CN105218281A - A kind of broom ripple colorful bright bead of fireworks - Google Patents
A kind of broom ripple colorful bright bead of fireworks Download PDFInfo
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- CN105218281A CN105218281A CN201510519051.XA CN201510519051A CN105218281A CN 105218281 A CN105218281 A CN 105218281A CN 201510519051 A CN201510519051 A CN 201510519051A CN 105218281 A CN105218281 A CN 105218281A
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- ripple
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- 244000007853 Sarothamnus scoparius Species 0.000 title claims abstract description 18
- 239000011324 bead Substances 0.000 title claims abstract description 14
- 230000000694 effects Effects 0.000 claims abstract description 61
- 239000003814 drug Substances 0.000 claims abstract description 47
- 239000000843 powder Substances 0.000 claims abstract description 39
- 238000007493 shaping process Methods 0.000 claims abstract description 14
- 238000005469 granulation Methods 0.000 claims abstract description 10
- 230000003179 granulation Effects 0.000 claims abstract description 10
- 238000003756 stirring Methods 0.000 claims abstract description 7
- 238000002156 mixing Methods 0.000 claims abstract description 5
- 239000007921 spray Substances 0.000 claims abstract description 4
- 239000003960 organic solvent Substances 0.000 claims abstract description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 26
- 229910052782 aluminium Inorganic materials 0.000 claims description 26
- 229910000838 Al alloy Inorganic materials 0.000 claims description 15
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 15
- AXZAYXJCENRGIM-UHFFFAOYSA-J dipotassium;tetrabromoplatinum(2-) Chemical compound [K+].[K+].[Br-].[Br-].[Br-].[Br-].[Pt+2] AXZAYXJCENRGIM-UHFFFAOYSA-J 0.000 claims description 15
- 239000011777 magnesium Substances 0.000 claims description 15
- 229910052749 magnesium Inorganic materials 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 15
- 229910001487 potassium perchlorate Inorganic materials 0.000 claims description 15
- 239000003795 chemical substances by application Substances 0.000 claims description 13
- 238000007429 general method Methods 0.000 claims description 12
- 239000004800 polyvinyl chloride Substances 0.000 claims description 12
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 12
- 239000002245 particle Substances 0.000 claims description 10
- 239000002383 tung oil Substances 0.000 claims description 7
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 6
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 229910002651 NO3 Inorganic materials 0.000 claims description 3
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 3
- 239000005864 Sulphur Substances 0.000 claims description 3
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 claims description 3
- 229910001864 baryta Inorganic materials 0.000 claims description 3
- 239000003610 charcoal Substances 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 229960004643 cupric oxide Drugs 0.000 claims description 3
- 239000012467 final product Substances 0.000 claims description 3
- BDAGIHXWWSANSR-NJFSPNSNSA-N hydroxyformaldehyde Chemical compound O[14CH]=O BDAGIHXWWSANSR-NJFSPNSNSA-N 0.000 claims description 3
- 235000010333 potassium nitrate Nutrition 0.000 claims description 3
- 239000004323 potassium nitrate Substances 0.000 claims description 3
- 229920003987 resole Polymers 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 229910000018 strontium carbonate Inorganic materials 0.000 claims description 3
- 239000002023 wood Substances 0.000 claims description 3
- 238000005253 cladding Methods 0.000 claims description 2
- 238000002485 combustion reaction Methods 0.000 abstract description 5
- 230000000007 visual effect Effects 0.000 abstract description 5
- 230000002265 prevention Effects 0.000 abstract description 3
- 238000000465 moulding Methods 0.000 abstract 1
- 239000000047 product Substances 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 229920002472 Starch Polymers 0.000 description 4
- 235000019698 starch Nutrition 0.000 description 4
- 239000008107 starch Substances 0.000 description 4
- 229920001353 Dextrin Polymers 0.000 description 3
- 239000004375 Dextrin Substances 0.000 description 3
- 235000019425 dextrin Nutrition 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000001976 improved effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000012800 visualization Methods 0.000 description 1
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- Cosmetics (AREA)
Abstract
The invention discloses a kind of broom ripple colorful bright bead of fireworks, be made up of the effect medicine core of internal layer and outer field ignition powder layer, wherein said effect medicine core is selected from following four kinds of red effect medicine cores, green effect medicine core, one of yellow effect medicine core and blue color effect medicine core, by formulated effect medicine and the medicinal powder that ignites, effect medicine mixes rear granulation, dries and obtain assorted molding effect medicine core.Shaping effect medicine core sprays organic solvent, reenters the medicinal powder that ignites and carry out mixing and stirring parcel and namely obtain bright pearl.This bright pearl possesses good bright pearl universal performance, duration of combustion is long; And visual effect is long for perdurability; Spectacular; Stable in properties under normal temperature, long quality-guarantee period; Flame color is pure, and colorimetric purity is more excellent, and burning elevation meets fire prevention standards.
Description
Technical field
The present invention relates to a kind of fireworks pyrotechnic agent composition, particularly a kind of fireworks colorful bright bead.
Background technology
In the prior art, the colorful bright bead of fireworks is all under high temperature action, redox reaction occurs with combustiblematerials and oxygenant, and in reaction process, produce a large amount of light and heat, added that different colorant adds, flame reaction will produce the flame of different colours.The firework display effect of existing colorful bright bead is all a kind of colorama group of momentary action, comprise the firework bright bead of existing generation " tail of a comet " effect, its duration of combustion is all very short, short to the visual effect time of spectators, and effect picture is little, cause to the overall visual effect of spectators not good enough.
Summary of the invention
In order to overcome above-mentioned defect, technical problem to be solved by this invention is, provides a kind of bright pearl burning after-vision effect time long, the bright pearl of color fireworks that effect picture is grand.In order to solve the problems of the technologies described above, the present invention's technical scheme used is that a kind of broom ripple colorful bright bead of fireworks, is characterized in that, this bright pearl is made up of the effect medicine core of internal layer and outer field ignition powder layer, wherein:
Described effect medicine core is selected from following four kinds of red effect medicine cores, green effect medicine core, one of yellow effect medicine core and blue color effect medicine core:
Component and the ratio of weight and number of red effect medicine core are: potassium perchlorate 50 parts, magnesium aluminum-alloy powder 15 parts, Strontium carbonate powder 10 parts, particle diameter is 70 ~ 80 object flake aluminum 15 parts, 5 parts, tackiness agent, polyvinyl chloride 5 parts, each component mixes rear granulation by general method, dries and obtain shaping red effect medicine core;
Component and the ratio of weight and number of green effect medicine core are: potassium perchlorate 20 parts, magnesium aluminum-alloy powder 15 parts, nitrate of baryta 40 parts, particle diameter is 70 ~ 80 object flake aluminum 15 parts, 5 parts, tackiness agent, polyvinyl chloride 5 parts, each component mixes rear granulation by general method, dries and obtain shaping green effect medicine core;
Component and the ratio of weight and number of yellow effect medicine core are: potassium perchlorate 45 parts, magnesium aluminum-alloy powder 20 parts, Sodium Silicofluoride 10 parts, particle diameter is 70 ~ 80 object flake aluminum 15 parts, 5 parts, tackiness agent, polyvinyl chloride 5 parts, each component mixes rear granulation by general method, dries and obtain shaping yellow effect medicine core;
Component and the ratio of weight and number of blue color effect medicine core are: potassium perchlorate 35 parts, magnesium aluminum-alloy powder 10 parts, cupric oxide 30 parts, particle diameter is 70 ~ 80 object flake aluminum 15 parts, 5 parts, tackiness agent, polyvinyl chloride 5 parts, each component mixes rear granulation by general method, dries and obtain shaping yellow effect medicine core;
Component and the ratio of weight and number of described ignition powder layer are: potassium perchlorate 10 parts, 50 parts, saltpetre, wood charcoal powder 15 parts, 10 parts, sulphur, magnesium aluminum-alloy powder 5 parts, 5 parts, tackiness agent, 5 parts, resol, each component mixes by general method and obtains the medicinal powder that ignites, shaping effect medicine core sprays organic solvent, add the medicinal powder that ignites again to carry out mixing and stirring parcel, the Jacket thickness of ignition powder layer is 0.5 ~ 1mm, obtains described broom ripple colorful bright bead.
In technique scheme, due in effect medicine and ignition powder all containing tackiness agent, described tackiness agent is as starch, dextrin etc.Described flake aluminum has another name called for aluminium pigment, one of important metallic pigment, flake aluminum is two-dimension plane structure, there is higher radius-thickness ratio, good shielding effect and special in corner effect, be applied to the industries such as building, automobile, chemical industry and ink, all the other each components are general fireworks material.
Beneficial effect of the present invention is, according to bright pearl prepared by technique scheme, under the synergy of each component, not only possesses good bright pearl universal performance, duration of combustion is long; And in the process of flying, bright pearl body after the flake aluminum that particle diameter is larger ignites, can be departed from aloft, produce second time burning in atmosphere, combustion particles can produce the photostar of the tail of a comet effect of long likeness in form fluctuation in atmosphere, can not disappear for a long time.Visual effect is long for perdurability; In effect picture, broom ripple traverses the night sky, spectacular; And this bright pearl stable in properties at normal temperatures, long quality-guarantee period; Through setting off situ visualization, flame color is pure, and colorimetric purity is all better than the effect of currently available products, and burning elevation meets fire prevention standards.Display shell or ground fireworks display product can be applied to.
With improvement, described flake aluminum is provided with the coated rete of tung oil.Its preferred cladding process comprises the steps:
The first step: tung oil is placed in container and is heated to 60 ~ 80 DEG C;
Second step: add flake aluminum in container and stir, take out flake aluminum after 3 ~ 5 minutes, spread cooling out, to obtain final product.Following effects can be played: 1. completely cut off and avoid air oxidation to improve the storge quality of flake aluminum monomer under the prerequisite of guaranteed performance; 2. avoid the storge quality of the bright pearl of oxygenant improved effect finished product; 3. optimize described " broom ripple " firework display effect further.
Below in conjunction with embodiment, the present invention will be further described.
Embodiment
Embodiment 1: the making processes of the red bright pearl of broom ripple of fireworks is as follows:
One, flake aluminum carries out the coated process of tung oil after crossing 80 mesh sieves, and technique comprises the steps:
The first step: tung oil is placed in container and is heated to 60 ~ 80 DEG C; Second step: add flake aluminum in container and stir, take out flake aluminum after 3 ~ 5 minutes, spread cooling out, to obtain final product.
Two, effect medicine core makes: weigh following component by ratio of weight and the number of copies: potassium perchlorate 50 parts, magnesium aluminum-alloy powder 15 parts, Strontium carbonate powder 10 parts, flake aluminum after coated process 15 parts, starch 5 parts, polyvinyl chloride 5 parts, each component, by general method sieve with after mixing, adds ethanol in proper amount granulation, dries and obtain shaping red effect medicine core;
Three, ignition powder makes: weigh following component by ratio of weight and the number of copies: potassium perchlorate 10 parts, 50 parts, saltpetre, wood charcoal powder 15 parts, 10 parts, sulphur, magnesium aluminum-alloy powder 5 parts, starch 5 parts, 5 parts, resol, each component is by general method sieve and mix, and must ignite medicinal powder;
Four, bright pearl is shaping: on shaping effect medicine core, spray ethanol, then adds the medicinal powder that ignites in appropriate amount and carry out mixing and stirring parcel, when the Jacket thickness of ignition powder layer is 0.5 ~ 1mm, obtains the red bright pearl of described broom ripple.
Embodiment 2: the green making processes of bright pearl of broom ripple of fireworks and the difference of embodiment 1 are: the formula that effect medicine core makes is: by ratio of weight and the number of copies, potassium perchlorate 20 parts, magnesium aluminum-alloy powder 15 parts, nitrate of baryta 40 parts, flake aluminum after coated process 15 parts, starch 5 parts, polyvinyl chloride 5 parts.All the other are all identical with embodiment 1.
Embodiment 3: the yellow making processes of bright pearl of broom ripple of fireworks and the difference of embodiment 1 are: the formula that effect medicine core makes is: by ratio of weight and the number of copies, potassium perchlorate 45 parts, magnesium aluminum-alloy powder 20 parts, Sodium Silicofluoride 10 parts, flake aluminum after coated process 15 parts, 5 parts, dextrin, polyvinyl chloride 5 parts.All the other are all identical with embodiment 1.
Embodiment 4: the blue making processes of bright pearl of broom ripple of fireworks and the difference of embodiment 1 are: the formula that effect medicine core makes is: by ratio of weight and the number of copies, potassium perchlorate 35 parts, magnesium aluminum-alloy powder 10 parts, cupric oxide 30 parts, flake aluminum after coated process 15 parts, 5 parts, dextrin, polyvinyl chloride 5 parts.All the other are all identical with embodiment 1.
Above-mentioned fireworks broom ripple colorful bright bead sample, test is seted off through random sampling scene, bright pearl can leave long broom ripple celestial body after altitude combustion on its movement locus, compare its visual effect time with currently available products, effect picture, colorimetric purity be all better than currently available products effect, and humidity resistance is good, long quality-guarantee period.Burning elevation meets fire prevention standards (>=5 meters).Fully achieve goal of the invention.
The above-mentioned implementation that the present invention describes is only in order to technical scheme of the present invention is clearly described, and can not be interpreted as and make any restriction to the present invention.The present invention has known multiple alternative or distortion in the art, under the prerequisite not departing from essential meaning of the present invention, all falls into protection scope of the present invention.
Claims (3)
1. a broom ripple colorful bright bead for fireworks, is characterized in that, this bright pearl is made up of the effect medicine core of internal layer and outer field ignition powder layer, wherein:
Described effect medicine core is selected from following four kinds of red effect medicine cores, green effect medicine core, one of yellow effect medicine core and blue color effect medicine core:
Component and the ratio of weight and number of red effect medicine core are: potassium perchlorate 50 parts, magnesium aluminum-alloy powder 15 parts, Strontium carbonate powder 10 parts, particle diameter is 70 ~ 80 object flake aluminum 15 parts, 5 parts, tackiness agent, polyvinyl chloride 5 parts, each component mixes rear granulation by general method, dries and obtain shaping red effect medicine core;
Component and the ratio of weight and number of green effect medicine core are: potassium perchlorate 20 parts, magnesium aluminum-alloy powder 15 parts, nitrate of baryta 40 parts, particle diameter is 70 ~ 80 object flake aluminum 15 parts, 5 parts, tackiness agent, polyvinyl chloride 5 parts, each component mixes rear granulation by general method, dries and obtain shaping green effect medicine core;
Component and the ratio of weight and number of yellow effect medicine core are: potassium perchlorate 45 parts, magnesium aluminum-alloy powder 20 parts, Sodium Silicofluoride 10 parts, particle diameter is 70 ~ 80 object flake aluminum 15 parts, 5 parts, tackiness agent, polyvinyl chloride 5 parts, each component mixes rear granulation by general method, dries and obtain shaping yellow effect medicine core;
Component and the ratio of weight and number of blue color effect medicine core are: potassium perchlorate 35 parts, magnesium aluminum-alloy powder 10 parts, cupric oxide 30 parts, particle diameter is 70 ~ 80 object flake aluminum 15 parts, 5 parts, tackiness agent, polyvinyl chloride 5 parts, each component mixes rear granulation by general method, dries and obtain shaping yellow effect medicine core;
Component and the ratio of weight and number of described ignition powder layer are: potassium perchlorate 10 parts, 50 parts, saltpetre, wood charcoal powder 15 parts, 10 parts, sulphur, magnesium aluminum-alloy powder 5 parts, 5 parts, tackiness agent, 5 parts, resol, each component mixes by general method and obtains the medicinal powder that ignites, shaping effect medicine core sprays organic solvent, add the medicinal powder that ignites again to carry out mixing and stirring parcel, the Jacket thickness of ignition powder layer is 0.5 ~ 1mm, obtains described broom ripple colorful bright bead.
2. the broom ripple colorful bright bead of a kind of fireworks as claimed in claim 1, is characterized in that, described flake aluminum is provided with the coated rete of tung oil.
3. the broom ripple colorful bright bead of a kind of fireworks as claimed in claim 2, is characterized in that, the cladding process of the coated rete of described tung oil comprises the steps:
The first step: tung oil is placed in container and is heated to 60 ~ 80 DEG C;
Second step: add flake aluminum in container and stir, take out flake aluminum after 3 ~ 5 minutes, spread cooling out, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510519051.XA CN105218281B (en) | 2015-08-23 | 2015-08-23 | A kind of broom ripple colorful bright bead of fireworks |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510519051.XA CN105218281B (en) | 2015-08-23 | 2015-08-23 | A kind of broom ripple colorful bright bead of fireworks |
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| Publication Number | Publication Date |
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| CN105218281A true CN105218281A (en) | 2016-01-06 |
| CN105218281B CN105218281B (en) | 2017-11-03 |
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| CN201510519051.XA Active CN105218281B (en) | 2015-08-23 | 2015-08-23 | A kind of broom ripple colorful bright bead of fireworks |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106370065A (en) * | 2016-08-29 | 2017-02-01 | 北海市铁山港区营盘烟花厂 | Making method for fireworks and firecrackers |
| CN107827685A (en) * | 2017-11-14 | 2018-03-23 | 舒辉 | Micro- cigarette combination of effects fireworks |
| CN109160865A (en) * | 2018-09-17 | 2019-01-08 | 浏阳市鼎腾烟花有限公司 | It is a kind of for manufacturing the blue flash bead of fireworks |
| CN110204405A (en) * | 2019-05-10 | 2019-09-06 | 湖南出入境检验检疫局检验检疫技术中心 | A kind of cladding fireworks material, celestial body medicament and its preparation and application |
| CN113091522A (en) * | 2021-04-16 | 2021-07-09 | 李亮 | Method for producing multi-sound colorful sand firecracker |
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| CN101451091A (en) * | 2007-12-04 | 2009-06-10 | 周泰成 | Color-flame candle and its preparing process |
| CN102910995A (en) * | 2011-08-02 | 2013-02-06 | 浏阳市五环烟花厂 | Sparkle beads producing cardamon green firework effect, and manufacturing method thereof |
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2015
- 2015-08-23 CN CN201510519051.XA patent/CN105218281B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1095366A (en) * | 1993-05-17 | 1994-11-23 | 贾雪芬 | The miniature colour firecracker of a kind of safety, toxicological harmless |
| CN1598474A (en) * | 2004-08-20 | 2005-03-23 | 姜锡松 | Flash star for mfg. fireworks |
| CN101016220A (en) * | 2007-04-03 | 2007-08-15 | 浏阳市庆典烟花有限公司 | Color open-bud firework and manufacturing method thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106370065A (en) * | 2016-08-29 | 2017-02-01 | 北海市铁山港区营盘烟花厂 | Making method for fireworks and firecrackers |
| CN107827685A (en) * | 2017-11-14 | 2018-03-23 | 舒辉 | Micro- cigarette combination of effects fireworks |
| CN109160865A (en) * | 2018-09-17 | 2019-01-08 | 浏阳市鼎腾烟花有限公司 | It is a kind of for manufacturing the blue flash bead of fireworks |
| CN110204405A (en) * | 2019-05-10 | 2019-09-06 | 湖南出入境检验检疫局检验检疫技术中心 | A kind of cladding fireworks material, celestial body medicament and its preparation and application |
| CN113091522A (en) * | 2021-04-16 | 2021-07-09 | 李亮 | Method for producing multi-sound colorful sand firecracker |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105218281B (en) | 2017-11-03 |
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Denomination of invention: A comet wave colored bright bead for fireworks Effective date of registration: 20220622 Granted publication date: 20171103 Pledgee: Huishang Bank Co.,Ltd. Tongling yangjiashan sub branch Pledgor: TONGLING RIKE ELECTRONICS Co.,Ltd. Registration number: Y2022980008490 |
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