TW584618B - Firework compounds - Google Patents

Firework compounds Download PDF

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Publication number
TW584618B
TW584618B TW88103022A TW88103022A TW584618B TW 584618 B TW584618 B TW 584618B TW 88103022 A TW88103022 A TW 88103022A TW 88103022 A TW88103022 A TW 88103022A TW 584618 B TW584618 B TW 584618B
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Taiwan
Prior art keywords
powder
fire
aluminum
magnesium alloy
polyvinyl chloride
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TW88103022A
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Chinese (zh)
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Sz-Hua Wu
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Sz-Hua Wu
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Priority to TW88103022A priority Critical patent/TW584618B/en
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Publication of TW584618B publication Critical patent/TW584618B/en

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Abstract

The invention provides a firework compound, which increases the content of inflammable mixture, which is composed of phenol aldehyde resin, polyvinyl chloride, and chlorinated rubber, and reduces the percentage of explosive aluminum magnesium alloy powder to the level below 20%. Firework compounds of different colors are squeezed into containers of different shapes and molded into different firework compound moldings or wrapped with waxed paper or brown paper into particular shapes for making different fireworks.

Description

584618 A7 B7 五、發明説明(/ ) 【發明背景】 a. 發明領域: 請 先 閱 讀 背 面 i 事- 項 再 填 寫 本 頁 本發明係有關一種彩色烟花火葯之組合物,尤指一種 可降低危險之烟花者。 b. 先前技術: 按,我們先祖自從發明火葯以來,施放煙火一直是國人 民俗慶典的重要節目之一,以添增熱鬧歡愉的氣氛;而根據 文獻記載,早期民間慶典常施放五色煙火、起輪、走線、 流星火爆及烟架等各式烟火,可見烟花自古以來即深受國 人所喜愛。 次按,目前擠壓入筒狀容器內之彩色烟花火葯,其火葯 成份中含有大量鋁鎂合金粉,因鋁鎂合金粉具有助燃增亮 之效果;惟査,其除了助燃外,亦是爆炸還原劑,而以目前彩 色烟花中的鋁鎂合金粉的含量,約在40%以上,如此一來, 極易造成爆炸,使原本不應爆炸的烟花,卻引爆而喪失其效 果;進而亦使得依靠彩色烟花火葯所推動的玩具煙火等,增 加危險性,為其缺失。 經濟部智慧財產局員工消費合作社印製 【發明目的】 本發明有鑑於上述習用彩色烟花火葯之缺失,乃針對 此一課題積極研究改良,經過長期測試,終有本發明之完 成。 緣是,本發明之主要目的,係在提供一種彩色烟花火葯 之組合物,尤指一種烟花火葯成份中,將具助燃增亮,但易 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 584618 A7 B7五、發明説明(之) 爆炸之鋁鎂合金粉的比例,降低在20%以內,改以酚醛樹 脂、聚氯乙烯,以及氯化橡膠之適當比例替代助燃,以降低 危險;再者,各種顔色之烟花火葯成品,可依需求選配後擠 壓入各種不同形狀的容器中,或者是以油光蜡紙(牛皮紙) 捲包成預定之各種形狀,而可製造出各式不同變化之彩色 烟花者。 >【附圖之簡單說明】 a. 圖式部分: 第一圖係本發明用於垂直噴口容器之使用狀態圖。 第二圖係本發明用於側邊噴口容器之使用狀態圖。 第三圖係本發明用於卷狀型態之使用狀態圖。 第四圖係本發明用於禮花彈之使用狀態圖。 b. 圖號部分: (23)垂直噴口 (3) 烟花容器 (31) 側噴口 (32) 翅膀 (4) 油光蜡紙 (請先閲讀背面之-注意Ϋ-項再填寫本頁) # I-訂 ί _ (1) 火葯成品 (2) 烟花容器 (21) 封口層 (22) 點火火葯 (221)引線 (5) 禮花彈殼 (51)孔洞 (6) 發射筒584618 A7 B7 V. Description of the invention (/) [Background of the invention] a. Field of invention: Please read the i-item on the back before filling out this page. This invention relates to a composition of colored fireworks and gunpowder. Fireworker. b. Prior technology: According to our ancestors, since the invention of gunpowder, the use of pyrotechnics has been one of the important programs of the national folklore celebrations to add a lively and cheerful atmosphere. According to the literature, early folk celebrations often used five-colored fireworks, Fireworks such as wheels, alignments, hot meteors, and smoke stands show that fireworks have been loved by people since ancient times. For the second press, the colored firework powder currently extruded into a cylindrical container contains a large amount of aluminum-magnesium alloy powder in the gunpowder composition. The aluminum-magnesium alloy powder has the effect of enhancing combustion and brightening. Reducing agent, with the current content of aluminum-magnesium alloy powder in color fireworks above about 40%. In this way, it is very easy to cause an explosion, which would detonate a firework that should not have exploded, but lost its effect; further, it also caused Relying on toy fireworks propelled by colored fireworks and gunpowder, the danger is increased and it is missing. Printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs [Objective of the Invention] In view of the lack of the above-mentioned conventional colored fireworks and gunpowder, the present invention is actively researched and improved on this subject. After long-term testing, the invention is finally completed. The reason is that the main purpose of the present invention is to provide a composition of colored firework gunpowder, especially a firework gunpowder composition, which will promote combustion and brighten, but the paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297). (Mm) 584618 A7 B7 V. Description of the invention (of) The proportion of explosive aluminum-magnesium alloy powder should be reduced to less than 20%, and the appropriate proportion of phenolic resin, polyvinyl chloride, and chlorinated rubber should be used instead of combustion support to reduce the danger. In addition, the finished products of fireworks and gunpowder in various colors can be extruded into containers of various shapes after being matched as required, or can be rolled into a predetermined shape with a waxed wax paper (kraft paper), and various types can be manufactured. Colorful fireworks with different variations. > [Brief description of the drawings] a. Schematic part: The first figure is a use state diagram of the present invention for a vertical nozzle container. The second figure is a use state diagram of the present invention for a side spout container. The third figure is a use state diagram of the present invention in a rolled shape. The fourth figure is a state diagram of the present invention used for a firework bomb. b. Part of drawing number: (23) Vertical spout (3) Firework container (31) Side spout (32) Wing (4) Polished wax paper (please read the-Note on the back-item before filling this page) # I- Order _ (1) Finished powder (2) Firework container (21) Sealing layer (22) Ignition powder (221) Lead (5) Fireworks cartridge case (51) Hole (6) Launch tube

經濟部智慧財產局員工消費合作社印製 【實施例詳細說明】 目前的綠火烟花成份中,係以過氯酸鉀10%作為較強 氧化劑,而以硝酸鋇40%作為發綠火的氧化劑;再以松香 5%作為增艷之用,但松香易阻擋火力,使得火舌較短,以致 烟花不夠亮麗;又以鋁鎂合金粉45%作為助燃劑,惟前述已 第4.具 本紙張尺度適用中國國家標準(CNS ) A4規格(210X 297公釐) 584618 經濟部智慧財產局員工消費合作社印製 A7 _ _B7_ 五、發明説明(J ) 闡明,鋁鎂合金粉含量過大,易造成爆炸,失去烟花效果及 增加危險性。 故,本發明之較佳可行實施例,係將鋁鎂合金粉之比例, 降低在20%以內,改以酚醛樹脂、聚氯乙烯、以及氯化橡 膠之適當比例,替代助燃,並捨棄松香成份。其中 (a) 綠火烟花之實施例:係以過氯酸鉀15%、硝酸鋇 50%、鋁鎂合金粉15%、酚醛樹脂10%、聚氯乙烯5%以 及氯化橡膠5%的重量百分比組合構成綠火之火葯; (b) 紅火烟花之實施例:係以過氯酸鉀50%、碳酸緦 15%、鋁鎂合金粉15%、酚醛樹脂10%,以及聚氯乙烯1〇% 組合構成紅火之火葯; (c) 青火烟花之實施例:係以過氯酸鉀50%、氧化銅 15%、鋁鎂合金粉10%、酚醛樹脂10%、聚氯乙烯5%、 以及氯化橡膠10%組合構成青火之火葯; (d) 黃火烟花之實施例:係以過氯酸鉀50%、氟硅酸鈉 15%、鋁鎂合金粉15%、酚醛樹脂10%、以及聚氯乙烯 10%組合構成黃火之火葯; (e) 紫色烟花之實施例:係以過氯酸鉀46%、氧化銅 16%、碳酸緦5%、酚醛樹脂8%、聚氯乙烯5%、氯化橡 膠10%、以及鋁鎂合美粉10%組合構成紫火之火葯; (f) 銀色烟花之實施例:係以過氯酸鉀63%、鋁鎂合金 粉5%、酚醛樹脂7%、以及鋁片25%之組合構成銀火之火 葯; (g) 將前述各不同顏色之烟花火葯,用篩子過篩攪拌均 ---z-----二 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) (請先閱讀背面之注意事項再填寫本頁)Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs [Detailed description of the embodiment] Among the green fireworks composition, 10% of potassium perchlorate is used as a strong oxidant, and 40% of barium nitrate is used as a green fire oxidant; Rosin 5% is used to enhance the beauty, but rosin is easy to block the fire, making the fire tongue shorter, so that the fireworks are not bright enough; and 45% of aluminum-magnesium alloy powder is used as a combustion accelerator, but the above has been applied to the country of paper size 4. Standard (CNS) A4 specification (210X 297 mm) 584618 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 _ _B7_ V. Description of the invention (J) states that the content of aluminum-magnesium alloy powder is too large, which is likely to cause an explosion and lose the fireworks effect. Increased risk. Therefore, the preferred feasible embodiment of the present invention is to reduce the proportion of aluminum-magnesium alloy powder to less than 20%, and change to appropriate proportions of phenolic resin, polyvinyl chloride, and chlorinated rubber to replace combustion support and discard the rosin component. . (A) Examples of green fireworks: a combination of 15% potassium perchlorate, 50% barium nitrate, 15% aluminum-magnesium alloy powder, 10% phenolic resin, 5% polyvinyl chloride, and 5% chlorinated rubber (B) Examples of red fireworks: 50% of potassium perchlorate, 15% of rhenium carbonate, 15% of aluminum-magnesium alloy powder, 10% of phenolic resin, and 10% of polyvinyl chloride constitute a red fire Gunpowder; (c) Examples of green fireworks: 50% potassium perchlorate, 15% copper oxide, 10% aluminum-magnesium alloy powder, 10% phenolic resin, 5% polyvinyl chloride, and 10% chlorinated rubber Green fire powder; (d) Example of yellow fireworks: The combination of 50% potassium perchlorate, 15% sodium fluorosilicate, 15% aluminum magnesium alloy powder, 10% phenolic resin, and 10% polyvinyl chloride Gunpowder; (e) Examples of purple fireworks: 46% potassium perchlorate, 16% copper oxide, 5% carbonate, 5% phenolic resin, 5% polyvinyl chloride, 10% chlorinated rubber, and aluminum-magnesium The combination of 10% powder constitutes the powder of purple fire; (f) Examples of silver fireworks: 63% potassium perchlorate, 5% aluminum magnesium alloy powder, 7% phenolic resin, The combination of 25% and aluminum flakes constitutes the powder of silver fire; (g) The fireworks powder of different colors mentioned above are sieved with a sieve and blended --- z ----- The two paper standards are applicable to Chinese national standards (CNS ) A4 size (210X297mm) (Please read the notes on the back before filling this page)

584618 經濟部智慧財產局員工消費合作社印製 A7 B7五、發明説明« ) 勻成40〜60目之間的粉狀,依需求選配後,以乾粉擠壓入各 種不同形狀的容器中,或以油光蜡紙捲包成預定之形狀;或 者是製成圓丸或塊狀等預定形狀之固狀體作為夜間禮花 彈或沖天焰火等之用。 由上揭各實施例顯示,本發明之鋁鎂合金粉含量約在 5%〜15%之間,較習用烟花約降低20%〜35%左右的含量, 而改由酚醛樹脂、氯化橡膠、以及聚氯乙烯所替代,其中 該酚醛樹脂係作為助燃顯色之用;而氯化橡膠除具有助燃 顯色之功用外,其更可使烟花鮮麗,此為發明人最新發現之 助燃劑,效果極佳;另聚氯乙烯可増進色彩美艷,進一步使 本發明得以摒棄松香成份,不僅艷色不減,使得施放效果更 佳更漂亮。 藉助上揭新組合物,本發之適用範圍增大,茲舉數個使 用狀態說明如下: 第一圖所示,係將本發明之火葯乾粉(1)以機械或人工 擠壓進入紙筒或塑膠筒所構成之烟花容器(2)內,該容器(2) 可為各種不同形狀,上下端為封口層(21),其內並壓入有點 火火葯(22),以及一垂直噴口(23),並使引線(221)由垂直 噴口(23)接出,當點燃時由垂直噴口(23)形成彩色煙火推 力;而此垂直噴口型態之烟花容器(2),可二個或多個組合 在一起作各種不同的花樣變化,例如將二個烟花容器(2)併 排,而垂直噴口反向擺放,則會形成前進、後退的造型烟花; 其他尚可作地面旋轉、旋轉升空等多種不同花樣變化,容 不一k 一"贅述。 (請先閲讀背面之·注意事項再填寫本頁) # 丨.訂584618 A7 B7 printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the invention «) uniformly into a powder form between 40 and 60 meshes, after selection and matching, use dry powder to squeeze into various shapes of containers, or It is wrapped in a varnished wax paper into a predetermined shape; or a solid body in a predetermined shape such as a pellet or a block is used for night fireworks or sky fireworks. The above examples show that the content of the aluminum-magnesium alloy powder of the present invention is between about 5% and 15%, which is about 20% to 35% lower than that of conventional fireworks. Instead, phenolic resin, chlorinated rubber, It is replaced by polyvinyl chloride, in which the phenolic resin is used to promote color development; in addition to the role of chlorinated rubber in color development, it can make fireworks more beautiful. Excellent; in addition, the polyvinyl chloride can be beautifully colored, which further enables the present invention to abandon the rosin component, not only the bright color is not reduced, but also the application effect is better and more beautiful. With the help of the new composition disclosed above, the scope of application of the present invention is increased, and several states of use are described below: As shown in the first figure, the dry powder (1) of the invention is mechanically or manually squeezed into a paper tube or Inside a firework container (2) made of a plastic tube, the container (2) can be of various shapes, with a sealing layer (21) at the upper and lower ends, and an ignition powder (22) and a vertical spout (23) are pressed into it. ), And the lead wire (221) is connected by the vertical spout (23), and when it is lit, the color pyrotechnic thrust is formed by the vertical spout (23); and the firework container (2) of this vertical spout type may have two or more Combined to make a variety of different pattern changes, such as placing two firework containers (2) side by side, and placing the vertical nozzles in the opposite direction will form a forward and backward shaped firework; other can also be used for ground rotation, rotation and lift-off, etc. A variety of different pattern changes, not tolerated. (Please read the notes on the back before filling out this page) # 丨. Order

本紙張尺度適用中國國家標準(CNS ) A4規格(2^Χ29%釐) 經濟部智慧財產局員工消費合作社印製 584618 A7 B7 _ 五、發明説明(5 ) 第二圖所示,係將本發明之火葯成品置入烟花容器(3) 中,並在外側鑽孔形成側噴口(31),如此一來,當點燃時由 側噴口(3 1)形成彩色烟花推力,使得容器在地面跳轉,當然 亦可將多個容器排裝在地面跳轉(圖未示);或是在烟花容 器(3)粘上紙製翅膀(32),則可旋轉飛行,作出各種不同之 烟花造型,容不逐一贅述。 第三圖所示,係將本發明之火葯成品(1)塗佈在油光蜡 紙(4)上,然後先卷成條狀,再卷成圓型之樣態,如此當點燃 時,可於地面形成旋轉烟花,非常美麗,且時間更久。 第四圖所示,係將本發明之火葯成品(1)製成丸狀置於 一禮花彈殼(5)內,藉由發射筒(6)將其引燃並發射出去,則 彩色烟花由禮花彈殼(5)之孔洞(5 1)施放出來,非常鮮艷壯 觀。 除了上述各種使用狀態之外,本發明當可被廣泛運用 於各種不同變化之烟花造型,此係藉助本發明之不易爆炸 而具有相當的使用安全性,故以前述發明之組合成份,及其 獲致之功效,均合於產業上利用價值,應符專利申請要件, 爰依法提出申請,祈請惠予審査,並核賜專利,以勵創新,無 任德感。 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) (請先閱讀背面之·注意夢項再填寫本頁)This paper size applies the Chinese National Standard (CNS) A4 specification (2 ^ × 29%) printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 584618 A7 B7 _ 5. Description of the invention (5) The second figure shows the invention The finished product of gunpowder is placed in the firework container (3), and the side nozzle (31) is drilled on the outside. In this way, when fired, the color firework thrust is formed by the side nozzle (31), so that the container jumps on the ground. Of course Multiple containers can also be mounted on the ground (not shown); or paper wings (32) can be attached to the firework container (3), which can be rotated and fly to make various firework shapes, which will not be described one by one. . As shown in the third figure, the finished powdered product (1) of the present invention is coated on a glossy wax paper (4), and then rolled into a strip shape, and then rolled into a round shape. The ground forms a rotating firework, which is very beautiful and lasts longer. As shown in the fourth figure, the powdered product (1) of the present invention is made into a pellet and placed in a fireworks shell (5), which is ignited and fired by a launch tube (6). The hole (5 1) of the bullet casing (5) is cast, which is very colorful and spectacular. In addition to the above-mentioned various use states, the present invention can be widely used in various firework shapes with different changes. This is based on the non-explosiveness of the present invention, which has considerable safety in use. Therefore, the combination of the foregoing inventions and their effects The effects are in line with the industrial use value, should meet the patent application requirements, apply according to law, ask for approval, and grant patents to encourage innovation without sense of virtue. This paper size applies to Chinese National Standard (CNS) A4 (210X297 mm) (Please read the note on the back before filling in this page)

Claims (1)

I I 6 84 公告本 )(U1· 30 修正 年月 β Α8 Β8 C8 D8 ^、申請專利範圍 請 先 閱 1 · 一種彩色册花火葯之組合物,其係包括有綠火、紅 火、青火、黃火、紫火及銀火等火葯構成,其成份中將鋁鎂 合金粉的比例降低在20%以內,並以酚醛樹脂、聚氯乙烯及 氯化橡膠替代,·其中 (a) 以過氯酸鉀15%、硝酸鋇50%、鋁鎂合金粉15%、 酚醛樹脂10%、聚氯乙烯5%以及氯化橡膠5%的重量百分 比組合構成綠火之火葯;II 6 84 Bulletin) (U1 · 30 revised year and month β Α8 Β8 C8 D8 ^, please read the scope of patent application 1 · A color book flower powder composition, which includes green fire, red fire, green fire, yellow Fire, purple fire, silver fire and other gunpowder composition. Its composition reduces the proportion of aluminum-magnesium alloy powder to less than 20%, and replaces it with phenolic resin, polyvinyl chloride and chlorinated rubber, where (a) is potassium perchlorate 15 The combination of weight percent of barium nitrate 50%, aluminum magnesium alloy powder 15%, phenolic resin 10%, polyvinyl chloride 5% and chlorinated rubber 5% constitutes green fire powder; (b) 以過氯酸鉀50%、碳酸緦15%、鋁鎂合金粉15%、 酚醛樹脂10°/。,以及聚氯乙烯10%組合構成紅火之火葯; 訂 (c) 以過氯酸鉀50%、氧化銅15%、鋁鎂合金粉10%、 酚醛樹脂10%、聚氯乙烯5%、以及氯化橡膠10%組合構 成青火之火葯; (d) 以過氯酸鉀50%、氟硅酸鈉15%、鋁鎂合金粉 15%、酚醛樹脂10%、以及聚氯乙烯10%組合構成黃火之 火葯; (e) 以過氯酸鉀46%、氧化銅16%、碳酸緦5%、酚醛 樹脂8%、聚氯乙烯5%、氯化橡膠10%、以及鋁鎂合美粉 10%組合構成紫火之火葯; 經濟部智慧財產局員工消費合作社印製 (f) 以過氯酸鉀63%、鋁鎂合金粉5%、酚醛樹脂7%、 以及鋁片25%之組合構成銀火之火葯; (g) 將前述各不同顔色之烟花火葯,用篩子過篩攪拌均 勻成40〜60目之間的粉狀,依需求選配後,以乾粉擠壓入各 種不同形狀的容器中,或以油光蜡紙捲包成預定之形狀;或 者是製成圓丸或塊狀等預定形狀之固狀體者。 本紙張尺度適用中國國家標準(CNS ) A4規格(?10^胃公釐(b) 50% potassium perchlorate, 15% rhenium carbonate, 15% aluminum-magnesium alloy powder, and 10 ° phenol resin. And 10% combination of polyvinyl chloride to form a red fire powder; Order (c) 50% potassium perchlorate, 15% copper oxide, 10% aluminum-magnesium alloy powder, 10% phenolic resin, 5% polyvinyl chloride, and chlorinated rubber The 10% combination constitutes the powder of green fire; (d) the combination of 50% potassium perchlorate, 15% sodium fluorosilicate, 15% aluminum magnesium alloy powder, 10% phenolic resin, and 10% polyvinyl chloride; (e) ) A combination of 46% potassium perchlorate, 16% copper oxide, 5% carbonate, phenolic resin 8%, polyvinyl chloride 5%, chlorinated rubber 10%, and aluminum magnesium magnesium powder 10% to form a powder of purple fire; economic Printed by the Consumer Cooperatives of the Ministry of Intellectual Property Bureau (f) A combination of 63% potassium perchlorate, 5% aluminum-magnesium alloy powder, 7% phenolic resin, and 25% aluminum flakes constitutes the powder of silver fire; Color fireworks and gunpowder, sieve through a sieve and stir to form a powder between 40 and 60 mesh. After selecting and matching according to demand, dry powder is squeezed into various shapes of containers, or wrapped in shiny wax paper into a predetermined Shape; or a solid body of a predetermined shape such as a pellet or a block. This paper size applies to China National Standard (CNS) A4 specification (? 10 ^ mm)
TW88103022A 1999-03-01 1999-03-01 Firework compounds TW584618B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103224434A (en) * 2013-05-03 2013-07-31 醴陵神马花炮有限公司 Sulfur-free fountain-type firework drug
CN111635286A (en) * 2020-06-16 2020-09-08 湖北航天化学技术研究所 Bonding system for improving safety performance of press-fitted PBX explosive and preparation method and application thereof
RU2795435C1 (en) * 2022-04-28 2023-05-03 Акционерное общество "Федеральный научно-производственный центр "Научно-исследовательский институт прикладной химии" Green fire pyrotechnic composition

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103224434A (en) * 2013-05-03 2013-07-31 醴陵神马花炮有限公司 Sulfur-free fountain-type firework drug
CN111635286A (en) * 2020-06-16 2020-09-08 湖北航天化学技术研究所 Bonding system for improving safety performance of press-fitted PBX explosive and preparation method and application thereof
CN111635286B (en) * 2020-06-16 2021-09-28 湖北航天化学技术研究所 Bonding system for improving safety performance of press-fitted PBX explosive and preparation method and application thereof
RU2795435C1 (en) * 2022-04-28 2023-05-03 Акционерное общество "Федеральный научно-производственный центр "Научно-исследовательский институт прикладной химии" Green fire pyrotechnic composition

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