CN106370065A - Making method for fireworks and firecrackers - Google Patents

Making method for fireworks and firecrackers Download PDF

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Publication number
CN106370065A
CN106370065A CN201610764536.XA CN201610764536A CN106370065A CN 106370065 A CN106370065 A CN 106370065A CN 201610764536 A CN201610764536 A CN 201610764536A CN 106370065 A CN106370065 A CN 106370065A
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parts
component
paper
medicament
divided
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CN201610764536.XA
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CN106370065B (en
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陈德华
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Yingpan Beihai Port City Of Tieshan Fireworks Factory
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Priority to CN201610764536.XA priority Critical patent/CN106370065B/en
Publication of CN106370065A publication Critical patent/CN106370065A/en
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F42AMMUNITION; BLASTING
    • F42BEXPLOSIVE CHARGES, e.g. FOR BLASTING, FIREWORKS, AMMUNITION
    • F42B4/00Fireworks, i.e. pyrotechnic devices for amusement, display, illumination or signal purposes
    • F42B4/30Manufacture
    • CCHEMISTRY; METALLURGY
    • C06EXPLOSIVES; MATCHES
    • C06BEXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
    • C06B29/00Compositions containing an inorganic oxygen-halogen salt, e.g. chlorate, perchlorate
    • C06B29/02Compositions containing an inorganic oxygen-halogen salt, e.g. chlorate, perchlorate of an alkali metal
    • C06B29/08Compositions containing an inorganic oxygen-halogen salt, e.g. chlorate, perchlorate of an alkali metal with an organic non-explosive or an organic non-thermic component
    • CCHEMISTRY; METALLURGY
    • C06EXPLOSIVES; MATCHES
    • C06BEXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
    • C06B31/00Compositions containing an inorganic nitrogen-oxygen salt
    • C06B31/02Compositions containing an inorganic nitrogen-oxygen salt the salt being an alkali metal or an alkaline earth metal nitrate
    • C06B31/08Compositions containing an inorganic nitrogen-oxygen salt the salt being an alkali metal or an alkaline earth metal nitrate with a metal oxygen-halogen salt, e.g. inorganic chlorate, inorganic perchlorate

Abstract

The invention discloses a making method for fireworks and firecrackers. The making method comprises the steps that (1), a first agent is prepared by using a component A and a component B; first agent particles with each part of the component A as the core and each part of the component B as the skin are made; the outer layer of each part of the first agent particles is wrapped with paper layers, the paper layers are untreated paper and treated paper in sequence from the inside to the outside, and the treated paper is paper soaked in a potassium permanganate solution; the first agent is put into a paper cylinder, and a first agent cylinder is made; (2), a second agent is prepared through a component C and a component D; each part of the component C is put into the corresponding component D, and second agent particles with each part of the component C as the core and each part of the component D as the skin are made; and the second agent is put into a paper cylinder, and a second agent cylinder is made; and (3), the first agent cylinders and the second agent cylinders are inserted into a paper board in a penetrating manner and fixed to the paper board. The fireworks and firecrackers made through the making method are more environmentally-friendly, safer and more colorful when discharged.

Description

The manufacture method of fireworks
Technical field
The present invention relates to a kind of manufacture method of fireworks.
Background technology
Firecracker is one of celebrating article that people commonly use, and either celebrates a festival or marriage marriage, enters to learn and be transferred and promoted and big Summer completion, shop opening, firecracker is seted off to show congratulation by metropolis.The oxidant that the first traditional medicament is adopted is potassium nitrate, Modern age then replaces potassium nitrate as oxidant by potassium chlorate, because the heat stability of both oxidants is all very poor, easily causes Security incident, and No. 52 files of the General Office of the State Council in 2002 are even more and specify: fireworks and firecrackers industry production is forbidden to use potassium chlorate; Sulfur is used in a large number as reducing agent simultaneously, and sulfur itself is a kind of very active combustible of chemical property, more drops The low stability of the first medicament, and poisonous and hazardous sulfur dioxide gas can be produced after setting off, affect environment, native land man is to this Limit and use.Accordingly, it would be desirable to a kind of more environmentally friendly and safe firecrackers.
Content of the invention
For the problems referred to above, the present invention has designed and developed a kind of more environmentally friendly, safer, the system of coloury fireworks Make method.
The technical scheme that the present invention provides is:
A kind of manufacture method of fireworks, comprising:
Step (1) utilizes component a and component b to prepare the first medicament;Described component a is by the following components of meter by weight Composition: 40~45 parts of potassium hyperchlorate, 7~10 parts of aluminium powder, 7~10 parts of barium nitrate, 2~2.5 parts of antimony oxide, chlorinated rubber 0.8~3 part;Described component b is made up of the following components of meter by weight: 40~45 parts of potassium hyperchlorate, 7~10 parts of aluminium powder, 7~10 parts of potassium nitrate, 1~4 part of chlorinated rubber, 7~9 parts of starch, 8~9 parts of phenolic resin;Component b is divided into several pieces, often Part 3~4g, and every part of component b kneading is become cake skin shape;Component a is divided into several pieces, every part of 0.5~1g;By every part of component a It is placed in every part of component b, make with every part of component a as core, the first pharmacy particle with every part of component b as skin;Each first Ply of paper on the outer layer covers of pharmacy particle, described ply of paper is from inside to outside followed successively by the paper of unprocessed mistake and processed Paper, described treated paper is the paper that immersion treatment is crossed in potassium permanganate solution;Described first medicament is loaded in paper web, system Become the first medicament cartridge;
Step (2) utilizes component c and component d to prepare second medicament;Described component c is by the following components of meter by weight Composition: 30~41 parts of potassium hyperchlorate, 5~9 parts of aluminium powder, 7~10 parts of strontium carbonate, 3~4.5 parts of antimony oxide, chlorinated rubber 0.8 ~3 parts;Described component d is made up of the following components of meter by weight: 46~51 parts of potassium hyperchlorate, 8~12 parts of aluminium powder, carbonic acid 5~10 parts of strontium, 6~9 parts of barium nitrate, 2~4 parts of chlorinated rubber, 9~12 parts of starch, 5~9 parts of phenolic resin;Component d is divided equally Become several pieces, every part of 3~4g, and every part of component d kneading is become cake skin shape;Component c is divided into several pieces, every part of 0.5~1g; Every part of component c is placed in every part of component d, makes with every part of component c as core, the second medicament granule with every part of component d as skin; Described second medicament is loaded in paper web, makes second medicament cylinder;
Step (3) is fixed on interspersed to multiple first medicament cartridge and multiple second medicament cylinder on cardboard.
Preferably, in the manufacture method of described fireworks, described component a is by the following components of meter by weight Composition: 45 parts of potassium hyperchlorate, 10 parts of aluminium powder, 10 parts of barium nitrate, 2.5 parts of antimony oxide, 3 parts of chlorinated rubber;Described component b by The following components of meter by weight forms: 40 parts of potassium hyperchlorate, 7 parts of aluminium powder, 7 parts of potassium nitrate, 1 part of chlorinated rubber, starch 7 Part, 8 parts of phenolic resin.
Preferably, in the manufacture method of described fireworks, described component c is by the following components of meter by weight Composition: 30 parts of potassium hyperchlorate, 5 parts of aluminium powder, 7 parts of strontium carbonate, 3 parts of antimony oxide, 0.8 part of chlorinated rubber;Described component d is by pressing The following components composition of parts by weight meter: 46 parts of potassium hyperchlorate, 8 parts of aluminium powder, 5 parts of strontium carbonate, 6 parts of barium nitrate, chlorinated rubber 2 Part, 9 parts of starch, 5 parts of phenolic resin.
Preferably, in the manufacture method of described fireworks, component b is divided into several pieces, every part of 4g;By component A is divided into several pieces, every part of 1g;Component d is divided into several pieces, every part of 4g, and every part of component d kneading is become cake skin shape;Will Component c is divided into several pieces, every part of 1g.
Preferably, in the manufacture method of described fireworks, the particle diameter of described first pharmacy particle is 0.8~1mm; The particle diameter of described second medicament granule is 0.8~1mm.
The manufacture method of fireworks of the present invention does not adopt potassium chlorate, sulfide, more environmentally friendly, safer, sets off When color more rich.
Specific embodiment
The present invention is described in further detail below, with make those skilled in the art with reference to specification word being capable of evidence To implement.
The present invention provides a kind of manufacture method of fireworks, comprising: step (1) utilizes component a and component b to prepare first Medicament;Described component a is made up of the following components of meter by weight: 40~45 parts of potassium hyperchlorate, 7~10 parts of aluminium powder, nitric acid 7~10 parts of barium, 2~2.5 parts of antimony oxide, 0.8~3 part of chlorinated rubber;Described component b is by meter by weight with the following group It is grouped into: 40~45 parts of potassium hyperchlorate, 7~10 parts of aluminium powder, 7~10 parts of potassium nitrate, 1~4 part of chlorinated rubber, 7~9 parts of starch, 8~9 parts of phenolic resin;Component b is divided into several pieces, every part of 3~4g, and every part of component b kneading is become cake skin shape;By component A is divided into several pieces, every part of 0.5~1g;Every part of component a is placed in every part of component b, makes with every part of component a as core, with every Part component b is the first pharmacy particle of skin;Ply of paper on the outer layer covers of each the first pharmacy particle, described ply of paper is from inside to outside It is followed successively by the paper of unprocessed mistake and processed paper, described treated paper is immersion treatment in potassium permanganate solution The paper crossed;Described first medicament is loaded in paper web, makes the first medicament cartridge;Step (2) utilizes component c and component d to prepare the Two medicaments;Described component c is made up of the following components of meter by weight: 30~41 parts of potassium hyperchlorate, 5~9 parts of aluminium powder, carbonic acid 7~10 parts of strontium, 3~4.5 parts of antimony oxide, 0.8~3 part of chlorinated rubber;Described component d is by meter by weight with the following group It is grouped into: 46~51 parts of potassium hyperchlorate, 8~12 parts of aluminium powder, 5~10 parts of strontium carbonate, 6~9 parts of barium nitrate, chlorinated rubber 2~4 Part, 9~12 parts of starch, 5~9 parts of phenolic resin;Component d is divided into several pieces, every part of 3~4g, and by every part of component d kneading Become cake skin shape;Component c is divided into several pieces, every part of 0.5~1g;Every part of component c is placed in every part of component d, makes with every Part component c is core, the second medicament granule with every part of component d as skin;Described second medicament is loaded in paper web, makes the second medicine Agent cylinder;Step (3) is fixed on interspersed to multiple first medicament cartridge and multiple second medicament cylinder on cardboard.
The present invention selects component a and component b, contains barium nitrate, contain potassium nitrate, barium nitrate and nitre in component b in component a Sour potassium can bring the smog of different colours.Phenolic resin in component b and starch ensure that component b can be with molding it is ensured that first The integrity of pharmacy particle.When setting off, component b of outer layer is first seted off, and sends a kind of smog of color;After intervals, Component a of internal layer is just burnt, and sends the smog of another kind of color.The firecracker that the present invention prepares is sent when setting off The smog of different colours discharges successively, thus increased the stereovision of smog color, forms more gorgeous visual effect.
The present invention is made up of two-layer in the outer layer covers ply of paper of each the first pharmacy particle, ply of paper, and outer layer is through too high manganese The paper that sour potassium solution immersion treatment is crossed makes it is ensured that outer layer can be ignited after-combustion in firecracker;Internal layer be by completely without The paper managed forms (paper of such as volume gun barrel, or the waste paper of books), and on the one hand it can slow down the first pharmacy particle Start the time burnt, so that the people lighting firecracker has what the more time left firecracker to set off place, it is to avoid the combustion of firecracker The people put excessive velocities and lead to light firecracker cannot leave situation about being injured by firecracker in time and occurs;On the other hand, it still may be used To play the effect of the first pharmacy particle of igniting it is ensured that setting off of firecracker.
Similarly, second medicament granule is also made up of component c and component d, and component d of outer layer is first seted off, component c of internal layer After set off, thus sending the smog of different colours.And because the first pharmacy particle has ply of paper, therefore, the first pharmacy particle Can set off compared to after second medicament granule, the smog that this results in four colors when firecracker is seted off is sequentially generated, thus bringing More gorgeous effect.
Preferably, in order to improve the color of smog, in the described manufacture method of fireworks, described component a is by pressing The following components composition of parts by weight meter: 45 parts of potassium hyperchlorate, 10 parts of aluminium powder, 10 parts of barium nitrate, 2.5 parts of antimony oxide, chlorine Change 3 parts of rubber;Described component b is made up of the following components of meter by weight: 40 parts of potassium hyperchlorate, 7 parts of aluminium powder, potassium nitrate 7 Part, 1 part of chlorinated rubber, 7 parts of starch, 8 parts of phenolic resin.
Preferably, in order to improve the color of smog, in the described manufacture method of fireworks, described component c is by pressing The following components composition of parts by weight meter: 30 parts of potassium hyperchlorate, 5 parts of aluminium powder, 7 parts of strontium carbonate, 3 parts of antimony oxide, chlorination rubber 0.8 part of glue;Described component d is made up of the following components of meter by weight: 46 parts of potassium hyperchlorate, 8 parts of aluminium powder, 5 parts of strontium carbonate, 6 parts of barium nitrate, 2 parts of chlorinated rubber, 9 parts of starch, 5 parts of phenolic resin.
Preferably, in order that the color of final smog is more rich in level, in the described manufacture method of fireworks, will Component b is divided into several pieces, every part of 4g;Component a is divided into several pieces, every part of 1g;Component d is divided into several pieces, every part 4g, and every part of component d kneading is become cake skin shape;Component c is divided into several pieces, every part of 1g.
Preferably, in order to promote the first pharmacy particle fully to set off, in the described manufacture method of fireworks, described The particle diameter of the first pharmacy particle is 0.8~1mm;The particle diameter of described second medicament granule is 0.8~1mm.
Embodiment one
Step (1) utilizes component a and component b to prepare the first medicament;Described component a is by the following components of meter by weight Composition: 40 parts of potassium hyperchlorate, 7 parts of aluminium powder, 7 parts of barium nitrate, 2 parts of antimony oxide, 0.8 part of chlorinated rubber;Described component b is by pressing The following components composition of parts by weight meter: 45 parts of potassium hyperchlorate, 10 parts of aluminium powder, 10 parts of potassium nitrate, 4 parts of chlorinated rubber, starch 9 Part, 9 parts of phenolic resin;Component b is divided into several pieces, every part of 3g, and every part of component b kneading is become cake skin shape;Component a is equal It is divided into several pieces, every part of 0.5g;Every part of component a is placed in every part of component b, makes with every part of component a as core, with every part of component B is the first pharmacy particle of skin;Ply of paper on the outer layer covers of each the first pharmacy particle, described ply of paper is from inside to outside followed successively by The paper of unprocessed mistake and processed paper, described treated paper immersion treatment in potassium permanganate solution is crossed Paper;Wherein, the thickness of undressed paper is 0.3mm, and the thickness of processed paper is 0.1mm;By described first medicament dress Enter in paper web, make the first medicament cartridge;
Step (2) utilizes component c and component d to prepare second medicament;Described component c is by the following components of meter by weight Composition: 30 parts of potassium hyperchlorate, 5 parts of aluminium powder, 7 parts of strontium carbonate, 3 parts of antimony oxide, 0.8 part of chlorinated rubber;Described component d is by pressing The following components composition of parts by weight meter: 46 parts of potassium hyperchlorate, 8 parts of aluminium powder, 5 parts of strontium carbonate, 6 parts of barium nitrate, chlorinated rubber 2 Part, 9 parts of starch, 5 parts of phenolic resin;Component d is divided into several pieces, every part of 3g, and every part of component d kneading is become cake skin shape; Component c is divided into several pieces, every part of 0.5g;Every part of component c is placed in every part of component d, makes with every part of component c as core, Second medicament granule with every part of component d as skin;Described second medicament is loaded in paper web, makes second medicament cylinder;
15 the first medicament cartridge and 15 second medicament cylinders are interted and are fixed on cardboard by step (3).
Embodiment two
Step (1) utilizes component a and component b to prepare the first medicament;Described component a is by the following components of meter by weight Composition: 45 parts of potassium hyperchlorate, 10 parts of aluminium powder, 10 parts of barium nitrate, 2.5 parts of antimony oxide, 3 parts of chlorinated rubber;Described component b by The following components of meter by weight forms: 40 parts of potassium hyperchlorate, 7 parts of aluminium powder, 7 parts of potassium nitrate, 1 part of chlorinated rubber, starch 7 Part, 8 parts of phenolic resin;Component b is divided into several pieces, every part of 4g, and every part of component b kneading is become cake skin shape;Component a is equal It is divided into several pieces, every part of 1g;Every part of component a is placed in every part of component b, makes with every part of component a as core, with every part of component b The first pharmacy particle for skin;Ply of paper on the outer layer covers of each the first pharmacy particle, described ply of paper is from inside to outside followed successively by The paper of unprocessed mistake and processed paper, described treated paper immersion treatment in potassium permanganate solution is crossed Paper;Wherein, the thickness of undressed paper is 0.3mm, and the thickness of processed paper is 0.1mm;By described first medicament dress Enter in paper web, make the first medicament cartridge;
Step (2) utilizes component c and component d to prepare second medicament;Described component c is by the following components of meter by weight Composition: 41 parts of potassium hyperchlorate, 9 parts of aluminium powder, 10 parts of strontium carbonate, 4.5 parts of antimony oxide, 3 parts of chlorinated rubber;Described component d by The following components of meter by weight forms: 51 parts of potassium hyperchlorate, 12 parts of aluminium powder, 10 parts of strontium carbonate, 9 parts of barium nitrate, chlorination rubber 4 parts of glue, 12 parts of starch, 9 parts of phenolic resin;Component d is divided into several pieces, every part of 4g, and every part of component d kneading is become cake skin Shape;Component c is divided into several pieces, every part of 1g;Every part of component c is placed in every part of component d, makes with every part of component c as core, Second medicament granule with every part of component d as skin;Described second medicament is loaded in paper web, makes second medicament cylinder;
10 the first medicament cartridge and 10 second medicament cylinders are interted and are fixed on cardboard by step (3).
Although embodiment of the present invention is disclosed as above, it is not restricted to listed in description and embodiment With, it can be applied to various suitable the field of the invention completely, for those skilled in the art, can be easily Realize other modification, therefore under the general concept being limited without departing substantially from claim and equivalency range, the present invention does not limit In specific details.

Claims (5)

1. a kind of manufacture method of fireworks is it is characterised in that include:
Step (1) utilizes component a and component b to prepare the first medicament;Described component a is by the following components group of meter by weight Become: 40~45 parts of potassium hyperchlorate, 7~10 parts of aluminium powder, 7~10 parts of barium nitrate, 2~2.5 parts of antimony oxide, chlorinated rubber 0.8 ~3 parts;Described component b is made up of the following components of meter by weight: 40~45 parts of potassium hyperchlorate, 7~10 parts of aluminium powder, nitric acid 7~10 parts of potassium, 1~4 part of chlorinated rubber, 7~9 parts of starch, 8~9 parts of phenolic resin;Component b is divided into several pieces, every part 3 ~4g, and every part of component b kneading is become cake skin shape;Component a is divided into several pieces, every part of 0.5~1g;Every part of component a is put In every part of component b, make with every part of component a as core, the first pharmacy particle with every part of component b as skin;In each the first medicine Ply of paper on the outer layer covers of agent granule, described ply of paper is from inside to outside followed successively by the paper of unprocessed mistake and processed paper, Described treated paper is the paper that immersion treatment is crossed in potassium permanganate solution;Described first medicament is loaded in paper web, makes First medicament cartridge;
Step (2) utilizes component c and component d to prepare second medicament;Described component c is by the following components group of meter by weight Become: 30~41 parts of potassium hyperchlorate, 5~9 parts of aluminium powder, 7~10 parts of strontium carbonate, 3~4.5 parts of antimony oxide, chlorinated rubber 0.8~ 3 parts;Described component d is made up of the following components of meter by weight: 46~51 parts of potassium hyperchlorate, 8~12 parts of aluminium powder, strontium carbonate 5~10 parts, 6~9 parts of barium nitrate, 2~4 parts of chlorinated rubber, 9~12 parts of starch, 5~9 parts of phenolic resin;Component d is divided into Several pieces, every part of 3~4g, and every part of component d kneading is become cake skin shape;Component c is divided into several pieces, every part of 0.5~1g;Will Every part of component c is placed in every part of component d, makes with every part of component c as core, the second medicament granule with every part of component d as skin;Will Described second medicament loads in paper web, makes second medicament cylinder;
Step (3) is fixed on interspersed to multiple first medicament cartridge and multiple second medicament cylinder on cardboard.
2. the manufacture method of fireworks as claimed in claim 1 is it is characterised in that described component a is by counting by weight Following components composition: 45 parts of potassium hyperchlorate, 10 parts of aluminium powder, 10 parts of barium nitrate, 2.5 parts of antimony oxide, 3 parts of chlorinated rubber; Described component b is made up of the following components of meter by weight: 40 parts of potassium hyperchlorate, 7 parts of aluminium powder, 7 parts of potassium nitrate, chlorinated rubber 1 part, 7 parts of starch, 8 parts of phenolic resin.
3. the manufacture method of fireworks as claimed in claim 2 is it is characterised in that described component c is by counting by weight Following components composition: 30 parts of potassium hyperchlorate, 5 parts of aluminium powder, 7 parts of strontium carbonate, 3 parts of antimony oxide, 0.8 part of chlorinated rubber;Institute State component d to be made up of the following components of meter by weight: 46 parts of potassium hyperchlorate, 8 parts of aluminium powder, 5 parts of strontium carbonate, 6 parts of barium nitrate, 2 parts of chlorinated rubber, 9 parts of starch, 5 parts of phenolic resin.
4. the manufacture method of fireworks as claimed in claim 3 is it is characterised in that be divided into several pieces by component b, every part 4g;Component a is divided into several pieces, every part of 1g;Component d is divided into several pieces, every part of 4g, and every part of component d kneading is become Cake skin shape;Component c is divided into several pieces, every part of 1g.
5. the manufacture method of fireworks as claimed in claim 1 is it is characterised in that the particle diameter of described first pharmacy particle is 0.8~1mm;The particle diameter of described second medicament granule is 0.8~1mm.
CN201610764536.XA 2016-08-29 2016-08-29 The production method of fireworks Active CN106370065B (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1348090A (en) * 2001-11-05 2002-05-08 欧定锋 Environment protecting explosive-free safe color-light firecrackers and the production technique
CN1374499A (en) * 2001-03-11 2002-10-16 宾攀 Safe colour-light firecrackers and their making process and apparatus
CN1438467A (en) * 2003-02-25 2003-08-27 赵月明 Safety fireworks
CN1490590A (en) * 2003-09-12 2004-04-21 黄远清 Mixing fireworks and producing method thereof
CN104829401A (en) * 2015-05-25 2015-08-12 雍和平 Safe environment-friendly colorful firecracker reagent and method for preparing colorful firecracker by using reagent
CN105218281A (en) * 2015-08-23 2016-01-06 孔维华 A kind of broom ripple colorful bright bead of fireworks

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1374499A (en) * 2001-03-11 2002-10-16 宾攀 Safe colour-light firecrackers and their making process and apparatus
CN1348090A (en) * 2001-11-05 2002-05-08 欧定锋 Environment protecting explosive-free safe color-light firecrackers and the production technique
CN1438467A (en) * 2003-02-25 2003-08-27 赵月明 Safety fireworks
CN1490590A (en) * 2003-09-12 2004-04-21 黄远清 Mixing fireworks and producing method thereof
CN104829401A (en) * 2015-05-25 2015-08-12 雍和平 Safe environment-friendly colorful firecracker reagent and method for preparing colorful firecracker by using reagent
CN105218281A (en) * 2015-08-23 2016-01-06 孔维华 A kind of broom ripple colorful bright bead of fireworks

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