2
- 229930195729 fatty acid Natural products 0.000 claims description 2
- 150000004665 fatty acids Chemical class 0.000 claims description 2
- 229920001519 homopolymer Polymers 0.000 claims description 2
- 150000002632 lipids Chemical class 0.000 claims description 2
- 150000002762 monocarboxylic acid derivatives Chemical group 0.000 claims description 2
- DGVVJWXRCWCCOD-UHFFFAOYSA-N naphthalene;hydrate Chemical compound O.C1=CC=CC2=CC=CC=C21 DGVVJWXRCWCCOD-UHFFFAOYSA-N 0.000 claims description 2
- 239000012188 paraffin wax Substances 0.000 claims description 2
- 229920003023 plastic Polymers 0.000 claims description 2
- 239000004033 plastic Substances 0.000 claims description 2
- 239000005871 repellent Substances 0.000 claims description 2
- 230000002940 repellent Effects 0.000 claims description 2
- 150000003376 silicon Polymers 0.000 claims description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 2
- 229920002554 vinyl polymer Polymers 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 abstract description 2
- 239000003086 colorant Substances 0.000 abstract 1
- 239000013538 functional additive Substances 0.000 abstract 1
- 230000035699 permeability Effects 0.000 abstract 1
- 239000002245 particle Substances 0.000 description 21
- 239000000843 powder Substances 0.000 description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 239000004744 fabric Substances 0.000 description 4
- 239000004205 dimethyl polysiloxane Substances 0.000 description 3
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 2
- 235000013539 calcium stearate Nutrition 0.000 description 2
- 239000008116 calcium stearate Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000010257 thawing Methods 0.000 description 2
- 230000008719 thickening Effects 0.000 description 2
- 229920000604 Polyethylene Glycol 200 Polymers 0.000 description 1
- WUGQZFFCHPXWKQ-UHFFFAOYSA-N Propanolamine Chemical compound NCCCO WUGQZFFCHPXWKQ-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 238000006253 efflorescence Methods 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 235000019633 pungent taste Nutrition 0.000 description 1
- 206010037844 rash Diseases 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
Landscapes
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The invention relates to a flame-retardant flexible facing brick and a preparation method thereof, which are characterized in that the flame-retardant flexible facing brick comprises the following raw material components in percentage by mass based on the total weight of the raw materials: 40.0-60.0% of aggregate, 10.0-40.0% of inorganic cementing material, 10.0-30.0% of flexible modifier, 1.0-5.5% of functional additive, 0-1.0% of fiber and 0-10.0% of water. The raw materials are prepared by mixing, stirring, molding and drying. The flame-retardant flexible facing brick prepared by the invention takes the inorganic cementing material as a bonding material and takes the high molecular polymer as a flexible modifier, so that the flame-retardant flexible facing brick not only has the advantages of high toughness, good air permeability, strong hydrophobicity, good matching degree with various base layers, rich pattern colors and the like, but also has very good flame-retardant property and excellent durability which can keep the integral structure for a long time.
Description
Technical field
The present invention relates to a kind of interior wall face, table top etc. of can be used for and have flame retardant type flexible clay facing tile of excellent flame retardancy energy and long service life and preparation method thereof, belong to a kind of building and ornament materials.
Background technology
Flexible clay facing tile is the finishing material that can be used for indoor and outdoor metope, table top with certain flexibility that latest developments are got up.It is easy construction not only, and good decorating effect, also is specially adapted to high-rise outer wall and uses with respect to the rigidity finishing material from the security aspect.But, present flexible clay facing tile mainly be with polymer emulsion as consolidating material and flexible properties-correcting agent, such material or goods have good elasticity and flexibility, but also have two subject matters:
The one, facing tile is mainly as ornament layer and the protective layer of metope etc.; but organic bonding component wherein can progressively occur aging under the effect of light, heat, water and atmosphere and decompose within a short period of time; thereby ineffective gradually, cause structure to be disintegrated, so that facing tile efflorescence or come off.
The 2nd, this flexible clay facing tile organic constituent accounts for significant proportion, and these component burning-points are very low, can discharge a large amount of pungencys, toxic gas during very easy firing, and burning, has more increased the harm when fire occurs.
Summary of the invention
The objective of the invention is in order to overcome the defects of prior art and product, and provide a kind of flame retardant type flexible clay facing tile, another object of the present invention has provided the preparation method of above-mentioned flame retardant type flexible clay facing tile, solves the problem of ageing-resistant poor, the poor fire of present flexible clay facing tile.
Technical scheme of the present invention is: a kind of flame retardant type flexible clay facing tile, it is as consolidating material by inorganic coagulation material, take emulsion polymerization as flexible properties-correcting agent, fiber or grid cloth are split material for resistance, with the inorganic powder particle for gathering materials, and add according to demand defoamer, dispersion agent, water reducer, anti-aging agent, hydrophober, the functional admixture such as consistency modifiers, by mixing, stir, moulding and in addition dry form a kind of have a low elastic modulus, high flame retardant, the finishing material of long-life characteristics, flame retardant properties reaches the A2 level, Young's modulus is minimum can to reach 1730.0MPa, and water-intake rate is the highest by 6.0%.
Concrete technical scheme of the present invention is: a kind of flame retardant type flexible clay facing tile, it is characterized in that, the quality percentage composition that its material component and each component account for the raw material total amount is respectively: 40.0～60.0% gather materials, 10.0～40.0% inorganic coagulation material, 10.0～30.0% flexible properties-correcting agent, 1.0～5.5% functional admixture, 0～1.0% fiber, 0～10.0% water.
Preferred described inorganic coagulation material is one or more in silicate cement, aluminosulfate cement, white cement or the building gypsum plaster, with one or more the mixture in flyash, breeze or the silicon ash; Wherein to account for the quality percentage composition of raw material total amount be 5-15% to one or more in silicate cement, aluminosulfate cement, white cement or the building gypsum plaster, and the quality percentage composition that one or more in flyash, breeze, the silicon ash account for the raw material total amount is 5-25%.
Preferred described flexible properties-correcting agent is vinyl acetate between to for plastic homopolymer emulsion, vinyl acetate between to for plastic-maleic acid ester copolymer emulsion, vinyl acetate-ethylene copolymer emulsion, vinyl acetate between to for plastic-tertiary monocarboxylic acid ethylene copolymer emulsion, the vinyl chloride-vinylidene chloride copolymer emulsion, the butadiene-styrene copolymer emulsion, the pure acrylate copolymer emulsion, the pure acrylate self-crossing emulsion, the vinyl acetate-acrylic copolymer emulsion, vinyl acetate between to for plastic-vinylchlorid-AA emulsion, latex of copolymer in cinnamic acrylic ester, tertiary ethylene carbonate-acrylate copolymer emulsion, one or more mixtures of Silicone-Acrylic Copolymer Emulsion; The quality solid content of flexible properties-correcting agent is 45.0%～60.0%.
Preferably described gathering materials be the mixture in a kind of or several in quartz sand, stone flour, clay, discarded concrete, bottom slag, grain slag, slag or the gas concrete scrap stock.The maximum particle size of preferably gathering materials is 1/4～1/3 of facing tile thickness, and grain size distribution meets particle closestpacking principle.
Preferred described functional admixture is at least a kind of in defoamer, dispersion agent, water reducer, anti-aging agent, hydrophober or the consistency modifiers; Wherein defoamer is at least a kind of in polyether antifoam agent, higher alcohols defoamer, polyether-modified silicon defoaming agent or the polysiloxane defoamers; Dispersion agent is at least a kind of in lipid acid dispersion agent, aliphatic amide dispersion agent or the paraffin dispersant; Water reducer is at least a kind of in naphthalene water reducer, aliphatic water reducing agent or the polycarboxylate water-reducer; Anti-aging agent is at least a kind of in two (2.2-dimethyl benzyl) pentanoic of N-phenyl-α-aniline, 4.4-or the N-phenyl-N`-sec.-propyl-Ursol D; Hydrophober is at least a kind of in organosilicon moisture repellent, higher fatty acid hydrophober or the modified polyvinyl alcohol hydrophober; Consistency modifiers is at least a kind of in methylcellulose gum, Vltra tears, Xylo-Mucine, Natvosol, lignocellulose or the polyvinyl alcohol.The quality percentage composition that more preferably individual component accounts for the raw material total amount in the functional admixture is respectively: 0～0.5% defoamer, 0～0.5% dispersion agent, 0～0.5% water reducer, 0.5～1.0% anti-aging agent, 0.5～2.0% hydrophober, 0～1.0% consistency modifiers.
Preferred described fiber is any one or a few in glass fibre, mineral fibre or the carbon fiber.
The present invention also provides the preparation method of above-mentioned flame retardant type flexible clay facing tile, and its concrete steps are: 40.0～60.0% gather materials of raw material total mass, 10.0～40.0% inorganic coagulation material, 10.0～30.0% flexible properties-correcting agent, 1.0～5.5% functional admixtures, 0～1.0% fiber and 0～10.0% water mixing and stirring are obtained having mobile slurry; Slurry is taken shape on the mould, perhaps be pressed into alkali-proof glass fiber mesh after the moulding; Carry out the drying oven dry after leaving standstill; Dried facing tile obtains the flame retardant type flexible clay facing tile through the demoulding and on demand cutting.
The compound use of one or more that preferred describedly be shaped to spraying, extrude, suppress or whitewash etc.
Preferred described time of repose is 0.5-1 hour, and drying temperature is 50-120 ℃.
Beneficial effect:
Product provided by the present invention has good flexibility, all has good matching from different body of wall basic unit, can avoid temperature variation etc. to cause producing displacement stress between body of wall and the facing tile and comes off; Product has good ventilation property, hydrophobic nature and very high degree of compactness, prevent that outside moisture from infiltrating, be conducive to simultaneously the evaporation of internal steam, not only be conducive to reduce in the facing tile preparation process and dry energy consumption, freeze thawing occurs and destroys the bonding of facing tile in the interface of avoiding body of wall basic unit and facing tile, also can at utmost avoid the facing tile internal moisture to disintegrate owing to freeze thawing destroys the facing tile one-piece construction simultaneously; Facing tile is take inorganic coagulation material as main consolidating material, and not only its weather resistance is the facing tile of binding agent preparation considerably beyond organic materials, and its flame retardant properties also far surpasses like product, can reach the A2 level.
Embodiment
Embodiment 1 is with the quartz sand of 58.3% maximum particle diameter 1.0mm, 52.5 grades of aluminosulfate cements of 5.0%, 52.5 grades of white cements of 5.0%, 10.0% breeze, 15.0% pure acrylate copolymer emulsion (solid content is 50.0%), 0.5% polydimethylsiloxane defoamer 5300,0.5% polysiloxane powder hydrophober SHP-50, N-phenyl-α of 0.5%-aniline anti-aging agent, 0.2% glass fibre, 5.0% water mixing and stirring obtains having the slurry of certain fluidity, the method of slurry with spraying is coated on the mould of certain decorative pattern, thickness reaches 3.0～5.0mm, then be pressed into alkali-proof glass fiber mesh, leave standstill and enter complete drying in 100.0 ± 10.0 ℃ of drying tunnels of temperature after 0.5 hour, then form removal can cut into the facing tile of the size that needs.After testing, the facing tile flame retardant properties reaches the A2 level, and Young's modulus is 4520.0MPa, and water-intake rate is 3.2%.
Embodiment 2 is the stone flour of 2.0mm with 50.0% maximum particle diameter, 52.5 grades of silicate cements of 8.0%, 3.0% building gypsum plaster, 5.0% silicon ash, 10.0% breeze, 10.0% latex of copolymer in cinnamic acrylic ester (solid content is 50.0%), 4.7% vinyl acetate-ethylene copolymer emulsion (solid content is 550%), N-phenyl-α of 0.5%-aniline anti-aging agent, 1.0% polysiloxane powder hydrophober SHP-50,0.8% glass fibre, 7.0% water mix and blend and with the preparation slurry with the compacting method be expressed on the mould, thickness 3.0～5.0mm, leaving standstill and entering temperature after 0.5 hour is in 80.0 ± 10.0 ℃ of drying tunnels behind the complete drying, can be cut into required big or small facing tile through form removal.After testing, the facing tile flame retardant properties reaches the A2 level, and Young's modulus is 3547.0MPa, and water-intake rate is 3.5%.
Embodiment 3 is with the quartz sand of 25.0% maximum particle diameter 1.0mm, the grain slag of 20.0% maximum particle diameter 1.0mm, 52.5 grades of aluminosulfate cements of 5.0%, 52.5 grades of white cements of 5.0%, 12.0% breeze, 8.0% pure acrylate copolymer emulsion (solid content is 50.0%), vinyl acetate between to for plastic-vinylchlorid of 15.0%-AA emulsion (solid content is 46.0%), 5.0% Silicone-Acrylic Copolymer Emulsion (solid content is 45.0%), 0.3% silicone ethylene glycol defoamer, two (2.2-dimethyl benzyl) the pentanoic anti-aging agent of 0.5% 4.4-, 0.5% calcium stearate hydrophober, 0.5% Vltra tears thickening material, 0.2% mineral fibre, 3% water mix and blend and with the preparation slurry be coated in 3.0～4.0mm on the mould with spraying method, leaving standstill and entering temperature after 1.0 hours is in 60.0 ± 10.0 ℃ of drying tunnels behind the complete drying, can be cut into the flame retardant type facing tile of desired size through form removal.After testing, the facing tile flame retardant properties reaches the A2 level, and Young's modulus is 1730.0MPa, and water-intake rate is 4.0%.
Embodiment 4 is the gas concrete scrap stock of 2.0mm with 8.0% maximum particle diameter, the bottom slag of 10.0% maximum particle diameter 2.0mm, 30.0% maximum particle diameter is no more than the discarded concrete of 1.0mm, 52.5 grades of silicate cements of 10.0%, 52.5 grades of aluminosulfate cements of 2.0%, 15.0% breeze, 10.0% flyash, tertiary ethylene carbonate-acrylate copolymer emulsion of 5.0% (solid content is 45.0%), 5.0% vinyl acetate between to for plastic-maleic acid ester copolymer emulsion (solid content is 50.0%), 0.5% polydimethylsiloxane defoamer 5300,1.5% polysiloxane powder hydrophober SHP-50,0.5% N-phenyl-N`-sec.-propyl-Ursol D anti-aging agent, 2.5% water mix and blend and with the preparation slurry be squeezed into 5.0～6.0mm and be pressed into the alkali resistant glass fiber reticular cloth, leave standstill and enter after 0.5 hour in 110.0 ± 10.0 ℃ of drying tunnels of temperature behind the complete drying, can be cut into the flame retardant type facing tile through form removal.After testing, the facing tile flame retardant properties reaches the A2 level, Young's modulus 3444.0MPa, water-intake rate 5.7%.
Embodiment 5 is the colour stone powder of 1.0mm with 52.0% maximum particle diameter, 52.5 grades of aluminosulfate cements of 10.0%, 15.0% breeze, 10.0% butadiene-styrene copolymer emulsion (solid content is 50.0%), tertiary ethylene carbonate-acrylate copolymer emulsion of 10.0% (solid content is 45.0%), 0.3% polyoxyethylene polyoxy Propanolamine ether defoaming agent, 0.7% polysiloxane powder hydrophober SHP-50,0.5% N-phenyl-N`-sec.-propyl-Ursol D anti-aging agent, 1.5% water mix and blend and with the preparation slurry be sprayed on the template, thickness 3.0～5.0mm, leave standstill and enter after 1 hour in the drying tunnel behind the complete drying, can be cut into colored flame retardant type facing tile through form removal.After testing, the facing tile flame retardant properties reaches the A2 level, and Young's modulus is 2305.0MPa, and water-intake rate is 4.2%.
Embodiment 6 is the stone flour of 1.0mm with 35.0% maximum particle diameter, 18.5% maximum particle diameter is no more than the clay of 0.5mm, 52.5 grades of silicate cements of 7.0%, 5.0% breeze, 10.0% pure acrylate copolymer emulsion (solid content is 50.0%), 10% pure acrylate self-crossing emulsion (solid content is 50.0%), 0.5% Polyether Modified Polysiloxanes Defoaming Agent LM110,1.5% polycarboxylate water-reducer (solid content is 40.0%), 1%N-phenyl-α-aniline anti-aging agent, 0.5% calcium stearate hydrophober, 0.5% lignocellulose thickening material, 0.5% polyoxyethylene glycol PEG-200 dispersion agent, 10% water mix and blend and with the preparation slurry be squeezed on the template, thickness 3.0～5.0mm, and be pressed into alkali-proof glass fiber mesh, leave standstill and enter after 1 hour in 80 ± 10 ℃ of drying tunnels of temperature behind the complete drying, can be cut into required big or small facing tile through form removal.After testing, the facing tile flame retardant properties reaches the A2 level, and Young's modulus is 4408.0MPa, and water-intake rate is 2.2%.
Embodiment 7 is with the stone flour of 28.0% maximum particle diameter 1.0mm, quartz sand with 15.0% maximum particle diameter 1.0mm, 52.5 grades of silicate cements of 10.0%, 10.0% flyash, 5.0% silicon ash, tertiary ethylene carbonate-acrylate copolymer emulsion of 25.0% (solid content is 45.0%), 0.2% Polyether Modified Polysiloxanes Defoaming Agent LM110, N-phenyl-α of 1.0%-aniline anti-aging agent, 0.5% polysiloxane powder hydrophober SHP-50,0.3% polyvinyl alcohol consistency modifiers, 0.7% carbon fiber, 4.3% water mix and blend and with the preparation slurry spray on the mould, thickness 3.0～5.0mm, leaving standstill after 1.0 hours in temperature is in 80.0 ± 10.0 ℃ the drying tunnel behind the complete drying, can be cut into the desired size facing tile through form removal.After testing, the facing tile flame retardant properties reaches the A2 level, and Young's modulus is 2196.0MPa, and water-intake rate is 4.7%.
Embodiment 8 is with the slag of 30.0% maximum particle diameter 1.0mm, the bottom slag of 20.0% maximum particle diameter 1.0mm, 10.0% building gypsum plaster, 15.0% flyash, 10.0% pure acrylate self-crossing emulsion (solid content is 50.0%), 10.0% vinyl acetate between to for plastic-maleic acid ester copolymer emulsion (solid content is 50.0%), two (2.2-dimethyl benzyl) the pentanoic anti-aging agent of 1.0% 4.4-, 1.0% polysiloxane powder hydrophober SHP-50,0.5% glass fibre, 2.5% water mix and blend and with the preparation slurry with the compacting method be expressed on the mould, leaving standstill and entering temperature after 0.5 hour is in 80.0 ± 10.0 ℃ the drying tunnel behind the complete drying, can be cut into the desired size facing tile through form removal.After testing, the facing tile flame retardant properties reaches the A2 level, and Young's modulus is 2706.0MPa, and water-intake rate is 2.7%.
Embodiment 9 is with the stone flour of 50.0% maximum particle diameter 0.5mm, 52.5 grades of white cements of 10.0%, 15.0% breeze, 15.0% pure acrylate copolymer emulsion (solid content is 50.0%), 6.0% vinyl chloride-vinylidene chloride copolymer emulsion (solid content is 48.0%), 0.5% polydimethylsiloxane defoamer 5300, N-phenyl-α of 1.0%-aniline anti-aging agent, 1.0% polysiloxane powder hydrophober SHP-50,0.5% methylcellulose thickener, 1.0% glass fibre mix and blend and with the preparation slurry whitewash on the mould, thickness 1.0～2.0mm, leaving standstill and entering temperature after 1.0 hours is in 100 ± 10 ℃ of drying tunnels behind the complete drying, can be cut into the desired size facing tile through form removal.After testing, the facing tile flame retardant properties reaches the A2 level, and Young's modulus is 3243.0MPa, and water-intake rate is 3.5%.
Embodiment 10 is with the stone flour of 35.0% maximum particle diameter 1.0mm, the quartz sand of 15.0% maximum particle diameter 0.5mm, the clay of 5.0% maximum particle diameter 0.5mm, 52.5 grades of aluminosulfate cements of 10.0%, 5.0% silicon ash, 10.0% breeze, tertiary ethylene carbonate-acrylate copolymer emulsion of 10.0% (solid content is 45.0%), 5.0% Silicone-Acrylic Copolymer Emulsion (solid content is 50.0%), N-phenyl-α of 0.5%-aniline anti-aging agent, 1.0% polysiloxane powder hydrophober SHP-50,0.5% glass fibre, 0.5% mineral fibre, 2.5% water mix and blend and with the preparation slurry with the compacting method be expressed on the mould, thickness 3.0～5.0mm, then be pressed into the alkali proof fiber grid cloth, leave standstill in the drying tunnel that enters 100.0 ± 10.0 ℃ after 1.0 hours behind the complete drying, can be cut into required big or small facing tile through form removal.After testing, the facing tile flame retardant properties reaches the A2 level, Young's modulus 3759.0MPa, water-intake rate 3.8%.
Below only be several preparation examples of flame retardant type flexible clay facing tile, according to above inorganic cementing, the principle of design that macromolecule membrane, inorganic fibre and grid cloth are toughness reinforcing can be prepared the flame retardant type flexible clay facing tile of different sizes, different specific weight, different texture and color.
Claims (8)
1. flame retardant type flexible clay facing tile, it is characterized in that, the quality percentage composition that its material component and each component account for the raw material total amount is respectively: 40.0 ~ 60.0% gather materials, 10.0 ~ 40.0% inorganic coagulation material, 10.0 ~ 30.0% flexible properties-correcting agent, 1.0 ~ 5.5% functional admixture, 0 ~ 1.0% fiber, 0 ~ 10.0% water.
2. according to flame retardant type flexible clay facing tile claimed in claim 1, it is characterized in that described inorganic coagulation material is one or more in silicate cement, aluminosulfate cement, white cement or the building gypsum plaster, with one or more the mixture in flyash, breeze or the silicon ash; Wherein to account for the quality percentage composition of raw material total amount be 5-15% to one or more in silicate cement, aluminosulfate cement, white cement or the building gypsum plaster, and the quality percentage composition that one or more in flyash, breeze, the silicon ash account for the raw material total amount is 5-25%.
3. according to flame retardant type flexible clay facing tile claimed in claim 1, it is characterized in that described flexible properties-correcting agent is vinyl acetate between to for plastic homopolymer emulsion, vinyl acetate between to for plastic-maleic acid ester copolymer emulsion, vinyl acetate-ethylene copolymer emulsion, vinyl acetate between to for plastic-tertiary monocarboxylic acid ethylene copolymer emulsion, the vinyl chloride-vinylidene chloride copolymer emulsion, the butadiene-styrene copolymer emulsion, the pure acrylate copolymer emulsion, the pure acrylate self-crossing emulsion, the vinyl acetate-acrylic copolymer emulsion, vinyl acetate between to for plastic-vinylchlorid-AA emulsion, latex of copolymer in cinnamic acrylic ester, tertiary ethylene carbonate-acrylate copolymer emulsion, one or more mixtures of Silicone-Acrylic Copolymer Emulsion; The quality solid content of flexible properties-correcting agent is 45.0% ~ 60.0%.
4. according to flame retardant type flexible clay facing tile claimed in claim 1, it is characterized in that described gathering materials is the mixture in a kind of or several in quartz sand, stone flour, clay, discarded concrete, bottom slag, grain slag, slag or the gas concrete scrap stock.
5. according to flame retardant type flexible clay facing tile claimed in claim 1, it is characterized in that described functional admixture is at least a kind of in defoamer, dispersion agent, water reducer, anti-aging agent, hydrophober or the consistency modifiers; Wherein defoamer is at least a kind of in polyether antifoam agent, higher alcohols defoamer, polyether-modified silicon defoaming agent or the polysiloxane defoamers; Dispersion agent is at least a kind of in lipid acid dispersion agent, aliphatic amide dispersion agent or the paraffin dispersant; Water reducer is at least a kind of in naphthalene water reducer, aliphatic water reducing agent or the polycarboxylate water-reducer; Anti-aging agent is at least a kind of in two (2.2-dimethyl benzyl) pentanoic of N-phenyl-α-aniline, 4.4-or the N-phenyl-N`-sec.-propyl-Ursol D; Hydrophober is at least a kind of in organosilicon moisture repellent, higher fatty acid hydrophober or the modified polyvinyl alcohol hydrophober; Consistency modifiers is at least a kind of in methylcellulose gum, Vltra tears, Xylo-Mucine, Natvosol, lignocellulose or the polyvinyl alcohol.
6. according to flame retardant type flexible clay facing tile claimed in claim 1, it is characterized in that described fiber is any one or a few in glass fibre, mineral fibre or the carbon fiber.
7. method for preparing flame retardant type flexible clay facing tile as claimed in claim 1, its concrete steps are: 40.0 ~ 60.0% gather materials of raw material total mass, 10.0 ~ 40.0% inorganic coagulation material, 10.0 ~ 30.0% flexible properties-correcting agent, 1.0 ~ 5.5% functional admixtures, 0 ~ 1.0% fiber and 0 ~ 10.0% water mixing and stirring are obtained having mobile slurry, slurry is taken shape on the mould, perhaps then be pressed into alkali-proof glass fiber mesh after the moulding; Carry out the drying oven dry after leaving standstill; Dried facing tile obtains the flame retardant type flexible clay facing tile through the demoulding and on demand cutting.
8. in accordance with the method for claim 7, it is characterized in that describedly being shaped to spraying, one or more the compound use in extruding, suppress or whitewashing.
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Application publication date: 20130501 Assignee: JIANGSU SUMEI MATERIAL TECHNOLOGY Co.,Ltd. Assignor: Nanjing Tech University Contract record no.: 2013320000169 Denomination of invention: Flame-retardant flexible facing tile and preparation method thereof License type: Exclusive License Record date: 20130320 |
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