CN106065224A - A kind of aqueous, environmental protective sense of touch ink and preparation method thereof - Google Patents
A kind of aqueous, environmental protective sense of touch ink and preparation method thereof Download PDFInfo
- Publication number
- CN106065224A CN106065224A CN201610641101.6A CN201610641101A CN106065224A CN 106065224 A CN106065224 A CN 106065224A CN 201610641101 A CN201610641101 A CN 201610641101A CN 106065224 A CN106065224 A CN 106065224A
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- China
- Prior art keywords
- aqueous
- touch
- water
- sense
- gravure ink
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
Abstract
The present invention provides a kind of aqueous, environmental protective sense of touch ink and preparation method thereof, and aqueous, environmental protective sense of touch ink includes following component count by weight percentage: water-base resin 60 ~ 70%, water-borne wax slurry 15 ~ 20%, dehydrated alcohol 2 ~ 5%, deionized water 2 ~ 5%, defoamer 0.3 ~ 1%, other auxiliary agents 1 ~ 3%, aqueous sense of touch powder 8 ~ 12%.Does not discharge poisonous gas when prepared aqueous, environmental protective sense of touch gravure ink uses, environment friendly and pollution-free, form and aspect are milky white, and film forming postadhesion power is strong, folding, wear-resisting, water-fast the most excellent.
Description
Technical field
The invention belongs to technical field of ink, in particular it relates to a kind of aqueous, environmental protective sense of touch gravure ink.
Background technology
Sense of touch gravure ink on the market is the most solvent type, all contains substantial amounts of organic solvent, such as ketone in its composition
Class, benzene class, esters, alcohols etc..Have a substantial amounts of organic solvent volatile emission in air when construction, environment is caused dirt
Dye, is unfavorable for environmental protection, and especially benzene kind solvent is unfavorable for that operator's is healthy.Patents is not had to report aqueous yet
Sense of touch gravure ink.
Therefore, need to develop a kind of feel good springiness, adhesive force is good, wear-resisting and resistance to water can meet decorative ink requirement
Aqueous, environmental protective sense of touch gravure ink.
Summary of the invention
It is contemplated that overcome the defect of above-mentioned prior art, it is provided that a kind of aqueous, environmental protective sense of touch gravure ink, this aqueous
Environmental protection sense of touch gravure ink curing rate is fast, and sense of touch good springiness, hands touches with fluffy feel, seems the sense touched on chamois leather
Feeling, adhesive force is strong, folding resistance, wearability, water-tolerant, it is adaptable to packaging for foodstuff, the front cover of books and periodicals magazine, wall calendar, medicine box, change
The printing decoration of cosmetic, tobacco bale etc..
Another object of the present invention is to provide the preparation method of described aqueous, environmental protective sense of touch gravure ink.
The goal of the invention of the present invention is achieved by the following technical programs:
A kind of aqueous, environmental protective sense of touch gravure ink, including the component of following parts by weight:
Water-base resin 60 ~ 70%
Water-borne wax slurry 15 ~ 20%
Dehydrated alcohol 2 ~ 5%
Deionized water 2 ~ 5%
Defoamer 0.3 ~ 1%
Other auxiliary agents 1 ~ 3%
Aqueous sense of touch powder 8 ~ 12%.
Preferably, described water-base resin is aqueous polyurethane elastic resin.It is highly preferred that described aqueous polyurethane elastic tree
Fat is Guangzhou Luo Chi trade Co., Ltd WPC-230C aqueous PUD resin.
Preferably, described water-borne wax slurry is aqueous high rigidity Tissuemat E aqueous dispersion.It is highly preferred that described aqueous is gathered
Ethylene waxes slurry is Germany Clariant Corporation water-borne wax liquid W-19.
Preferably, described defoamer is waterborne organic silicon defoamer.It is highly preferred that described waterborne organic silicon defoamer is moral
State wins the enlightening height Airex901W under wound industrial group.
Preferably, described levelling agent is waterborne organic silicon levelling agent；Described antifungus agent is heterocycles dry film mildew-resistant
Agent；Described preservative is aqueous in-can preservation agent.
Preferably, described sense of touch agent is aqueous elastic powder.Have it is highly preferred that described aqueous elastic powder is source, Shanghai standing grain chemical industry
Limit company ACURE D87.
Preferably, described aqueous, environmental protective sense of touch gravure ink is made up of following component count by weight percentage:
Waterborne polyurethane resin 60 ~ 70%
Aqueous polyethylene wax slurry 15 ~ 20%
Dehydrated alcohol 2 ~ 5%
Deionized water 2 ~ 5%
Waterborne organic silicon defoamer 0.3 ~ 1%
Waterborne organic silicon levelling agent, water mildow-proof agent, waterborne preservative totally 1 ~ 3%
Aqueous polyurethane elastic powder 8 ~ 12%.
The present invention uses waterborne polyurethane resin as matrix resin, and it is fast that this resin has rate of drying, and good springiness is resistance to
Folding, wear-resisting, the advantage such as have excellent water-resistance；Add aqueous polyethylene wax slurry and can improve ink pellet surface resistance to scraping and slippery；Add water
Property elastic polyurethane powder, can produce elastic tactility effect；Adding preservative can prevent ink corrupt smelly during storing；Anti-
Mould dose can prevent after ink setting film forming because environmental effect produces the problems such as mouldy；Levelling agent and defoamer improve leaflet
Levelability and the bad phenomenon such as foaming when preventing high speed printing.
The preparation method of above-mentioned aqueous sense of touch gravure ink, comprises the steps:
S1. water-base resin, water-borne wax slurry, defoamer, other auxiliary agent are uniformly mixed, mixing speed 500～700 turns/
Minute, stir 10～20 minutes；
Improve rotating speed to 900～1100 revs/min the most again, add aqueous sense of touch powder, stir 20～30 minutes, to stirring,
Fineness is up to standard；
Reduce rotating speed to 500～700 revs/min the most again, add dehydrated alcohol and deionized water stirs 5～10 minutes, to stirring
Uniformly, filter and package with 80 mesh filter screens.
Compared with prior art, there is advantages that the present invention selects aqueous polyurethane elastic resin to make
For matrix resin, impart gravure ink rate of drying fast, the advantage such as folding, wear-resisting and water-tolerant；Add aqueous polyethylene
Wax slurry can improve ink pellet surface resistance to scraping and slippery；Add aqueous polyurethane elastic powder, elastic tactility effect can be produced；Add anti-
Rotten agent can prevent ink corrupt smelly during storing；Antifungus agent is sent out because environmental effect produces after preventing ink setting film forming
The problem such as mould；The bad phenomenon such as foaming when levelling agent and defoamer improve the levelability of leaflet and prevent high speed printing.
The not toxic gas such as containing benezene, alcohols solvent content is relatively low, good environmental protection.
Detailed description of the invention
The raw materials used model of following example is as follows:
Water-base resin is Guangzhou Luo Chi trade Co., Ltd WPC-230C aqueous PUD resin；
Water-borne wax slurry is Germany Clariant Corporation water-borne wax liquid W-19；
Waterborne organic silicon defoamer is the Airex901W that enlightening is high；
Aqueous polyurethane elastic powder is Shanghai Yuan He Chemical Co., Ltd. ACURE D87；
Other are common commercially available prod.
Embodiment 1
S1. by water-base resin 60 kilograms, 20 kilograms of water-borne wax slurry, waterborne organic silicon defoamer 1 kilogram, waterborne organic silicon levelling agent
0.5 kilogram, aqueous dry film antifungus agent 0.25 kilogram, aqueous in-can preservation agent 0.25 kilogram be uniformly mixed, mixing speed is
500 revs/min, stir 20 minutes；
Improve rotating speed to 900 revs/min the most again, add 8 kilograms of aqueous polyurethane elastic powder, stir 30 minutes, reach to fineness
Mark；
Reduce rotating speed to 500 revs/min the most again, add dehydrated alcohol 5 kilograms and deionized water 5 kilograms stirs 10 minutes, to stirring
Mix uniformly, filter and package with 80 mesh filter screens.
Embodiment 2
S1. by water-base resin 70 kilograms, 15 kilograms of water-borne wax slurry, waterborne organic silicon defoamer 0.3 kilogram, waterborne organic silicon levelling
Agent 1 kilogram, aqueous dry film antifungus agent 0.5 kilogram, aqueous in-can preservation agent 0.5 kilogram are uniformly mixed, and mixing speed is 600
Rev/min, stir 15 minutes；
Improve rotating speed to 1000 revs/min the most again, add 8.7 kilograms of aqueous polyurethane elastic powder, stir 25 minutes, to fineness
Up to standard；
Reduce rotating speed to 600 revs/min the most again, add dehydrated alcohol 2 kilograms and deionized water 2 kilograms stirs 8 minutes, to stirring
Mix uniformly, filter and package with 80 mesh filter screens.
Embodiment 3
S1. by water-base resin 65 kilograms, 15.5 kilograms of water-borne wax slurry, waterborne organic silicon defoamer 0.5 kilogram, waterborne organic silicon stream
Flat agent 1.5 kilograms, aqueous dry film antifungus agent 0.75 kilogram, aqueous in-can preservation agent 0.75 kilogram are uniformly mixed, stirring speed
Degree is 700 revs/min, stirs 10 minutes；
Improve rotating speed to 1100 revs/min the most again, add 12 kilograms of aqueous polyurethane elastic powder, stir 10 minutes, reach to fineness
Mark；
Reduce rotating speed to 700 revs/min the most again, add dehydrated alcohol 2 kilograms and deionized water 2 kilograms stirs 5 minutes, to stirring
Mix uniformly, filter and package with 80 mesh filter screens.
Comparative example 1
S1. water-base resin (Guangzhou Luo Chi trade Co., Ltd WPC-305) 60 kilograms, 20 kilograms of water-borne wax slurry, aqueous are had
Machine silicon defoaming agent 1 kilogram, waterborne organic silicon levelling agent 0.5 kilogram, aqueous dry film antifungus agent 0.25 kilogram, aqueous in-can preservation agent
0.25 kilogram is uniformly mixed, and mixing speed is 500 revs/min, stirs 20 minutes；
Improve rotating speed to 900 revs/min the most again, add 8 kilograms of aqueous polyurethane elastic powder, stir 30 minutes；Reach to fineness
Mark；
Reduce rotating speed to 500 revs/min the most again, add dehydrated alcohol 5 kilograms and deionized water 5 kilograms stirs 10 minutes, to stirring
Mix uniformly, filter and package with 80 mesh filter screens.
Comparative example 2
S1. by water-base resin 70 kilograms, 15 kilograms of water-borne wax slurry, waterborne organic silicon defoamer 0.3 kilogram, waterborne organic silicon levelling
Agent 1 kilogram, aqueous dry film antifungus agent 0.5 kilogram, aqueous in-can preservation agent 0.5 kilogram are uniformly mixed, and mixing speed is 600
Rev/min, stir 15 minutes；
Improving rotating speed to 1000 revs/min the most again, addition water soluble acrylic acid elasticity powder be (Shanghai Yuan He Chemical Co., Ltd.
Acure 7) 8.7 kilograms, stir 25 minutes；Up to standard to fineness；
Reduce rotating speed to 600 revs/min the most again, add dehydrated alcohol 2 kilograms and deionized water 2 kilograms stirs 8 minutes, to stirring
Mix uniformly, filter and package with 80 mesh filter screens.
Aqueous, environmental protective sense of touch gravure ink all form and aspect obtained by embodiment and comparative example are milky white.
The aqueous, environmental protective sense of touch gravure ink preparing embodiment and comparative example carries out performance detection, and detection method is as follows:
Being printed in gold silver paperboard by ink intaglio printing press, after 120 degree are toasted 2 minutes, room temperature is tested after placing 60 minutes:
Adhesive force: test by film coated surface being carried out hundred lattice methods by " GB9286-1988 ".
Folding: 180 degree of doublings, investigates the number of times of explosion.
Water-fast: by the test of " GB1733-1988 " regulation.
Wear-resisting: to test with ink wear-resistant tester, select 2 pounds of counterweights, counter records coefficient of friction.
Viscosity: survey Cai's grace 3# cup viscosity with flow cup at 23 DEG C.
Testing result is shown in Table 1.
Embodiment described above only have expressed embodiments of the present invention, therefore it describes more concrete and detailed, but can not be
And it is interpreted as the restriction to the scope of the claims of the present invention, as long as using the technical side that the form of equivalent or equivalent transformation is obtained
Case, within all should being included in the protection domain of the claims in the present invention.
Claims (8)
1. aqueous, environmental protective sense of touch ink and preparation method thereof, it is characterised in that include following count by weight percentage
Component:
Water-base resin 60 ~ 70%
Water-borne wax slurry 15 ~ 20%
Dehydrated alcohol 2 ~ 5%
Deionized water 2 ~ 5%
Defoamer 0.3 ~ 1%
Other auxiliary agents 1 ~ 3%
Aqueous sense of touch powder 8 ~ 12%.
Aqueous sense of touch gravure ink the most according to claim 1, it is characterised in that described water-base resin is aqueous polyurethane tree
Fat.
Aqueous sense of touch gravure ink the most according to claim 1, it is characterised in that described water-borne wax slurry is aqueous polyethylene wax
Slurry.
Aqueous sense of touch gravure ink the most according to claim 1, it is characterised in that described defoamer is waterborne organic silicon froth breaking
Agent.
Aqueous sense of touch gravure ink the most according to claim 1, it is characterised in that other auxiliary agents described are waterborne organic silicon stream
Flat agent, water mildow-proof agent, waterborne preservative.
Aqueous sense of touch gravure ink the most according to claim 1, it is characterised in that described aqueous sense of touch powder is aqueous polyurethane
Elastic powder.
7. according to aqueous sense of touch gravure ink described in claim 1 to 6 any one, it is characterised in that by following by weight hundred
The component composition that proportion by subtraction calculates:
Waterborne polyurethane resin 60 ~ 70%
Aqueous polyethylene wax slurry 15 ~ 20%
Dehydrated alcohol 2 ~ 5%
Deionized water 2 ~ 5%
Waterborne organic silicon defoamer 0.3 ~ 1%
Waterborne organic silicon levelling agent, water mildow-proof agent, waterborne preservative totally 1 ~ 3%
Aqueous polyurethane elastic powder 8 ~ 12%.
8. the preparation method of aqueous sense of touch gravure ink as described in claim 1 to 7 any one claim, its feature exists
In, comprise the steps:
S1. water-base resin, water-borne wax slurry, defoamer, other auxiliary agent are uniformly mixed, mixing speed 500～700 turns/
Minute, stir 10～20 minutes；
Improve rotating speed to 900～1100 revs/min the most again, add aqueous sense of touch powder, stir 20～30 minutes, to stirring,
Fineness is up to standard；
Reduce rotating speed to 500～700 revs/min the most again, add dehydrated alcohol and deionized water stirs 5～10 minutes, to stirring
Uniformly, filter and package with 80 mesh filter screens.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610641101.6A CN106065224A (en) | 2016-08-08 | 2016-08-08 | A kind of aqueous, environmental protective sense of touch ink and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610641101.6A CN106065224A (en) | 2016-08-08 | 2016-08-08 | A kind of aqueous, environmental protective sense of touch ink and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106065224A true CN106065224A (en) | 2016-11-02 |
Family
ID=57207643
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610641101.6A Pending CN106065224A (en) | 2016-08-08 | 2016-08-08 | A kind of aqueous, environmental protective sense of touch ink and preparation method thereof |
Country Status (1)
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106566314A (en) * | 2016-11-10 | 2017-04-19 | 安徽集友纸业包装有限公司 | Water-based matt tactility printing ink, tipping paper for cigarette, and preparation method of tipping paper for cigarette |
| CN107489066A (en) * | 2017-09-19 | 2017-12-19 | 浙江特美新材料股份有限公司 | The cork paper production technology and its equipment of a kind of combination sense of touch ink |
| CN109021677A (en) * | 2018-09-30 | 2018-12-18 | 中山市中益油墨涂料有限公司 | A kind of aqueous feel or sense of touch ink and preparation method thereof |
| CN109278435A (en) * | 2018-09-10 | 2019-01-29 | 河南省防伪保密印刷公司（河南省邮电印刷厂） | A kind of environmental protection sense of touch oil glazing process |
| CN109969548A (en) * | 2017-12-28 | 2019-07-05 | 战马（北京）饮料有限公司 | A kind of more sense of touch regions tank body |
| CN110358355A (en) * | 2019-07-02 | 2019-10-22 | 惠州市至上新材料有限公司 | A kind of high abrasion aluminum foil lining paper water-based inks and preparation method thereof for exempting from finishing oil |
| CN110722871A (en) * | 2018-07-17 | 2020-01-24 | 深圳市科彩印务有限公司 | Single-concave flocking printing process |
| CN112111238A (en) * | 2020-08-12 | 2020-12-22 | 安徽国风塑业股份有限公司 | Touch type bottomless BOPET matte pre-coating film and preparation method thereof |
| CN112980306A (en) * | 2019-12-16 | 2021-06-18 | 江苏泰格油墨有限公司 | Water-based gravure touch gloss oil and preparation process thereof |
| CN114163869A (en) * | 2021-12-20 | 2022-03-11 | 中山市中益油墨涂料有限公司 | Water-based roller coating touch oil and preparation method thereof |
| CN114196256A (en) * | 2021-12-30 | 2022-03-18 | 中山市中益油墨涂料有限公司 | Water-based gravure white ink for film printing and preparation method thereof |
| CN115197605A (en) * | 2022-06-17 | 2022-10-18 | 佛山市儒林化工有限公司 | Printing ink with wrinkle texture effect and preparation method thereof |
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Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106566314A (en) * | 2016-11-10 | 2017-04-19 | 安徽集友纸业包装有限公司 | Water-based matt tactility printing ink, tipping paper for cigarette, and preparation method of tipping paper for cigarette |
| CN107489066A (en) * | 2017-09-19 | 2017-12-19 | 浙江特美新材料股份有限公司 | The cork paper production technology and its equipment of a kind of combination sense of touch ink |
| CN109969548B (en) * | 2017-12-28 | 2023-10-13 | 战马（北京）饮料有限公司 | Multi-touch area tank |
| CN109969548A (en) * | 2017-12-28 | 2019-07-05 | 战马（北京）饮料有限公司 | A kind of more sense of touch regions tank body |
| CN110722871A (en) * | 2018-07-17 | 2020-01-24 | 深圳市科彩印务有限公司 | Single-concave flocking printing process |
| CN109278435A (en) * | 2018-09-10 | 2019-01-29 | 河南省防伪保密印刷公司（河南省邮电印刷厂） | A kind of environmental protection sense of touch oil glazing process |
| CN109021677A (en) * | 2018-09-30 | 2018-12-18 | 中山市中益油墨涂料有限公司 | A kind of aqueous feel or sense of touch ink and preparation method thereof |
| CN110358355A (en) * | 2019-07-02 | 2019-10-22 | 惠州市至上新材料有限公司 | A kind of high abrasion aluminum foil lining paper water-based inks and preparation method thereof for exempting from finishing oil |
| CN112980306A (en) * | 2019-12-16 | 2021-06-18 | 江苏泰格油墨有限公司 | Water-based gravure touch gloss oil and preparation process thereof |
| CN112111238A (en) * | 2020-08-12 | 2020-12-22 | 安徽国风塑业股份有限公司 | Touch type bottomless BOPET matte pre-coating film and preparation method thereof |
| CN114163869A (en) * | 2021-12-20 | 2022-03-11 | 中山市中益油墨涂料有限公司 | Water-based roller coating touch oil and preparation method thereof |
| CN114196256A (en) * | 2021-12-30 | 2022-03-18 | 中山市中益油墨涂料有限公司 | Water-based gravure white ink for film printing and preparation method thereof |
| CN115197605A (en) * | 2022-06-17 | 2022-10-18 | 佛山市儒林化工有限公司 | Printing ink with wrinkle texture effect and preparation method thereof |
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Application publication date: 20161102 |
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