CN103224434A - Sulfur-free fountain-type firework drug - Google Patents
Sulfur-free fountain-type firework drug Download PDFInfo
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- CN103224434A CN103224434A CN2013101591606A CN201310159160A CN103224434A CN 103224434 A CN103224434 A CN 103224434A CN 2013101591606 A CN2013101591606 A CN 2013101591606A CN 201310159160 A CN201310159160 A CN 201310159160A CN 103224434 A CN103224434 A CN 103224434A
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- rice flour
- resin
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- 239000003814 drug Substances 0.000 title claims abstract description 21
- 229940079593 drug Drugs 0.000 title abstract description 11
- 239000000843 powder Substances 0.000 claims abstract description 136
- 230000000694 effects Effects 0.000 claims abstract description 64
- 241000209094 Oryza Species 0.000 claims description 85
- 235000007164 Oryza sativa Nutrition 0.000 claims description 85
- 235000009566 rice Nutrition 0.000 claims description 85
- 235000013312 flour Nutrition 0.000 claims description 83
- 239000000956 alloy Substances 0.000 claims description 80
- 229910045601 alloy Inorganic materials 0.000 claims description 80
- 239000011347 resin Substances 0.000 claims description 75
- 229920005989 resin Polymers 0.000 claims description 75
- 239000011324 bead Substances 0.000 claims description 55
- AXZAYXJCENRGIM-UHFFFAOYSA-J dipotassium;tetrabromoplatinum(2-) Chemical compound [K+].[K+].[Br-].[Br-].[Br-].[Br-].[Pt+2] AXZAYXJCENRGIM-UHFFFAOYSA-J 0.000 claims description 55
- 229910001487 potassium perchlorate Inorganic materials 0.000 claims description 55
- IWOUKMZUPDVPGQ-UHFFFAOYSA-N barium nitrate Chemical compound [Ba+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O IWOUKMZUPDVPGQ-UHFFFAOYSA-N 0.000 claims description 50
- 239000003973 paint Substances 0.000 claims description 44
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 40
- 239000005751 Copper oxide Substances 0.000 claims description 40
- 229910000431 copper oxide Inorganic materials 0.000 claims description 40
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims description 33
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 30
- 239000004800 polyvinyl chloride Substances 0.000 claims description 30
- BDAGIHXWWSANSR-NJFSPNSNSA-N hydroxyformaldehyde Chemical compound O[14CH]=O BDAGIHXWWSANSR-NJFSPNSNSA-N 0.000 claims description 25
- 229910000018 strontium carbonate Inorganic materials 0.000 claims description 25
- 238000005507 spraying Methods 0.000 claims description 19
- 239000004922 lacquer Substances 0.000 claims description 16
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 15
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 15
- 235000010333 potassium nitrate Nutrition 0.000 claims description 15
- 239000004323 potassium nitrate Substances 0.000 claims description 15
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- 229910001610 cryolite Inorganic materials 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 claims description 3
- 239000010936 titanium Substances 0.000 claims description 3
- 229910052719 titanium Inorganic materials 0.000 claims description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract description 16
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 abstract description 8
- 238000002844 melting Methods 0.000 abstract description 7
- 230000008018 melting Effects 0.000 abstract description 7
- 230000035945 sensitivity Effects 0.000 abstract description 7
- 239000000126 substance Substances 0.000 abstract description 6
- 230000007547 defect Effects 0.000 abstract description 4
- 239000005864 Sulphur Substances 0.000 abstract 4
- 239000011593 sulfur Substances 0.000 description 12
- 229910052717 sulfur Inorganic materials 0.000 description 12
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
- Fire-Extinguishing Compositions (AREA)
Abstract
The present invention relates to a sulfur-free fountain-type firework drug, which refers to two firework drugs in fountain-type products, wherein the two firework drugs comprise effect bright star and black powder, the effect bright star is divided into color effect bright star and sound effect bright star, the color effect bright star comprises red color effect bright star, yellow color effect bright star, blue color effect bright star, green color effect bright star, white color effect bright star and purple color effect bright star, and the effect bright star and the black powder are prepared from drug components according to a certain weight ratio. The sulfur-free fountain-type firework drug has characteristics of high melting point, low mechanical sensitivity, and good safety, does not adopt sulphur, and is prepared by using the components according to a certain weight ratio to eliminate the sulphur substance so as to overcome defects of low melting point of the sulphur and easy accident occurrence, and substantially improve environment pollution and harm on human health due to sulphur contained in the original fountain-type firework drug and sulfur dioxide gas generated after igniting.
Description
Technical Field
The invention relates to a sulfur-free firework spraying chemical, which is sulfur-free smoke
The formula of the flower spraying medicine.
Background
At present, the components of the firework spraying drug contain sulfur, and the sulfur has the characteristics of low melting point, flammability, explosiveness, high sensitivity and the like, so that the firework spraying drug is easy to combust or explode due to the external effects of mechanical impact, friction, extrusion, static electricity and the like on the firework spraying drug in the processes of processing, dosing, charging, storage, transportation and the like in production, and is easy to cause safe accidents; meanwhile, a large amount of sulfur dioxide gas is generated during the burning, so that air pollution is caused, and the human health and the life and property are seriously harmed.
Disclosure of Invention
The invention aims to overcome the defects and provide a sulfur-free firework powder which has low mechanical sensitivity and good safety performance and reduces environmental pollution in the production and setting off processes.
The technical scheme of the invention is as follows: the sulfur-free firework powder is characterized in that the sulfur-free firework powder is firework powder with bright beads and firework powder;
the effect bright beads are divided into color effect bright beads and sound effect bright beads, wherein the color effect bright beads comprise red, yellow, blue, green, white and purple color effect bright beads;
the two parts of the sulfur-free firework spraying medicine, namely the effect bright bead and the firework spraying nitre, are prepared from medicine components in a weight ratio;
the sulfur-free firework powder with the red effect bright beads comprises the following components in percentage by weight:
10-60 parts of potassium perchlorate, 5-40 parts of alloy powder, 1-20 parts of paint flake, 1-20 parts of resin, 1-25 parts of polyvinyl chloride, 5-35 parts of strontium carbonate and 1-20 parts of rice flour;
or,
10-60 parts of potassium perchlorate, 5-40 parts of alloy powder, 1-20 parts of paint flake, 1-20 parts of carbon powder, 1-25 parts of polyvinyl chloride, 5-35 parts of strontium carbonate and 1-20 parts of rice flour;
the values between the two end points of each component are arbitrarily selected; the sum of the percentage contents of all the components is 100 percent;
the sulfur-free firework powder with the yellow effect bright beads comprises the following components in percentage by weight:
10-50 parts of potassium perchlorate, 10-40 parts of alloy powder, 1-20 parts of lacquer, 1-20 parts of resin, 1-20 parts of polyvinyl chloride, 5-30 parts of strontium carbonate, 1-20 parts of cryolite and 1-20 parts of rice flour;
or,
10-50 parts of potassium perchlorate, 10-40 parts of alloy powder, 1-20 parts of paint chips, 1-20 parts of resin, 1-20 parts of yellow agent and 1-20 parts of rice flour;
the values between the two end points of each component are arbitrarily selected; the sum of the percentage contents of all the components is 100 percent;
the sulfur-free firework powder with the blue effect bright beads comprises the following components in percentage by weight:
10-60 parts of potassium perchlorate, 5-35 parts of copper oxide, 1-20 parts of paint chips,
10-20 parts of alloy powder, 1-20 parts of resin, 1-20 parts of polyvinyl chloride,
1-20 parts of rice flour;
or,
10-60 parts of potassium perchlorate, 5-35 parts of copper oxide, 1-20 parts of paint chips,
10-20 parts of alloy powder, 1-20 parts of resin and 5-20 parts of chloride ion resin; 1-20 parts of rice flour;
the values between the two end points of each component are arbitrarily selected; the sum of the percentage contents of all the components is 100 percent;
the sulfur-free firework powder with the green effect bright beads comprises the following components in percentage by weight:
5-20 parts of potassium perchlorate, 30-60 parts of barium nitrate, 10-40 parts of alloy powder,
1-20 parts of resin, 1-20 parts of chloride ion resin and 1-20 parts of rice flour;
or,
5-20 parts of potassium perchlorate, 30-70 parts of barium nitrate, 10-35 parts of alloy powder,
1-20 parts of paint chips, 1-20 parts of resin, 1-20 parts of polyvinyl chloride,
1-20 parts of rice flour;
the values between the two end points of each component are arbitrarily selected; the sum of the percentage contents of all the components is 100 percent;
the sulfur-free firework powder with the white effect bright beads comprises the following components in percentage by weight:
1-30 parts of potassium perchlorate, 20-60 parts of barium nitrate, 5-40 parts of alloy powder,
1-30 parts of lacquer chips, 1-30 parts of resin and 1-20 parts of rice flour;
or,
10-60 parts of barium nitrate, 1-30 parts of potassium nitrate, 5-40 parts of alloy powder,
1-30 parts of lacquer chips, 1-30 parts of resin and 1-20 parts of rice flour;
or,
10-60 parts of barium nitrate, 1-30 parts of copper oxide, 5-40 parts of alloy powder,
1-30 parts of lacquer chips, 1-30 parts of resin and 1-20 parts of rice flour;
the values between the two end points of each component are arbitrarily selected; the sum of the percentage contents of all the components is 100 percent;
the weight ratio (weight percent) of the components of the sulfur-free firework powder with the purple effect bright beads is as follows:
15-50 parts of potassium perchlorate, 10-30 parts of alloy powder, 10-30 parts of copper oxide,
5-35 parts of strontium carbonate, 1-20 parts of paint chips, 1-30 parts of resin,
1-20 parts of polyvinyl chloride and 1-20 parts of rice flour;
or,
15-50 parts of potassium perchlorate, 10-30 parts of alloy powder, 10-30 parts of copper oxide,
5-35 parts of strontium carbonate, 1-20 parts of paint chips, 1-30 parts of resin,
1-20 parts of chloride ion resin and 1-20 parts of rice flour;
the values between the two end points of each component are arbitrarily selected; the sum of the percentage contents of all the components is 100 percent;
the sulfur-free firework powder capable of generating the sound effect bright bead comprises the following components in percentage by weight:
30-80 parts of first-type copper oxide, 10-50 parts of alloy, 1-30 parts of titanium and 1-20 parts of rice flour;
or,
20-80 parts of first-type copper oxide, 10-50 parts of alloy and 1-20 parts of rice flour;
or,
30-80 parts of first-type copper oxide, 10-50 parts of alloy, 1-30 parts of aluminum and 1-20 parts of rice flour
The values between the two end points of each component are arbitrarily selected; the sum of the percentage contents of all the components is 100 percent;
the weight ratio (wt%) of the components of the sulfur-free firework gunning nitrite is as follows:
30-90 parts of potassium nitrate, 5-70 parts of carbon powder and 1-20 parts of rice flour;
or,
30-90 parts of potassium nitrate and 5-70 parts of carbon powder;
the values between the two end points of each component are arbitrarily selected; the sum of the percentage contents of all the components is 100 percent.
The sulfur-free spraying flower firework powder has high melting point, low mechanical sensitivity and good safety performance, and in view of the harmfulness of sulfur, sulfur which is a substance harmful to human bodies is not adopted in the sulfur-free spraying flower firework powder, and the sulfur substance is eliminated by the components and the weight proportion; the defects of low melting point and high sensitivity of sulfur and easiness in occurrence of safe accidents are overcome, and the pollution of sulfur contained in the conventional firework spraying medicine and sulfur dioxide gas generated after ignition to the surrounding environment and the harm to human health are greatly improved.
Detailed Description
The sulfur-free firework powder is characterized in that the sulfur-free firework powder is firework powder with bright beads and firework powder;
the effect bright beads are divided into color effect bright beads and sound effect bright beads, wherein the color effect bright beads comprise red, yellow, blue, green, white and purple color effect bright beads;
the two parts of the sulfur-free firework spraying medicine, namely the effect bright bead and the firework spraying nitre, are prepared from medicine components in a weight ratio;
the sulfur-free firework powder with the red effect bright beads comprises the following components in percentage by weight:
10-60 parts of potassium perchlorate, 5-40 parts of alloy powder, 1-20 parts of paint flake, 1-20 parts of resin, 1-25 parts of polyvinyl chloride, 5-35 parts of strontium carbonate and 1-20 parts of rice flour;
or,
10-60 parts of potassium perchlorate, 5-40 parts of alloy powder, 1-20 parts of paint flake, 1-20 parts of carbon powder, 1-25 parts of polyvinyl chloride, 5-35 parts of strontium carbonate and 1-20 parts of rice flour;
the values between the two end points of each component are arbitrarily selected; the sum of the percentage contents of all the components is 100 percent;
the sulfur-free firework powder with the yellow effect bright beads comprises the following components in percentage by weight:
10-50 parts of potassium perchlorate, 10-40 parts of alloy powder, 1-20 parts of lacquer, 1-20 parts of resin, 1-20 parts of polyvinyl chloride, 5-30 parts of strontium carbonate, 1-20 parts of cryolite and 1-20 parts of rice flour;
or,
10-50 parts of potassium perchlorate, 10-40 parts of alloy powder, 1-20 parts of paint chips, 1-20 parts of resin, 1-20 parts of yellow agent and 1-20 parts of rice flour;
the values between the two end points of each component are arbitrarily selected; the sum of the percentage contents of all the components is 100 percent;
the sulfur-free firework powder with the blue effect bright beads comprises the following components in percentage by weight:
10-60 parts of potassium perchlorate, 5-35 parts of copper oxide, 1-20 parts of paint chips,
10-20 parts of alloy powder, 1-20 parts of resin, 1-20 parts of polyvinyl chloride,
1-20 parts of rice flour;
or,
10-60 parts of potassium perchlorate, 5-35 parts of copper oxide, 1-20 parts of paint chips,
10-20 parts of alloy powder, 1-20 parts of resin and 5-20 parts of chloride ion resin; 1-20 parts of rice flour;
the values between the two end points of each component are arbitrarily selected; the sum of the percentage contents of all the components is 100 percent;
the sulfur-free firework powder with the green effect bright beads comprises the following components in percentage by weight:
5-20 parts of potassium perchlorate, 30-60 parts of barium nitrate, 10-40 parts of alloy powder,
1-20 parts of resin, 1-20 parts of chloride ion resin and 1-20 parts of rice flour;
or,
5-20 parts of potassium perchlorate, 30-70 parts of barium nitrate, 10-35 parts of alloy powder,
1-20 parts of paint chips, 1-20 parts of resin, 1-20 parts of polyvinyl chloride,
1-20 parts of rice flour;
the values between the two end points of each component are arbitrarily selected; the sum of the percentage contents of all the components is 100 percent;
the sulfur-free firework powder with the white effect bright beads comprises the following components in percentage by weight:
1-30 parts of potassium perchlorate, 20-60 parts of barium nitrate, 5-40 parts of alloy powder,
1-30 parts of lacquer chips, 1-30 parts of resin and 1-20 parts of rice flour;
or,
10-60 parts of barium nitrate, 1-30 parts of potassium nitrate, 5-40 parts of alloy powder,
1-30 parts of lacquer chips, 1-30 parts of resin and 1-20 parts of rice flour;
or,
10-60 parts of barium nitrate, 1-30 parts of copper oxide, 5-40 parts of alloy powder,
1-30 parts of lacquer chips, 1-30 parts of resin and 1-20 parts of rice flour;
the values between the two end points of each component are arbitrarily selected; the sum of the percentage contents of all the components is 100 percent;
the weight ratio (weight percent) of the components of the sulfur-free firework powder with the purple effect bright beads is as follows:
15-50 parts of potassium perchlorate, 10-30 parts of alloy powder, 10-30 parts of copper oxide,
5-35 parts of strontium carbonate, 1-20 parts of paint chips, 1-30 parts of resin,
1-20 parts of polyvinyl chloride and 1-20 parts of rice flour;
or,
15-50 parts of potassium perchlorate, 10-30 parts of alloy powder, 10-30 parts of copper oxide,
5-35 parts of strontium carbonate, 1-20 parts of paint chips, 1-30 parts of resin,
1-20 parts of chloride ion resin and 1-20 parts of rice flour;
the values between the two end points of each component are arbitrarily selected; the sum of the percentage contents of all the components is 100 percent;
the sulfur-free firework powder capable of generating the sound effect bright bead comprises the following components in percentage by weight:
30-80 parts of first-type copper oxide, 10-50 parts of alloy, 1-30 parts of titanium and 1-20 parts of rice flour;
or,
20-80 parts of first-type copper oxide, 10-50 parts of alloy and 1-20 parts of rice flour;
or,
30-80 parts of first-type copper oxide, 10-50 parts of alloy, 1-30 parts of aluminum and 1-20 parts of rice flour
The values between the two end points of each component are arbitrarily selected; the sum of the percentage contents of all the components is 100 percent;
the weight ratio (wt%) of the components of the sulfur-free firework gunning nitrite is as follows:
30-90 parts of potassium nitrate, 5-70 parts of carbon powder and 1-20 parts of rice flour;
or,
30-90 parts of potassium nitrate and 5-70 parts of carbon powder;
the values between the two end points of each component are arbitrarily selected; the sum of the percentage contents of all the components is 100 percent.
Examples are as follows (weight ratio of components):
the weight ratio (weight percent) of the components of the sulfur-free firework powder with the red bright bead is as follows:
45 parts of potassium perchlorate, 15 parts of alloy powder, 4 parts of paint flake, 4 parts of resin,
8 parts of polyvinyl chloride, 20 parts of strontium carbonate and 4 parts of rice flour;
or,
45 parts of potassium perchlorate, 15 parts of alloy powder, 6 parts of paint flake, 2 parts of carbon powder,
8 parts of polyvinyl chloride, 20 parts of strontium carbonate and 4 parts of rice flour.
The sulfur-free firework powder with the yellow effect bright beads comprises the following components in percentage by weight:
45 parts of potassium perchlorate, 20 parts of alloy powder, 5 parts of paint chips, 5 parts of resin, 5 parts of polyvinyl chloride, 5 parts of strontium carbonate, 10 parts of cryolite and 5 parts of rice flour;
or,
45 parts of potassium perchlorate, 20 parts of alloy powder, 5 parts of paint chips, 5 parts of resin,
yellower 20 and rice flour 5.
The weight ratio (weight percent) of the components of the sulfur-free firework powder with the blue effect bright bead is as follows:
45 parts of potassium perchlorate, 25 parts of copper oxide, 7 parts of paint,
alloy powder 5, resin 5, polyvinyl chloride 10,
3, rice flour;
or,
50 parts of potassium perchlorate, 20 parts of copper oxide, 10 parts of paint chips,
alloy powder 5, resin 5 and chloride ion resin 7;
and (3) rice flour.
The weight ratio (weight percent) of the components of the sulfur-free firework powder with the green effect and the bright bead is as follows:
potassium perchlorate 20, barium nitrate 40, alloy powder 20,
resin 10, chloride ion resin 5 and rice flour 5;
or,
15 parts of potassium perchlorate, 45 parts of barium nitrate, 20 parts of alloy powder,
paint 3, resin 3, polyvinyl chloride 5,
and (3) rice flour 2.
The weight ratio (wt%) of the components of the sulfur-free firework powder with the white bright bead is as follows:
10 parts of potassium perchlorate, 50 parts of barium nitrate, 20 parts of alloy powder, 10 parts of paint chips,
resin 5, rice flour 5;
or,
50 parts of barium nitrate, 10 parts of potassium nitrate, 20 parts of alloy powder,
10 parts of lacquer flakes, 5 parts of resin and 5 parts of rice flour.
Or,
barium nitrate 60, copper oxide 5, alloy powder 20,
5 parts of lacquer chips, 5 parts of resin and 5 parts of rice flour.
The weight ratio (weight percent) of the components of the purple effect bright bead sulfur-free firework spraying type firework powder is as follows:
40 parts of potassium perchlorate, 15 parts of alloy powder, 10 parts of copper oxide,
strontium carbonate 10, paint chips 5, resin 6,
10 parts of polyvinyl chloride and 4 parts of rice flour;
or,
40 parts of potassium perchlorate, 20 parts of alloy powder, 10 parts of copper oxide,
strontium carbonate 10, paint chips 5, resin 5,
chloride ion resin 7 and rice flour 3.
The weight ratio (weight percent) of the components of the sulfur-free firework powder capable of producing the sound effect bright bead is as follows:
60 parts of type A copper oxide, 30 parts of alloy powder, 5 parts of titanium powder and 5 parts of rice powder;
or,
65 parts of first-type copper oxide, 30 parts of alloy powder and 5 parts of rice flour;
or,
60 parts of first-type copper oxide, 30 parts of alloy powder, 5 parts of aluminum and 5 parts of rice flour.
The weight ratio (wt%) of the components of the sulfur-free firework gunning nitrate medicine is as follows:
potassium nitrate 63, carbon powder 35 and rice flour 2;
or,
potassium nitrate 65 and carbon powder 35.
The sulfur-free spraying flower firework powder has high melting point, low mechanical sensitivity and good safety performance, and in view of the harmfulness of sulfur, sulfur which is a substance harmful to human bodies is not adopted in the sulfur-free spraying flower firework powder, and the sulfur substance is eliminated by the components and the weight proportion; the defects of low melting point and high sensitivity of sulfur and easiness in occurrence of safe accidents are overcome, and the pollution of sulfur contained in the conventional firework spraying medicine and sulfur dioxide gas generated after ignition to the surrounding environment and the harm to human health are greatly improved.
Claims (9)
1. A sulfur-free firework powder, which is characterized in that
A. The sulfur-free firework powder is firework powder with bright beads and firework powder;
the effect bright beads are divided into color effect bright beads and sound effect bright beads, wherein the color effect bright beads comprise red, yellow, blue, green, white and purple color effect bright beads;
the two parts of the sulfur-free firework spraying medicine, namely the effect bright bead and the firework spraying nitre, are prepared from medicine components in a weight ratio;
B. the weight ratio (weight percent) of the components of the sulfur-free firework powder with the bright white-red effect is as follows:
10-60 parts of potassium perchlorate, 5-40 parts of alloy powder, 1-20 parts of paint flake, 1-20 parts of resin, 1-25 parts of polyvinyl chloride, 5-35 parts of strontium carbonate and 1-20 parts of rice flour;
or,
10-60 parts of potassium perchlorate, 5-40 parts of alloy powder, 1-20 parts of paint flake, 1-20 parts of carbon powder, 1-25 parts of polyvinyl chloride, 5-35 parts of strontium carbonate and 1-20 parts of rice flour;
the values between the two end points of each component are arbitrarily selected; the sum of the percentage contents of all the components is 100 percent;
C. the sulfur-free firework powder with the yellow effect bright beads comprises the following components in percentage by weight:
10-50 parts of potassium perchlorate, 10-40 parts of alloy powder, 1-20 parts of lacquer, 1-20 parts of resin, 1-20 parts of polyvinyl chloride, 5-30 parts of strontium carbonate, 1-20 parts of cryolite and 1-20 parts of rice flour;
or,
10-50 parts of potassium perchlorate, 10-40 parts of alloy powder, 1-20 parts of paint chips, 1-20 parts of resin, 1-20 parts of yellow agent and 1-20 parts of rice flour;
the values between the two end points of each component are arbitrarily selected; the sum of the percentage contents of all the components is 100 percent;
D. the sulfur-free firework powder with the blue effect bright beads comprises the following components in percentage by weight:
10-60 parts of potassium perchlorate, 5-35 parts of copper oxide, 1-20 parts of paint chips,
10-20 parts of alloy powder, 1-20 parts of resin, 1-20 parts of polyvinyl chloride,
1-20 parts of rice flour;
or,
10-60 parts of potassium perchlorate, 5-35 parts of copper oxide, 1-20 parts of paint chips,
10-20 parts of alloy powder, 1-20 parts of resin and 5-20 parts of chloride ion resin; 1-20 parts of rice flour;
the values between the two end points of each component are arbitrarily selected; the sum of the percentage contents of all the components is 100 percent;
E. the sulfur-free firework powder with the green effect bright beads comprises the following components in percentage by weight:
5-20 parts of potassium perchlorate, 30-60 parts of barium nitrate, 10-40 parts of alloy powder,
1-20 parts of resin, 1-20 parts of chloride ion resin and 1-20 parts of rice flour;
or,
5-20 parts of potassium perchlorate, 30-70 parts of barium nitrate, 10-35 parts of alloy powder,
1-20 parts of paint chips, 1-20 parts of resin, 1-20 parts of polyvinyl chloride,
1-20 parts of rice flour;
the values between the two end points of each component are arbitrarily selected; the sum of the percentage contents of all the components is 100 percent;
F. the sulfur-free firework powder with the white effect bright beads comprises the following components in percentage by weight:
1-30 parts of potassium perchlorate, 20-60 parts of barium nitrate, 5-40 parts of alloy powder,
1-30 parts of lacquer chips, 1-30 parts of resin and 1-20 parts of rice flour;
or,
10-60 parts of barium nitrate, 1-30 parts of potassium nitrate, 5-40 parts of alloy powder,
1-30 parts of lacquer chips, 1-30 parts of resin and 1-20 parts of rice flour;
or,
10-60 parts of barium nitrate, 1-30 parts of copper oxide, 5-40 parts of alloy powder,
1-30 parts of lacquer chips, 1-30 parts of resin and 1-20 parts of rice flour;
the values between the two end points of each component are arbitrarily selected; the sum of the percentage contents of all the components is 100 percent;
G. the weight ratio (weight percent) of the components of the sulfur-free firework powder with the purple effect bright beads is as follows:
15-50 parts of potassium perchlorate, 10-30 parts of alloy powder, 10-30 parts of copper oxide,
5-35 parts of strontium carbonate, 1-20 parts of paint chips, 1-30 parts of resin,
1-20 parts of polyvinyl chloride and 1-20 parts of rice flour;
or,
15-50 parts of potassium perchlorate, 10-30 parts of alloy powder, 10-30 parts of copper oxide,
5-35 parts of strontium carbonate, 1-20 parts of paint chips, 1-30 parts of resin,
1-20 parts of chloride ion resin and 1-20 parts of rice flour;
the values between the two end points of each component are arbitrarily selected; the sum of the percentage contents of all the components is 100 percent;
H. the sulfur-free firework powder capable of generating the sound effect bright bead comprises the following components in percentage by weight:
30-80 parts of first-type copper oxide, 10-50 parts of alloy, 1-30 parts of titanium and 1-20 parts of rice flour;
or,
20-80 parts of first-type copper oxide, 10-50 parts of alloy and 1-20 parts of rice flour;
or,
30-80 parts of first-type copper oxide, 10-50 parts of alloy, 1-30 parts of aluminum and 1-20 parts of rice flour
The values between the two end points of each component are arbitrarily selected; the sum of the percentage contents of all the components is 100 percent;
I. the weight ratio (wt%) of the components of the sulfur-free firework gunning nitrite is as follows:
30-90 parts of potassium nitrate, 5-70 parts of carbon powder and 1-20 parts of rice flour;
or,
30-90 parts of potassium nitrate and 5-70 parts of carbon powder;
the values between the two end points of each component are arbitrarily selected; the sum of the percentage contents of all the components is 100 percent.
2. The sulfur-free firework powder of claim 1, wherein the red effect bright bead sulfur-free firework powder comprises the following components in percentage by weight:
45 parts of potassium perchlorate, 15 parts of alloy powder, 4 parts of paint chips, 4 parts of resin, 8 parts of polyvinyl chloride, 20 parts of strontium carbonate and 4 parts of rice flour;
or,
45 parts of potassium perchlorate, 15 parts of alloy powder, 6 parts of paint flake, 2 parts of carbon powder,
8 parts of polyvinyl chloride, 20 parts of strontium carbonate and 4 parts of rice flour.
3. The sulfur-free firework powder of claim 1, wherein the yellow effect bright bead sulfur-free firework powder comprises the following components in percentage by weight:
45 parts of potassium perchlorate, 20 parts of alloy powder, 5 parts of paint chips, 5 parts of resin, 5 parts of polyvinyl chloride, 5 parts of strontium carbonate, 10 parts of cryolite and 5 parts of rice flour;
or,
45 parts of potassium perchlorate, 20 parts of alloy powder, 5 parts of paint chips, 5 parts of resin, 20 parts of yellow light agent and 5 parts of rice flour.
4. The sulfur-free firework powder of claim 1, wherein the sulfur-free firework powder with blue effect bright beads comprises the following components in percentage by weight:
45 parts of potassium perchlorate, 25 parts of copper oxide, 7 parts of paint,
alloy powder 5, resin 5, polyvinyl chloride 10,
3, rice flour;
or,
50 parts of potassium perchlorate, 20 parts of copper oxide, 10 parts of paint chips,
alloy powder 5, resin 5 and chloride ion resin 7;
and (3) rice flour.
5. The sulfur-free firework powder of claim 1, wherein the sulfur-free firework powder with green effect bright beads comprises the following components in percentage by weight:
potassium perchlorate 20, barium nitrate 40, alloy powder 20,
resin 10, chloride ion resin 5 and rice flour 5;
or,
15 parts of potassium perchlorate, 45 parts of barium nitrate, 20 parts of alloy powder,
paint 3, resin 3, polyvinyl chloride 5,
and (3) rice flour 2.
6. The sulfur-free firework powder of claim 1, wherein the white effect bright bead sulfur-free firework powder comprises the following components in percentage by weight:
10 parts of potassium perchlorate, 50 parts of barium nitrate, 20 parts of alloy powder, 10 parts of paint chips,
resin 5, rice flour 5;
or,
50 parts of barium nitrate, 10 parts of potassium nitrate, 20 parts of alloy powder,
10 parts of lacquer flakes, 5 parts of resin and 5 parts of rice flour;
or,
barium nitrate 60, copper oxide 5, alloy powder 20,
5 parts of lacquer chips, 5 parts of resin and 5 parts of rice flour.
7. The sulfur-free firework powder of claim 1, wherein the purple effect bright bead sulfur-free firework powder comprises the following components in percentage by weight:
40 parts of potassium perchlorate, 15 parts of alloy powder, 10 parts of copper oxide,
strontium carbonate 10, paint chips 5, resin 6,
10 parts of polyvinyl chloride and 4 parts of rice flour;
or,
40 parts of potassium perchlorate, 20 parts of alloy powder, 10 parts of copper oxide,
strontium carbonate 10, paint chips 5, resin 5,
chloride ion resin 7 and rice flour 3.
8. The sulfur-free firework powder of claim 1, wherein the sulfur-free firework powder capable of producing the sound effect bright bead comprises the following components in percentage by weight:
60 parts of type A copper oxide, 30 parts of alloy powder, 5 parts of titanium powder and 5 parts of rice powder;
or,
65 parts of first-type copper oxide, 30 parts of alloy powder and 5 parts of rice flour;
or,
60 parts of first-type copper oxide, 30 parts of alloy powder, 5 parts of aluminum and 5 parts of rice flour.
9. The sulfur-free firework powder as claimed in claim 1, wherein the sulfur-free firework powder comprises the following components in percentage by weight:
potassium nitrate 63, carbon powder 35 and rice flour 2;
or,
potassium nitrate 65 and carbon powder 35.
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| CN2013101591606A CN103224434A (en) | 2013-05-03 | 2013-05-03 | Sulfur-free fountain-type firework drug |
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| CN2013101591606A CN103224434A (en) | 2013-05-03 | 2013-05-03 | Sulfur-free fountain-type firework drug |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103497077A (en) * | 2013-09-21 | 2014-01-08 | 安徽省无为县花炮总厂 | Formula for colorful fireworks |
| CN103497080A (en) * | 2013-09-21 | 2014-01-08 | 安徽省无为县花炮总厂 | Formula of firecracker |
| CN103739415A (en) * | 2013-12-17 | 2014-04-23 | 江西省李渡烟花集团有限公司 | Novel firework gold scintillation powder |
| CN104860787A (en) * | 2015-04-08 | 2015-08-26 | 江西省万载县金峰花炮有限公司 | Safe and environment-friendly slight-smoke colored spraying fireworks |
| RU2567635C1 (en) * | 2014-10-28 | 2015-11-10 | Открытое Акционерное Общество "Федеральный Научно-Производственный Центр "Нии Прикладной Химии" | Pyrotechnic composition for fireworks |
| CN106518586A (en) * | 2016-10-13 | 2017-03-22 | 湖南荣晖实业有限公司 | Sulfur-free composite material, preparation method and application thereof |
| CN107619364A (en) * | 2016-11-30 | 2018-01-23 | 湖北航天化学技术研究所 | A kind of red bright pearl material of few cigarette and its preparation method and application |
| RU2710186C1 (en) * | 2019-08-29 | 2019-12-24 | Акционерное общество "Федеральный научно-производственный центр "Научно-исследовательский институт прикладной химии" | Pyrotechnic spark-force compound of yellow fire |
| RU2710190C1 (en) * | 2019-08-29 | 2019-12-24 | Акционерное общество "Федеральный научно-производственный центр "Научно-исследовательский институт прикладной химии" | Pyrotechnical composition of yellow fire |
| CN111763129A (en) * | 2020-07-01 | 2020-10-13 | 肖永日 | Sulfur-free sulfoblue agent and preparation method thereof |
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| CN104860787A (en) * | 2015-04-08 | 2015-08-26 | 江西省万载县金峰花炮有限公司 | Safe and environment-friendly slight-smoke colored spraying fireworks |
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| CN107619364A (en) * | 2016-11-30 | 2018-01-23 | 湖北航天化学技术研究所 | A kind of red bright pearl material of few cigarette and its preparation method and application |
| RU2710186C1 (en) * | 2019-08-29 | 2019-12-24 | Акционерное общество "Федеральный научно-производственный центр "Научно-исследовательский институт прикладной химии" | Pyrotechnic spark-force compound of yellow fire |
| RU2710190C1 (en) * | 2019-08-29 | 2019-12-24 | Акционерное общество "Федеральный научно-производственный центр "Научно-исследовательский институт прикладной химии" | Pyrotechnical composition of yellow fire |
| CN111763129A (en) * | 2020-07-01 | 2020-10-13 | 肖永日 | Sulfur-free sulfoblue agent and preparation method thereof |
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