CN106380362B - A kind of colored flute sound fireworks combination medicament - Google Patents
A kind of colored flute sound fireworks combination medicament Download PDFInfo
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- CN106380362B CN106380362B CN201610737964.3A CN201610737964A CN106380362B CN 106380362 B CN106380362 B CN 106380362B CN 201610737964 A CN201610737964 A CN 201610737964A CN 106380362 B CN106380362 B CN 106380362B
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- perchlorate
- chloro
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- flute sound
- combination
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- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B33/00—Compositions containing particulate metal, alloy, boron, silicon, selenium or tellurium with at least one oxygen supplying material which is either a metal oxide or a salt, organic or inorganic, capable of yielding a metal oxide
- C06B33/12—Compositions containing particulate metal, alloy, boron, silicon, selenium or tellurium with at least one oxygen supplying material which is either a metal oxide or a salt, organic or inorganic, capable of yielding a metal oxide the material being two or more oxygen-yielding compounds
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- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
The invention discloses a kind of colored flute sound fireworks combination medicament, the component and quality proportioning of the medicament are：The nitrophthalic acid salt of 4 chlorine 3 10% 15%, to benzene dipotassium potassium hydrogen phthalate 15% 30%, potassium hyperchlorate 35 50 and remaining perchlorate 20% 30%, carbon material 1% 5%, metal dust 1% 5%, all medicament each component toatl proportion sums are 100%.Perchlorate is perchloric acid strontium, Calcium perchlorate, one kind of barium perchlorate；Carbon material is bamboo charcoal powder or carbon nanotube powders or the one or more combination of active powdered carbon；Metal dust is titanium valve, aluminium powder, the one or more combination of magnesium powder.The colored flute sound fireworks medicament of the present invention has the advantages that good acoustical quality, bright colors, hygroscopicity are small, safe and reliable when setting off, and has good application prospect.
Description
Technical field
The present invention relates to a kind of fireworks combination medicament, more particularly to a kind of colored flute sound fireworks combination medicament.
Background technology
Fireworks are divided into two classes, and one kind is sibilant rale class fireworks, can send whistle during such firework display, this fireworks are general
Containing sibilant rale medicament, such as gallic acid Potassium Benzoate, Potassium Hydrogen Phthalate；One kind is colourful fireworks, during such firework display
Miscellaneous color can be produced, such as red, green, blue, this fireworks with the addition of metal salt, only using different metal
Special flame reaction produces color, such as adds strontium carbonate, strontium chloride, barium chloride, sodium sulphate.
At present, also there is document report both to produce color, the fireworks of melodious sibilant rale can be sent again, as Mo Runping works out one
Kind new firework raw material-red sibilant rale agent, Chemical Industry in Guangzhou, 04 phase in 1988, the sibilant rale agent is with the aromatic acid containing phenyl ring and inorganic
Strontium is raw material, by dissolving, filtering, synthetic reaction, concentration, centrifugal dehydration, drying, crushing and prepare, although the sibilant rale agent was both
Red can be produced, and can sends birdie, but the cigarette medicine made using the sibilant rale agent has paler colour, and lifting height is not high,
The shortcomings of reducing agent can only be made with potassium chlorate.
Wang Chunnian have developed a kind of in the method for industrial terylene waste material two hydrogen terephthalate strontiums of preparation and its in fireworks side
The application in face, priming system, 03 phase in 1997, still, show in the document, should by the use of two hydrogen terephthalate strontiums as sibilant rale agent
Make oxidant from potassium chlorate, sibilant rale agent optimum formula is 30% 2 para Toluic Acid's hydrogen strontium, 70% potassium chlorate.Because potassium chlorate is sensitive
Degree is high, has been prohibited to be used as fireworks and firecrackers medicament, thus two para Toluic Acid's hydrogen strontiums of use do sibilant rale agent can not industrial applications.
The content of the invention
The present invention is completed to solve deficiency of the prior art, and it is an object of the invention to provide a kind of tonequality effect
Fruit is good, bright colors, the colored flute sound fireworks combination medicament that hygroscopicity is small, safe and reliable.
The each component and quality proportioning of colored flute sound fireworks combination medicament of the present invention be：The chloro- 3- nitros neighbour benzene two of 4-
Formates 10%-15%, to benzene dipotassium potassium hydrogen phthalate 15%-30%, potassium hyperchlorate 35-50 and remaining perchlorate 20%-30%, carbon materials
Expect 1%-5%, metal dust 1%-5%, all medicament each component toatl proportion sums are 100%.
A kind of colored flute sound fireworks combination medicament of the present invention, can also be：
Further, the chloro- 3- nitrophthalic acids salt of the 4- is that 3- nitrophthalic acids strontium chloro- to 4-, 4- are chloro-
One kind of the chloro- 3- nitrophthalic acids barium of 3- nitrophthalic acids calcium, 4-.
Further, the perchlorate is perchloric acid strontium, Calcium perchlorate, one kind of barium perchlorate；The perchlorate
Metal ion it is consistent with the metal ion of the chloro- 3- nitrophthalic acids salt of the 4-.
Further, the carbon material is bamboo charcoal powder, carbon nanometer tube powder, the one or more combination of active powdered carbon.
Further, the metal dust is titanium valve, aluminium powder, the one or more combination of magnesium powder.
Further, the grain diameter of the chloro- 3- nitrophthalic acids salt of the 4- is 30-100 μm, the perchlorate
Grain diameter be 50-120 μm.
The chloro- 3- nitrophthalic acids salt of 4- can also select Strontium terephthalate described in the described component of the present invention
Or terephthalic acid (TPA) barium, its proportioning are same as described above.
A kind of colored flute sound fireworks combination medicament of the present invention, in terms of existing technologies, it this have the advantage that sound
Matter effect is good, bright colors, hygroscopicity are small, safe and reliable；Due to the synergy of nitro, make terephthalate and perchloric acid
Acoustical quality caused by reactant salt strengthens；Because terephthalate and perchlorate contain identical metal ion, and by
In the synergy of chlorion on phenyl, strengthen the flame reaction of metal ion, during firework display, color is brighter；Due to
The effect of nitro and carbon material, strengthen medicament reaction, improve the quick-fried of fireworks and make dynamics；Cladding and drying due to carbon material
Effect, the moisture absorption of medicament is avoided, improve the security of medicament；Due to adding metal dust, the blast of medicament can be improved
Dynamics, strengthen acoustical quality.
Embodiment：With reference to embodiment, the present invention is described in further detail, each group of the present invention
Divide by commercially available acquisition, each group is divided into quality proportioning or mass parts described in embodiment or embodiment.
Components description, remaining perchlorate of the present invention refer to the perchloric acid used in the present invention in addition to potassium hyperchlorate
Any one in salt such as perchloric acid strontium, Calcium perchlorate, barium perchlorate.
The embodiment of the present invention is as follows：
A kind of colored flute sound fireworks combination medicament of the present invention, its component and quality proportioning are as follows：The chloro- 3- nitros of 4- are adjacent
Phthalate 10%-15%, to benzene dipotassium potassium hydrogen phthalate 15%-30%, potassium hyperchlorate 35-50% and remaining perchlorate 20%-
30%th, carbon material 1%-5%, metal dust 1%-5%, all medicament each component toatl proportion sums are 100%.
A kind of colored flute sound fireworks combination medicament of the present invention, specifically can also be the chloro- 3- nitros O-phthalics of the 4-
Hydrochlorate is 3- nitrophthalic acids strontium chloro- to 4-, the chloro- 3- nitrophthalic acids calcium of 4-, the chloro- 3- nitrophthalic acids of 4-
One kind of barium, different metal ions produce different colors；The perchlorate is perchloric acid strontium, Calcium perchlorate, perchloric acid
One kind of barium, on the one hand, due to adding the content of metal ion, flame reaction intensity can be improved, strengthens the lightness of color,
On the other hand, due to without using potassium hyperchlorate, reducing influence of the potassium ion to flame reaction, and improve the stability of medicament
And security；The carbon material is bamboo charcoal powder, carbon nanometer tube powder, the one or more combination of active powdered carbon, and these carbon materials can
To coat medicament well, the hygroscopicity of material is reduced；The metal dust be titanium valve, aluminium powder, one or more of groups of magnesium powder
Close, these materials have good combustion heat value, can improve the blast dynamics of medicament；It is described to benzene dipotassium potassium hydrogen phthalate, the chloro- 3- of 4-
The grain diameter of nitrophthalic acid salt is 30-100 μm, and the grain diameter of the potassium hyperchlorate and remaining perchlorate is
50-120 μm, in this particle size range, caused acoustical quality is best, and color is most bright.
Embodiment 1：
The component and proportioning of colored flute sound fireworks combination medicament are as follows：
The chloro- 3- nitrophthalic acids strontiums 10% of 4-, perchloric acid strontium 25%, to benzene dipotassium potassium hydrogen phthalate 15%, potassium hyperchlorate 40,
Bamboo charcoal powder 5%, titanium valve 5%.
Embodiment 2：
The component and proportioning of colored flute sound fireworks combination medicament are as follows：
The chloro- 3- nitrophthalic acids strontiums 15% of 4-, perchloric acid strontium 20%, to benzene dipotassium potassium hydrogen phthalate 20%, potassium hyperchlorate 35,
Bamboo charcoal powder 5%, titanium valve 5%.
Embodiment 3：
The component and proportioning of colored flute sound fireworks combination medicament are as follows：
The chloro- 3- nitrophthalic acids strontiums 15% of 4-, perchloric acid strontium 25%, to benzene dipotassium potassium hydrogen phthalate 15%, potassium hyperchlorate 40,
Bamboo charcoal powder 1%, titanium valve 4%.
Embodiment 4：
The component and proportioning of colored flute sound fireworks combination medicament are as follows：
The chloro- 3- nitrophthalic acids strontiums 10% of 4-, perchloric acid strontium 30%, to benzene dipotassium potassium hydrogen phthalate 15%, potassium hyperchlorate 40,
Bamboo charcoal powder 4%, titanium valve 1%.
Embodiment 5：
The component and proportioning of colored flute sound fireworks combination medicament are as follows：
The chloro- 3- nitrophthalic acids barium 15% of 4-, barium perchlorate 20%, to benzene dipotassium potassium hydrogen phthalate 20%, potassium hyperchlorate 35,
Carbon nanotube powders 5%, aluminium powder 5%.
Embodiment 6：
The component and proportioning of colored flute sound fireworks combination medicament are as follows：
The chloro- 3- nitrophthalic acids calcium 15% of 4-, Calcium perchlorate 20%, to benzene dipotassium potassium hydrogen phthalate 15%, potassium hyperchlorate 40,
Active powdered carbon 5%, magnesium powder 5%.
The colored flute sound fireworks combination medicament technical target of the product prepared in above-described embodiment is shown in Table 1：
The colored flute sound fireworks combination medicament technical target of the product of table 1
It is above-mentioned that only several specific embodiments in the present invention are illustrated, but can not be as the protection model of the present invention
Enclose, the equivalent change or modification or equal proportion made by every design spirit according in the present invention zoom in or out, all should
Think to fall into protection scope of the present invention.
Claims (3)
- A kind of 1. colored flute sound fireworks combination medicament, it is characterised in that：The each component of the colored flute sound fireworks combination medicament and Quality proportioning is：The chloro- 3- nitrophthalic acids salt 10%-15% of 4-, potassium hydrogen terephthalate 15%-30%, potassium hyperchlorate 35- 50%th, remaining perchlorate 20%-30%, carbon material 1%-5%, metal dust 1%-5%, all medicament each component toatl proportion sums For 100%；The chloro- 3- nitrophthalic acids salt of 4- is the chloro- 3- nitrophthalic acids strontiums of 4-, the chloro- 3- nitros O-phthalics of 4- The chloro- 3- nitrophthalic acids barium of sour calcium, 4- or one kind；Remaining described perchlorate is perchloric acid strontium, Calcium perchlorate, one kind of barium perchlorate, controls the gold of the perchlorate It is consistent with the metal ion of the chloro- 3- nitrophthalic acids salt of the 4- to belong to ion；The carbon material is bamboo charcoal powder, carbon nanotube powders, the one or more combination of active powdered carbon.
- A kind of 2. colored flute sound fireworks combination medicament according to claim 1, it is characterised in that：The metal dust is titanium Powder, aluminium powder, the one or more combination of magnesium powder.
- A kind of 3. colored flute sound fireworks combination medicament according to claim 1, it is characterised in that：The chloro- 3- nitros of 4- The grain diameter of phthalate is 30 ~ 100 μm, the grain diameter of the potassium hyperchlorate and remaining perchlorate for 50 ~ 120μm。
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610737964.3A CN106380362B (en) | 2016-08-29 | 2016-08-29 | A kind of colored flute sound fireworks combination medicament |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610737964.3A CN106380362B (en) | 2016-08-29 | 2016-08-29 | A kind of colored flute sound fireworks combination medicament |
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| CN106380362A CN106380362A (en) | 2017-02-08 |
| CN106380362B true CN106380362B (en) | 2018-03-13 |
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| CN107141187A (en) * | 2017-05-14 | 2017-09-08 | 蒋春霞 | A kind of preparation method of the antistatic firework launching medicine of microcellular structure |
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| CN1305814C (en) * | 2004-08-30 | 2007-03-21 | 龙文革 | Fireworks and firecrackers oxidant |
| CN1290805C (en) * | 2005-02-02 | 2006-12-20 | 上海冠珠礼仪用品有限公司 | Firework spraying agent for low temperature no-smoke colored-light firework spraying pipe |
| CN101619009B (en) * | 2009-06-22 | 2011-12-21 | 鲁向华 | Fireworks safety firing cable and manufacturing method thereof |
| CN102718614B (en) * | 2012-06-25 | 2014-12-10 | 李炳 | Explosive composition for preparing fireworks and firecracker-fuse |
| CN103739413A (en) * | 2013-12-17 | 2014-04-23 | 江西省李渡烟花集团有限公司 | Novel firework bursting charge |
| CN104710252A (en) * | 2015-02-10 | 2015-06-17 | 张光辉 | Firework initiating explosive and preparation method thereof |
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