CN106566314A - Water-based matt tactility printing ink, tipping paper for cigarette, and preparation method of tipping paper for cigarette - Google Patents
Water-based matt tactility printing ink, tipping paper for cigarette, and preparation method of tipping paper for cigarette Download PDFInfo
- Publication number
- CN106566314A CN106566314A CN201610992527.6A CN201610992527A CN106566314A CN 106566314 A CN106566314 A CN 106566314A CN 201610992527 A CN201610992527 A CN 201610992527A CN 106566314 A CN106566314 A CN 106566314A
- Authority
- CN
- China
- Prior art keywords
- touch
- tipping paper
- aqueouss
- auxiliary agent
- sense
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/12—Coatings without pigments applied as a solution using water as the only solvent, e.g. in the presence of acid or alkaline compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
- D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
- D21H23/22—Addition to the formed paper
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention relates to water-based matt tactility printing ink, which comprises a water-based resin and a tactility auxiliary agent. The tactility auxiliary agent is at least one of a multiamino silicone microemulsion and polyether-amino-modified silicone, and the mass ratio of the tactility auxiliary agent and the water-based resin is 1:5 to 2:5. The invention further provides tipping paper for a cigarette prepared by adopting the water-based matt tactility printing ink and a preparation method of the tipping paper for the cigarette. The water-based matt tactility printing ink provided by the invention is green and environmentally friendly, can realize extremely low VOC (Volatile Organic Compounds) discharge volume, and meets the safety and sanitation standard of Tobacco Bereau on tipping paper, a tipping paper product for the cigarette with low glossiness and remarkable tactility can be obtained, the packaging quality and the grade of cigarette products are improved, and the comfortable experiences of consumers are improved.
Description
Technical field
The present invention relates to ink area, more particularly to a kind of aqueouss matte touch ink, using the aqueouss matte touch
Cigarette tipping paper of ink and preparation method thereof.
Background technology
With developing rapidly for living standard, the safety criterion more and more higher of cigarette package tipping paper, equally, to top grade
The demand of secondary, high-quality Medicated cigarette also day by day increases, and not only requires the gorgeous of appearance luster, for it there has also been more using sense of touch
High requirement.However, the VOC emission amount of existing sense of touch ink is higher, be unsuitable for for the Medicated cigarette of lip directly contact with connecing
Dress paper, it is impossible to reach the production standard of volume cigarette tipping paper.
The content of the invention
Based on this, it is necessary to for the high problem of existing sense of touch ink VOC emission amount, there is provided a kind of VOC emission amount is low, symbol
Close aqueouss matte touch ink, the cigarette tipping paper using the aqueouss matte touch ink and its preparation side of production of cigarettes standard
Method.
A kind of aqueouss matte touch ink, including water-base resin and sense of touch auxiliary agent, the sense of touch auxiliary agent is multi-amino silicone
At least one in microemulsion and polyethers amino-modified silicone, the sense of touch auxiliary agent is 1 with the mass ratio of the water-base resin:
5 to 2:5.
Wherein in one embodiment, the sense of touch auxiliary agent is 1 with the mass ratio of the water-base resin:4 to 1:3.
Wherein in one embodiment, the water-base resin is aliphatic polyurethane resin, acrylic resin and asphalt mixtures modified by epoxy resin
At least one in fat.
Wherein in one embodiment, the viscosity of the aqueouss matte touch ink is 18s to 40s (English 3# Cai grace
Cup).
A kind of cigarette tipping paper, including base paper for tipping paper and the aqueouss matte touch oil being arranged on the base paper for tipping paper
Layer of ink, it is characterised in that the aqueouss matte touch ink layer includes water-base resin and sense of touch auxiliary agent, and the sense of touch auxiliary agent is many
At least one in amodimethicone microemulsion and polyethers amino-modified silicone, the matter of the sense of touch auxiliary agent and the water-base resin
Amount is than being 1:5 to 2:5.
Wherein in one embodiment, the sense of touch auxiliary agent is 1 with the mass ratio of the water-base resin:4 to 1:3.
A kind of preparation method of cigarette tipping paper, including:
S1, there is provided base paper for tipping paper and aqueouss matte touch ink, the aqueouss matte touch ink includes water-base resin
With sense of touch auxiliary agent, the sense of touch auxiliary agent be multi-amino silicone microemulsion and polyethers amino-modified silicone at least one, institute
It is 1 that sense of touch auxiliary agent is stated with the mass ratio of the water-base resin:5 to 2:5;
S2, the aqueouss matte touch ink is coated on the base paper for tipping paper;
S3, drying, obtains the cigarette tipping paper.
Wherein in one embodiment, the sense of touch auxiliary agent is 1 with the mass ratio of the water-base resin:4 to 1:3.
Wherein in one embodiment, the viscosity of the aqueouss matte touch ink is 18s to 40s (English 3# Cai grace
Cup).
Wherein in one embodiment, the method for the coating is intaglio printing, and the version depth of the intaglio printing is 30 micro-
Rice is to 45 microns.
The aqueouss matte touch ink that the present invention is provided, environmental protection is capable of achieving extremely low VOC emission, meets Nicotiana tabacum L. office
Safety and sanitation standard to cigarette tipping paper, and can obtain that glossiness is low, sense of touch significantly and cigarette paper product, carry
High cigarette product packaging quality and class, increase the comfortable experience of consumer.The aqueouss matte touch ink that the present invention is provided is not
Cigarette tipping paper is only applicable to, other is also applied for and is required the various leaflets with good sense of touch.
Description of the drawings
Fig. 1 is the preparation flow figure of cigarette tipping paper.
Specific embodiment
In order that the objects, technical solutions and advantages of the present invention become more apparent, by the following examples and with reference to attached
Figure, the present invention will be described in further detail.
The present invention provides a kind of aqueouss matte touch ink, including water-base resin and sense of touch auxiliary agent.The sense of touch auxiliary agent is
At least one in multi-amino silicone microemulsion and polyethers amino-modified silicone, the sense of touch auxiliary agent and the water-base resin
Mass ratio 1:5 to 2:5.
The water-base resin is the resin without aromatic rings, it is preferable that the water-base resin be aliphatic polyurethane resin,
At least one in acrylic resin and epoxy resin.
The present invention is to the selection of sense of touch auxiliary agent based on considered below:Cigarette tipping paper is used for tobacco shred and filter tip cigarette one
Rise, user in smoking cigarettes, lip directly contact cigarette tipping paper, therefore, the VOC emission amount of cigarette tipping paper is to using
Person's is healthy and safe with large effect, and it is standard compliant that the use of sense of touch auxiliary agent has must the cigarette tipping paper
VOC emission amount.The present invention is simultaneously tight by selecting multi-amino silicone microemulsion and polyethers amino-modified silicone to be used as sense of touch auxiliary agent
Lattice control its usage amount, and the aqueouss matte touch ink is coated in the cigarette tipping paper obtained after base paper for tipping paper, no
VOC emission amount containing the harmful components such as toluene, dimethylbenzene, and the cigarette tipping paper is far smaller than standard regulation, so as to carry
The safety that high Medicated cigarette is used.
The sense of touch auxiliary agent can interact with the water-base resin, so as to get ink layer have concurrently floss sense of touch and
Smooth sense, the consumption of the sense of touch auxiliary agent is more, and the smooth sense of the ink layer is better, yet with the densification of the ink layer
Degree is reduced, and its floss sense of touch can decline therewith, especially when the mass ratio of the sense of touch auxiliary agent and the water-base resin is more than 2:When 5,
Its floss sense of touch effect is reduced rapidly, substantially lint-free sense of touch effect.Preferably, the quality of the sense of touch auxiliary agent and the water-base resin
Than for 1:4 to 1:3, the proportion can give the senses of touch such as soft and moist, fine and smooth smooth, the elastic meat thickness of the ink layer surface, together
Shi Suoshu ink layers also have matte effect, can bring good experience to user.
The viscosity of the aqueouss matte touch ink is too small, and continuous film layer is not easily formed on the base paper for tipping paper,
The viscosity of the aqueouss matte touch ink is excessive, and the ink layer levelability can be made poor, and then it is not beautiful to form film layer outward appearance
See, it is preferable that the viscosity of the aqueouss matte touch ink is 18s to 40s (English 3# Cai grace cup), more preferably 18s to 25s
(English 3# Cai grace cup).The viscosity of the aqueouss matte touch ink can be adjusted with water.
The aqueouss matte touch ink can further include that wax powder, flatting silica, aqueous dispersion, aqueous defoamer etc. are helped
Agent.The wax powder can be aqueouss high density polyethylene waxes.The flatting silica can be silicon dioxide.The aqueous dispersion can
Being at least one in BYK-190 and BYK-2010.The aqueous defoamer can be in BYK-093 and BYK-094
Kind.It is appreciated that the aqueouss matte touch ink can also include other auxiliary agents, the species of above-mentioned auxiliary agent is also not necessarily limited to herein
Cited auxiliary agent species.
The present invention further provides a kind of cigarette tipping paper, including base paper for tipping paper and it is arranged on the base paper for tipping paper
Aqueouss matte touch ink layer, the aqueouss matte touch ink layer includes the water-base resin and the sense of touch auxiliary agent, institute
The mass ratio for stating sense of touch auxiliary agent and the water-base resin is 1:5 to 2:5.Preferably, the sense of touch auxiliary agent and the water-base resin
Mass ratio be 1:4 to 1:3.
Fig. 1 is referred to, the present invention further provides a kind of preparation method of the cigarette tipping paper, comprises the following steps:
S1, there is provided the base paper for tipping paper and the aqueouss matte touch ink;
S2, the aqueouss matte touch ink is coated on the base paper for tipping paper;
S3, drying, obtains the cigarette tipping paper.
In step s 2, before being coated, first the viscosity of the aqueouss matte touch ink can be adjusted with water
Section.Preferably, by the viscosity adjustment of the aqueouss matte touch ink to 18s to 40s (English 3# Cai grace cup), the aqueouss are mute
The viscosity of light sense of touch ink is too small, and it is not easy film forming on the base paper for tipping paper, the aqueouss matte touch ink it is viscous
Spend greatly, the ink layer can be made uneven.It is further preferable that the viscosity adjustment by the aqueouss matte touch ink is extremely
18s to 25s (English 3# Cai grace cup).
The method of the coating can be intaglio printing.It can be 30~45 microns that the version of the intaglio printing is deep, this
The version of scope is deep can to obtain the uniform and smooth aqueouss matte touch ink layer on the base paper for tipping paper.It is described recessed
The paper migration rate of version printing can be 80~120 ms/min.The aqueouss matte touch oil can be on the base paper for tipping paper
Carry out the printing of full version, word or pattern.
In step s3, the drying temperature can be 105~120 DEG C.After drying, the water on the cigarette tipping paper
The dry grammes per square metre of property matte touch ink layer can be 1.2~2.5g/m2。
Embodiment 1
By 60 parts of polyaminoester emulsions, 20 parts of emulsion acrylic resins, 20 parts of multi-amino silicone microemulsions, 0.5 part of wax powder,
0.6 part of flatting silica, 0.2 part of aqueous dispersion and 0.1 part of aqueous defoamer are sequentially added in dispersion cylinder, and stirring mixing dispersion is equal
It is even, aqueouss matte touch ink is obtained, the regulation viscosity that adds water is 18s (English 3# Cai grace cup).
Full version printing is carried out to base paper for tipping paper with the mode of intaglio printing, gravure printing depth is 35 microns, paper migration speed
Rate is 100 ms/min;Baking oven is put into after finishing printing to dry at 115 DEG C, the cigarette tipping paper is obtained, and the cigarette is with connecing
The dry-coated grammes per square metre of ink of dress paper is 1.5 ± 0.1g/m2。
To above-mentioned aqueouss matte touch ink and cigarette tipping paper according to GB/T 26395-2011 and GB/T 26395-
2011 standards carry out VOC discharge capacity measure using headspace gas chromatography instrument.
Embodiment 2
By 60 parts of polyaminoester emulsions, 15 parts of epoxy resin latexes, 25 parts of polyethers amino-modified silicones, 0.8 part of wax powder,
0.8 part of flatting silica, 0.5 part of aqueous dispersion and 0.1 part of aqueous defoamer are sequentially added in dispersion cylinder, and stirring mixing dispersion is equal
It is even, aqueouss matte touch ink is obtained, the regulation viscosity that adds water is 30s (English 3# Cai grace cup).
Full version printing is carried out to base paper for tipping paper with the mode of intaglio printing, gravure printing depth is 42 microns, paper migration speed
Rate is 80 ms/min;Baking oven is put into after finishing printing to dry at 105 DEG C, obtains the cigarette tipping paper, the cigarette
The dry-coated grammes per square metre of ink of paper is 2.0 ± 0.1g/m2。
To above-mentioned aqueouss matte touch ink and cigarette tipping paper according to GB/T 26395-2011, GB/T 26461-2011
VOC discharge capacity measure is carried out using headspace gas chromatography instrument with YC/T 207-2014 standards.
The result that the VOC of embodiment 1 and embodiment 2 is determined is as follows:
The VOC measurement results of the aqueouss matte touch ink of table 1
The VOC measurement results of the cigarette tipping paper of table 2
From the above Tables 1 and 2 cigarette of aqueouss matte touch ink provided by the present invention and its preparation is can be seen that with connecing
The VOC emission amount of dress paper is far below required standard.
The aqueouss matte touch ink that the present invention is provided, environmental protection is capable of achieving extremely low VOC emission, meets Nicotiana tabacum L. office
Safety and sanitation standard to cigarette tipping paper, and can obtain that glossiness is low, the significant cigarette paper product of sense of touch, improve
Cigarette product packs quality and class, increases the comfortable experience of consumer.The aqueouss matte touch ink that the present invention is provided is not only
Suitable for cigarette tipping paper, it is also applied for other and requires the various leaflets with good sense of touch.
Each technical characteristic of embodiment described above can be combined arbitrarily, to make description succinct, not to above-mentioned reality
Apply all possible combination of each technical characteristic in example to be all described, as long as however, the combination of these technical characteristics is not deposited
In contradiction, the scope of this specification record is all considered to be.
Embodiment described above only expresses the several embodiments of the present invention, and its description is more concrete and detailed, but and
Can not therefore be construed as limiting the scope of the patent.It should be pointed out that for one of ordinary skill in the art comes
Say, without departing from the inventive concept of the premise, some deformations and improvement can also be made, these belong to the protection of the present invention
Scope.Therefore, the protection domain of patent of the present invention should be defined by claims.
Claims (10)
1. a kind of aqueouss matte touch ink, including water-base resin and sense of touch auxiliary agent, the sense of touch auxiliary agent is that multi-amino silicone is micro-
At least one in emulsion and polyethers amino-modified silicone, the sense of touch auxiliary agent is 1 with the mass ratio of the water-base resin:5
To 2:5.
2. aqueouss matte touch ink according to claim 1, it is characterised in that the sense of touch auxiliary agent and the aqueouss tree
The mass ratio of fat is 1:4 to 1:3.
3. aqueouss matte touch ink according to claim 1, it is characterised in that the water-base resin is aliphatic poly ammonia
At least one in ester resin, acrylic resin and epoxy resin.
4. aqueouss matte touch ink according to claim 1, it is characterised in that the aqueouss matte touch ink it is viscous
Spend for 18s to 40s (English 3# Cai grace cup).
5. a kind of cigarette tipping paper, including base paper for tipping paper and the aqueouss matte touch ink being arranged on the base paper for tipping paper
Layer, it is characterised in that the aqueouss matte touch ink layer includes water-base resin and sense of touch auxiliary agent, the sense of touch auxiliary agent is many ammonia
At least one in base silicone microemulsion and polyethers amino-modified silicone, the quality of the sense of touch auxiliary agent and the water-base resin
Than for 1:5 to 2:5.
6. cigarette tipping paper according to claim 5, it is characterised in that the matter of the sense of touch auxiliary agent and the water-base resin
Amount is than being 1:4 to 1:3.
7. a kind of preparation method of cigarette tipping paper, including:
S1, there is provided base paper for tipping paper and aqueouss matte touch ink, the aqueouss matte touch ink includes water-base resin and touches
Sense auxiliary agent, the sense of touch auxiliary agent is at least one in multi-amino silicone microemulsion and polyethers amino-modified silicone, described to touch
Sense auxiliary agent is 1 with the mass ratio of the water-base resin:5 to 2:5;
S2, the aqueouss matte touch ink is coated on the base paper for tipping paper;
S3, drying, obtains the cigarette tipping paper.
8. the preparation method of cigarette tipping paper according to claim 7, it is characterised in that the sense of touch auxiliary agent and the water
Property resin mass ratio be 1:4 to 1:3.
9. the preparation method of cigarette tipping paper according to claim 7, it is characterised in that the aqueouss matte touch ink
Viscosity be 18s to 40s (English 3# Cai grace cup).
10. the preparation method of cigarette tipping paper according to claim 7, it is characterised in that the method for the coating is recessed
Version printing, the version depth of the intaglio printing is 30 microns to 45 microns.
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CN201610992527.6A CN106566314A (en) | 2016-11-10 | 2016-11-10 | Water-based matt tactility printing ink, tipping paper for cigarette, and preparation method of tipping paper for cigarette |
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CN201610992527.6A CN106566314A (en) | 2016-11-10 | 2016-11-10 | Water-based matt tactility printing ink, tipping paper for cigarette, and preparation method of tipping paper for cigarette |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110722871A (en) * | 2018-07-17 | 2020-01-24 | 深圳市科彩印务有限公司 | Single-concave flocking printing process |
CN111218182A (en) * | 2020-03-20 | 2020-06-02 | 南京力坤包装材料有限公司 | Water-based touch gloss oil and preparation method thereof |
CN116163159A (en) * | 2023-04-03 | 2023-05-26 | 湖南和锐镭射科技有限公司 | Touch frame paper for cigarettes and method for manufacturing same |
Citations (2)
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US20030188841A1 (en) * | 2001-04-09 | 2003-10-09 | Philip Buder | Tissue products containing softness |
CN106065224A (en) * | 2016-08-08 | 2016-11-02 | 惠州市至上新材料有限公司 | A kind of aqueous, environmental protective sense of touch ink and preparation method thereof |
-
2016
- 2016-11-10 CN CN201610992527.6A patent/CN106566314A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20030188841A1 (en) * | 2001-04-09 | 2003-10-09 | Philip Buder | Tissue products containing softness |
CN106065224A (en) * | 2016-08-08 | 2016-11-02 | 惠州市至上新材料有限公司 | A kind of aqueous, environmental protective sense of touch ink and preparation method thereof |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110722871A (en) * | 2018-07-17 | 2020-01-24 | 深圳市科彩印务有限公司 | Single-concave flocking printing process |
CN111218182A (en) * | 2020-03-20 | 2020-06-02 | 南京力坤包装材料有限公司 | Water-based touch gloss oil and preparation method thereof |
CN116163159A (en) * | 2023-04-03 | 2023-05-26 | 湖南和锐镭射科技有限公司 | Touch frame paper for cigarettes and method for manufacturing same |
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