CN102807788A - High-adhesion ink - Google Patents
High-adhesion ink Download PDFInfo
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- CN102807788A CN102807788A CN2012103022465A CN201210302246A CN102807788A CN 102807788 A CN102807788 A CN 102807788A CN 2012103022465 A CN2012103022465 A CN 2012103022465A CN 201210302246 A CN201210302246 A CN 201210302246A CN 102807788 A CN102807788 A CN 102807788A
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Abstract
The invention discloses high-adhesion ink, which comprises following components in parts by weight: 20 to 23 parts of alcohol-soluble polyurethane solution, 5 to 8 parts of chloride-vinyl acetae terpolymer resin, 28 to 30 parts of pigment, 33 to 35 parts of acetic acid, 18 to 20 parts of ethanol, 0 to 5 parts of ethyl acetate, 3 to 4 parts of buna-N rubber and 2 to 3 parts of acetone, and the mass concentration of the alcohol-soluble polyurethane solution is 30 to 35 percent. The ink has strong adhesive force and is suitable for the printing of different materials, and the pigment is durable to drop off; the ink is rapid to dry, and the residual of the solvent on a printed product after the ink is printed is small, so that the body health of ink manufacturers, printing workers and print product users can be guaranteed; and the ink also has good adaptability, consistent printed product can be obtained in different seasons, and the printing effect is good.
Description
Technical field
The present invention relates to a kind of high adhesive force printing ink.
Background technology
In the prior art, the printing ink that is used to print, sticking power are not strong, and pigment comes off easily, and the material that is suitable for is limited; Use the stronger solvents of toxicity such as a large amount of benzene classes, ketone during its preparation; In the printing ink production process, worked as solvent treatment not at that time; Health to the direct labor damages easily, and when printing ink was used to print, the volatilization of printing ink toxic solvent also can produce certain injury to pressman's health; Also can residual certain amount of solvent on the printed matter, certainly will also can have influence on the healthy of printed matter user.
Summary of the invention
The purpose of this invention is to provide a kind of high adhesive force printing ink, very strong sticking power is arranged, be applicable to the printing of various materials, pigment is prolonged not to come off, and makes simultaneously to have reduced in the printing ink noxious solvent to the hazardness of the person.
To achieve these goals, technical scheme of the present invention is:
A kind of high adhesive force printing ink comprises following component: alcohol contains intermingle with ammonia ester solution 20-23 part, ternary chlorine wax tree fat 5-8 part; Pigment 28-30 part, acetic acid 33-35 part, ethanol 18-20 part; ETHYLE ACETATE 0-5 part, nitrile rubber 3-4 part, acetone 2-3 part; Said umber is parts by weight, and the mass concentration that alcohol contains intermingle with the ammonia ester solution is 30-35%.
It is following that above-mentioned alcohol contains intermingle with ammonia ester solution preparation method: the urethane of selecting to dissolve in alcohol; According to desired concn urethane is dropped in the alcohol, be stirred to dissolving fully.Alcohol contains intermingle with the ammonia ester solution and can oneself prepare, and also can on market, buy.
Ternary chlorine wax tree fat is to grind base material and siccative, and in the manufacturing of printing ink, ternary chlorine wax tree fat not only has provide protection to urethane, and urges the effect of doing in addition, can shorten the required time of ink setting, thereby improve the film forming properties of printing ink.
Pigment can be allocated as required, when the preparation white pigment, uses white titanium pigment; When the preparation black pigment, use carbon black; When preparation during coloured pigment, can be selected from that phthalocyanine blue, permanent bordeaux, sun-proof are red, indigo plant etc. adapts to the pigment of solvent inkjet inks admittedly forever, each pigment all can be bought.
Acetic acid mainly is the solvent that is used for dissolving ternary chlorine wax tree fat.
It is to be used for regulating the concentration of printing ink and the rate of drying of printing ink that ETHYLE ACETATE mainly acts on.
In order further to increase the sticking power of printing ink, preferred, also comprise neoprene latex 2-3 part.
For material can be disperseed more fully, preferred, also comprise toluene 2-3 part.
As a kind of technical scheme of the present invention, preferred, the solvent that said alcohol contains intermingle with the ammonia ester solution is the mixture of Virahol or ethanol or both any proportionings.
As another kind of technical scheme of the present invention, preferred, the solvent that said alcohol contains intermingle with the ammonia ester solution is that Virahol and ethanol mass ratio are the mixture of (1:1)-(6:1).
Printing ink of the present invention can adopt conventional method preparation.Specifically can be prepared as follows: be equipped with raw material in proportion, then with each raw materials mix, high-speed stirring is dissolved ternary chlorine wax tree fat fully again, and makes each raw material uniform mixing, is ground to fineness then and is required, check, filters, packing.
Printing ink of the present invention has very strong sticking power, is applicable to the printing of various materials, and pigment is prolonged not to come off; Ink setting solvent residual amount rapid, that print on the printed matter of back is little, thereby has guaranteed ink manufacturers, pressman and printed matter user's physical and mental health; Printing ink of the present invention also has excellent adaptability, and Various Seasonal can obtain consistent print product, and printing effect is fine.
Embodiment
In order to understand the present invention better, further illustrate content of the present invention below in conjunction with embodiment, but content of the present invention not only is confined to following embodiment.
Among each embodiment alcohol dissolve urethane available from the Zhong Shan of Guangdong Province stone east rise the smooth back of the body in town white in the manufacturing district, the trade mark is XH-PU304; Ternary chlorine wax tree fat is available from the auspicious rich trading firm in Guangzhou, and the trade mark is E15/45M, and the place of production is a Germany; Nitrile rubber was available from great day international (Chengdu) ltd; Neoprene latex, 224, deify worker ltd available from Xingtai City magnesium; Other is commercially available analytical pure.
Embodiment 1
A kind of high adhesive force printing ink comprises following component: alcohol contains intermingle with 20 parts of ammonia ester solutions, 8 parts in ternary chlorine wax tree fat, 28 parts of white titanium pigments; 35 parts of acetic acid, 18 parts of ethanol, 3 parts of nitrile rubbers; 2 parts in acetone, said umber are parts by weight, and the mass concentration that alcohol contains intermingle with the ammonia ester solution is 30%; The solvent that alcohol contains intermingle with the ammonia ester solution is that Virahol and ethanol mass ratio are the mixture of 1:1.
Above-mentioned raw materials is mixed, and 1000 rev/mins are stirred to that ternary chlorine wax tree fat dissolves fully, each raw material thorough mixing, be ground to fineness then and be not more than 8 microns, printed in white printing ink.Wherein white titanium pigment is a pigment.
Embodiment 2
Basic identical with embodiment 1, the different component formula of being: alcohol contains intermingle with 21 parts of ammonia ester solutions, 6 parts in ternary chlorine wax tree fat, 29 parts of pigment, 34 parts of acetic acid, 19 parts of ethanol, 2 parts in ETHYLE ACETATE, 3 parts of nitrile rubbers, 2 parts in acetone.
Embodiment 3
Basic identical with embodiment 1, the solvent of different is said alcohol contains intermingle with ammonia ester solution is an ethanol.
Embodiment 4
Basic identical with embodiment 1, the solvent of different is said alcohol contains intermingle with ammonia ester solution is a Virahol.
Embodiment 5
A kind of high adhesive force printing ink comprises following component: alcohol contains intermingle with 23 parts of ammonia ester solutions, 5 parts in ternary chlorine wax tree fat, 30 parts of carbon blacks; 33 parts of acetic acid, 20 parts of ethanol, 5 parts in ETHYLE ACETATE; 4 parts of nitrile rubbers, 3 parts in acetone, 2 parts of neoprene latexs; Toluene 2-3 part, said umber are parts by weight, and the mass concentration that alcohol contains intermingle with the ammonia ester solution is 35%; The solvent that alcohol contains intermingle with the ammonia ester solution is that Virahol and ethanol mass ratio are the mixture of 6:1.
Above-mentioned raw materials is mixed, and 1000 rev/mins are stirred to that ternary chlorine wax tree fat dissolves fully, each raw material thorough mixing, be ground to fineness then and be not more than 8 microns, black printing printing ink.Wherein carbon black is a pigment.
Can find out that from raw material the foregoing description solvent for use is innoxious solvent.
On steel work, plastics and paper, pigment is prolonged not to be fallen (2 years no any fading or obscission) with above-mentioned five embodiment gained ink printings, and sticking power is extremely strong.
Claims (6)
1. high adhesive force printing ink, it is characterized in that: comprise following component: alcohol contains intermingle with ammonia ester solution 20-23 part, ternary chlorine wax tree fat 5-8 part; Pigment 28-30 part, acetic acid 33-35 part, ethanol 18-20 part; ETHYLE ACETATE 0-5 part, nitrile rubber 3-4 part, acetone 2-3 part; Said umber is parts by weight, and the mass concentration that alcohol contains intermingle with the ammonia ester solution is 30-35%.
2. high adhesive force printing ink as claimed in claim 1 is characterized in that: also comprise neoprene latex 2-3 part.
3. high adhesive force printing ink as claimed in claim 2 is characterized in that: also comprise toluene 2-3 part.
4. like any described high adhesive force printing ink of claim 1 to 3, it is characterized in that: the solvent that said alcohol contains intermingle with the ammonia ester solution is the mixture of Virahol or ethanol or both any proportionings.
5. high adhesive force printing ink as claimed in claim 4 is characterized in that: the solvent that said alcohol contains intermingle with the ammonia ester solution is that Virahol and ethanol mass ratio are the mixture of (1:1)-(6:1).
6. high adhesive force printing ink as claimed in claim 5 is characterized in that: the solvent that said alcohol contains intermingle with the ammonia ester solution is that Virahol and ethanol mass ratio are 6:1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012103022465A CN102807788A (en) | 2012-08-23 | 2012-08-23 | High-adhesion ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012103022465A CN102807788A (en) | 2012-08-23 | 2012-08-23 | High-adhesion ink |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102807788A true CN102807788A (en) | 2012-12-05 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012103022465A Pending CN102807788A (en) | 2012-08-23 | 2012-08-23 | High-adhesion ink |
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| CN (1) | CN102807788A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104312268A (en) * | 2014-11-14 | 2015-01-28 | 句容市茂源织造厂 | Environment-friendly printing ink with high adhesive force |
| CN104312279A (en) * | 2014-11-14 | 2015-01-28 | 句容市茂源织造厂 | Printing ink with high heat resistance |
| CN115353774A (en) * | 2022-09-20 | 2022-11-18 | 上海紫江彩印包装有限公司 | Freezing reversible temperature change printing film and preparation method and application thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3226368A1 (en) * | 1982-07-14 | 1984-03-01 | Basf Farben + Fasern Ag, 2000 Hamburg | Printing ink |
| CN1757685A (en) * | 2005-11-07 | 2006-04-12 | 汕头市金平区五星油墨实业有限公司 | Printing ink |
| CN101353498A (en) * | 2008-08-28 | 2009-01-28 | 郜爱民 | Printing ink |
| CN102061113A (en) * | 2011-01-31 | 2011-05-18 | 郑州峰源油墨有限公司 | Alcohol soluble polyurethane gravure plastic ink and preparation method thereof |
-
2012
- 2012-08-23 CN CN2012103022465A patent/CN102807788A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3226368A1 (en) * | 1982-07-14 | 1984-03-01 | Basf Farben + Fasern Ag, 2000 Hamburg | Printing ink |
| CN1757685A (en) * | 2005-11-07 | 2006-04-12 | 汕头市金平区五星油墨实业有限公司 | Printing ink |
| CN101353498A (en) * | 2008-08-28 | 2009-01-28 | 郜爱民 | Printing ink |
| CN102061113A (en) * | 2011-01-31 | 2011-05-18 | 郑州峰源油墨有限公司 | Alcohol soluble polyurethane gravure plastic ink and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104312268A (en) * | 2014-11-14 | 2015-01-28 | 句容市茂源织造厂 | Environment-friendly printing ink with high adhesive force |
| CN104312279A (en) * | 2014-11-14 | 2015-01-28 | 句容市茂源织造厂 | Printing ink with high heat resistance |
| CN115353774A (en) * | 2022-09-20 | 2022-11-18 | 上海紫江彩印包装有限公司 | Freezing reversible temperature change printing film and preparation method and application thereof |
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20121205 |