CN108300200A - A kind of waterborne UV coating and preparation method thereof - Google Patents
A kind of waterborne UV coating and preparation method thereof Download PDFInfo
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- CN108300200A CN108300200A CN201711409535.4A CN201711409535A CN108300200A CN 108300200 A CN108300200 A CN 108300200A CN 201711409535 A CN201711409535 A CN 201711409535A CN 108300200 A CN108300200 A CN 108300200A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/24—Electrically-conducting paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The invention discloses a kind of waterborne UV coatings and preparation method thereof, are prepared by following component by weight：40 60 parts of aqueous unsaturated polyester (UP) acrylate resin, 20 30 parts of polyurethane acrylate resin, 5 10 parts of methacrylate acrylonitrile butyl acrylate copolymer, 10 15 parts of photoinitiator, 10 30 parts of reactive diluent, 0.1 1.0 parts of wetting agent, 15 parts of nano silicon dioxide, 0.1 1.0 parts of levelling agent, 0.1 1.0 parts of antifoaming agent, 1 10 parts of silane coupling agent, 0.1 1.5 parts of preservative, 35 parts of antistatic agent, 35 parts of titanium dioxide, 10 20 parts of deionized water.The present invention has storage stability good, and paint film water-tolerant, solvent resistance are good, and wear-resisting property is good, and the characteristics of being easy to apply cloth base material, while it also has antistatic property.
Description
Technical field
The present invention relates to a kind of coating used on woodenware, in particular to a kind of waterborne UV coating and its preparation
Method.
Background technology
With the enhancing of mankind's environmental consciousness, various countries have formulated ring in succession to the discharge of VOC (volatile organic compounds)
Regulation is protected, and it is increasingly stringent to limit discharge standard, it is intended to which environmentally protective, energy-saving and emission-reduction new products are promoted the use of in encouragement.Therefore,
In paint spraying field, the development and application gesture of the safe Environmentally friendly coatings that grade with the aqueous of low VOC, powder and high solid
It must go.Since waterborne UV coating has the characteristics that more achievable technological approaches, wide application, safety, construction are relatively easy, closely
Several years very fast in the development of the developed countries such as America and Europe, is popular.
Relative to traditional UV coating, waterborne UV coating has apparent advantage, is mainly manifested in：Viscosity is low；Because of shipwreck
Combustion is difficult quick-fried, and tradition UV coating has certain flash-point, and flammable explosive, aqueous UV is fire retardant quick-fried；Hypotoxicity, and traditional UV coating ratio,
Waterborne UV coating is greatly lowered containing, anaphylaxis irritant to human body or other active components to human body adverse effect；Anti-current
Extension property, waterborne UV coating before curing or even have obtained the coating of surface drying, before traditional UV paint solidifications if too thick or too
It is dilute all to lead to sagging；Can be with scumbling, it is partially thick that 100% solid part of traditional UV coating is easy to cause coating, it is difficult to obtain than relatively thin
Coating, to cause the waste of material；Using wide, because the shrinking percentage of waterborne UV coating is low, wetability is good, in some hardly possiblies
Also good adhesive force, equipment cleaning are easy on the base material of attachment.But existing waterborne UV coating there is a problem in that：
Waterborne UV coating there are storage stabilities bad, paint film water resistance, poor solvent resistance, wear-resisting property are poor, it is not easy to apply cloth base material,
Easily cause to be unevenly coated and do not have the problems such as antistatic property.
Invention content
In view of the deficiencies of the prior art, of the invention first is designed to provide a kind of waterborne UV coating, it, which has, deposits
Storage stability is good, and paint film water-tolerant, solvent resistance are good, and wear-resisting property is good, and the characteristics of being easy to apply cloth base material, while it also has
Antistatic property.
Second object of the present invention is to provide for a kind of preparation method of waterborne UV coating.
Realize that first purpose of the present invention can reach by adopting the following technical scheme that：
A kind of waterborne UV coating, which is characterized in that be prepared by following component by weight：It is aqueous unsaturated poly-
40-60 parts of ester acrylate resin, 20-30 parts of polyurethane acrylate resin, methyl-acrylate-butyl acetate copolymer
5-10 parts, 10-15 parts of photoinitiator, 10-30 parts of reactive diluent, 0.1-1.0 parts of wetting agent, 1-5 parts of nano silicon dioxide, stream
Flat agent 0.1-1.0 parts, 0.1-1.0 parts of antifoaming agent, 1-10 parts of silane coupling agent, 0.1-1.5 parts of preservative, 3-5 parts of antistatic agent,
3-5 parts of titanium dioxide, 10-20 parts of deionized water.
Preferably, the waterborne UV coating, is prepared by following component by weight：Aqueous unsaturated polyester (UP)
50 parts of acrylate resin, 25 parts of polyurethane acrylate resin, 8 parts of methyl-acrylate-butyl acetate copolymer, light draws
12 parts of agent of hair, 15 parts of reactive diluent, 0.5 part of wetting agent, 2 parts of nano silicon dioxide, 0.5 part of levelling agent, 0.5 part of antifoaming agent,
5 parts of silane coupling agent, 1 part of preservative, 4 parts of antistatic agent, 4 parts of titanium dioxide, 15 parts of deionized water.
Preferably, the photoinitiator is -2 methyl-1s of 2- hydroxyls-phenyl-propanone.
Preferably, the reactive diluent is polyethylene glycol diacrylate fat.
Preferably, the wetting agent is organic silicon surfactant.
Preferably, the nano silicon dioxide is polyether polyester azo polyether polyeste.
Preferably, the levelling agent is polyurethanes levelling agent.
Preferably, the antifoaming agent is organic silicon defoamer.
Preferably, the silane coupling agent is the model of Nanjing Xuan Hao new materials Science and Technology Ltd. production
The silane coupling agent of kh550.
Preferably, the preservative is the combination of the LX150 of Dow Chemical and the R640 of Dow Chemical,
The weight ratio of the two is 1:1.
Preferably, the antistatic agent is ethoxylated alkylamine.
A kind of preparation method of waterborne UV coating, which is characterized in that include the following steps：
1) deionized water of formula ratio is added in Scattered Kettle, starts blender, governing speed to 450rpm/min is being stirred
It mixes down the preservative for sequentially adding formula ratio, antifoaming agent, improves rotating speed to 1000rpm/min, high speed dispersion 30min, reduction is stirred
After mixing speed to 650rpm/min, sequentially add aqueous unsaturated polyester (UP) acrylate resin, polyurethane acrylate resin,
Methyl-acrylate-butyl acetate copolymer stirs evenly, and obtains uniform first solution；
2) nano silicon dioxide, titanium dioxide, silane coupling agent and the antistatic agent of formula ratio, control are added in the first solution
Rotating speed processed is 1150 turns/min, jitter time 20min, obtains uniform second solution；
3) in the second solution after the photoinitiator of addition formula ratio, levelling agent, reactive diluent, wetting agent, stirring
0.5-2h, control rotating speed are 550 turns/min, obtain uniform third solution；
4) third solution be filtered, packed, is put in storage to get to waterborne UV coating.
The beneficial effects of the present invention are：
The present invention has obtained a kind of waterborne UV coating by the optimization to raw material composition and dosage, it has stable storage
Property it is good, paint film water-tolerant, solvent resistance are good, and wear-resisting property is good, be easy apply cloth base material the characteristics of, while it also have it is antistatic
Property.The storage stability of the present invention：12 months product viscosities of room temperature become 25s from 20s, no to precipitate, without layering, it was demonstrated that production
Product Storage period is more than 12 months.Salt water resistance (5% sodium chloride), 30 days without significant change (GB/T9274-88), 0 grade (hundred of adhesive force
Lattice method), salt spray resistance (3% sodium chloride) 30 days is without significant change (GB/1771-91).The antistatic tests (changing value) of AATCC≤
2.5%.
Specific implementation mode
In the following, in conjunction with specific implementation mode, the present invention is described further：
In an embodiment of the present invention, the photoinitiator is -2 methyl-1s of 2- hydroxyls-phenyl-propanone.The work
Property diluent be polyethylene glycol diacrylate fat.The wetting agent is organic silicon surfactant.The nanometer titanium dioxide
Silicon is polyether polyester azo polyether polyeste.The levelling agent is polyurethanes levelling agent.The antifoaming agent is organosilicon
Antifoaming agent.The silane coupling agent is that the silane of the model kh550 of Nanjing Xuan Hao new materials Science and Technology Ltd. production is even
Join agent.The preservative is the combination of the LX150 of Dow Chemical and the R640 of Dow Chemical, the weight ratio of the two
It is 1:1.The antistatic agent is ethoxylated alkylamine.
Embodiment 1：
A kind of waterborne UV coating is prepared by following component by weight：Aqueous unsaturated polyester (UP) acrylate
40 parts of resin, 20 parts of polyurethane acrylate resin, 5 parts of methyl-acrylate-butyl acetate copolymer, photoinitiator 10
Part, 10 parts of reactive diluent, 0.1 part of wetting agent, 1 part of nano silicon dioxide, 0.1 part of levelling agent, 0.1 part of antifoaming agent, silane idol
Join 1 part of agent, 0.1 part of preservative, 3 parts of antistatic agent, 3 parts of titanium dioxide, 10 parts of deionized water.
A kind of preparation method of waterborne UV coating, which is characterized in that include the following steps：
1) deionized water of formula ratio is added in Scattered Kettle, starts blender, governing speed to 450rpm/min is being stirred
It mixes down the preservative for sequentially adding formula ratio, antifoaming agent, improves rotating speed to 1000rpm/min, high speed dispersion 30min, reduction is stirred
After mixing speed to 650rpm/min, sequentially add aqueous unsaturated polyester (UP) acrylate resin, polyurethane acrylate resin,
Methyl-acrylate-butyl acetate copolymer stirs evenly, and obtains uniform first solution；
2) nano silicon dioxide, titanium dioxide, silane coupling agent and the antistatic agent of formula ratio, control are added in the first solution
Rotating speed processed is 1150 turns/min, jitter time 20min, obtains uniform second solution；
3) in the second solution after the photoinitiator of addition formula ratio, levelling agent, reactive diluent, wetting agent, stirring
0.5-2h, control rotating speed are 550 turns/min, obtain uniform third solution；
4) third solution be filtered, packed, is put in storage to get to waterborne UV coating.
Embodiment 2：
A kind of waterborne UV coating is prepared by following component by weight：Aqueous unsaturated polyester (UP) acrylate
50 parts of resin, 25 parts of polyurethane acrylate resin, 8 parts of methyl-acrylate-butyl acetate copolymer, photoinitiator 12
Part, 15 parts of reactive diluent, 0.5 part of wetting agent, 2 parts of nano silicon dioxide, 0.5 part of levelling agent, 0.5 part of antifoaming agent, silane idol
Join 5 parts of agent, 1 part of preservative, 4 parts of antistatic agent, 4 parts of titanium dioxide, 15 parts of deionized water.
The preparation method of waterborne UV coating is same as Example 1.
Embodiment 3：
A kind of waterborne UV coating is prepared by following component by weight：Aqueous unsaturated polyester (UP) acrylate
55 parts of resin, 25 parts of polyurethane acrylate resin, 6 parts of methyl-acrylate-butyl acetate copolymer, photoinitiator 13
Part, 25 parts of reactive diluent, 0.8 part of wetting agent, 4 parts of nano silicon dioxide, 0.7 part of levelling agent, 0.7 part of antifoaming agent, silane idol
Join 4 parts of agent, 1.2 parts of preservative, 4.5 parts of antistatic agent, 3.5 parts of titanium dioxide, 18 parts of deionized water.
The preparation method of waterborne UV coating is same as Example 1.
Embodiment 4：
A kind of waterborne UV coating is prepared by following component by weight：Aqueous unsaturated polyester (UP) acrylate
60 parts of resin, 30 parts of polyurethane acrylate resin, 10 parts of methyl-acrylate-butyl acetate copolymer, photoinitiator 15
Part, 30 parts of reactive diluent, 1.0 parts of wetting agent, 5 parts of nano silicon dioxide, 1.0 parts of levelling agent, 1.0 parts of antifoaming agent, silane idol
Join 10 parts of agent, 1.5 parts of preservative, 5 parts of antistatic agent, 5 parts of titanium dioxide, 20 parts of deionized water.
The preparation method of waterborne UV coating is same as Example 1.
The obtained waterborne UV coatings of the present embodiment 1-4 are detected, specific testing result is as follows：
Storage stability：12 months product viscosities of room temperature become 25s from 20s, no to precipitate, without layering, it was demonstrated that product
Storage period is more than 12 months.Salt water resistance (5% sodium chloride), 30 days without significant change (GB/T9274-88), 0 grade of (hundred lattice of adhesive force
Method), salt spray resistance (3% sodium chloride) 30 days is without significant change (GB/1771-91).The antistatic tests (changing value) of AATCC≤
2.5%.
After the waterborne UV coating of the above embodiments 1-4 is coated in industrial equipment surface, it is measured with paint film abrasion instrument
Wear-resisting property, load weight are after 1000g abrasions 2000 are enclosed, to calculate the weight loss of coating.
After the waterborne UV coating of the above embodiments is coated in industrial equipment surface again, it is placed at 80 DEG C and places 60 days,
Observe the variation of coating.As a result such as table 1：
Table 1
For those skilled in the art, technical solution that can be as described above and design are made other each
Kind is corresponding to be changed and deforms, and all these change and deform the protection model that should all belong to the claims in the present invention
Within enclosing.
Claims (10)
1. a kind of waterborne UV coating, which is characterized in that be prepared by following component by weight：Aqueous unsaturated polyester (UP)
40-60 parts of acrylate resin, 20-30 parts of polyurethane acrylate resin, methyl-acrylate-butyl acetate copolymer 5-
10 parts, 10-15 parts of photoinitiator, 10-30 parts of reactive diluent, 0.1-1.0 parts of wetting agent, 1-5 parts of nano silicon dioxide, levelling
0.1-1.0 parts of agent, 0.1-1.0 parts of antifoaming agent, 1-10 parts of silane coupling agent, 0.1-1.5 parts of preservative, 3-5 parts of antistatic agent, titanium
3-5 parts of white powder, 10-20 parts of deionized water.
2. waterborne UV coating according to claim 1, which is characterized in that by following component preparation by weight
At：50 parts of aqueous unsaturated polyester (UP) acrylate resin, 25 parts of polyurethane acrylate resin, methacrylate-acrylic acid
8 parts of acrylate copolymer, 12 parts of photoinitiator, 15 parts of reactive diluent, 0.5 part of wetting agent, 2 parts of nano silicon dioxide, levelling agent
0.5 part, 0.5 part of antifoaming agent, 5 parts of silane coupling agent, 1 part of preservative, 4 parts of antistatic agent, 4 parts of titanium dioxide, 15 parts of deionized water.
3. waterborne UV coating according to claim 1, which is characterized in that the photoinitiator is -2 methyl of 2- hydroxyls -
1- phenyl-propanones.
4. waterborne UV coating according to claim 1, which is characterized in that the reactive diluent is polyethylene glycol dipropyl
Olefin(e) acid fat.
5. waterborne UV coating according to claim 1, which is characterized in that the wetting agent is organosilicone surfactant
Agent.
6. waterborne UV coating according to claim 1, which is characterized in that the nano silicon dioxide changes for polyether polyester
Property organosiloxane；The levelling agent is polyurethanes levelling agent；The antifoaming agent is organic silicon defoamer.
7. waterborne UV coating according to claim 1, which is characterized in that the silane coupling agent is the great green wood in Nanjing pavilion
Expect the silane coupling agent of the model kh550 of Science and Technology Ltd.'s production.
8. waterborne UV coating according to claim 1, which is characterized in that the preservative is Dow Chemical
The weight ratio of the combination of the R640 of LX150 and Dow Chemical, the two is 1:1.
9. waterborne UV coating according to claim 1, which is characterized in that the antistatic agent is ethoxylated alkyl
Amine.
10. a kind of preparation method of waterborne UV coating according to claim 1, which is characterized in that include the following steps：
1) deionized water of formula ratio is added in Scattered Kettle, starts blender, governing speed to 450rpm/min, under stiring
Preservative, the antifoaming agent of formula ratio are sequentially added, rotating speed is improved to 1000rpm/min, high speed dispersion 30min, reduces stirring speed
After degree to 650rpm/min, aqueous unsaturated polyester (UP) acrylate resin, polyurethane acrylate resin, methyl are sequentially added
Acrylate-Acrylic acrylate copolymer, stirs evenly, and obtains uniform first solution；
2) nano silicon dioxide, titanium dioxide, silane coupling agent and the antistatic agent of formula ratio are added in the first solution, control turns
Speed is 1150 turns/min, jitter time 20min, obtains uniform second solution；
3) 0.5-2h is stirred after the photoinitiator of addition formula ratio, levelling agent, reactive diluent, wetting agent in the second solution,
Control rotating speed is 550 turns/min, obtains uniform third solution；
4) third solution be filtered, packed, is put in storage to get to waterborne UV coating.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201711409535.4A CN108300200A (en) | 2017-12-23 | 2017-12-23 | A kind of waterborne UV coating and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201711409535.4A CN108300200A (en) | 2017-12-23 | 2017-12-23 | A kind of waterborne UV coating and preparation method thereof |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109468066A (en) * | 2018-10-19 | 2019-03-15 | 东莞大宝化工制品有限公司 | A kind of waterborne UV wood paint and preparation method thereof with overexposure protection |
| CN110746570A (en) * | 2019-10-30 | 2020-02-04 | 武汉港川科技有限公司 | Preparation method of multi-silicon modified waterborne light-cured resin and gloss oil application thereof |
| CN111393585A (en) * | 2020-04-07 | 2020-07-10 | 湖南湘江关西涂料(长沙)有限公司 | Water-based resin, preparation method and application thereof, water-based paint and film product |
| CN111718647A (en) * | 2019-03-19 | 2020-09-29 | 立邦涂料（中国）有限公司 | Environment-friendly water-based UV coating and preparation method thereof |
| CN112680089A (en) * | 2019-10-18 | 2021-04-20 | 苏州辅朗光学材料有限公司 | Long-acting antistatic coating and application and product thereof |
| CN113372797A (en) * | 2021-06-29 | 2021-09-10 | 广东康伴新材料科技有限公司 | High-gloss high-fullness UV coating and preparation method thereof |
| US20210408513A1 (en) * | 2020-06-30 | 2021-12-30 | Nano Shield Technology Co., Ltd. | Battery module with nano composite coating |
| CN114350192A (en) * | 2021-02-01 | 2022-04-15 | 中南林业科技大学 | Coating with hydrophilic self-cleaning capability and preparation method thereof |
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| CN104592883A (en) * | 2015-01-31 | 2015-05-06 | 广东华兹卜化学工业有限公司 | Water-based UV coating and preparation method thereof |
| CN104673080A (en) * | 2013-11-27 | 2015-06-03 | 李应芝 | Antistatic water-borne UV coating |
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| CN102206461A (en) * | 2010-03-31 | 2011-10-05 | 东莞市佩琦涂料有限公司 | Waterborne UV coating |
| CN104673080A (en) * | 2013-11-27 | 2015-06-03 | 李应芝 | Antistatic water-borne UV coating |
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Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109468066A (en) * | 2018-10-19 | 2019-03-15 | 东莞大宝化工制品有限公司 | A kind of waterborne UV wood paint and preparation method thereof with overexposure protection |
| CN109468066B (en) * | 2018-10-19 | 2021-02-12 | 东莞大宝化工制品有限公司 | Water-based UV wood lacquer with overexposure protection and preparation method thereof |
| CN111718647A (en) * | 2019-03-19 | 2020-09-29 | 立邦涂料（中国）有限公司 | Environment-friendly water-based UV coating and preparation method thereof |
| CN112680089B (en) * | 2019-10-18 | 2022-07-05 | 安徽辅朗光学材料有限公司 | Long-acting antistatic coating and application and product thereof |
| CN112680089A (en) * | 2019-10-18 | 2021-04-20 | 苏州辅朗光学材料有限公司 | Long-acting antistatic coating and application and product thereof |
| CN110746570A (en) * | 2019-10-30 | 2020-02-04 | 武汉港川科技有限公司 | Preparation method of multi-silicon modified waterborne light-cured resin and gloss oil application thereof |
| CN111393585A (en) * | 2020-04-07 | 2020-07-10 | 湖南湘江关西涂料(长沙)有限公司 | Water-based resin, preparation method and application thereof, water-based paint and film product |
| CN111393585B (en) * | 2020-04-07 | 2023-03-31 | 湖南湘江关西涂料(长沙)有限公司 | Water-based resin, preparation method and application thereof, water-based paint and film product |
| US20210408513A1 (en) * | 2020-06-30 | 2021-12-30 | Nano Shield Technology Co., Ltd. | Battery module with nano composite coating |
| US11936057B2 (en) * | 2020-06-30 | 2024-03-19 | Nano Shield Technology Co., Ltd. | Battery module with nano composite coating |
| CN114350192A (en) * | 2021-02-01 | 2022-04-15 | 中南林业科技大学 | Coating with hydrophilic self-cleaning capability and preparation method thereof |
| CN114350192B (en) * | 2021-02-01 | 2023-01-06 | 中南林业科技大学 | Coating with hydrophilic self-cleaning capability and preparation method thereof |
| CN113372797A (en) * | 2021-06-29 | 2021-09-10 | 广东康伴新材料科技有限公司 | High-gloss high-fullness UV coating and preparation method thereof |
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Application publication date: 20180720 |