CN106830862B - A kind of lime base raw-soil texture ornament materials and preparation method thereof - Google Patents
A kind of lime base raw-soil texture ornament materials and preparation method thereof Download PDFInfo
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- CN106830862B CN106830862B CN201710032012.6A CN201710032012A CN106830862B CN 106830862 B CN106830862 B CN 106830862B CN 201710032012 A CN201710032012 A CN 201710032012A CN 106830862 B CN106830862 B CN 106830862B
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- 239000002689 soil Substances 0.000 title claims abstract description 69
- 235000008733 Citrus aurantifolia Nutrition 0.000 title claims abstract description 46
- 235000015450 Tilia cordata Nutrition 0.000 title claims abstract description 46
- 235000011941 Tilia x europaea Nutrition 0.000 title claims abstract description 46
- 239000004571 lime Substances 0.000 title claims abstract description 46
- 239000000463 material Substances 0.000 title claims abstract description 40
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 239000000843 powder Substances 0.000 claims abstract description 17
- 239000011230 binding agent Substances 0.000 claims abstract description 15
- 239000000835 fiber Substances 0.000 claims abstract description 15
- 229920001479 Hydroxyethyl methyl cellulose Polymers 0.000 claims abstract description 12
- 229920000126 Latex Polymers 0.000 claims abstract description 12
- 239000004816 latex Substances 0.000 claims abstract description 12
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims abstract description 11
- 230000002940 repellent Effects 0.000 claims abstract description 7
- 239000005871 repellent Substances 0.000 claims abstract description 7
- 238000002156 mixing Methods 0.000 claims description 7
- 239000002994 raw material Substances 0.000 claims description 7
- 238000006477 desulfuration reaction Methods 0.000 claims description 4
- 230000003009 desulfurizing Effects 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 239000012530 fluid Substances 0.000 claims description 3
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 2
- 239000004115 Sodium Silicate Substances 0.000 claims description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N Sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 2
- NTGONJLAOZZDJO-UHFFFAOYSA-M disodium;hydroxide Chemical compound [OH-].[Na+].[Na+] NTGONJLAOZZDJO-UHFFFAOYSA-M 0.000 claims description 2
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 2
- 125000003342 alkenyl group Chemical group 0.000 claims 1
- 229920002678 cellulose Polymers 0.000 claims 1
- 239000001913 cellulose Substances 0.000 claims 1
- -1 hydroxyethyl methyl Chemical group 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 11
- 238000010276 construction Methods 0.000 abstract description 7
- 238000005034 decoration Methods 0.000 abstract description 5
- 239000000758 substrate Substances 0.000 abstract description 5
- 239000007787 solid Substances 0.000 abstract description 3
- 230000001070 adhesive Effects 0.000 abstract description 2
- 230000035699 permeability Effects 0.000 abstract 1
- 239000002699 waste material Substances 0.000 abstract 1
- 239000002585 base Substances 0.000 description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 238000010521 absorption reaction Methods 0.000 description 5
- 238000007906 compression Methods 0.000 description 3
- 238000001514 detection method Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000011056 performance test Methods 0.000 description 3
- 238000009825 accumulation Methods 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive Effects 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 230000003628 erosive Effects 0.000 description 2
- 230000002209 hydrophobic Effects 0.000 description 2
- 238000002386 leaching Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2R,3R,4S,5R,6S)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2S,3R,4S,5R,6R)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2R,3R,4S,5R,6R)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 description 1
- 229920002522 Wood fibre Polymers 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 230000000875 corresponding Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 239000002910 solid waste Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/10—Lime cements or magnesium oxide cements
- C04B28/12—Hydraulic lime
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
Abstract
The present invention relates to a kind of lime base raw-soil texture ornament materials and preparation method thereof.The weight fraction of each component is as follows: white lime is 25~40 parts, Desulphurization is 10~20 parts, vinyl redispersable latex powder is 0.4~1.2 part, hydroxyethylmethylcellulose is 0.03~0.15 part, organosilicon moisture repellent is 0.1~0.3 part, raw-soil binder is 0.5~1.0 part, and fiber is 0.05~0.2 part, and total weight number is 100 parts.Construction wall compatibility, the matching of lime base raw-soil texture ornament materials of the present invention and various substrates are good, and have many advantages, such as good workability, adhesive property, gas permeability and waterproofness, construction wall can be made to have the decoration texture similar with traditional earth building wall, it can be applied to the wall facing decoration engineering of various substrates, and largely utilize industrial solid castoff, economic cost is lower, has good environmental protection and energy-conserving profit waste effect.
Description
Technical field
The invention belongs to building material technical fields, and in particular to arrive a kind of lime base raw-soil sense ornament materials and preparation side
Method.
Background technique
China has a large amount of historical building to build using the raw-soil, the spy that appearance has raw-soil wall unique, natural, simple and unsophisticated
Color, but find exist in historical building region and largely use other during the reparation of these historical buildings and protection
The building of the construction such as construction material such as brick, stone, concrete, decorating inner and external walls mostly use the Modern Decoratives material such as coating, ceramic tile
Material, appearance and traditional history building are extremely uncoordinated, seriously destroy the whole style and features of historical building block.To keep historical building all
The modern architecture enclosed have with the consistent inside and outside looks of serveing as a lookout of traditional earth building, maintain historical building block style and features harmony,
The decoration material that a kind of and various substrates construction wall compatibilities are good, caking property is excellent and have raw-soil wall appearance need to be designed
Material, to meet the requirement of the different inside and outside layer decorations of wall substrate.
Summary of the invention
The present invention passes through scientific research and practice test, the activity of integrated reuse-recycle fluidized-bed combustion boiler Desulphurization and lime
Excitation, the exterior decorative effect of the raw-soil, the adhesion strength of polymeric additive and the reinforcement effect of raw-soil binder, and
By Study on Preparation, successfully prepare it is a kind of meet different substrate materials construction wall decorative engineering needs, have traditional life
Native architectural appearance, one-component lime base raw-soil texture ornament materials, but also industrial solid castoff is largely comprehensively utilized,
With significant economic benefit, social benefit and environmental benefit.
In view of the deficiencies of the prior art, the present invention intends to be ground by mixtures optimal design and preparation method
Study carefully, prepares physical and mechanical property good stable, the lime base raw-soil matter with good wall body decoration effect and adhesive property
Feel ornament materials and preparation method, and largely comprehensively utilize industrial solid castoff, economize on resources and the energy, protects environment.
In order to solve the above-mentioned technical problem, the application, which adopts the following technical scheme that, is achieved:
A kind of lime base raw-soil texture ornament materials, be made of following raw material: the raw-soil, white lime, Desulphurization, vinyl can
Redisperse latex powder, hydroxyethylmethylcellulose, organosilicon moisture repellent, raw-soil binder and fiber.
With weight basis, form by following raw material: the raw-soil is 45~65 parts, and white lime is 25~40 parts, and Desulphurization is
10~20 parts, vinyl redispersable latex powder is 0.4~1.2 part, and hydroxyethylmethylcellulose is 0.03~0.15 part, organic
Silicon hydrophober is 0.1~0.3 part, and raw-soil binder is 0.5~1.0 part, and fiber is 0.05~0.2 part, and total weight number is 100
Part.
Specifically, the raw-soil was grit number in 100 mesh raw-soil powder below.
Preferably, the Desulphurization is circulating fluid bed boiler desulfurization ash.
Specifically, the hydroxyethylmethylcellulose viscosity is 10000~45000mPas.
Specifically, the fiber is the wood fibre that diameter is 0.5~3mm.
Specifically, the raw-soil binder is the sodium silicate of modulus 3.3, molecular formula Na2O·nSiO2。
Preferably, with weight basis, form by following raw material: white lime is 38 parts, and Desulphurization is 12 parts, and vinyl can
Redisperse latex powder is 1.0 parts, and hydroxyethylmethylcellulose is 0.08 part, and organosilicon moisture repellent is 0.3 part, and raw-soil binder is
0.8 part, fiber is 0.1 part, and the raw-soil is 47.72 parts, and total weight number is 100 parts.
The preparation method of the lime base raw-soil texture ornament materials:
On the basis of the composition of raw materials of the lime base raw-soil texture ornament materials,
This method includes following procedure: firstly, vinyl redispersable latex powder, ethoxy are added into high-speed mixer
Methylcellulose, organosilicon moisture repellent, raw-soil binder and fiber mix equal under the mixing rate of 500~1000r/min
Even, then, the mixed mixing rate for adjusting high-speed mixer is 80~250r/min, and white lime, Desulphurization and the raw-soil is added,
It is uniformly mixed, obtains lime base raw-soil texture ornament materials.
Lime base raw-soil texture ornament materials finished product of the present invention is the powder body material of one pack system, only need to be when construction
It is stirred 3~4min with water by construction site at a given proportion, that is, can be used.
Lime base raw-soil texture ornament materials testing result proposed by the present invention is as shown in table 1.
1 lime base raw-soil texture ornament materials basic performance of table
As can be seen from Table 1, lime base raw-soil texture ornament materials proposed by the present invention, physical and mechanical property is good,
It can meet or more than relevant criterion requirement, there is good water resistance and adhesion strength and excellent outer wall decorative effect.
Compared with prior art, the present invention beneficial has the technical effect that
Lime base raw-soil texture ornament materials proposed by the present invention is made using the raw-soil as filler and pigment with white lime
For major gelled material, while circulating fluid bed boiler desulfurization ash is added as hydraulicity additive improve the strong of white lime material
Degree and water resistance etc., on the one hand can reduce using high energy consumption caused by cement, on the other hand can also promote solid waste
Resource utilization.
Lime base raw-soil texture ornament materials proposed by the present invention, has a wide range of application, smears suitable for various building inside and outside walls
Face engineering especially needs and the consistent various plastering engineerings of raw-soil wall body decoration effect.The present invention has excellent application property
Can, operable time is long, water absorption rate is low, compression strength is high, performance is good for knot, good decorating effect, also with particularly pertinent weather-proof
Property and long-term behaviour.
Each performance indicator of lime base raw-soil texture ornament materials proposed by the present invention is excellent, and preparation method is simple and easy to do, produces
Product quality is easily controllable, and workability is excellent, and decorative effect is prominent, and long-term behaviour is superior, and durability is good, is suitable for various buildings
Exterior wall plastering engineering, is convenient for large-scale promotion application.
Specific embodiment
The present invention is further illustrated below by embodiment.
Embodiment 1: a kind of lime base raw-soil texture ornament materials, component and proportion (mass percent) are as follows: white lime
It is 38 parts, Desulphurization is 12 parts, and vinyl redispersable latex powder is 1.0 parts, and hydroxyethylmethylcellulose is 0.08 part, organic
Silicon hydrophober is 0.3 part, and raw-soil binder is 0.8 part, and fiber is 0.1 part, and the raw-soil is 47.72 parts, and total weight number is 100
Part.
The results of property that detection test obtains is as shown in table 2.
The lime base raw-soil texture ornament materials the performance test results of 2 embodiment 1 of table
| Project | Measured performance |
| Operable time | 180min |
| Initial dry cracking resistance | Flawless |
| 30min water absorption/g | 0.8 |
| 240min water absorption/g | 1.5 |
| Flexural strength/MPa | 5.6 |
| Compression strength/MPa | 8.5 |
| Tensile bond strength/MPa | 1.5 |
| Alkali burnout resistance | Without the visible accumulation of salt in the surface soil, do not lose powder |
| Stain resistance | 1 |
| Weatherability | Appearance is unchanged after 28 rainwater leaching erosions |
Embodiment 2: a kind of lime base raw-soil texture ornament materials, component and proportion (mass percent) are as follows: white lime
It is 25 parts, Desulphurization is 18 parts, and vinyl redispersable latex powder is 0.8 part, and hydroxyethylmethylcellulose is 0.06 part, hydrophobic
Agent is 0.25 part, and raw-soil binder is 0.6 part, and fiber is 0.15 part, and the raw-soil is 55.14 parts, and total weight number is 100 parts.
The results of property that detection test obtains is as shown in table 3.
The lime base raw-soil texture ornament materials the performance test results of 3 embodiment 2 of table
Embodiment 3: a kind of lime base raw-soil texture ornament materials, component and proportion (mass percent) are as follows: white lime
It is 35 parts, Desulphurization is 20 parts, and vinyl redispersable latex powder is 1.0 parts, and hydroxyethylmethylcellulose is 0.12 part, hydrophobic
Agent is 0.3 part, and raw-soil binder is 1.0 parts, and fiber is 0.15 part, and the raw-soil is 42.43 parts, and total weight number is 100 parts.
The results of property that detection test obtains is as shown in table 4.
The lime base raw-soil texture ornament materials the performance test results of 4 embodiment 3 of table
| Project | Measured performance |
| Operable time | 130min |
| Initial dry cracking resistance | Flawless |
| 30min water absorption/g | 0.8 |
| 240min water absorption/g | 1.3 |
| Flexural strength/MPa | 5.0 |
| Compression strength/MPa | 9.5 |
| Tensile bond strength/MPa | 1.8 |
| Alkali burnout resistance | Without the visible accumulation of salt in the surface soil, do not lose powder |
| Stain resistance | 1 |
| Weatherability | Appearance is unchanged after 28 rainwater leaching erosions |
It, can be according to architectural engineering by above embodiments as it can be seen that lime base raw-soil texture ornament materials proposed by the present invention
It is required that making corresponding product.Performance indexes is all satisfied or is more than relevant criterion and engine request, and it is outer to can be used as building
Wall decorative engineering material, plays good decorative effect, can be with wide popularization and application in various external walls plastering engineering.
Claims (2)
1. a kind of lime base raw-soil texture ornament materials, it is characterised in that: be made of following raw material: the raw-soil, white lime, desulfurization
Ash, vinyl redispersable latex powder, hydroxyethylmethylcellulose, organosilicon moisture repellent, raw-soil binder and fiber；
With weight basis, form by following raw material: the raw-soil is 45~65 parts, and white lime is 25~40 parts, Desulphurization is 10~
20 parts, vinyl redispersable latex powder is 0.4~1.2 part, and hydroxyethylmethylcellulose is 0.03~0.15 part, and organosilicon is hated
Aqua is 0.1~0.3 part, and raw-soil binder is 0.5~1.0 part, and fiber is 0.05~0.2 part, the sum of parts by weight of raw material
It is 100 parts；
The raw-soil was grit number in 100 mesh raw-soil powder below；The Desulphurization is circulating fluid bed boiler desulfurization ash；
The hydroxyethylmethylcellulose viscosity is 10000~45000mPas；The fibre diameter is the wooden fibre of 0.5~3mm
Dimension；The raw-soil binder is the sodium silicate of modulus 3.3, molecular formula Na2O·nSiO2；
The preparation method of the lime base raw-soil texture ornament materials includes following procedure: firstly, second is added into high-speed mixer
Alkenyl redispersable latex powder, hydroxyethylmethylcellulose, organosilicon moisture repellent, raw-soil binder and fiber, 500~
It is uniformly mixed under the mixing rate of 1000r/min, then, the mixed mixing rate for adjusting high-speed mixer is 80~250r/
White lime, Desulphurization and the raw-soil is added in min, is uniformly mixed, obtains lime base raw-soil texture ornament materials.
2. a kind of preparation method of lime base raw-soil texture ornament materials, it is characterised in that: this method is used such as claim 1 institute
The formula for the lime base raw-soil texture ornament materials stated；
This method includes following procedure: firstly, vinyl redispersable latex powder, hydroxyethyl methyl are added into high-speed mixer
Cellulose, organosilicon moisture repellent, raw-soil binder and fiber are uniformly mixed, so under the mixing rate of 500~1000r/min
Afterwards, the mixed mixing rate for adjusting high-speed mixer is 80~250r/min, and white lime, Desulphurization and the raw-soil, mixing is added
Uniformly, lime base raw-soil texture ornament materials is obtained.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710032012.6A CN106830862B (en) | 2017-01-17 | 2017-01-17 | A kind of lime base raw-soil texture ornament materials and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710032012.6A CN106830862B (en) | 2017-01-17 | 2017-01-17 | A kind of lime base raw-soil texture ornament materials and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106830862A CN106830862A (en) | 2017-06-13 |
| CN106830862B true CN106830862B (en) | 2019-04-12 |
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ID=59124116
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110240459A (en) * | 2019-06-29 | 2019-09-17 | 西安建筑科技大学 | A kind of masonry ancient building reinforcement and repair fluidized bed combustion coal ash/slag reconciliation water lime mortar and preparation method |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110194638A (en) * | 2019-06-24 | 2019-09-03 | 西安建筑科技大学 | A kind of earth building reinforcement and repair slag reconciliation water lime mortar and preparation method thereof |
| CN110317029A (en) * | 2019-07-03 | 2019-10-11 | 西安建筑科技大学 | A kind of masonry ancient building reinforcement and repair silicon ash reconciliation water lime mortar and preparation method |
| CN112940545A (en) * | 2021-02-08 | 2021-06-11 | 天津城建大学 | Decorative waterproof coating for protecting raw soil surface and construction method |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102010173B (en) * | 2010-11-15 | 2012-08-15 | 重庆大学 | Method for preparing heat insulation anti-cracking raw soil bricks |
| CN104844090B (en) * | 2015-05-05 | 2018-01-12 | 中国建筑材料科学研究总院 | A kind of raw-soil suitable for raw-soil building block is plastered binding material and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110240459A (en) * | 2019-06-29 | 2019-09-17 | 西安建筑科技大学 | A kind of masonry ancient building reinforcement and repair fluidized bed combustion coal ash/slag reconciliation water lime mortar and preparation method |
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