CN1019995C - Safety colour ball flashing firecrackers - Google Patents
Safety colour ball flashing firecrackers Download PDFInfo
- Publication number
- CN1019995C CN1019995C CN 89100283 CN89100283A CN1019995C CN 1019995 C CN1019995 C CN 1019995C CN 89100283 CN89100283 CN 89100283 CN 89100283 A CN89100283 A CN 89100283A CN 1019995 C CN1019995 C CN 1019995C
- Authority
- CN
- China
- Prior art keywords
- powder
- sons
- transom
- medicine grain
- mother
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B33/00—Compositions containing particulate metal, alloy, boron, silicon, selenium or tellurium with at least one oxygen supplying material which is either a metal oxide or a salt, organic or inorganic, capable of yielding a metal oxide
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06C—DETONATING OR PRIMING DEVICES; FUSES; CHEMICAL LIGHTERS; PYROPHORIC COMPOSITIONS
- C06C15/00—Pyrophoric compositions; Flints
Abstract
The present invention discloses safe electric flashing firecrackers and a preparation method thereof. Powder grains of the electric flashing firecrackers are composed of parent-subsidiary ingredients and ryoxko ingredients, wherein the parent-subsidiary ingredients comprise red lead powder, cupric oxides and aluminum-magnesium alloy powder, and the ryoxko ingredients comprise potassium perchlorate, barium nitrate, phenolic resins, hexachlorobenzene and aluminum-magnesium alloy powder. The present invention is formed by that unexplosive solid chemistry substances are combined, and a safety problem in the overall course of preparation, transportation, storage and firing in firecracker industry is thoroughly solved. The present invention has the characteristics of reasonable prescription, simple production process, low cost, silvery sound, vivid color without paper scraps after firing, etc. powder grains do not make sound when the powder grains are crushed, explosion is not generated during frictional vibration, and human bodies and clothes are not hurt during firing.
Description
The present invention relates to a kind of pyrotechnics, specifically a kind of firecracker that becomes the ammunition form.
Chinese patent application 86105418 promptly is a kind of similar firecracker.The medicine grain of the flash firecracker of gunpowder granules of this patent application is formed by ringing medicine and ignition powder.Though this flash fireworks has had very big improvement than traditional firecrackers on form, technology and the prescription made, but it is ring in the prescription of medicine and ignition powder at it, all contain the composition of sulphur, thereby more at the content of setting off back sulfurous gas, pollute the infringement people ' s health to environment.In its making method, adopt paste to make tackiness agent, cause medicine grain hardness very poor, have pressure to be easy to fragmentation slightly, thereby medicine grain percentage of damage is higher in process of production.In the forming process of ringing son, to or dry this step through overbaking at last in addition, operation is increased, and ring son after baking or shining, easy to crack, be mixed and made into flash fireworks with ignition powder after, can therefore reduce the sound of firecracker, influence quality product.At the firecracker shaping stage, make tackiness agent with non-aqueous glue, glue is done very soon, make operation inconvenient, and the cost of water-insoluble glue is higher.
Purpose of the present invention just provides not sulfureted and bounding force is good, pellet hardness is strong safe electric light big gun in a kind of medicine grain composition, and a kind of operation simplify, easy to operate, the manufacture method of the safe electric light big gun of yield rate height, good product quality.
The present invention is achieved in that the electric light roasting and boiling as two means of processing crude drugs grain of forming by mothers and sons and transom, mutually
Connection is thrown on the adhesive tape, is bundled into strip with glossy paraffin paper, or the medicine grain is directly put into container, inserts lead-in wire, promptly makes various safe electric light big guns.Wherein mothers and sons are detonated to ring and are acted on, and composition is red lead powder, cupric oxide, aluminium-magnesium alloy powder; Transom plays and ignites and the illuminated light effect, and composition is potassium perchlorate, nitrate of baryta, resol, hexachlorobenzene, aluminium-magnesium alloy powder.Its composition scope (weight percent) is respectively:
Mothers and sons: red lead powder 40-70%, aluminium-magnesium alloy powder 20-50%, cupric oxide 10-30%;
Transom: potassium perchlorate 30-60%, nitrate of baryta 20-50%, resol 5-20%, hexachlorobenzene 2-8%, aluminium-magnesium alloy powder 5-15%.
Said medicine is the above powder of 150 orders.
The manufacture method of safety colour ball flashing firecrackers of the present invention is:
1. medicine grain preparation: above-mentioned mother and sons' powder is added water soluble adhesive, rubs ripe material, make the particle more than 2 millimeters again, mother and sons' particle.After treating that mother and sons' particle is stopped paying out firmly slightly, put into a container, brush coating is put into the transom powder again, makes it uniform mixing.So repeatedly several times, make the transom powder evenly coated on mothers and sons, dry by the fire or dry, be i.e. the patent medicine grain.The weight ratio of mothers and sons and transom is between 2: 1.
2. the electric light big gun is shaped: the tight connection of electric light roasting and boiling as two means of processing crude drugs grain is thrown on the adhesive tape, is bundled into strip with glossy paraffin paper, or the medicine grain is directly put into difform container, insert lead-in wire, promptly make various safe electric light big guns.
Safety electric light big gun of the present invention adopts non-quick-fried property solid chemical material to combine, in the medicine grain composition, do not contain black, baiyao in the common firecracker, and manufacturing processed is to carry out under wet condition, therefore, thoroughly solve firecracker and made, transport, store and setting off the process safe problem.And do not contain sulphur in the medicine grain composition, when setting off, can not cause environmental pollution, do not have paper scrap yet and produce, can not influence environmental health.In mother and sons' prescription, replace aluminium powder and sulphur simultaneously, not only increased the color that firecracker is seted off, and reduced cost with red lead powder.In the transom prescription, replace saltpetre with potassium perchlorate and nitrate of baryta, produce green when firecracker is seted off, and further reduce cost.Safe electric light big gun of the present invention like this can produce red, green, blue and white four kinds of colors, and cost reduces greatly.In manufacturing processed, replace the flour paste to make the medicine grain with water soluble adhesive, and saved mother and sons' baking simultaneously or dried this operation, thereby make that medicine grain bounding force is good, hardness strengthens greatly, and percentage of damage reduces greatly, and yield rate improves.And it is bonding that the medicine grain sticks with glue agent, makes the product damp proof insulation, and preservation period increases.In manufacturing processed, with the adhesive tape medicine grain that bonds, make easy to operately, the more water-insoluble glue of cost reduces greatly.Safe electric light big gun of the present invention has the sound clear and melodious, crush sound, the characteristics such as body and clothing of not hurting sb.'s feelings when setting off, and to there not being the strip electric light big gun of lead-in wire, is difficult to light with cigarette end.This product noisemaking rate and the rate of starting to exchange fire all reach more than 98% impact sensitivity: 1.6 kilograms/meter, a fried rate is 0; Friction sensitivity: 150 ℃ of spontaneous ignition points, so safe electric light big gun of the present invention is safe and reliable, and can reduce by 50% than the cost of flash firecracker of gunpowder granules.Manufacture method of the present invention, operation is few, and technology is simple and direct, and is easy to operate, saves starting material, saves the paper resource.
Embodiment 1:
1. medicine grain preparation: get red lead powder 40%, aluminium-magnesium alloy powder 50%, cupric oxide 10% is mixed into mother and sons' powder.Get potassium perchlorate 30%, nitrate of baryta 40%, resol 7%, hexachlorobenzene 8%, aluminium-magnesium alloy powder 15% is mixed into the transom powder.More than each medicine be the above powder of 150 orders.In mother and sons' powder, add the white glue with vinyl of concentration about 10%, rub ripe material, in tablets press, make 2 millimeters particle, mother and sons' particle.Stop slightly, treat that mothers and sons are hardened after, put into tablets press, brush one time white glue with vinyl, put into part transom powder again, make it attached on mother and sons' particle.Brush coating adds powder several times so repeatedly, makes the transom powder evenly coated on mothers and sons, and oven dry is the patent medicine grain.The weight ratio of mothers and sons and transom is between 2: 1.
2. the electric light big gun is shaped: above-mentioned medicine grain is interconnected be thrown on the Pressuresensitive Tape paper, be bundled into strip with glossy paraffin paper, insertion goes between, and glues, i.e. safety colour ball flashing firecrackers into strips.
Embodiment 2:
1. medicine grain preparation: get red lead powder 70%, aluminium-magnesium alloy powder 20%, cupric oxide 10% is mixed into mother and sons' powder.Get potassium perchlorate 60%, nitrate of baryta 20%, resol 10%, hexachlorobenzene 5%, aluminium-magnesium alloy powder 5% is mixed into the transom powder.Above medicine is the above powder of 150 orders.In mother and sons' powder, add concentration and be 8% peach gum, rub ripe material, be pressed into particle by 26 purpose sieves, mothers and sons.After treating that mothers and sons are hardened, put into a basin, brush one time peach gum, put into the transom powder again, rock mixing, brush coating adds powder repeatedly
Several times, make the transom powder evenly coated on mothers and sons, drying is the patent medicine grain.
2. the electric light big gun is shaped: above-mentioned medicine grain is interconnected be thrown on the Pressure sensitive adhesive tape paper, be bundled into strip with glossy paraffin paper, inserting lead does not directly glue, the nothing strip safety colour ball flashing firecrackers that goes between.Light an end of big gun simultaneously with two matches, can ignite, but then be difficult for lighting, increased security with the first-class flames of anger thing of cigarette.
Embodiment 3:
1. medicine grain preparation: get red lead powder 50%, aluminium-magnesium alloy powder 25%, cupric oxide 25% is mixed into mother and sons' powder.Get potassium perchlorate 38%, nitrate of baryta 50%, resol 5%, hexachlorobenzene 2%, aluminium-magnesium alloy powder 5% is mixed into the transom powder.In mother and sons' powder, add concentration and be 6% arab resin glue, rub ripe material, make the particle more than 2 millimeters by hand, mothers and sons.After treating that mothers and sons are hardened, put into an enamel basin, brush one time arab resin glue, add the transom powder again, rock mixing, repeatedly for several times, make the transom powder evenly coated on mothers and sons, oven dry patent medicine grain.
2. the electric light big gun is shaped: the medicine grain is directly put into difform container, insert lead-in wire, post with paper and seal, promptly make various safety colour ball flashing firecrackers.Also the medicine grain can be put into the upper strata of double-bang firecracker firecracker, make the mixing double-bang firecracker.The firework display effect of this firecracker is the same just as a Fireworks and firecrackers.
Embodiment 4: the shaping of the preparation of medicine grain and electric light big gun is the same substantially, and just medicine grain prescription is:
Mothers and sons: red lead powder 45%, aluminium-magnesium alloy powder 25%, cupric oxide 30%;
Transom: potassium perchlorate 45%, nitrate of baryta 20%, resol 20%, hexachlorobenzene 5%, aluminium-magnesium alloy powder 10%.
Embodiment 5: the shaping of the preparation of medicine grain and electric light big gun is the same substantially, and the prescription of medicine grain is an optimum formula, that is:
Mothers and sons: red lead powder 65%, aluminium-magnesium alloy powder 25%, cupric oxide 10%;
Transom: potassium perchlorate 40%, nitrate of baryta 34%, resol 11%, hexachlorobenzene 5%, aluminium-magnesium alloy powder 10%.
Embodiment 6: the preparation of medicine grain and electric light big gun are shaped the same substantially, and mother and sons' prescription is also the same in the medicine grain, and transom adopts three kinds of compositions, i.e. resol, and hexachlorobenzene, aluminium-magnesium alloy powder also has essentially identical effect, and just cost increases to some extent.Its prescription is: resol 42%, hexachlorobenzene 18%, aluminium-magnesium alloy powder 40%.
Embodiment 7: the preparation of medicine grain and electric light big gun are shaped the same substantially, and mother and sons' prescription is also the same in the medicine grain, add the sub grey composition of China fir fire in the transom, can make that electric light big gun firework display effect is better, and spark is brighter, brighter.Concrete prescription is: potassium perchlorate 40%, nitrate of baryta 33%, resol 10%, hexachlorobenzene 2%, aluminium-magnesium alloy powder 10%, China fir fire ash 5%.
Above pharmaceutical compositions all is weight percentage.
Claims (4)
1, a kind of safety colour ball flashing firecrackers is made up of medicine grain, adhesive tape, glossy paraffin paper or container, and the medicine grain is made of the outer coated transom of mothers and sons, it is characterized in that medicine grain composition scope (weight percent) is:
Mothers and sons: red lead powder 40-70% aluminium-magnesium alloy powder 20-50%
Cupric oxide 10-30%
Transom: potassium perchlorate 30-60% nitrate of baryta 20-50%
Resol 5-20% hexachlorobenzene 2-8%
Aluminium-magnesium alloy powder 5-15%.
2, electric light according to claim 1 is concocted making method, and mother and sons' powder is in harmonious proportion, and rubs ripe material, make the particle more than 2 millimeters, put into container, brush coating, put into the transom powder again, make it uniform mixing, brush coating adds powder for several times repeatedly, make the transom powder evenly coated on mother and sons' particle, dry by the fire or dry the patent medicine grain, the medicine grain is closely connected adhere on the paper tape, stick into strip with glossy paraffin paper bag, it is characterized in that having omitted mother and sons' baking operation, treat that mother and sons' particle hardens after, directly mix with the transom powder.
3, manufacture method according to claim 2 is characterized in that mother and sons' powder is in harmonious proportion the articles for use that mix brush coating of articles for use and mothers and sons and transom powder, is water soluble adhesive.
4, manufacture method according to claim 2 is characterized in that the medicine grain bonding articles for use in the electric light big gun forming process are Pressuresensitive Tape.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 89100283 CN1019995C (en) | 1989-01-15 | 1989-01-15 | Safety colour ball flashing firecrackers |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 89100283 CN1019995C (en) | 1989-01-15 | 1989-01-15 | Safety colour ball flashing firecrackers |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1044086A CN1044086A (en) | 1990-07-25 |
| CN1019995C true CN1019995C (en) | 1993-03-03 |
Family
ID=4853784
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 89100283 Expired - Fee Related CN1019995C (en) | 1989-01-15 | 1989-01-15 | Safety colour ball flashing firecrackers |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1019995C (en) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1098238C (en) * | 1998-12-28 | 2003-01-08 | 罗永年 | Application of chlorinated paraffin in fireworks |
| CN100398974C (en) * | 2002-04-04 | 2008-07-02 | 石柏青 | Non-pollution safety fireworks |
| CN100351605C (en) * | 2003-02-25 | 2007-11-28 | 赵月明 | Safety fireworks |
| CN100360890C (en) * | 2004-08-20 | 2008-01-09 | 姜锡松 | Flash star for mfg. fireworks |
| CN101386558B (en) * | 2008-08-22 | 2012-05-23 | 王贤凤 | Fireworks spraying pyrotechnic compound composition with composite effect |
| CN104829401B (en) * | 2015-05-25 | 2017-03-15 | 雍和平 | A kind of safety and environmental protection colorful firecrackers medicament and the method for preparing colorful firecrackers with the medicament |
| CN106288975A (en) * | 2016-09-26 | 2017-01-04 | 张容恺 | Air sterillization fireworks and preparation method thereof |
| CN107963952A (en) * | 2017-08-22 | 2018-04-27 | 东莞市力优机械设备有限公司 | Electrical fire medicine available for machinery production manufacture |
| CN110595290A (en) * | 2019-09-25 | 2019-12-20 | 浏阳市长寿玩具烟花制造有限公司 | Preparation method of electrooptical flower |
| CN110526792A (en) * | 2019-09-25 | 2019-12-03 | 浏阳市长寿玩具烟花制造有限公司 | A kind of electrical fire effect medicine |
| CN110631429A (en) * | 2019-11-08 | 2019-12-31 | 余庆县吉盛烟花爆竹有限责任公司 | Firework manufacturing method |
| CN110963868A (en) * | 2019-12-20 | 2020-04-07 | 江西吉润花炮新材料科技有限公司 | High-explosive-sound firecracker medicament |
| CN110963871A (en) * | 2019-12-20 | 2020-04-07 | 江西吉润花炮新材料科技有限公司 | Preparation method of firecracker medicament with high firecracker sound |
-
1989
- 1989-01-15 CN CN 89100283 patent/CN1019995C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1044086A (en) | 1990-07-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C53 | Correction of patent for invention or patent application | ||
| CB02 | Change of applicant information |
Address after: 056003 Hebei Province, Handan city construction of Tiexi street by fireworks Applicant after: Guo Xueming Address before: 056001 Hebei province Handan County sand mouth Village West Applicant before: Guo Xueming |
|
| COR | Change of bibliographic data |
Free format text: CORRECT: APPLICANT ADDRESS; FROM: SHAKOU VILLAGE WEST HANDAN COUNTY HEBEI PROVINCE 056001 TO: FIREWORK INSTITUTE WEST JIANSHE STREET HANDAN COUNTY HEBEI PROVINCE 056003 |
|
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |