CN109053056A - A method of city-wall brick is prepared using shield waste pulp - Google Patents

A method of city-wall brick is prepared using shield waste pulp Download PDF

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Publication number
CN109053056A
CN109053056A CN201811174288.9A CN201811174288A CN109053056A CN 109053056 A CN109053056 A CN 109053056A CN 201811174288 A CN201811174288 A CN 201811174288A CN 109053056 A CN109053056 A CN 109053056A
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CN
China
Prior art keywords
city
waste pulp
wall brick
shield
preparing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811174288.9A
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Chinese (zh)
Inventor
符勇
台枫
王铁成
朱智超
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Henan Skillful Craftsman Network Technology Co Ltd
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Henan Skillful Craftsman Network Technology Co Ltd
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Publication date
Application filed by Henan Skillful Craftsman Network Technology Co Ltd filed Critical Henan Skillful Craftsman Network Technology Co Ltd
Priority to CN201811174288.9A priority Critical patent/CN109053056A/en
Publication of CN109053056A publication Critical patent/CN109053056A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/006Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing mineral polymers, e.g. geopolymers of the Davidovits type
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

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  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The present invention discloses a kind of method for preparing city-wall brick using shield waste pulp, belong to ancient building recovery technology field, the following steps are included: by percentage to the quality, by raw material by following proportion mixing: shield waste pulp 55%~65%, flyash 15%~25%, miberal powder 15%~20%, exciting agent 3%~5%, iron oxide black 0~2%;Raw material after mixing evenly is sent into hydraulic brick making machine molding, briquetting pressure is 20~40MPa, opens sample after 24 hours;Molding city-wall brick sprinkling maintenance 7 days.Of the invention preparation method is simple, at low cost, and energy conservation and environmental protection.

Description

A method of city-wall brick is prepared using shield waste pulp
Technical field
The present invention relates to ancient building recovery technology field, in particular to a kind of side that city-wall brick is prepared using shield waste pulp Method.
Background technique
With the continuous promotion of Chinese national economy, more and more tier 2 cities, even three line cities are high, also start to repair Subway is built, thus generates a large amount of shield waste pulp every year.During shield-tunneling construction, excavation earth material is mixed to form highly dense with muddy water Mud is spent, by slurry pump and pipeline to ground, by drum screen, the physical separation such as desander are formed can not reuse in engineering Thick slurry, thickness slurry is discharged into abandoning stock tank.The slurry-outlet quantity of slurry shield is generally 2~3 times of digging volume, if without appropriate, it will Periphery ecological environment can be damaged.Meanwhile shield spoir is underground deep layer soil property, the pollution of itself is small, is fabulous Recycling material, therefore proper treatment should be subject to, in favor of development and utilization from now on.
Traditional mud conditioning technology has landfill method, solidification method, soil cultivating method etc..Common landfill method volume of earthwork It is bigger, and do not have ecological functions, hidden danger may be left for Environmental security;Solidification method high expensive, and thoroughly change The physical property for having become shield spoir increases the difficulty of resource utilization;Soil cultivating method is to topography and geomorphology and soil knot Structure is more demanding, is not easy expansion and implements.
Currently, the construction of the characteristic small town town He Gu old countries is being carried out in domestic many places, need a large amount of caesious imitative Ancient city wall brick, country again forbid fire clay brick, this for the resource utilization of shield waste pulp provide good Policy Background with Huge social demand.
Summary of the invention
The present invention provides a kind of methods for preparing city-wall brick using shield waste pulp, and preparation method is simple for this, cost It is low, energy conservation and environmental protection, use easy to spread.
The technical solution of the present invention is as follows:
A method of city-wall brick is prepared using shield waste pulp, comprising the following steps:
(1) it stirs: by percentage to the quality, by raw material by following proportion mixing: shield waste pulp 55%~65%, flyash 15%~25%, miberal powder 15%~20%, exciting agent 3%~5%, iron oxide black 0~2%;
(2) it forms: hydraulic brick making machine molding, briquetting pressure 20 will be sent by the raw material of step (1) after mixing evenly ~40MPa opened sample after 24 hours;
(6) it conserves: molding city-wall brick sprinkling maintenance 7 days.
Wherein it is preferred to which the moisture content of the shield waste pulp, less than 25%, density is less than 1.3g/cm3
Wherein it is preferred to which the miberal powder is solid waste-Water Quenching Slag of iron-smelter sale, drying grinding to 300 mesh The above fineness.
Wherein it is preferred to which it is 0.5~1.5:1 bunt gypsum and white cement that the exciting agent, which is weight ratio,.
Wherein it is preferred to which the fineness of the bunt gypsum is 200 mesh, the fineness of the white cement is 200 mesh.
The exciting agent is saline and alkaline composite material, and bunt gypsum and white cement clinker can provide villaumite excitation, sulphate activation It with good triple stimulation effects caused by alkali-activated carbonatite, can react, aggregate into strong with shield waste pulp, flyash and miberal powder Higher bulk material is spent, the intensity requirement of city-wall brick is met.Also, added with iron oxide black, the mesh for adjusting city-wall brick color is played 's.If flyash color is darker, iron oxide black can be used less, can also not have to, keep the color of city-wall brick more life-like.
Beneficial effects of the present invention:
1. shield waste pulp have been carried out resource utilization by preparation method of the invention, scientific disposal makes its minimizing, harmless Change, recycling and innoxious, it is at low cost, and energy-saving ring is kept.
2. there is good compression strength and frost resistance using the city-wall brick of the method for the present invention preparation, and brick body color is blueness Grey, color are more life-like.
3. city-wall brick of the invention uses compression moulding, complex production process in sintering process, energy consumption height, Yi Chan great are avoided The problem of carbon dioxide isothermal chamber gas of amount.
4. of the invention, preparation method is simple, at low cost, and energy conservation and environmental protection.
Specific embodiment
Below in conjunction with the specific embodiment of the invention, technical solution of the present invention is clearly and completely described, is shown So, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based on the reality in the present invention Example is applied, every other embodiment obtained by those of ordinary skill in the art without making creative efforts all belongs to In the scope of protection of the invention.
In following embodiments, used useless structure shield slurry is the pulp of slurry shield by pre-sifted separation and cyclonic separation Thickness slurry, moisture content 20%, density 1.2g/cm3.The miberal powder is Water Quenching Slag, drying grinding to 300 mesh.
Embodiment 1
The present embodiment provides a kind of methods for preparing city-wall brick using shield waste pulp, comprising the following steps:
(1) it stirs: by percentage to the quality, by raw material by following proportion mixing: shield waste pulp 60%, flyash 20%, Miberal powder 15%, exciting agent 4%, iron oxide black 1%;
(2) it forms: hydraulic brick making machine molding will be sent by the raw material of step (1) after mixing evenly, briquetting pressure is 30MPa opened sample after 24 hours;
(6) it conserves: molding city-wall brick sprinkling maintenance 7 days.
Wherein, it is 1:1 bunt gypsum and white cement that the exciting agent, which is weight ratio, and the fineness of the bunt gypsum is 200 mesh, institute The fineness for stating white cement is 200 mesh.
Embodiment 2
The present embodiment provides a kind of methods for preparing city-wall brick using shield waste pulp, comprising the following steps:
(1) it stirs: by percentage to the quality, by raw material by following proportion mixing: shield waste pulp 55%, flyash 25%, Miberal powder 15%, exciting agent 5%;
(2) it forms: hydraulic brick making machine molding will be sent by the raw material of step (1) after mixing evenly, briquetting pressure is 40MPa opened sample after 24 hours;
(6) it conserves: molding city-wall brick sprinkling maintenance 7 days.
Wherein, it is 0.5:1 bunt gypsum and white cement that the exciting agent, which is weight ratio, and the fineness of the bunt gypsum is 200 mesh, The fineness of the white cement is 200 mesh.
Embodiment 3
The present embodiment provides a kind of methods for preparing city-wall brick using shield waste pulp, comprising the following steps:
(1) it stirs: by percentage to the quality, by raw material by following proportion mixing: shield waste pulp 65%, flyash 15%, Miberal powder 15%, exciting agent 3%, iron oxide black 2%;
(2) it forms: hydraulic brick making machine molding will be sent by the raw material of step (1) after mixing evenly, briquetting pressure is 20MPa opened sample after 24 hours;
(6) it conserves: molding city-wall brick sprinkling maintenance 7 days.
Wherein, it is 1.5:1 bunt gypsum and white cement that the exciting agent, which is weight ratio, and the fineness of the bunt gypsum is 200 mesh, The fineness of the white cement is 200 mesh.
Embodiment 4
The present embodiment provides a kind of methods for preparing city-wall brick using shield waste pulp, comprising the following steps:
(1) it stirs: by percentage to the quality, by raw material by following proportion mixing: shield waste pulp 58%, flyash 20%, Miberal powder 15%, exciting agent 5%, iron oxide black 2%;
(2) it forms: hydraulic brick making machine molding will be sent by the raw material of step (1) after mixing evenly, briquetting pressure is 30MPa opened sample after 24 hours;
(6) it conserves: molding city-wall brick sprinkling maintenance 7 days.
Wherein, it is 1:1 bunt gypsum and white cement that the exciting agent, which is weight ratio, and the fineness of the bunt gypsum is 200 mesh, institute The fineness for stating white cement is 200 mesh.
Embodiment 5
The present embodiment provides a kind of methods for preparing city-wall brick using shield waste pulp, comprising the following steps:
(1) it stirs: by percentage to the quality, by raw material by following proportion mixing: shield waste pulp 62%, flyash 16%, Miberal powder 18%, exciting agent 3%, iron oxide black 1%;
(2) it forms: hydraulic brick making machine molding will be sent by the raw material of step (1) after mixing evenly, briquetting pressure is 30MPa opened sample after 24 hours;
(6) it conserves: molding city-wall brick sprinkling maintenance 7 days.
Wherein, it is 1:1 bunt gypsum and white cement that the exciting agent, which is weight ratio, and the fineness of the bunt gypsum is 200 mesh, institute The fineness for stating white cement is 200 mesh.
City-wall brick performance system made from embodiment 1 to 5 is detected, the specification of brick is 480mm × 240mm when test × 100mm, test result is as follows shown in table 1:
As upper table content it is found that using romote antiquity brick made from preparation method of the present invention with good compression strength and freeze proof Property, meet GB/T8239-2014 standard requirements.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention Within mind and principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.

Claims (5)

1. a kind of method for preparing city-wall brick using shield waste pulp, it is characterised in that the following steps are included:
(1) it stirs: by percentage to the quality, by raw material by following proportion mixing: shield waste pulp 55%~65%, flyash 15% ~25%, miberal powder 15%~20%, exciting agent 3%~5%, iron oxide black 0~2%;
(2) form: will by the raw material of step (1) after mixing evenly be sent into hydraulic brick making machine molding, briquetting pressure be 20~ 40MPa opened sample after 24 hours;
(6) it conserves: molding city-wall brick sprinkling maintenance 7 days.
2. a kind of method for preparing city-wall brick using shield waste pulp according to claim 1, it is characterised in that: the shield For the moisture content of waste pulp less than 25%, density is less than 1.3g/cm3
3. a kind of method for preparing city-wall brick using shield waste pulp according to claim 1, it is characterised in that: the miberal powder For the Water Quenching Slag of iron-smelter sale, drying grinding to the above fineness of 300 mesh.
4. a kind of method for preparing city-wall brick using shield waste pulp according to claim 1, it is characterised in that: the excitation Agent is that weight ratio is 0.5~1.5:1 bunt gypsum and white cement.
5. a kind of method for preparing city-wall brick using shield waste pulp according to claim 4, it is characterised in that: the salt stone The fineness of cream is 200 mesh, and the fineness of the white cement is 200 mesh.
CN201811174288.9A 2018-10-09 2018-10-09 A method of city-wall brick is prepared using shield waste pulp Pending CN109053056A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110451855A (en) * 2019-07-27 2019-11-15 中建科技有限公司 A kind of processing method and cement products of engineering spoir

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3437680A1 (en) * 1984-10-15 1986-04-17 Tubag Trass-, Zement- Und Steinwerke Gmbh, 5473 Kruft Binder for restoration mortar
CN103073254A (en) * 2013-02-05 2013-05-01 南京工业大学 Flame-retardant flexible facing brick and preparation method thereof
CN104788063A (en) * 2015-04-29 2015-07-22 河海大学 Unfired and pressing-free sludge brick and preparation method thereof
CN108358491A (en) * 2018-02-02 2018-08-03 中南大学 A kind of integrated conduct method and mixing feeding device of shield discarded slurry

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3437680A1 (en) * 1984-10-15 1986-04-17 Tubag Trass-, Zement- Und Steinwerke Gmbh, 5473 Kruft Binder for restoration mortar
CN103073254A (en) * 2013-02-05 2013-05-01 南京工业大学 Flame-retardant flexible facing brick and preparation method thereof
CN104788063A (en) * 2015-04-29 2015-07-22 河海大学 Unfired and pressing-free sludge brick and preparation method thereof
CN108358491A (en) * 2018-02-02 2018-08-03 中南大学 A kind of integrated conduct method and mixing feeding device of shield discarded slurry

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
洛阳建筑材料工业学校等: "《水泥工艺原理》", 31 May 1981, 中国建筑工业出版社 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110451855A (en) * 2019-07-27 2019-11-15 中建科技有限公司 A kind of processing method and cement products of engineering spoir
CN110451855B (en) * 2019-07-27 2022-05-06 中建科技有限公司 Treatment method of engineering waste soil and cement product

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Application publication date: 20181221