CN106433923A - 环境友好合金钢精密丝杆车削液组合物 - Google Patents

环境友好合金钢精密丝杆车削液组合物 Download PDF

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CN106433923A
CN106433923A CN201610840975.4A CN201610840975A CN106433923A CN 106433923 A CN106433923 A CN 106433923A CN 201610840975 A CN201610840975 A CN 201610840975A CN 106433923 A CN106433923 A CN 106433923A
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agent
turning liquid
lead screw
steel alloy
environmental friendliness
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黄福川
王玥
赵金城
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Guangxi University
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Guangxi University
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/08—Halogenated waxes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/04—Detergent property or dispersant property
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/14—Metal deactivation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/18—Anti-foaming property
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/64—Environmental friendly compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

本发明公开了环境友好合金钢精密丝杆车削液组合物，采用10号工业白油作为基础油，配合多种复合添加剂，它们包拈：抗氧剂、金属减活剂、油性剂、摩擦改进剂、极压剂、抗磨剂、防锈剂、抗氧抗腐剂、抗泡剂、催冷剂等。本发明的组合物具有良好的冷却性，降低被加工件的温度，减小热变形，且可以提高刀具的使用寿命和螺纹表面的光洁度，还具有良好的扩散性、渗透性、极压抗磨性、抗氧抗腐性、防锈性、清洁性、抗泡性以及漆料相容性。

Description

环境友好合金钢精密丝杆车削液组合物
技术领域
本发明属于金属加工润滑剂领域，特别涉及环境友好合金钢精密丝杆车削液组合物。
背景技术
在机床制造过程中，经常要车削精密的丝杆，其材质是合金钢。由于丝杆是刚性较差的细长轴，加上其结构的形状交杂，车削精度和表面光洁度的要求很高。因此，精密丝杆的车削比普通螺纹的车削要困难得多。为了确保精密丝杆的精度要求，工艺上必须采用相应的技术手段来解决车削加工中遇到的困难。这些措施包括：车刀的形状和几何角度、切削用量的选择、膜的材料、车刀的总长以及车削冷却液的选择。而切削冷却液应具有良好的冷却性，降低被加工件的温低，减小热变形，且可以提高刀具的使用寿合和螺纹表面的光洁度，还具有良好的扩散性、渗透性、极压抗磨性、抗氧抗腐性、防锈性、清洁性、抗泡性以及漆料相容性。
发明内容
本发明要解决的技术问题是提供一种具有良好的冷却性，降低被加工件的温度，减小热变形，且可以提高刀具的使用寿命和螺纹表面的光洁度，还具有良好的扩散性、渗透性、极压抗磨性、抗氧抗腐性、防锈性、清洁性、抗泡性以及漆料相容性的环境友好合金钢精密丝杆车削液组合物。
本发明采用以下技术方案解决上述技术问题：
环境友好合金钢精密丝杆车削液组合物，采用10号工业白油作为基础油，配合多种复合添加剂，其各自质量百分数的成分组成：
组分 质量百分比含量
基础油 余量
抗氧剂 0.08～0.3％
金属减活剂 0.05～0.15％
油性剂 4～6％
摩擦改进剂 2～4％
极压剂 3～5％
抗磨剂 3～5％
防锈剂 0.08～1.5％
抗氧抗腐剂 0.8～1.5％
抗泡剂 50～100ppm
催冷剂 0.5～2％
以上各组分质量百分比总和为100％。
抗氧剂是质量比50％的2，6-二叔丁基混合酚T502A和50％二烷基二苯胺T534复合；金属减活剂是质量比50％的噻重氮和50％苯三唑衍生物T551复合。
油性剂是硫化棉籽油T404；摩擦改进剂是磷酸酯T451A。
极压剂是氯化石蜡T302。
抗磨剂是硫化异丁烯T321；防锈剂是质量比50％的石油磺酸钠T701和50％烷基磷酸咪唑啉盐T708复合。
抗氧抗腐剂是硫磷丁辛基锌盐T202；抗泡剂是1号复合抗泡剂T921。
催冷剂是石油磺酸钠45#。
本发明的环境友好合金钢精密丝杆车削液组合物的显著优点：具有良好的冷却性，降低被加工件的温度，减小热变形，且可以提高刀具的使用寿命和螺纹表面的光洁度，还具有良好的扩散性、渗透性、极压抗磨性、抗氧抗腐性、防锈性、清洁性、抗泡性以及漆料相容性。
具体实施方式
实施例1：
将以下各组分按质量百分比调和而成：
以上各组分质量百分比总和为100％。
实施例2：
将以下各组分按质量百分比调和而成：
以上各组分质量百分比总和为100％。
实施例3：
将以下各组分按质量百分比调和而成：
以上各组分质量百分比总和为100％。
实施例3产品的主要理化指标：
项目 质量指标
40℃运动粘度/mm2·s-1 13.1
凝点/℃ -8
闪点(开口)/％ 155
腐蚀试验(铜片，100℃，3h) 合格
四球机试验，Pa/N 887
水分/％ 痕迹
液相锈蚀试验(合成海水) 无锈
机械杂质 无
空气释放值(50℃)/min 7
破乳化值(40-37-3),54℃/min 15
烧结负荷，PD/N 6760
梯姆肯，N 291
氷溶性酸或碱 无
FZG，级 14

Claims (7)

1.环境友好合金钢精密丝杆车削液组合物，其特征在于：采用10号工业白油作为基础油，配合多种复合添加剂，其各自质量百分数的成分组成：
组分 质量百分比含量 基础油 余量 抗氧剂 0.08～0.3％ 金属减活剂 0.05～0.15％ 油性剂 4～6％ 摩擦改进剂 2～4％ 极压剂 3～5％ 抗磨剂 3～5％ 防锈剂 0.08～1.5％ 抗氧抗腐剂 0.8～1.5％ 抗泡剂 50～100ppm 催冷剂 0.5～2％
以上各组分质量百分比总和为100％。
2.如权利要求1所述的环境友好合金钢精密丝杆车削液组合物，其特征在于抗氧剂是质量比50％的2，6-二叔丁基混合酚T502A和50％二烷基二苯胺T534复合；金属减活剂是质量比50％的噻重氮和50％苯三唑衍生物T551复合。
3.如权利要求1所述的环境友好合金钢精密丝杆车削液组合物，其特征在于油性剂是硫化棉籽油T404；摩擦改进剂是磷酸酯T451A。
4.如权利要求1所述的环境友好合金钢精密丝杆车削液组合物，其特征在于极压剂是氯化石蜡T302。
5.如权利要求1所述的环境友好合金钢精密丝杆车削液组合物，其特征在于抗磨剂是硫化异丁烯T321；防锈剂是质量比50％的石油磺酸钠T701和50％烷基磷酸咪唑啉盐T708复合。
6.如权利要求1所述的环境友好合金钢精密丝杆车削液组合物，其特征在于抗氧抗腐剂是硫磷丁辛基锌盐T202；抗泡剂是1号复合抗泡剂T921。
7.如权利要求1所述的环境友好合金钢精密丝杆车削液组合物，其特征在于催冷剂是石油磺酸钠45#。
CN201610840975.4A 2016-09-21 2016-09-21 环境友好合金钢精密丝杆车削液组合物 Pending CN106433923A (zh)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102533418A (zh) * 2010-12-20 2012-07-04 中国第一汽车集团公司 环保型微乳切削液
CN102766510A (zh) * 2012-08-16 2012-11-07 温州宝罗润滑材料有限公司 一种超高极压型微乳化切削液及其制备方法
CN103666704A (zh) * 2013-12-14 2014-03-26 广西大学 挤压铅及铅合金材料的润滑剂
CN104893807A (zh) * 2015-05-28 2015-09-09 华北水利水电大学 一种无尘室导轨丝杆机构润滑脂

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102533418A (zh) * 2010-12-20 2012-07-04 中国第一汽车集团公司 环保型微乳切削液
CN102766510A (zh) * 2012-08-16 2012-11-07 温州宝罗润滑材料有限公司 一种超高极压型微乳化切削液及其制备方法
CN103666704A (zh) * 2013-12-14 2014-03-26 广西大学 挤压铅及铅合金材料的润滑剂
CN104893807A (zh) * 2015-05-28 2015-09-09 华北水利水电大学 一种无尘室导轨丝杆机构润滑脂

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
熊云等: "《油品应用及管理》", 31 May 2004, 中国石化出版社 *

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Application publication date: 20170222