CN109651872A - A kind of cigarette tipping paper, internal lining paper environment-friendly antibacterial water-based ink and preparation method thereof - Google Patents
A kind of cigarette tipping paper, internal lining paper environment-friendly antibacterial water-based ink and preparation method thereof Download PDFInfo
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- CN109651872A CN109651872A CN201910092869.6A CN201910092869A CN109651872A CN 109651872 A CN109651872 A CN 109651872A CN 201910092869 A CN201910092869 A CN 201910092869A CN 109651872 A CN109651872 A CN 109651872A
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- water
- based ink
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- internal lining
- cigarette tipping
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/033—Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
Abstract
The invention discloses a kind of cigarette tipping papers, internal lining paper environment-friendly antibacterial water-based ink, consist of the following components in percentage by weight: 12-18% water-soluble resin liquid；35-45% solvent；25-35% composite antibacterial filler, the composite antibacterial filler include nano-titanium dioxide, silver ion antimicrobial agent, chitosan-copper complex and soy meal；8-20% pigment；0-3% auxiliary agent.The present invention also provides the preparation methods of the water-based ink.Environment-friendly antibacterial water-based ink in the present invention, substantially eliminate the harm of the heavy metals bring such as the volatile organic matters such as benzene, toluene, ethylbenzene, dimethylbenzene, n-butyl acetate and arsenic, mercury, lead, cadmium, nickel, chromium, and it is with stronger antibacterial effect, can reach 99% or more to the bactericidal effect of bacillus, Escherichia coli and staphylococcus aureus.
Description
Technical field
The present invention relates to printing raw material fields, in particular to a kind of cigarette tipping paper, internal lining paper environment-friendly antibacterial are aqueous
Ink and preparation method thereof.
Background technique
Cigarette tipping paper, internal lining paper are the important packaging materials for producing cigarette.It is using body paper as substrate, by setting before print
The processes such as meter, printing processing and print post-processing, filter tip and a kind of Special industrial that Cigarette cigarette is got up are known as connecing with paper
Fill paper；And internal lining paper is then the inner packaging paper of box cigarette small packaging, is printed again with ink after being made by aluminum tissue paper and body paper bonding
The cigarette packaging paper of upper pattern for the moisture-proof of cigarette and is protected fragrant most important.
In recent years, as safe and environment-friendly, the healthy consciousness of people is constantly reinforced, the alcohol-soluble printing ink that largely uses,
Dissolvent residual (VOCS) and heavy metal in a large amount of volatile organic solvents and printed matter involved in printing process etc. can be to rings
The physical and mental health of border and printing machine operative employee and smoking property of cigarette consumer bring large effect.Cigarette tipping paper, except volatilization
Property organic matter influence outside, filter tip and lip directly contact when due to smoking, the harmful heavy metal ingredient in tipping paper, such as
Arsenic, lead, mercury, chromium, every, nickel etc., the health that consumer is directly influenced in human body can be entered by oral cavity.Therefore, country is right
Considering for the safety and sanitation of cigarette tipping paper has promoted comparable height.Countries tobacco general bureau put into effect in 2007 about
The sanitary index mandatory professional standard of tobacco package cigarette tipping paper dissolvent residual and inorganic elements limitation: YC171-2009
" cigarette tipping paper " and YC264-2008 " tobacco lining paper " and thus limit standard, have formulated corresponding detection method, implement
Strict control.
The increase of demand with people to environment-friendlyink ink, the environmental protection that cigarette tipping paper, internal lining paper print ink will
It is inevitable.Sight has all been invested water-based ink by many printing factories at present.Water-based ink mainly takes water as a solvent
It is process through science, water-based ink due to being free of volatility toxic organic solvents, therefore is printing compared with other print ink
It has no adverse effects in the process to the health of printing machine operator, the maximum feature of water-based ink is the reduction of VOC into atmosphere
Discharge improve presswork environment to prevent atmosphere pollution, it, which can be completely eliminated, certain in solvent-based ink has
Harm of the noxious material to human body and the pollution to package goods improve overall environmental quality.Further, since water-based ink has not
Inflammable feature, can eliminate hidden danger inflammable and explosive in machine room, and low burn safety is conducive to keep the safety in production.The ink body
System is conducive to increase the clarity of printing, and water-resistance is good after printing solidification, and volatile dissolvent residual (VOCS) is few, and heavy metal contains
It measures low, is compared to each other with traditional ink, cause to reduce by 70% or so less.
But cigarette in the prior art is with packaging material gravure water-based ink that it is primarily present following problems: 1, printing effect
Fruit is less than satisfactory, and film forming and printing adhesive force have to be hoisted；2, antibacterial effect is general, and universality is poor；3, ink is filled
Material is generally not environmentally, followed by first using inorganic minerals materials such as powder lime carbonate, aluminium powder, aluminium hydroxide, talcum powder
Arsenic, lead, mercury, chromium, the content every, nickel heavy metal are increased, cigarette packaging material tipping paper, the internal lining paper heavy metal of institute's printing contain
Amount is high, and the injury of health can be constituted to the consumer of long-term smoking.
Therefore, a kind of cigarette tipping paper, internal lining paper environment-friendly antibacterial water-based ink are researched and developed, good anti-bacterial effect is fitted
Ying Xingguang, printing effect is good, especially reduction source of heavy metal pollution its seem that extremely have must to consumer's bring actual bodily harm
It wants.
Summary of the invention
To solve the above-mentioned problems, it is anti-to be to provide a kind of cigarette tipping paper, internal lining paper environmental protection for an object of the present invention
Bacterium water-based ink.
The second object of the present invention is to provide a kind of method for preparing environment-friendly antibacterial water-based ink described above.
In order to solve the above-mentioned technical problem, the technical solution of the present invention is as follows:
A kind of cigarette tipping paper, internal lining paper environment-friendly antibacterial water-based ink, consist of the following components in percentage by weight:
12-18% water-soluble resin liquid；
35-45% solvent；
25-35% composite antibacterial filler, the composite antibacterial filler include nano-titanium dioxide, silver ion antimicrobial agent, shell
Glycan-copper complex and soy meal；
8-20% pigment；
0-3% auxiliary agent.
Preferably, nano-titanium dioxide, silver ion antimicrobial agent, chitosan-copper complex in the composite antibacterial filler
And the weight percent of soy meal is respectively 20-45%, 4-10%, 4-10%, 45-60%.
Preferably, the solvent is made of soybean oil, ethyl alcohol and tap water.
Preferably, the tap water is substituted by deionized water.
Preferably, the weight proportion of soybean oil, ethyl alcohol and tap water is 1:2:1 in the solvent.
Preferably, the water-soluble resin liquid comprises the following raw materials by weight percent: 15%-25% acrylic acid tree
The water-soluble resin that rouge and polyvinyl butyral are mixed according to 1:1, surplus are ethyl alcohol.
Preferably, being also added with precipitated calcium carbonate in the composite antibacterial filler.
Preferably, the pigment is iron oxide red and the mixture that iron oxide yellow forms.
Preferably, the auxiliary agent be defoaming agent, antisettling agent either one of levelling agent or more than one.
The present invention also provides a kind of sides for preparing cigarette tipping paper described above, internal lining paper environment-friendly antibacterial water-based ink
Method comprising following steps:
(1) configuration of water-soluble resin liquid
Water-soluble resin solvent is added in reaction kettle, is heated to 55-70 DEG C；Then acrylic resin and poly- second is added
Enol butyral stirs 12-14 hours, and adjusting solution terminal pH by neutralizer is 7.5-8.5, that is, water-soluble resin is made
Liquid is cooled to room temperature spare；
(2) preparation of environment-friendly antibacterial water-based ink
Ingredient: 12-18% water-soluble resin liquid is carried out in a kettle according to following weight percents；35-45% solvent；
25-35% composite antibacterial filler；0-3% auxiliary agent；
After ingredient, after reaction kettle carries sieve artificial filter, material pot horizontal sand mill is concentrated in ink
Circular grinding 3-10 hours in bucket, that is, it is configured to environment-friendly antibacterial water-based ink.
Preferably, the neutralizer is monoethanolamine.
In the present invention, filler mainly plays filling effect, both reduces cost as ingredient important in water-based ink composition
Ink property, such as dilute thick, fluidity, viscosity are adjusted again, to improve the flexibility of formula design, improve ink quality.Water
Property ink be to the basic demand of filler: whiteness is high, it is lipophilic it is strong, easily dispersion, without objectionable impurities, particle fine uniform, stabilization
Property is good.Filler in the prior art generally selects white clear, translucent or opaque flour, such as talcum powder, again
Calcium, light calcium, kaolin, wollastonite in powder etc., it is not uniform enough in the presence of dispersing, it cannot effectively play the role of loading fungicide,
And content of beary metal is generally higher.
Soy meal, nano-titanium dioxide, silver ion antimicrobial agent and chitosan-copper complex are mixed in the present invention
Collocation, for soy meal as antibacterial filler, nano-titanium dioxide plays peptizaiton, silver ion antimicrobial agent and chitosan-copper network
It closes object and is then used as wide-spectrum bactericide, its function of not only realizing filler of said combination also achieves preferable anti-microbial property.It is multiple
Close in antibacterial filler, choose soy meal as most important filler, not only have preferable dispersibility and with basis material phase
Capacitive, and soy meal is from a wealth of sources, cheap, particle fine uniform, it is nontoxic；Above-mentioned composite antibacterial filler is to gemma
The bactericidal effect of bacillus, Escherichia coli and staphylococcus aureus can reach 99% or more.
The one of feature of the present invention is to select soybean oil as main solvent in solvent.Soybean oil belongs to edible oil,
Natural environment can be fully immersed into after decomposition.In the vegetable oil ink of various formulas, soya-bean ink is applying for real meaning
Environment-friendlyink ink；And the abundance of soybean, cheap, performance safety is reliable.It is used soybean oil as main solvent
In ink, printing effect is good, lovely luster, concentration height, good luster, preferable water adaptability, stability, rub resistance and resistance to
Performances such as dry, and meet all standard of printing ink, compare various organic solvents more in the prior art, the feature of environmental protection,
Safety is excellent.
The one of feature of the present invention is that water-soluble resin liquid is the key that one of water-based ink, and determines ink
An important factor for physics and chemical property for forming a film later.Under normal conditions, water-soluble resin includes tap water soluble resin
With buck water-soluble resin.Tap water soluble resin generally refers to the resin containing-OH, and buck water-soluble resin is usually to contain
There are-COOH ,-NH2 resin.The present invention is using buck water-soluble resin, by introducing the hydrophilic of sufficient amount to macromolecular chain
Group, such as-COOH ,-OH ,-NH2 make resin reach water-soluble effect, are conducive in cigarette tipping paper and internal lining paper surface
There are preferable film forming and printing adhesive force in printing.
The beneficial effects of the present invention are:
(1) preferable antibacterial functions apply to tipping paper, internal lining paper is the inevitable requirement and trend of cigarette consumption, but to protect
Fungistatic effect is held but to be difficult.Soy meal, nano-titanium dioxide, silver ion antimicrobial agent and chitosan-copper are complexed in the present invention
Object carries out the composite antibacterial filler of mix and match preparation, has preferable antibacterial effect, to bacillus, Escherichia coli and gold
The bactericidal effect of staphylococcus aureus can reach 99% or more.
(2) present invention selects soybean oil and tap water as main solvent, using substituted alcohols, lipid organic solvent as
The ink of tipping paper printing, thoroughly changes existing industry operating condition, purifies operating environment, substantially eliminates benzene, toluene, second
The harm of the volatile organic matters bring such as benzene, dimethylbenzene, n-butyl acetate, prints out the tipping paper with human oral cavity deep contact
With with the food-grade internal lining paper packed for cigarette and be largely used to cigarette package, can reduce cost and eliminate it is toxic,
The damage that harmful substance generates environment or even human body.
(3) the soy meal category renewable resource chosen in composite antibacterial filler material of the present invention, it is from a wealth of sources, it is cheap,
Grain thickness is uniform, because there is starch, has preferable dispersibility, attachment adhesive, good with basis material compatibility；Especially
Ground can significantly reduce the content of arsenic, mercury, lead in printing, avoid arsenic in printed article, mercury, lead, cadmium, nickel, chromium heavy metal to people
It is endangered caused by body, tipping paper, the internal lining paper printed using the water-based ink is harmless.
(4) ink system is conducive to increase tipping paper, liner printed paper presentation quality clarity, and water-resistance is good, can wave
Volatile material (VOCS) is few, practical, possesses the stability and low flame properties safety of preferably printing viscosity, can improve printing
The working environment of worker can simplify printing cleaning amount, improve production efficiency, can promote to food packaging printing industry.
Specific embodiment
Below with reference to embodiment, specific embodiments of the present invention will be further explained.It should be noted that right
It is used to help understand the present invention in the explanation of these embodiments, but and does not constitute a limitation of the invention.In addition, being retouched below
Technical characteristic involved in each embodiment of the present invention stated can be combined with each other as long as they do not conflict with each other.
Embodiment 1
A kind of cigarette tipping paper, internal lining paper environment-friendly antibacterial water-based ink, consist of the following components in percentage by weight:
15% water-soluble resin liquid, 10% soybean oil, 10% tap water, 20% edible ethanol, 10% iron oxide red, 4% iron oxide yellow；
1% defoaming agent；
30% composite antibacterial filler, the compound composite antibacterial filler includes nano-titanium dioxide, silver ion antimicrobial agent, shell
Glycan-copper complex and soy meal, wherein the weight percent of soy meal is 55%, nanometer two in the composite antibacterial filler
Titanium oxide is 31%, silver ion antimicrobial agent 10%, chitosan-copper complex are 4%；
In the present embodiment each raw material used is commercially available raw material, such as silver ion antimicrobial agent using selling in the market
The silver ion antimicrobial agent CY-T07L of nine friend's new material company of Hangzhou；Iron oxide red and iron oxide yellow are happy using the abundant joyous Bayer in Shanghai
The synthetic dyestuff iron oxide yellow and synthetic hematite of Co., Ltd's production；
The water-soluble resin liquid is prepared by following methods step:
(1) ethyl alcohol for adding 85Kg in a kettle, is heated to 60 DEG C；Be then respectively adding 7.5Kg acrylic resin and
Polyvinyl butyral stirs 12 hours, and whipping process mid-score time addition neutralizer adjusts water-soluble resin liquid pH, adds altogether
The monoethanolamine of 0.25Kg, solution terminal pH are 8.0, and water-soluble resin liquid is made, is cooled to room temperature spare；
(2) preparation of environment-friendly antibacterial water-based ink
Put into following raw materials according in a kettle: 10Kg iron oxide red, 4Kg iron oxide yellow, 16.5Kg soy meal, 9.3Kg receive
Rice titanium dioxide, the agent of 3Kg ion antibacterial, 1.2Kg chitosan-copper complex；
Solubilizer: 40Kg solvent is added in same reaction kettle, wherein 10Kg soybean oil, 10Kg tap water and 20Kg second
Alcohol；
Adding assistant: 1Kg defoaming agent is added in same reaction kettle；
After above-mentioned ingredient, after reaction kettle carries sieve artificial filter, concentrates on material pot horizontal sand mill and exist
Circular grinding 8 hours in ink barrel, that is, be configured to environment-friendly antibacterial water-based ink.
Embodiment 2
A kind of cigarette tipping paper, internal lining paper environment-friendly antibacterial water-based ink, consist of the following components in percentage by weight:
18% water-soluble resin liquid, 15% soybean oil, 10% tap water, 20% edible ethanol, 6% iron oxide red, 5% iron oxide yellow；
0.5% defoaming agent；0.5% levelling agent；
25% composite antibacterial filler, the composite antibacterial filler include that nano-titanium dioxide, silver ion antimicrobial agent, shell are poly-
Sugar-copper complex, soy meal and precipitated calcium carbonate, wherein the weight percent of soy meal is in the composite antibacterial filler
60%, nano-titanium dioxide 20%, silver ion antimicrobial agent 10%, chitosan-copper complex are 5%, precipitated calcium carbonate is
5%；
Each raw material used is commercially available raw material in the present embodiment, such as silver ion antimicrobial agent is the Hangzhoupro sold in the market
The silver ion antimicrobial agent CY-T07L of nine friend's new material company of state；Iron oxide red and iron oxide yellow are that the abundant joyous Bayer pleasure in Shanghai has
The synthetic dyestuff iron oxide yellow and synthetic hematite of limit company production；
The water-soluble resin liquid is prepared by following methods step:
(1) ethyl alcohol for adding 80Kg in a kettle, is heated to 55 DEG C；Be then respectively adding 10Kg acrylic resin,
10Kg polyvinyl butyral stirs 14 hours, and whipping process mid-score time addition neutralizer adjusts water-soluble resin liquid pH, this
Neutralizer is monoethanolamine in embodiment, and solution terminal pH is 8.5, and water-soluble resin liquid is made, is cooled to room temperature spare；
(2) preparation of environment-friendly antibacterial water-based ink
Following raw materials according is put into a kettle: 6Kg iron oxide red, 5Kg iron oxide yellow, 15Kg soy meal, 5Kg nano-silica
Change titanium, the agent of 2.5Kg ion antibacterial, 1.25Kg chitosan-copper complex, 1.25Kg precipitated calcium carbonate；
Solubilizer: 45Kg solvent is added in same reaction kettle, wherein 15Kg soybean oil, 10Kg tap water and 20Kg second
Alcohol；
Adding assistant: 0.5Kg defoaming agent, 0.5Kg levelling agent are added in same reaction kettle；
After above-mentioned ingredient, after reaction kettle carries sieve artificial filter, concentrates on material pot horizontal sand mill and exist
Circular grinding 10 hours in ink barrel, that is, be configured to environment-friendly antibacterial water-based ink.
Embodiment 3
A kind of cigarette tipping paper, internal lining paper environment-friendly antibacterial water-based ink, consist of the following components in percentage by weight:
12% water-soluble resin liquid, 15% soybean oil, 5% tap water, 15% edible ethanol, 8% iron oxide red, 8% iron oxide yellow；
1% defoaming agent, 0.5% levelling agent, 0.5% antisettling agent；
35% composite antibacterial filler, the composite antibacterial filler include that nano-titanium dioxide, silver ion antimicrobial agent, shell are poly-
Sugar-copper complex and soy meal, wherein the weight percent of soy meal is 45%, nano-silica in the composite antibacterial filler
Change titanium is 35%, silver ion antimicrobial agent 10%, chitosan-copper complex are 10%；
Each raw material used is commercially available raw material in the present embodiment, such as silver ion antimicrobial agent is the Hangzhoupro sold in the market
The silver ion antimicrobial agent CY-T07L of nine friend's new material company of state；Iron oxide red and iron oxide yellow are that the abundant joyous Bayer pleasure in Shanghai has
The synthetic dyestuff iron oxide yellow and synthetic hematite of limit company production；
The water-soluble resin liquid is prepared by following methods step:
(1) ethyl alcohol for adding 75Kg in a kettle, is heated to 70 DEG C；Be then respectively adding 15Kg acrylic resin,
10Kg polyvinyl butyral stirs 13 hours, and whipping process mid-score time addition neutralizer adjusts water-soluble resin liquid pH, altogether
The monoethanolamine of 0.25Kg is added, solution terminal pH is 7.5, and water-soluble resin liquid is made, is cooled to room temperature spare；
(2) preparation of environment-friendly antibacterial water-based ink
Following raw materials according is put into a kettle: 8Kg iron oxide red, 8Kg iron oxide yellow, 15.75Kg soy meal, 12.25Kg
Nano-titanium dioxide, the agent of 3.5Kg ion antibacterial, 3.5Kg chitosan-copper complex；
Solubilizer: 35Kg solvent is added in same reaction kettle, wherein 15Kg soybean oil, 5Kg tap water and 15Kg second
Alcohol；
Adding assistant: 1Kg defoaming agent, 0.5Kg levelling agent and 0.5Kg antisettling agent are added in same reaction kettle.
After above-mentioned ingredient, after reaction kettle carries sieve artificial filter, concentrates on material pot horizontal sand mill and exist
Circular grinding 3 hours in ink barrel, that is, be configured to environment-friendly antibacterial water-based ink.
Technical indicator such as 1 institute of table that environment friendly bacteriostatic water color ink in the present invention reaches after using in tipping paper printing
Show, table 2 is environment friendly bacteriostatic water color ink microbiological Test in the present invention, volatile organic compounds and heavy metals
Professional standard and the testing result table of comparisons.
1 cigarette tipping paper of table, internal lining paper environment-friendly antibacterial water-based ink the key technical indexes
| Project | Technical indicator | Survey index | Examination criteria |
| Color | E≤2.0 △ or standard specimen | E≤1.5 △ are near the mark | GB/T13217.1 |
| Tinting strength, tinting power (%) | 90-110 | 99 | GB/T13217.6 |
| Viscosity (S) | 50±30 | 51 | GB/T13217.4 |
| Gloss (%) | >=60% | > 80 | GB/T13217.2 |
| Fineness (um) | ≤10 | 8 | GB/T13217.3 |
| PH value | 8.0-9.5 | 9 | |
| Alkaline-resisting, water resistance | 24 | Well (printing is impregnated colour-fast) | |
| First stemness (mm) | 15-30 | 20 | |
| Storage stability | 5-30℃ | Well | |
| Upper machine adaptability | It is required that good | Good and cleaning printing plate is convenient |
2 cigarette tipping paper of table, internal lining paper environment-friendly antibacterial water-based ink microbiological Test, volatile organic compounds
And the professional standard of heavy metals and actually detected comparison table
Note: 1, index is classified as ABC three classes in standard, and A class is the index of strict control important in all standards, refer to as
A class index is unqualified in inspection in fruit product can determine that entire block is unqualified.
2, cigarette tipping paper and internal lining paper heavy metal arsenic, lead are pressed by the measurement of YC/T268 graphite furnace atomic absorption spectrometry, mercury
The measurement of YC/T278 cold-vapour atomic absorption method, cadmium, chromium, nickel are good by YC/T279 graphite furnace atomic absorption spectrometry or instrument condition
Printing packaging enterprise, cigarette tipping paper, internal lining paper can also be measured by YC/T316 inductively coupled plasma mass spectrometry arsenic, lead,
Cadmium, chromium, nickel, six heavy metal species of mercury.Cigarette packaging paper (contain cigarette tipping paper, tobacco lining paper) be all made of volatile organic by
Volatile organic compounds measures ketone, esters, alcohols index in YC/T207 cigarette barrel.
The antibacterial aqueous ink anti-microbial property detection of environmental protection in the present invention
In the present invention when doing antibacterial effect detection, by the sanitary index requirement that cigarette packaging material printing product control, root
According to the anti-microbial property detection method of national regulations, staphylococcus aureus and Escherichia coli both common bacteriums is selected to carry out
Detection, testing result are as shown in table 3:
3 cigarette tipping paper of table, internal lining paper environment-friendly antibacterial water-based ink anti-microbial property test
From in above-mentioned table 1, table 2 and table 3 as can be seen that environment-friendly antibacterial water-based ink its inspection result in the present invention is complete
Reach and be better than national sector standard, securely and reliably, with excellent anti-microbial property.
The embodiments of the present invention are described in detail in conjunction with the embodiments above, but the present invention is not limited to described realities
Apply mode.For a person skilled in the art, in the case where not departing from the principle of the invention and spirit, to these embodiment party
Formula carries out a variety of change, modification, replacement and modification, still falls in protection scope of the present invention.
Claims (10)
1. a kind of cigarette tipping paper, internal lining paper environment-friendly antibacterial water-based ink, which is characterized in that by the group of following weight percent
It is grouped as:
12-18% water-soluble resin liquid；
35-45% solvent；
25-35% composite antibacterial filler, the composite antibacterial filler include nano-titanium dioxide, silver ion antimicrobial agent, chitosan-
Copper complex and soy meal；
8-20% pigment；
0-3% auxiliary agent.
2. a kind of cigarette tipping paper according to claim 1, internal lining paper environment-friendly antibacterial water-based ink, which is characterized in that
The weight hundred of nano-titanium dioxide, silver ion antimicrobial agent, chitosan-copper complex and soy meal in the composite antibacterial filler
Divide than being respectively 20-45%, 4-10%, 4-10%, 45-60%.
3. a kind of cigarette tipping paper according to claim 2, internal lining paper environment-friendly antibacterial water-based ink, which is characterized in that
The solvent is made of soybean oil, ethyl alcohol and tap water.
4. a kind of cigarette tipping paper according to claim 3, internal lining paper environment-friendly antibacterial water-based ink, which is characterized in that
The weight proportion of soybean oil, ethyl alcohol and tap water is 1:2:1 in the solvent.
5. a kind of cigarette tipping paper according to claim 4, internal lining paper environment-friendly antibacterial water-based ink, which is characterized in that
The water-soluble resin liquid comprises the following raw materials by weight percent: 15%-25% acrylic resin and polyvinyl alcohol contracting fourth
The water-soluble resin that aldehyde is mixed according to 1:1, surplus are ethyl alcohol.
6. a kind of cigarette tipping paper according to claim 5, internal lining paper environment-friendly antibacterial water-based ink, which is characterized in that
Precipitated calcium carbonate is also added in the composite antibacterial filler.
7. a kind of cigarette tipping paper according to claim 6, internal lining paper environment-friendly antibacterial water-based ink, which is characterized in that
The pigment is iron oxide red and the mixture that iron oxide yellow forms.
8. a kind of cigarette tipping paper according to claim 7, internal lining paper environment-friendly antibacterial water-based ink, which is characterized in that
The auxiliary agent be defoaming agent, antisettling agent either one of levelling agent or more than one.
9. the preparation method of a kind of cigarette tipping paper according to claim 5, internal lining paper environment-friendly antibacterial water-based ink,
It is characterized in that, comprising the following steps:
(1) configuration of water-soluble resin liquid
Water-soluble resin solvent is added in reaction kettle, is heated to 55-70 DEG C；Then acrylic resin and polyvinyl alcohol is added
The water-soluble resin that butyral mixes stirs 12-14 hours, and adjusting solution terminal pH by neutralizer is 7.5-8.5, i.e.,
Water-soluble resin liquid is made, is cooled to room temperature spare；
(2) preparation of environment-friendly antibacterial water-based ink
Ingredient: 12-18% water-soluble resin liquid is carried out in a kettle according to following weight percents；35-45% solvent；25-
35% composite antibacterial filler；0-3% auxiliary agent；
After ingredient, after reaction kettle carries sieve artificial filter, material pot horizontal sand mill is concentrated in ink barrel
Circular grinding 3-10 hours, that is, it is configured to environment-friendly antibacterial water-based ink.
10. the preparation method of a kind of cigarette tipping paper according to claim 9, internal lining paper environment-friendly antibacterial water-based ink,
It is characterized in that, the neutralizer is monoethanolamine.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910092869.6A CN109651872A (en) | 2019-01-30 | 2019-01-30 | A kind of cigarette tipping paper, internal lining paper environment-friendly antibacterial water-based ink and preparation method thereof |
Applications Claiming Priority (1)
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| CN111647308A (en) * | 2020-06-06 | 2020-09-11 | 浙江本科特水松纸有限公司 | Sterile green ink for tipping paper and preparation method thereof |
| CN112662227A (en) * | 2020-12-11 | 2021-04-16 | 上海美美良虹印刷有限公司 | Carbon-free environment-friendly offset printing black ink and preparation method thereof |
| CN113234358A (en) * | 2021-06-07 | 2021-08-10 | 江苏唐彩新材料科技股份有限公司 | Water-based flexo printing temperature-variable anti-counterfeiting ink and preparation method thereof |
| CN113527943A (en) * | 2020-04-20 | 2021-10-22 | 云南玉溪水松纸厂 | Antibacterial and antiviral alcohol-soluble printing ink containing EGCG and tipping paper prepared from antibacterial and antiviral alcohol-soluble printing ink |
| WO2022103716A1 (en) * | 2020-11-12 | 2022-05-19 | Sun Chemical Corporation | Titanium dioxide-free cigarette tipping inks |
| CN115700314A (en) * | 2021-07-21 | 2023-02-07 | 湖北中烟工业有限责任公司 | Preparation method for preparing sweet lasting cigarette transfer paper by using double blocking agents |
| CN116411475A (en) * | 2023-03-17 | 2023-07-11 | 青岛嘉泽包装有限公司 | Production process of high-barrier aluminized lining paper with local laser and color watermarking effects |
| CN116589882A (en) * | 2023-06-06 | 2023-08-15 | 湖州乐通新材料科技有限公司 | Preparation method of antibacterial printing ink |
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| CN113527943A (en) * | 2020-04-20 | 2021-10-22 | 云南玉溪水松纸厂 | Antibacterial and antiviral alcohol-soluble printing ink containing EGCG and tipping paper prepared from antibacterial and antiviral alcohol-soluble printing ink |
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| CN113234358A (en) * | 2021-06-07 | 2021-08-10 | 江苏唐彩新材料科技股份有限公司 | Water-based flexo printing temperature-variable anti-counterfeiting ink and preparation method thereof |
| CN115700314A (en) * | 2021-07-21 | 2023-02-07 | 湖北中烟工业有限责任公司 | Preparation method for preparing sweet lasting cigarette transfer paper by using double blocking agents |
| CN115700314B (en) * | 2021-07-21 | 2023-09-08 | 湖北中烟工业有限责任公司 | Preparation method for preparing transfer paper for cigarettes with lasting sweet feeling by using double blocking agents |
| CN116411475A (en) * | 2023-03-17 | 2023-07-11 | 青岛嘉泽包装有限公司 | Production process of high-barrier aluminized lining paper with local laser and color watermarking effects |
| CN116589882B (en) * | 2023-06-06 | 2024-01-09 | 湖州乐通新材料科技有限公司 | Preparation method of antibacterial printing ink |
| CN116589882A (en) * | 2023-06-06 | 2023-08-15 | 湖州乐通新材料科技有限公司 | Preparation method of antibacterial printing ink |
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