CN106380362A - Colorful whistling type firework combined reagent - Google Patents
Colorful whistling type firework combined reagent Download PDFInfo
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- CN106380362A CN106380362A CN201610737964.3A CN201610737964A CN106380362A CN 106380362 A CN106380362 A CN 106380362A CN 201610737964 A CN201610737964 A CN 201610737964A CN 106380362 A CN106380362 A CN 106380362A
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- perchlorate
- chloro
- powder
- colour
- flute sound
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- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B33/00—Compositions containing particulate metal, alloy, boron, silicon, selenium or tellurium with at least one oxygen supplying material which is either a metal oxide or a salt, organic or inorganic, capable of yielding a metal oxide
- C06B33/12—Compositions containing particulate metal, alloy, boron, silicon, selenium or tellurium with at least one oxygen supplying material which is either a metal oxide or a salt, organic or inorganic, capable of yielding a metal oxide the material being two or more oxygen-yielding compounds
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- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
Abstract
The invention discloses a colorful whistling type firework combined reagent, which comprises the following components in mass percentage: 10-15% of 4-chloro-3-nitro-phthalate, 15-30% of p-potassium biphthalate, 20-30% of barium perchlorate 35-50 and rest perchlorate, 1-5% of carbon material and 1-5% of metal powder. The total proportion of all the components is 100%. The perchlorate is one selected from strontium perchlorate, calcium perchlorate and barium perchlorate. The carbon material is one or the combination of several components selected from bamboo charcoal powder, carbon nanotube powder and activated carbon powder. The metal powder is one or the combination of several components selected from titanium powder, aluminum powder and magnesium powder. According to the technical scheme of the invention, during the setting off process, the colorful whistling type firework combined reagent is good in acoustical quality, bright in color, small in hygroscopicity, safe, and reliable. Therefore, the colorful whistling type firework combined reagent is good in application prospect.
Description
Technical field
The present invention relates to a kind of fireworks combination medicament, more particularly to a kind of colour flute sound fireworks combination medicament.
Background technology
Fireworks are divided into two classes, and a class is sibilant rale class fireworks, can send whistle during such firework display, and this fireworks typically contain
Sibilant rale medicament, such as gallic acid Potassium Benzoate, Potassium Hydrogen Phthalate；One class is colourful fireworks, permissible during such firework display
Produce color miscellaneous, such as redness, green, blue etc., this fireworks with the addition of slaine, unique using different metal
Flame reaction produces color, such as adds strontium carbonate, strontium chloride, barium chloride, sodium sulfate etc..
At present, also there is document report both can produce color, the fireworks of melodious sibilant rale can be sent again, such as Mo Runping works out one
Kind new firework raw material-redness sibilant rale agent, Chemical Industry in Guangzhou, 04 phase in 1988, this sibilant rale agent is with the aromatic acid containing phenyl ring and inorganic
Strontium be raw material, through dissolving, filtration, synthetic reaction, concentration, centrifuge dehydration, drying, pulverizing and prepare although this sibilant rale agent both
Can produce red, birdie can be sent again, but there is paler colour using the cigarette medicine that this sibilant rale agent makes, lifting height is not high,
The shortcomings of reducing agent can only be made with potassium chlorate.
Wang Chunnian have developed a kind of method with industrial terylene waste material preparation two hydrogen terephthalate strontiums and its in fireworks side
The application in face, priming system, 03 phase in 1997, but, show in the document, with two hydrogen terephthalate strontiums as sibilant rale agent, should
Make oxidant from potassium chlorate, sibilant rale agent optimum formula is 30% 2 para Toluic Acid's hydrogen strontium, 70% potassium chlorate.Because potassium chlorate is sensitive
Degree is high, has been prohibited as fireworks and firecrackers medicament, therefore doing sibilant rale agent using two para Toluic Acid's hydrogen strontiums cannot industrial applications.
Content of the invention
The present invention completes to solve of the prior art not enough, it is an object of the invention to provide a kind of acoustical quality
Colored flute sound fireworks combination medicament good, that bright colors, hygroscopicity are little, safe and reliable.
Each component of colour flute sound fireworks combination medicament of the present invention and quality proportioning are：4- chloro- 3- nitro neighbour's benzene two
Formates 10%-15%, to benzene dipotassium potassium hydrogen phthalate 15%-30%, potassium hyperchlorate 35-50 and remaining perchlorate 20%-30%, carbon materials
Material 1%-5%, metal dust 1%-5%, each component toatl proportion sum of all medicaments is 100%.
A kind of colour flute sound fireworks combination medicament of the present invention, can also be：
Further, the chloro- 3- nitrophthalic acid salt of described 4- is 3- nitrophthalic acid strontium chloro- to 4-, 4- chloro- 3- nitre
One kind of base calcium phthalate, 4- chloro- 3- nitrophthalic acid barium.
Further, described perchlorate is perchloric acid strontium, Calcium perchlorate, one kind of barium perchlorate；Described perchlorate
Metal ion 3- chloro- with described 4- nitrophthalic acid salt metal ion consistent.
Further, described material with carbon element is bamboo charcoal powder, carbon nanometer tube powder, the one or more combination of activated carbon powder.
Further, described metal dust is titanium valve, aluminium powder, the one or more combination of magnesium powder.
Further, the grain diameter of the chloro- 3- nitrophthalic acid salt of described 4- is 30-100 μm, described perchlorate
Grain diameter be 50-120 μm.
4- chloro- 3- nitrophthalic acid salt described in the described component of the present invention can also select Strontium terephthalate
Or p-phthalic acid barium, its proportioning is same as described above.
A kind of colour flute sound fireworks combination medicament of the present invention, in terms of existing technologies, it this have the advantage that sound
Matter effect is good, bright colors, hygroscopicity are little, safe and reliable；Due to the synergism of nitro, make terephthalate and perchloric acid
The acoustical quality that reactant salt produces strengthens；Because terephthalate and perchlorate are all containing identical metal ion, and by
The synergism of chloride ion on phenyl, makes the flame reaction of metal ion strengthen, during firework display, color is brighter；Due to
Nitro and the effect of material with carbon element, make medicament react and strengthen, improve the quick-fried of fireworks and make dynamics；Cladding and drying due to material with carbon element
Effect, it is to avoid the moisture absorption of medicament, improves the safety of medicament；The blast of medicament due to adding metal dust, can be improved
Dynamics, strengthens acoustical quality.
Specific embodiment：With reference to embodiment, the present invention is described in further detail, each group of the present invention
Divide all by commercially available acquisition, described in specific embodiment or embodiment, each group is divided into quality proportioning or mass parts.
Components description, remaining perchlorate of the present invention refers to the perchloric acid used by the present invention in addition to potassium hyperchlorate
Any one in salt such as perchloric acid strontium, Calcium perchlorate, barium perchlorate.
The specific embodiment of the present invention is as follows：
A kind of colour flute sound fireworks combination medicament of the present invention, its component and quality proportioning are as follows：4- chloro- 3- nitro neighbour's benzene two
Formates 10%-15%, to benzene dipotassium potassium hydrogen phthalate 15%-30%, potassium hyperchlorate 35-50% and remaining perchlorate 20%-30%, carbon
Material 1%-5%, metal dust 1%-5%, each component toatl proportion sum of all medicaments is 100%.
A kind of colour flute sound fireworks combination medicament of the present invention, specifically can also be described 4- chloro- 3- nitro O-phthalic
Hydrochlorate is 3- nitrophthalic acid strontium chloro- to 4-, 4- chloro- 3- nitrophthalic acid calcium, 4- chloro- 3- nitrophthalic acid
One kind of barium, different metal ions produces different colors；Described perchlorate is perchloric acid strontium, Calcium perchlorate, perchloric acid
One kind of barium, on the one hand, due to increased the content of metal ion, can improve flame reaction intensity, strengthen the lightness of color,
On the other hand, due to not using potassium hyperchlorate, decrease the impact to flame reaction for the potassium ion, and improve the stability of medicament
And safety；Described material with carbon element is bamboo charcoal powder, carbon nanometer tube powder, the one or more combination of activated carbon powder, and these material with carbon elements can
With good cladding medicament, reduce the hygroscopicity of material；Described metal dust is titanium valve, aluminium powder, one or more groups of magnesium powder
Close, these materials have good combustion heat value, can improve the blast dynamics of medicament；Described to benzene dipotassium potassium hydrogen phthalate, the chloro- 3- of 4-
The grain diameter of nitrophthalic acid salt is 30-100 μm, and the grain diameter of described potassium hyperchlorate and remaining perchlorate is
50-120 μm, in this particle size range, preferably, color is the brightest for the acoustical quality of generation.
Embodiment 1：
The component of colored flute sound fireworks combination medicament and proportioning are as follows：
4- chloro- 3- nitrophthalic acid strontium 10%, perchloric acid strontium 25%, to benzene dipotassium potassium hydrogen phthalate 15%, potassium hyperchlorate 40, bamboo charcoal
Powder 5%, titanium valve 5%.
Embodiment 2：
The component of colored flute sound fireworks combination medicament and proportioning are as follows：
4- chloro- 3- nitrophthalic acid strontium 15%, perchloric acid strontium 20%, to benzene dipotassium potassium hydrogen phthalate 20%, potassium hyperchlorate 35, bamboo charcoal
Powder 5%, titanium valve 5%.
Embodiment 3：
The component of colored flute sound fireworks combination medicament and proportioning are as follows：
4- chloro- 3- nitrophthalic acid strontium 15%, perchloric acid strontium 25%, to benzene dipotassium potassium hydrogen phthalate 15%, potassium hyperchlorate 40, bamboo charcoal
Powder 1%, titanium valve 4%.
Embodiment 4：
The component of colored flute sound fireworks combination medicament and proportioning are as follows：
4- chloro- 3- nitrophthalic acid strontium 10%, perchloric acid strontium 30%, to benzene dipotassium potassium hydrogen phthalate 15%, potassium hyperchlorate 40, bamboo charcoal
Powder 4%, titanium valve 1%.
Embodiment 5：
The component of colored flute sound fireworks combination medicament and proportioning are as follows：
4- chloro- 3- nitrophthalic acid barium 15%, barium perchlorate 20%, benzene dipotassium potassium hydrogen phthalate 20%, potassium hyperchlorate 35, carbon are received
Mitron powder 5%, aluminium powder 5%.
Embodiment 6：
The component of colored flute sound fireworks combination medicament and proportioning are as follows：
4- chloro- 3- nitrophthalic acid calcium 15%, Calcium perchlorate 20%, to benzene dipotassium potassium hydrogen phthalate 15%, potassium hyperchlorate 40, activity
Powdered carbon 5%, magnesium powder 5%.
In above-described embodiment, the colored flute sound fireworks combination medicament technical target of the product of preparation is shown in Table 1：
The colored flute sound fireworks combination medicament technical target of the product of table 1
Above-mentioned only several specific embodiments in the present invention are illustrated, but can not be all as protection scope of the present invention
It is to zoom in or out according to the equivalence changes done by design spirit in the present invention or modification or equal proportion, all be considered as
Enter protection scope of the present invention.
Claims (6)
1. a kind of colour flute sound fireworks combination medicament it is characterised in that：Described colour flute sound fireworks combination medicament each component and
Quality proportioning is：4- chloro- 3- nitrophthalic acid salt 10%-15%, to benzene dipotassium potassium hydrogen phthalate 15%-30%, potassium hyperchlorate 35-50
And remaining perchlorate 20%-30%, material with carbon element 1%-5%, metal dust 1%-5%, each component toatl proportion sum of all medicaments is
100%.
2. according to claim 1 a kind of colour flute sound fireworks combination medicament it is characterised in that：The chloro- 3- nitro of described 4-
Phthalate is 4- chloro- 3- nitrophthalic acid strontium, 4- chloro- 3- nitrophthalic acid calcium, 4- chloro- 3- nitro neighbour's benzene
Dioctyl phthalate barium or one kind.
3. according to claim 1 a kind of colour flute sound fireworks combination medicament it is characterised in that：Described perchlorate is height
Strontium chlorate, Calcium perchlorate, one kind of barium perchlorate, control the metal ion of described perchlorate and the chloro- 3- nitro of described 4- adjacent
The metal ion of phthalate is consistent.
4. according to claim 1 a kind of colour flute sound fireworks combination medicament it is characterised in that：Described material with carbon element is bamboo
Powdered carbon, carbon nanometer tube powder, the one or more combination of activated carbon powder.
5. a kind of colour flute sound fireworks combination medicament according to claim 1, described metal dust is titanium valve, aluminium powder, magnesium
The one or more combination of powder.
6. a kind of colour flute sound fireworks combination medicament according to claim 1, the chloro- 3- nitrophthalic acid salt of described 4-
Grain diameter be 30-100 μm, the grain diameter of described perchlorate is 50-120 μm.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610737964.3A CN106380362B (en) | 2016-08-29 | 2016-08-29 | A kind of colored flute sound fireworks combination medicament |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610737964.3A CN106380362B (en) | 2016-08-29 | 2016-08-29 | A kind of colored flute sound fireworks combination medicament |
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| CN106380362A true CN106380362A (en) | 2017-02-08 |
| CN106380362B CN106380362B (en) | 2018-03-13 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107141187A (en) * | 2017-05-14 | 2017-09-08 | 蒋春霞 | A kind of preparation method of the antistatic firework launching medicine of microcellular structure |
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| CN1673203A (en) * | 2005-02-02 | 2005-09-28 | 上海冠珠礼仪用品有限公司 | Firework spraying agent for low temperature no-smoke colored-light firework spraying pipe |
| CN101619009A (en) * | 2009-06-22 | 2010-01-06 | 鲁向华 | Fireworks safety firing cable and manufacturing method thereof |
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| CN106380362B (en) | 2018-03-13 |
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