CN107619364B - Bright pearl material of a kind of few cigarette red and its preparation method and application - Google Patents
Bright pearl material of a kind of few cigarette red and its preparation method and application Download PDFInfo
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- CN107619364B CN107619364B CN201611076901.4A CN201611076901A CN107619364B CN 107619364 B CN107619364 B CN 107619364B CN 201611076901 A CN201611076901 A CN 201611076901A CN 107619364 B CN107619364 B CN 107619364B
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- bright pearl
- strontium
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Abstract
Bright pearl material of a kind of few cigarette red and its preparation method and application replaces existing frequently-used inorganic strontium salt luminescent material as luminescent material using organic salts of strontium, and formula includes the composition such as oxidant, luminescent material, fuel, adhesive and burning ratemodifier.Firework product produced by the present invention has moisture-resistant moisture-proof, is not easy to catch fire, and securely and reliably, combustion fumes and residue are few, and combustion product is without organic chloride poisonous substance, the advantages that no pollution to the environment.
Description
Technical field
The invention belongs to fireworks and firecrackers fields, and in particular to a kind of few red bright pearl material of cigarette.
Background technique
The material that colorful effect is generated in spraying decoration, fireworks display class fireworks kind is referred to as bright pearl.Bright pearl is usually by each
Kind luminescent material is mixed with transmitting medicament, and formula substantially meets zero oxygen balance.Prescription medicament includes oxidant, flammable
Agent, adhesive, common oxidant include potassium hyperchlorate, potassium nitrate, barium nitrate, strontium nitrate, copper nitrate etc., and fuel agent has magnalium
Alloyed powder, sulphur, phenolic resin, carbon dust etc., usually using phenolic resin as adhesive.In order to guarantee that it is higher that bright pearl obtains
Catches fire rate, the outer surface of bright pearl need the ignition powder of one layer of low ignition point, and formula contains potassium hyperchlorate, Al-Mg alloy powder, sulphur
Equal substances.Red bright pearl material is the common effect color of fireworks, can increase red-letter day celebrating atmosphere.It is all at present with strontium nitrate
Make chromogenic agent with strontium carbonate.Strontium nitrate easily moisture absorption, with its prepare flame flower prod often due to the moisture absorption and influence to use, produce
Product must have stringent moisture preventive measure in storage.It is general to be seldom used alone although strontium nitrate and oxidant, actually answer
With mainly strontium carbonate.Such as a kind of fountain pyrotechnic compound of patent CN101475425A, red pearl brightening drug component and weight ratio are as follows: high chlorine
Sour potassium 37-41 parts, 16-20 parts of almag, 16-20 parts, 6-8 parts of polyvinyl chloride, 3-7 parts of coating agent which has to be dissolved in alcohol before use, 4-8 parts of dextrin.
A kind of fireworks of patent CN1597644A bright pearl and preparation method thereof, red pearl brightening drug component and weight ratio are as follows: potassium hyperchlorate
55%, strontium carbonate 24%, epoxy slice 17%, dextrin 4%.Patent CN1490590A Mixing fireworks and
Producing method thereof red pearl brightening drug component and weight ratio are as follows: potassium hyperchlorate 18-40%, almag 15-
30%, strontium carbonate 27-65 %, phenolic resin 6-20%, polyvinyl chloride 6-12%.Strontium carbonate is in a medicament neither oxidant
It is not fuel agent, only plays chromogenic agent, and because fusing point is higher, at a high temperature of medicament burns and generates, slowly decomposes and generate oxygen
Change strontium and carbon dioxide, so the content of strontium carbonate must be less, in order to avoid lead to the difficult non-luminous problem of burning.On in addition,
It states some in patent and uses polyvinyl chloride, a kind of noxious material for being Polychlorinated biphenyls can be discharged in burning.
Summary of the invention
It is an object of the invention to overcome, luminescent material strontium carbonate can not ignite, strontium nitrate is compared with moisture-sensitive in the prior art
Disadvantage, and provide it is a kind of can ignite, not moisture-sensitive, do not generate the red bright pearl material of few cigarette of organic chloride poisonous substance.
The object of the invention is also to provide the preparation methods of above-mentioned few red bright pearl material of cigarette.
Another object of the present invention is to provide above-mentioned few red bright pearl materials of cigarette in combined firework, lift-off class, fireworks display class
Application in the equal firework products such as high-altitudes product and ground firework spraying device, group of spitting out pearl.
The technical scheme is that it is characterized in that the component comprising following mass percent:
Oxidant 30% ~ 70%, red illuminating material 20% ~ 50%, fuel 0 ~ 25%, burning ratemodifier 0 ~ 10%, adhesive 0 ~
10%。
Preferred ingredient of the invention are as follows:
Oxidant 40% ~ 60%, red illuminating material 30% ~ 40%, fuel 5% ~ 15%, burning ratemodifier 1 ~ 5%, adhesive 2% ~
5%。
Oxidant of the present invention is one of potassium hyperchlorate, ammonium perchlorate, potassium nitrate or a variety of.
Red illuminating material of the present invention is organic salts of strontium.
Organic salts of strontium of the present invention is benzoic acid strontium, paranitrobenzoic acid strontium, o-nitrobenzoic acid strontium, M-phthalic acid
One of hydrogen strontium, hydrogen terephthalate strontium, hydrogen phthalate strontium or combination.
Fuel of the present invention is one of aluminium powder, magnesium powder or Al-Mg alloy powder.
Burning ratemodifier of the present invention is that iron oxide, manganese oxide, octyl ferrocene, Kato are one of pungent or a variety of groups
It closes.
Adhesive of the present invention is one of single original washing powder, phenolic resin, epoxy resin, rice flour.
The red bright pearl material of few cigarette of the present invention the preparation method comprises the following steps: raw material are weighed according to mass ratio, root
According to the dissolubility of adhesive therefor, be added solvent or dispersing agent, raw material Zong Zhi Liang ﹕ solvent or dispersing agent mass ratio be 100 ﹕ 0 ~
10, solvent is one kind or combination of alcohol, acetone, water, after mechanical mixture, is granulated with pelletizer or tablet press machine pressing mode is made
Bright pearl, spontaneously dries or baking oven heating, drying removes solvent.
The red bright pearl material of few cigarette of the invention uses luminescent material for organic salts of strontium.Organic salts of strontium is not only fuel agent,
It is also chromogenic agent, it is nonhygroscopic, while organic salts of strontium is misfired with friction impact, open fire is difficult to after lighting, being lighted with strong fire
In air the features such as nonflame, low velocity combustion, securely and reliably, using organic salts of strontium luminescent material, existing frequently-used carbon can be overcome
The shortcomings that inorganic strontium salt luminescent material such as sour strontium and strontium nitrate.
The firework product of the red bright pearl material manufacture of few cigarette of the invention can use no or little ignition powder, anti-with moisture-resistant
Tide is not easy to catch fire, and securely and reliably, combustion fumes and residue are few, and combustion product is without organic chloride poisonous substance, no pollution to the environment etc.
Advantage, when burning, can produce beautiful red color flame, and hydrogen terephthalate strontium, hydrogen phthalate strontium are alternatively arranged as sibilant rale agent hair
Clear and melodious euphony out.
Specific embodiment
With hereinafter all concentration mentioned or ratio are mass percent in addition to indicating.
Embodiment 1
1, potassium hyperchlorate 55%, paranitrobenzoic acid strontium 35%, Kato pungent 5%, phenolic resin 5%, alcohol 5%.
, by preceding four kinds of powder mechanical mixtures, spray alcohol, the bright pearl of spherical shape be made with Rollig nodulizer.
It spontaneously dries and removes alcohol.
Bright pearl is used for combined firework product, lights the red light of rear capable of emitting beauty, generates less smog and residue, and cigarette
Mist scatters comparatively fast.
Embodiment 2
1, potassium hyperchlorate 40%, ammonium perchlorate 10%, hydrogen terephthalate strontium 30%, almag 8%, iron oxide 2%, Dan Ji
Powder 10%, acetone 3%.
, the first six is planted to powder mechanical mixture, single original washing powder is configured to acetone soln as adhesive, uses tabletting after all mixing
Machine is pressed into cylindric bright pearl.
, spontaneously dry remove acetone.
, bright pearl for the rocket gun that goes up to the air, light the red light of rear capable of emitting beauty, generate less smog and residue, and cigarette
Mist scatters comparatively fast.
Embodiment 3
1, potassium hyperchlorate 30%, potassium nitrate 20%, M-phthalic acid hydrogen strontium 10%, hydrogen phthalate strontium 20%, almag
12%, octyl ferrocene 3%, rice flour 5%, water 3%.
, by the first six plant powder mechanical mixture, water spray, the bright pearl of spherical shape is made with Rollig nodulizer.
, spontaneously dry remove acetone.
, bright pearl be used for ground firework spraying device, light the red light of rear capable of emitting beauty, generate less smog and residue, and smog
It scatters very fast.
Embodiment 4
1, ammonium perchlorate 40%, benzoic acid strontium 5%, hydrogen terephthalate strontium 30%, almag 15%, manganese oxide 5%, epoxy
Resin 5%, water 5%.
, the first six is planted to powder mechanical mixture, single original washing powder is configured to acetone soln as adhesive, uses tabletting after all mixing
Machine is pressed into cylindric bright pearl.
, baking oven heat drying remove water.
, bright pearl be used for group of spitting out pearl potted flower, light the red light of rear capable of emitting beauty, generate less smog and residue, and cigarette
Mist scatters comparatively fast.
Embodiment 5
1, potassium hyperchlorate 60%, M-phthalic acid hydrogen strontium 20%, hydrogen phthalate strontium 20%.
, by three kinds of powder mechanical mixtures, be pressed into cylindric bright pearl with tablet press machine.
, bright pearl be used for Fireworks and firecrackers, light the red light of rear capable of emitting beauty, generate less smog and residue, and smog is scattered
It opens very fast.
Claims (8)
1. a kind of red bright pearl material of few cigarette, it is characterised in that be grouped as by the group of following mass percent:
Oxidant 30% ~ 70%, red illuminating material 20% ~ 50%, fuel 0 ~ 25%, burning ratemodifier 0 ~ 10%, adhesive 0 ~ 10%；
The oxidant is one of potassium hyperchlorate, ammonium perchlorate, potassium nitrate or multiple combinations；
The red illuminating material is paranitrobenzoic acid strontium, o-nitrobenzoic acid strontium, M-phthalic acid hydrogen strontium, terephthalic acid (TPA)
One of hydrogen strontium, hydrogen phthalate strontium or combination.
2. lacking the red bright pearl material of cigarette according to claim 1, it is characterised in that its component are as follows:
Oxidant 40% ~ 60%, red illuminating material 30% ~ 40%, fuel 5% ~ 15%, burning ratemodifier 1% ~ 5%, adhesive 2% ~ 5%.
3. lacking the red bright pearl material of cigarette according to claim 1, it is characterised in that: the fuel is aluminium powder, magnesium powder or magnalium
One of alloyed powder.
4. lacking the red bright pearl material of cigarette according to claim 1, it is characterised in that: described adhesive is single original washing powder, phenolic aldehyde tree
One of rouge, epoxy resin, rice flour.
5. lacking the red bright pearl material of cigarette according to claim 1, it is characterised in that: burning ratemodifier be iron oxide, manganese oxide,
Octyl ferrocene, Kato be one of pungent or multiple combinations.
6. the preparation method of few red bright pearl material of cigarette described in a kind of claim 1, it is characterised in that: by raw material according to quality
Ratio weighs, be added solvent, raw material gross mass: solvent quality ratio be 100:0 ~ 10, solvent be alcohol, acetone, water one
Kind combines, and after mechanical mixture, is granulated with pelletizer or bright pearl is made in tablet press machine pressing mode, spontaneously dried or baking oven heats baking
It is dry to remove solvent.
7. a kind of red bright pearl material of few cigarette described in claim 1 in combined firework, lift-off class high-altitude product and ground firework spraying device, spit
Application in pearl class firework product.
8. the red bright pearl material of few cigarette according to claim 7 combined firework, lift-off class high-altitude product and ground firework spraying device,
Application in vomit bead fireworks product, it is characterised in that: the lift-off class high-altitude product is fireworks display class high-altitude product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611076901.4A CN107619364B (en) | 2016-11-30 | 2016-11-30 | Bright pearl material of a kind of few cigarette red and its preparation method and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611076901.4A CN107619364B (en) | 2016-11-30 | 2016-11-30 | Bright pearl material of a kind of few cigarette red and its preparation method and application |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107619364A CN107619364A (en) | 2018-01-23 |
| CN107619364B true CN107619364B (en) | 2019-09-17 |
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| CN201611076901.4A Active CN107619364B (en) | 2016-11-30 | 2016-11-30 | Bright pearl material of a kind of few cigarette red and its preparation method and application |
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Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108218644A (en) * | 2018-01-29 | 2018-06-29 | 泸州北方化学工业有限公司 | A kind of smokeless dulcet cold light firework medicament |
| CN108299135A (en) * | 2018-01-29 | 2018-07-20 | 泸州北方化学工业有限公司 | A kind of smokelessly cold light firework medicament without ammonia odor |
| CN109956843A (en) * | 2019-03-08 | 2019-07-02 | 醴陵恒达烟花有限公司 | A kind of smokeless propellant and preparation method thereof |
| CN110963862B (en) * | 2019-12-03 | 2020-12-01 | 北京理工大学 | Smokeless and sulfur-free firework speed regulating agent and preparation method thereof |
| CN110986688A (en) * | 2019-12-09 | 2020-04-10 | 泸州北方化学工业有限公司 | Colorful bright bead of micro-smoke firework and preparation method thereof |
| CN111410593A (en) * | 2020-03-14 | 2020-07-14 | 中北大学 | Environment-friendly firework and preparation method and assembly method thereof |
| CN111620756A (en) * | 2020-06-05 | 2020-09-04 | 湖南坤普科技有限公司 | Formula and preparation process of bright bead for fireworks |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1078964A (en) * | 1993-01-05 | 1993-12-01 | 庞凯宇 | The production method of coloured flame and device thereof |
| CN1242354A (en) * | 1998-07-16 | 2000-01-26 | 李谟国 | Barium benzoate and strontium benzoate used as passivator of chlorate series gunpowder |
| CN101475425A (en) * | 2008-08-06 | 2009-07-08 | 浏阳市官渡烟花集团有限公司 | Fountain pyrotechnic compound |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1490590A (en) * | 2003-09-12 | 2004-04-21 | 黄远清 | Mixing fireworks and producing method thereof |
| CN103224434A (en) * | 2013-05-03 | 2013-07-31 | 醴陵神马花炮有限公司 | Sulfur-free fountain-type firework drug |
| CN104860787A (en) * | 2015-04-08 | 2015-08-26 | 江西省万载县金峰花炮有限公司 | Safe and environment-friendly slight-smoke colored spraying fireworks |
-
2016
- 2016-11-30 CN CN201611076901.4A patent/CN107619364B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1078964A (en) * | 1993-01-05 | 1993-12-01 | 庞凯宇 | The production method of coloured flame and device thereof |
| CN1242354A (en) * | 1998-07-16 | 2000-01-26 | 李谟国 | Barium benzoate and strontium benzoate used as passivator of chlorate series gunpowder |
| CN101475425A (en) * | 2008-08-06 | 2009-07-08 | 浏阳市官渡烟花集团有限公司 | Fountain pyrotechnic compound |
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| CN107619364A (en) | 2018-01-23 |
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